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Home My WebLink AboutCO2020-2500 Maximum Capacities of Hazardous and Flammable Materials Description Quantity Vertibond Adhesive 200 5 gallon containers Water Stop 800 10.3 oz Tubes Solar Seal 200011 oz Tubes Rapid Set Insulation Adhesive Part 1 48 Cases @ 41.5 liter cartridges per case IB Roof Systems 506 E. Dallas Rd Grapevine, TX 76051 Suite 300 Permit#20-3440 Occupancy ID #01841-5 nCT 07 20211 a.o -3q-� Page: 1 SAFETY DATA SHEET Revision Date: 07/02/2015 Print Date: 7/7/2015 IB ROOFING VERTIBOND ADHESIVE SDS Number: R0378847Version: 2.0 150635 29 CFR 1910.1200(OSHA HazCom 2012) SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product identifier Trade name IB ROOFING VERTIBOND ADHESIVE Recommended use of the chemical and restrictions on use Details of the supplier of the safety data Emergency telephone number sheet 1-800-ASHLAND (1-800-274-5263) Ashland P.O. Box 2219 Regulatory Information Number Columbus, OH 43216 1-800-325-3751 United States of America Product Information 614-790-3333 EHS Customer Requests@ashland.com SECTION 2. HAZARDS IDENTIFICATION GHS Classification Flammable liquids Category 2 Serious eye damage Category 1 Skin sensitization Category 1 Reproductive toxicity Category 2 Specific target organ Category 3 (Central nervous system) systemic toxicity-single exposure GHS Label element Hazard pictograms O Signal Word Danger Hazard Statements Highly flammable liquid and vapor. May cause an allergic skin reaction. Causes serious eye damage. May cause drowsiness or dizziness. 1 /25 HL "o Page:2 SAFETY DATA SHEET Revision Date: 07/02/2015 Print Date: 7/7/2015 SIDS Number: R0378847 IB ROOFING VERTIBOND ADHESIVE Version: 2.0 150635 Suspected of damaging fertility or the unborn child. Precautionary Statements Prevention: Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Keep away from heat/sparks/open Flames/hot surfaces. -No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Contaminated work clothing must not be allowed out of the workplace. Wear protective gloves/protective clothing/eye protection/face protection. Response: IF ON SKIN (or hair):Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER or doctor/ physician. IF exposed or concerned: Get medical advice/attention. If skin irritation or rash occurs: Get medical advice/attention. Wash contaminated clothing before reuse. In case of fire: Use dry sand,dry chemical or alcohol-resistant foam to extinguish. Storage: Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place. Keep cool. Store locked up. Disposal: Dispose of contents/container to an approved waste disposal plant. Other hazards None known. SECTION 3.COMPOSITION/INFORMATION ON INGREDIENTS Substance/Mixture Mixture Chemical nature Defatter 2/25 Page: 3 SAFETY DATA SHEET Revision Date: 07/02/2015 Print Date: 7/7/2015 SIDS Number: R0378847 IB ROOFING VERTIBOND ADHESIVE Version: 2.0 150635 Hazardous components Chemical Name CAS-No. Classification Concentration POLYMER 800986-5750P Skin Irrit, 2; H315 >= 1.50- <5.00 Eye Irrit. 2A, H319 Skin Sens. 1; H317 The identity of one or more component(s) is being withheld under business confidentiality. ACETONE 67-64-1 Flam. Liq.2; H225 31.37 Eye Irrit. 2A; H319 STOT SE 3; H336 METHYL ACETATE 79-20-9 Flam. Liq.2; H225 31.32 Eye Irrit. 2A; H319 STOT SE 3; H336 BUTANOL NORMAL 71-36-3 Flam. Liq. 3; H226 3.85 Acute Tox.4; H302 Skin Irrit. 2; H315 Eye Dam. 1; H318 STOT SE 3; H335, H336 TRIM ETHYLBENZENE 1,2,4- 95-63-6 Flam. Liq. 3; H226 2.05 Skin Irrit. 2; H315 Eye Irrit. 2A; H319 STOT SE 3; H335 Asp.Tox. 1;H304 3/25 HPage:4 SAFETY DATA SHEET Revision Date: 07/02/2015 Print Date: 7/7/2015 SIDS Number: R0378847 IB ROOFING VERTIBOND ADHESIVE Version: 2.0 150635 PETROLEUM NAPHTHA, LIGHT 64742-95-6 Flam. Liq.3; H226 1.38 AROMATIC Skin Irrit.2; H315 Eye Irrit. 2A; H319 Asp,Tax. 1; H304 SECTION 4. FIRST AID MEASURES General advice Move out of dangerous area. Consult a physician. Show this safety data sheet to the doctor in attendance. Do not leave the victim unattended. If inhaled Move to fresh air. If unconscious place in recovery position and seek medical advice. Consult a physician after significant exposure. In case of skin contact Remove contaminated clothing. If irritation develops, get medical attention. If on skin, rinse well with water. Wash contaminated clothing before re-use. If on clothes, remove clothes. In case of eye contact In the case of contact with eyes, rinse immediately with plenty of water and seek medical advice. Continue rinsing eyes during transport to hospital. Remove contact lenses. Protect unharmed eye. If swallowed Obtain medical attention. Do NOT induce vomiting. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Most important symptoms This material (or a component) has produced hyperglycemia and effects, both acute and and ketosis following substantial ingestion. delayed Inhalation of high concentrations of this material, as could occur in enclosed spaces or during deliberate abuse, may be associated with cardiac arrhythmias. Sympathomimetic drugs may initiate cardiac arrhythmias in persons exposed to this material. Signs and symptoms of exposure to this material through breathing,swallowing, and/or passage of the material through 4/25 HL ®eo Page: 5 SAFETY DATA SHEET Revision Date: 07/02/2015 Print Date: 7/7/2015 SIDS Number: R0378847 IB ROOFING VERTIBOND ADHESIVE Version: 2.0 150635 the skin may include: redness of the skin stomach or intestinal upset(nausea,vomiting, diarrhea) irritation (nose,throat, airways) Cough temporary changes in behavior effects on memory loss of appetite visual disturbances chest pain Blurred vision Shortness of breath confusion irregular heartbeat respiratory failure Difficulty in breathing May cause an allergic skin reaction. Causes serious eye damage. May cause drowsiness or dizziness. Suspected of damaging fertility or the unborn child. Notes to physician No hazards which require special first aid measures. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Water spray Foam Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical Unsuitable extinguishing High volume water jet media Specific hazards during Never use welding or cutting torch on or near drum (even firefighting empty) because product(even just residue) can ignite explosively. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Do not allow run-off from fire fighting to enter drains or water courses. Hazardous combustion carbon dioxide and carbon monoxide products Hydrocarbons Hydrogen cyanide (hydrocyanic acid) nitrogen oxides (NOx) hydrogen chloride toxic fumes Carbon oxides Nitrogen oxides (NOx) 5/25 JASHL "s Page:6 SAFETY DATA SHEET Revision Date: 07/02/2015 Print Date: 7/7/2015 SIDS Number: R0378847 IB ROOFING VERTIBOND ADHESIVE Version: 2.0 150635 Sulphur oxides Specific extinguishing methods Product is compatible with standard fire-fighting agents. Further information Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Use a water spray to cool fully closed containers. Special protective equipment In the event of fire, wear self-contained breathing apparatus. for firefighters SECTION 6.ACCIDENTAL RELEASE MEASURES Personal precautions, Evacuate personnel to safe areas. protective equipment and Remove all sources of ignition. emergency procedures Use personal protective equipment. Ensure adequate ventilation. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Environmental precautions Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials for Contain spillage, and then collect with non-combustible containment and cleaning up absorbent material, (e.g. sand, earth, diatomaceous earth, vermiculite) and place in container for disposal according to local/national regulations(see section 13). Other information Comply with all applicable federal, state, and local regulations. Suppress (knock down)gases/vapours/mists with a water spray jet. SECTION 7. HANDLING AND STORAGE Advice on safe handling Open drum carefully as content may be under pressure. Avoid formation of aerosol. Provide sufficient air exchange and/or exhaust in work rooms. Do not breathe vapours/dust. Do not smoke. Persons susceptible to skin sensitisation problems or asthma, allergies,chronic or recurrent respiratory disease should not be employed in any process in which this mixture is being used. 6/25 Page: 7 SAFETY DATA SHEET Revision Date: 07/02/2015 Print Date: 7/7/2015 SIDS Number: R0378847 IB ROOFING VERTIBOND ADHESIVE Version 2.0 150635 Container hazardous when empty. Take precautionary measures against static discharges. Avoid exposure-obtain special instructions before use. Avoid contact with skin and eyes. Smoking, eating and drinking should be prohibited in the application area. For personal protection see section 8. Dispose of rinse water in accordance with local and national regulations. Container may be opened only under exhaust ventilation hood. Conditions for safe storage Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Observe label precautions. No smoking. Electrical installations/working materials must comply with the technological safety standards. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No. Value type Control Basis (Form of parameters/ exposure) Permissible concentration ACETONE 67-64-1 TWA 500 ppm ACGIH STEL 750 ppm ACGIH REL 250 ppm NIOSH/GUID 590 m /m3 E PEL 1,000 ppm OSHA_TRA 2,400 m /m3 NS TWA 250 opm ACGIHLIS P STEL 500 ppm ACGIHLIS P TWA 750 ppm Z1A 1,800 m /m3 STEL 1,000 ppm Z1A 2,400 m /m3 METHYL ACETATE 79-20-9 TWA 200 ppm ACGIH STEL 250 ppm ACGIH REL 200 ppm NIOSH/GUID 610 m /m3 E STEL 250 ppm NIOSH/GUID 760 m /m3 E PEL 200 ppm OSHA_TRA 610 m /m3 NS BUTANOL NORMAL 71-36-3 TWA 20 m ACGIH Ceil Time 50 p m I NIOSH/GUID 7/25 H 13a Page: 8 SAFETY DATA SHEET Revision Date: 0 7/0 212 01 5 Print Date: 7/7/2015 SIDS Number: R0378847 IB ROOFING VERTIBOND ADHESIVE Version: 2.0 150635 150 m /m3 E PEL 100 ppm OSHA_TRA 300 m /m3 NS TRIM ETHYLBENZENE 1,2,4- 95-63-6 REL 25 ppm NIOSH/GUID 125 m /m3 E TWA 25 ppm ACGIH CUMENE 98-82-8 TWA 50 ppm ACGIH REL 50 ppm NIOSH/GUID 245 m /m3 E PEL 50 ppm OSHA_TRA 245 m /m3 NS Biolo ical occupations exposure limits Components CAS-No. Control Biological Sampling Permissible Basis parameters specimen time concentration ACETONE 67-64-1 1 acetone Urine Sampling 150 mg/I time: End of shift. Remarks: Nons ecific Engineering measures Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if applicable)or below levels that cause known, suspected or apparent adverse effects. Personal protective equipment Respiratory protection In the case of vapour formation use a respirator with an approved filter. A NIOSH-approved air-purifying respirator with an appropriate cartridge and/or filter may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits (if applicable)or if overexposure has otherwise been determined. Protection provided by air- purifying respirators is limited. Use a positive pressure, air- supplied respirator if there is any potential for uncontrolled release, exposure levels are not known or any other circumstances where an air-purifying respirator may not provide adequate protection. Hand protection Remarks The suitability for a specific workplace should be discussed with the producers of the protective gloves. Eye protection Wear chemical splash goggles and face shield when there is potential for exposure of the eyes or face to liquid,vapor or mist. Maintain eye wash station in immediate work area. Skin and body protection Wear as appropriate: impervious clothing Safety shoes Flame-resistant clothing Choose body protection according to the amount and 8/25 Aoe�H KX Page:9 SAFETY DATA SHEET Revision Date: 07/02/2015 Print Date: 7/7/2015 SIDS Number: R0378847 IB ROOFING VERTIBOND ADHESIVE Version: 2.0 150635 concentration of the dangerous substance at the work place. Discard gloves that show tears, pinholes, or signs of wear. Wear resistant gloves(consult your safety equipment supplier). Hygiene measures Wash hands before breaks and at the end of workday. When using do not eat or drink. When using do not smoke. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state liquid Colour amber Odour No data available Odour Threshold No data available pH No data available No data available Boiling point/boiling range 133.0 °F/56.1 °C Flash point -4 °F/-20 °C Method: Seta closed cup Evaporation rate No data available Flammability(solid, gas) No data available Upper explosion limit 16%(V) Calculated Explosive Limit Lower explosion limit 2.6%(V) Calculated Explosive Limit Vapour pressure 307.9692 hPa (25°C) Calculated Vapor Pressure Relative vapour density > 1AIR=1 Relative density 0.93 (25°C) Density 0.93 g/cm3(25°C) Solubility(ies) Water solubility No data available Solubility in other solvents No data available Partition coefficient: n- No data available 9/25 AAS♦ �L 130 Page: 10 SAFETY DATA SHEET Revision Date: 07/02/2015 Print Date: 7/7/2015 SIDS Number: R0378847 IB ROOFING VERTIBOND ADHESIVE Version: 2.0 150635 octanol/water Thermal decomposition No data available Viscosity Viscosity, dynamic No data available Viscosity, kinematic No data available Oxidizing properties No data available SECTION 10. STABILITY AND REACTIVITY Reactivity No decomposition if stored and applied as directed. Chemical stability Stable under recommended storage conditions. Possibility of hazardous Vapours may form explosive mixture with air. reactions Conditions to avoid Heat,flames and sparks. Incompatible materials Acids Alkali metals alkalis aluminum Amines Ammonia halogens Lead nitrates Oxidizing agents peroxides Reducing agents strong alkalis water Peroxides Hazardous decomposition products acetic acid carbon dioxide and carbon monoxide Carbon oxides Hydrocarbons Methanol Nitrogen oxides (NOx) Sulphur oxides toxic fumes SECTION 11. TOXICOLOGICAL INFORMATION 10/25 Page: 11 SAFETY DATA SHEET Revision Date: 07/02/2015 Print Date: 7/7/2015 SIDS Number: R0378847 IB ROOFING VERTIBOND ADHESIVE Version: 2.0 150635 Information on likely routes of : Inhalation exposure Skin contact Eye Contact Ingestion Acute toxicity Not classified based on available information. Components: POLYMER: Acute oral toxicity LD50(Rat): > 15,000 mg/kg Acute dermal toxicity LD50 (Rabbit): 23,000 mg/kg Components: ACETONE: Acute oral toxicity LD 50 (Rat, female): 5,800 mg/kg Acute inhalation toxicity LC 50(Rat,female): 76 mg/I Exposure time:4 h Acute dermal toxicity LD 50 (Rabbit): > 7,426 mg/kg METHYL ACETATE: Acute oral toxicity LD 50(Rat, male): 6,482 mg/kg Method: OECD Test Guideline 401 Acute inhalation toxicity LC50(Rabbit): >49.2 mg/I Exposure time: 4 h Test atmosphere: vapour Acute dermal toxicity LD 50 (Rat): >2,000 mg/kg Method: OECD Test Guideline 402 Assessment: No adverse effect has been observed in acute dermal toxicity tests. BUTANOLNORMAL: Acute oral toxicity LD 50 (Rat): 790 mg/kg Acute inhalation toxicity LC 50 (Rat): >24 mg/I Exposure time:4 h Assessment: No adverse effect has been observed in acute inhalation toxicity tests. Acute dermal toxicity LD 50 (Rabbit): 3,400 mg/kg TRIMETHYLBENZENE 1,2,4-: Acute oral toxicity LD 50 (Rat): 6 g/kg Method: EC Directive 92/69/EEC B.1 Acute Toxicity(Oral) GLP: yes Acute inhalation toxicity LC 50 (Rat): >2000 ppm Exposure time: 12 h Acute dermal toxicity LD 50 (Rabbit): >3,440 mg/kg 11 /25 AASHL 13m Page: 12 SAFETY DATA SHEET Revision Date: 07/02/2015 Print Date: 7/7/2015 SDS Number: R0378847 IB ROOFING VERTIBOND ADHESIVE Version: 2.0 150635 Assessment: No adverse effect has been observed in acute dermal toxicity tests. Remarks: Information given is based on data obtained from similar substances. PETROLEUM NAPHTHA, LIGHT AROMATIC: Acute oral toxicity LD 50 (Rat): >5,000 mg/kg Acute inhalation toxicity LC 50(Rat): >7.6 mg/I Exposure time:4 h Test atmosphere:vapour Method: OECD Test Guideline 403 Assessment: No adverse effect has been observed in acute inhalation toxicity tests. Acute dermal toxicity LID 50 (Rabbit): >2,000 mg/kg Method: OECD Test Guideline 402 Assessment: No adverse effect has been observed in acute dermal toxicity tests. Skin corrosion/irritation Not classified based on available information. Product: Result: Repeated exposure may cause skin dryness or cracking. Remarks: May cause skin irritation in susceptible persons. Components: POLYMER: Result: Irritating to skin Components: ACETONE: Result: Mildly irritating to skin Result: Repeated exposure may cause skin dryness or cracking. METHYL ACETATE: Species: Rabbit Method: OECD Test Guideline 404 Result: Slightly irritating to skin BUTANOLNORMAL: Result: Irritating to skin TRIM ETHYLBENZENE 1,2,4-: Result: Irritating to skin PETROLEUM NAPHTHA, LIGHT AROMATIC: Species: Rabbit Method: OECD Test Guideline 404 Result: Irritating to skin 12/25 HL Qo Page: 13 SAFETY DATA SHEET Revision Date: 07/02/2015 Print Date: 7/7/2015 SDS Number: R0378847 IB ROOFING VERTIBOND ADHESIVE Version: 2.0 150635 Serious eye damage/eye irritation Causes serious eye damage. Product: Remarks: May cause irreversible eye damage. Components: POLYMER: Result: Irritating to eyes Components: ACETONE: Result: Irritating to eyes METHYL ACETATE: Species: Rabbit Result: Irritating to eyes Method: OECD Test Guideline 405 BUTANOLNORMAL: Result: Corrosive to eyes TRIMETHYLBENZENE 1,2,4-: Result: Irritating to eyes PETROLEUM NAPHTHA, LIGHT AROMATIC: Result: Irritating to eyes Respiratory or skin sensitisation Skin sensitisation: May cause an allergic skin reaction. Respiratory sensitisation: Not classified based on available information. Components: POLYMER: Assessment: May cause sensitization by skin contact. Components: METHYL ACETATE: Assessment: Does not cause skin sensitisation. TRIM ETHYLBENZENE 1,2,4-: Species: Guinea pig Result: Did not cause sensitisation on laboratory animals. Germ cell mutagenicity Not classified based on available information. Components: POLYMER: Genotoxicity in vitro Test Type: in vitro assay Result: Positive results were obtained in some in vitro tests. Components: METHYL ACETATE: Genotoxicity in vitro Remarks: In vitro tests did not show mutagenic effects Genotoxicity in vivo Test Type: Micronucleus test 13/25 HU 13, Page: 14 SAFETY DATA SHEET Revision Date: 07/02/2015 Print Date: 7/7/2015 SIDS Number: R0378847 IB ROOFING VERTIBOND ADHESIVE Version: 2.0 150635 Test species: Rat Method: OECD Test Guideline 474 Result: negative TRIM ETHYLBENZENE 1,2,4-: Genotoxicity in vitro Test Type:Ames test Result: negative Genotoxicity in vivo Test Type: In vivo micronucleus test Test species: Mouse Result: negative PETROLEUM NAPHTHA, LIGHT AROMATIC: Genotoxicity in vitro Test Type:Ames test Metabolic activation:with and without metabolic activation Result: negative Genotoxicity in vivo Test Type: In vivo micronucleus test Test species: Rat Application Route: Inhalation Method: OPPTS 870.5395 Result: negative Test Type: in vivo assay Test species: Rat Method: OECD Test Guideline 475 Result: negative Carcinogenicity Not classified based on available information. Reproductive toxicity Suspected of damaging fertility or the unborn child. Components: METHYL ACETATE: Effects on fertility Symptoms: No effects on reproduction parameters Remarks: Information taken from reference works and the literature. Effects on foetal Symptoms: No specific developmental abnormalities development Remarks: Information taken from reference works and the literature. STOT-single exposure May cause drowsiness or dizziness. Components: ACETONE: Exposure routes: Inhalation Target Organs: Nervous system Assessment: May cause drowsiness or dizziness. METHYL ACETATE: Target Organs: Central nervous system Assessment: The substance or mixture is classified as specific target organ toxicant,single exposure,category 3 with narcotic effects. 14/25 ANSHLANNIX Page: 15 SAFETY DATA SHEET Revision Date: 07/02/2015 Print Date: 7/7/2015 SIDS Number: R0378847 IB ROOFING VERTIBOND ADHESIVE Version: 2.0 150635 BUTANOL NORMAL: Target Organs: Respiratory system Assessment: May cause respiratory irritation. Target Organs: Central nervous system Assessment: May cause drowsiness or dizziness. TRIMETHYLBENZENE 1,2,4-: Exposure routes: Inhalation Target Organs: Respiratory Tract Assessment: May cause respiratory irritation. STOT-repeated exposure Not classified based on available information. Repeated dose toxicity Components: METHYL ACETATE: Species: Rat NOAEL 1.05 mg/I Application Route: Inhalation Test atmosphere: dust/mist Exposure time: 28-day Method: OECD Test Guideline 412 Aspiration toxicity Not classified based on available information. Product: No aspiration toxicity classification Components: ACETONE: May be harmful if swallowed and enters airways. TRIMETHYLBENZENE 1,2,4-: May be fatal if swallowed and enters airways. PETROLEUM NAPHTHA, LIGHT AROMATIC: May be fatal if swallowed and enters airways. Further information Product: Remarks: Symptoms of overexposure may be headache, dizziness, tiredness, nausea and vomiting., Concentrations substantially above the TLV value may cause narcotic effects., Solvents may degrease the skin. Carcinogenicity: IARC Group 213: Possibly carcinogenic to humans CUMENE 98-82-8 OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. 15/25 HL Ie Page: 16 SAFETY DATA SHEET Revision Date: 07/02/2015 Print Date: 7/7/2015 SIDS Number: R0378847 IB ROOFING VERTIBOND ADHESIVE Version: 2.0 150635 NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Product: Ecotoxicology Assessment Acute aquatic toxicity Acute aquatic toxicity Category 3; Harmful to aquatic life. Chronic aquatic toxicity Chronic aquatic toxicity Category 3; Harmful to aquatic life with long lasting effects. Components: POLYMER: Toxicity to fish LC50 (Oncorhynchus mykiss (rainbow trout)): 2 mg/I Exposure time: 96 h Test Type: semi-static test Toxicity to daphnia and other EC50 (Water flea(Daphnia magna)): 1.8 mg/I aquatic invertebrates Exposure time: 48 h Test Type: static test Toxicity to algae ErC50 (Pseudokirchneriella subcapitata (microalgae)): 11 mg/I End point: Growth inhibition Exposure time: 72 h Test Type: static test ACETONE: Toxicity to fish LC 50 (Rainbow trout,donaldson trout(Oncorhynchus mykiss)):4,740-6,330 mg/I Exposure time: 96 h Test Type: static test LC 50 (Fathead minnow(Pimephales promelas)):8,733- 9,482 mg/I Exposure time: 96 h Test Type:flow-through test Toxicity to algae NOEC (Microcystis aeruginosa): 530 mg/I Exposure time: 8 d Test Type: static test Toxicity to daphnia and other NOEC (Daphnia magna(Water flea)): 2,112 mg/I aquatic invertebrates Exposure time: 28 d (Chronic toxicity) Test Type:flow-through test 16/25 HL �� Page: 17 SAFETY DATA SHEET Revision Date: 07/02/2015 Print Date: 7/7/2015 SIDS Number: R0378847 IB ROOFING VERTIBOND ADHESIVE Version: 2.0 150635 METHYL ACETATE: Toxicity to fish LC 50(Danio rerio (zebra fish)): >250 mg/I Exposure time: 95 h Test Type: static test Method: OECD Test Guideline 203 Toxicity to daphnia and other EC50 (Water flea (Daphnia magna)): 1,026 mg/I aquatic invertebrates Exposure time:48 h Test Type: static test Method: OECD Test Guideline 202 Toxicity to algae EC50 (Scenedesmus capricornutum (fresh water algae)): > 120 mg1I End point: Growth inhibition Exposure time: 72 h Test Type: static test Method: OECD Test Guideline 201 BUTANOL NORMAL: Toxicity to fish LC 50(Blueglll (Lepomis macrochirus)): > 100-500 mg/I Exposure time: 96 h Test Type: static test Method: Static Remarks: Mortality Toxicity to daphnia and other EC 50(Water flea(Daphnia magna)): 1,897-2,072 mg/I aquatic invertebrates Exposure time: 48 h Test Type: static test Method: Static Remarks: Intoxication TRIM ETHYLBENZENE 1,2,4-: Toxicity to fish LC 50 (Fathead minnow(Pimephales promelas)): 7.72 mg/I Exposure time: 96 h Test Type:flow-through test Toxicity to daphnia and other LC 50 (Daphnia magna (Water flea)): 3.6 mg/I aquatic invertebrates Exposure time:48 h Test Type: static test Method: OECD Test Guideline 202 PETROLEUM NAPHTHA, LIGHT AROMATIC: Toxicity to fish LL50 (Pimephales promelas (fathead minnow)): 8.2 mg/I Exposure time: 96 h Test Type: semi-static test Test substance:WAF Remarks: Information given is based on data obtained from similar substances. LL50 (Oncorhynchus mykiss (rainbow trout)): 10 mg/I Exposure time: 96.h Test Type: semi-static test Test substance:WAF 17/25 JASHL Page: 18 SAFETY DATA SHEET Revision Date: 07/02/2015 Print Date: 7/7/2015 SIDS Number: R0378847 IB ROOFING VERTIBOND ADHESIVE Version: 2.0 150635 Method: OECD Test Guideline 203 Remarks: Information given is based on data obtained from similar substances. Toxicity to daphnia and other EL50(Water flea(Daphnia magna)):4.5 mg/I aquatic invertebrates Exposure time: 48 h Test Type: static test Test substance:WAF Method: OECD Test Guideline 202 Remarks: Information given is based on data obtained from similar substances. Toxicity to algae EL50(Pseudokirchneriella subcapitata (green algae)): 3.7 mg/1 End point: Growth inhibition Exposure time: 96 h Test Type: static test Test substance:WAF Method: OECD Test Guideline 201 Remarks: Information given is based on data obtained from similar substances. Toxicity to fish (Chronic NOEC (Pimephales promelas (fathead minnow)):2.6 mg/I toxicity) Exposure time: 14 d Test Type: semi-static test Test substance:WAF Method: OECD Test Guideline 204 Remarks: Information given is based on data obtained from similar substances. Toxicity to daphnia and other NOEC (Water flea(Daphnia magna)): 2.6 mg/I aquatic invertebrates Exposure time: 21 d (Chronic toxicity) Test Type: semi-static test Test substance:WAF Method: OECD Test Guideline 211 Persistence and degradability Components: POLYMER: Biodegradability Result: Not readily biodegradable. Biodegradation: 12% Exposure time: 28 d Method: OECD Test Guideline 302B ACETONE: Biodegradability Result: Readily biodegradable Biodegradation: 90.9% Exposure time: 28 d Method: OECD Test Guideline 3016 METHYL ACETATE: Biodegradability Result: Readily biodegradable 18/25 As"LAXNE3, Page: 19 SAFETY DATA SHEET Revision Date: 07/0212ot5 Print Date: 7/7/2015 SDS Number: R0378847 IB ROOFING VERTIBOND ADHESIVE Version: 2.0 150635 Biodegradation: >68 % Exposure time: 10 d Method: OECD Test Guideline 301D BUTANOLNORMAL: Biodegradability Result: Readily biodegradable Biodegradation: 98% Exposure time: 19 d Method: OECD Test Guideline 301 E Biochemical Oxygen Theoretical oxygen demand Demand (BOD) 2.59 mg/g Chemical Oxygen Demand 2.45 mg/g (COD) Method: Chemical oxygen demand TRIM ETHYLBENZENE 1,2,4-: Biodegradability Result: Not readily biodegradable. Result: Not readily biodegradable. Bioaccumulative potential Components: POLYMER: Partition coefficient: n- log Pow: Estimated 3.242 octanol/water ACETONE: Partition coefficient: n- log Pow:-0.24 octanol/water METHYL ACETATE: Bioaccumulation Remarks: Bioaccumulation is unlikely. Partition coefficient: n- log Pow: 0.18 octanol/water BUTANOLNORMAL: Bioaccumulation Species: Oncorhynchus mykiss(rainbow trout) Bioconcentration factor(BCF): 0.38 Exposure time: 24 h Concentration: 921 mg/I Method: Static Partition coefficient: n- log Pow:0.88 octanol/water TRIMETHYLBENZENE 1,2,4-: Bioaccumulation Remarks: Bioaccumulation is unlikely. 19/25 HL �� Page 20 SAFETY DATA SHEET Revision Date: 07/02/2015 Print Date: 7/7/2015 SIDS Number: R0378847 IB ROOFING VERTIBOND ADHESIVE Version: 2.0 150635 Mobility in soil Components: No data available Other adverse effects No data available Product: Additional ecological An environmental hazard cannot be excluded in the event of information unprofessional handling or disposal., Harmful to aquatic life with long lasting effects. Components: SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods General advice The product should not be allowed to enter drains,water courses or the soil. Do not contaminate ponds,waterways or ditches with chemical or used container. Send to a licensed waste management company. Dispose of in accordance with all applicable local, state and federal regulations. Contaminated packaging Empty remaining contents. Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum. SECTION 14. TRANSPORT INFORMATION International transport regulations REGULATION ID NUMBER PROPER SHIPPING NAME *HAZARD SUBSIDIARY PACKING MARINE CLASS HAZARDS GROUP POLLUTANT/ LTD. QTY. U.S. DOT -ROAD UN 1133 Adhesives 3 II U.S. DOT-RAIL UN 1133 Adhesives 3 II U.S. DOT-INLAND WATERWAYS UN 1133 Adhesives 3 II 20/25 �JASH ` Page: 21 SAFETY DATA SHEET Revision Date: 07/02/2015 Print Date: 7/7/2015 SDS Number: R0378847 IB ROOFING VERTIBOND ADHESIVE Version: 2.0 150635 TRANSPORTCANADA -ROAD UN 1133 ADHESIVES 3 II TRANSPORT CANADA - RAIL UN 1133 ADHESIVES 3 II TRANSPORT CANADA -INLAND WATERWAYS UN 1133 ADHESIVES 3 II INTERNATIONAL MARITIME DANGEROUS GOODS UN 1133 ADHESIVES 3 II INTERNATIONAL AIR TRANSPORT ASSOCIATION -CARGO UN 1133 Adhesives 3 II INTERNATIONAL AIR TRANSPORT ASSOCIATION -PASSENGER UN 1133 Adhesives 3 II MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARDOUS MATERIALS AND WASTES UN 1133 ADHESIVOS 3 II *ORM =ORM-D, CBL=COMBUSTIBLE LIQUID Marine pollutant no t Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. SECTION 15. REGULATORY INFORMATION EPCRA-Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity Components CAS-No. Component RQ Calculated product RQ Ibs Ibs XYLENE 1 1330-20-7 100 13489.81519 SARA 3111312 Hazards Acute Health Hazard 21 /25 H 13, Page: 22 SAFETY DATA SHEET Revision Date: 07/02/2015 Print Date: 7/7/2015 SIDS Number: R0378847 IB ROOFING VERTIBOND ADHESIVE Version: 2.0 150635 Fire Hazard Chronic Health Hazard SARA 313 Component(s) BUTANOL NORMAL 71-36-3 3.85% TRIMETHYLBENZENE 95-63-6 2.05% 1,2,4- California Prop 65 WARNING!This product contains a chemical known to the State of California to cause cancer. CUMENE 98-82-8 FORMALDEHYDE 50-00-0 ETHYL BENZENE 100-41-4 VINYLCYCLOHEXENE,4- 100-40-3 BENZENE 71-43-2 ACRYLONITRILE 107-13-1 1,3, BUTADIENE 106-99-0 ACETALDEHYDE 75-07-0 WARNING:This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. VINYLCYCLOHEXENE,4- 100-40-3 TOLUENE 108-88-3 BENZENE 71-43-2 1,3, BUTADIENE 106-99-0 The components of this product are reported in the following inventories: TSCA On TSCA Inventory DSL All components of this product are on the Canadian DSL. AICS Not in compliance with the inventory ENCS Not in compliance with the inventory KECI On the inventory, or in compliance with the inventory PICCS On the inventory, or in compliance with the inventory IECSC Not in compliance with the inventory 22/25 yL �y Page: 23 SAFETY DATA SHEET Revision Date: 07/02/2015 Print Date: 7/7/2015 SIDS Number: R0378847 IB ROOFING VERTIBOND ADHESIVE Version: 2.0 150635 Inventories AICS (Australia), DSL (Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA (USA) Re istration: T rade Secret Chemical Name Identification number POLYMER 800986-5750P SECTION 16. OTHER INFORMATION Further information Revision Date: 07/02/2015 NFPA: HMIS III: Flammability HEALTH 3* o °' FLAMMABILITY3 PHYSICAL HAZARD 0 0=not significant, 1=Slight, Special hazard. 2=Moderate,3=High 4=Extreme,`=Chronic NFPA Flammable and Combustible Liquids Classification Flammable Liquid Class IB Full text of H-Statements referred to under sections 2 and 3. 23/25 JAS"LAjq130 Page: 24 SAFETY DATA SHEET Revision Date: 07/02/2015 Print Date: 7/7/2015 SDS Number: R0378847 IB ROOFING VERTIBOND ADHESIVE Version: 2.0 15D635 H225 Highly flammable liquid and vapor. H226 Flammable liquid and vapor. H227 Combustible liquid. H301 Toxic if swallowed. H302 Harmful if swallowed. H303 May be harmful if swallowed. H304 May be fatal if swallowed and enters airways. H305 May be harmful if swallowed and enters airways. H311 Toxic in contact with skin. H313 May be harmful in contact with skin. H314 Causes severe skin burns and eye damage. H315 Causes skin irritation. H317 May cause an allergic skin reaction. H318 Causes serious eye damage. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. H361f Suspected of damaging fertility. H401 Toxic to aquatic life. H410 Very toxic to aquatic life with long lasting effects. H411 Toxic to aquatic life with long lasting effects. Further information Sources of key data used to compile the Safety Data Sheet Ashland internal data including own and sponsored test reports The UNECE administers regional agreements implementing harmonised classification for labelling (GHS) and transport. The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This SDS has been prepared by Ashland's Environmental Health and Safety Department(1-800-325-3751). List of abbreviations and acronyms that could be, but not necessarily are, used in this safety data sheet : ACGIH : American Conference of Industrial Hygienists BEI : Biological Exposure Index CAS : Chemical Abstracts Service (Division of the American Chemical Society). CMR : Carcinogenic, Mutagenic or Toxic for Reproduction FG : Food grade GHS : Globally Harmonized System of Classification and Labeling of Chemicals. H-statement : Hazard Statement IATA : International Air Transport Association. IATA-DGR:Dangerous Goods Regulation by the"International Air Transport Association"(IATA). ICAO : International Civil Aviation Organization ICAO-TI (ICAO) :Technical Instructions by the"International Civil Aviation Organization" IMDG : International Maritime Code for Dangerous Goods ISO : International Organization for Standardization IogPow: octanol-water partition coefficient LCxx : Lethal Concentration,for xx percent of test population 24/25 Page:25 �n SAFETY DATA SHEET Revision Date: 07/02/2015 Print Date: 7/7/2015 SDS Number: R0378847 IB ROOFING VERTIBOND ADHESIVE Version: 2.0 150635 LDxx : Lethal Dose,for xx percent of test population. ICxx : Inhibitory Concentration for xx of a substance Ecxx : Effective Concentration of xx N.O.S.: Not Otherwise Specified OECD : Organization for Economic Co-operation and Development OEL : Occupational Exposure Limit P-Statement : Precautionary Statement PBT : Persistent, Bioaccumulative and Toxic PPE : Personal Protective Equipment STEL : Short-term exposure limit STOT : Specific Target Organ Toxicity TLV: Threshold Limit Value TWA :Time-weighted average vPvB : Very Persistent and Very Bioaccumulative WEL :Workplace Exposure Level CERCLA: Comprehensive Environmental Response, Compensation, and Liability Act DOT : Department of Transportation FIFRA: Federal Insecticide, Fungicide, and Rodenticide Act HMIRC : Hazardous Materials Information Review Commission HMIS : Hazardous Materials Identification System NFPA : National Fire Protection Association NIOSH : National Institute for Occupational Safety and Health OSHA : Occupational Safety and Health Administration PMRA : Health Canada Pest Management Regulatory Agency RTK: Right to Know WHMIS :Workplace Hazardous Materials Information System 25/25 Page: 1 w SAFETY DATA SHEET Revision Date: 05/25/2015 Print Date: 7/7/2015 SDS Number: R0205917 IB WATER STOP Version: 1.1 602471 29 CFR 1910.1200 (OSHA HazCom 2012) SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product identifier Trade name IB WATER STOP Recommended use of the chemical and restrictions on use Details of the supplier of the safety data Emergency telephone number sheet 1-800-ASHLAND (1-800-274-5263) Ashland P.O. Box 2219 Regulatory Information Number Columbus, OH 43216 1-800-325-3751 United States of America Product Information 614-790-3333 EHS Customer Requests@ashland.com SECTION 2. HAZARDS IDENTIFICATION GHS Classification Flammable liquids Category 3 Combustible Dust Acute toxicity(Inhalation) Category 1 Skin irritation Category 2 Specific target organ Category 2(Central nervous system) systemic toxicity-single exposure GHS Label element Hazard pictograms O Signal Word Danger Hazard Statements Flammable liquid and vapor. Causes skin irritation. Fatal if inhaled. May cause damage to organs (Central nervous system). 1 /21 CT 0 7 2020 JASHLJAN131 Page: 2 SAFETY DATA SHEET Revision Date: 05/25/2015 Print Date: 7/7/2015 SIDS Number: R0205917 IB WATER STOP Version. 1.1 602471 May form combustible dust concentrations in air. Precautionary Statements Prevention: Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Keep container tightly closed. Ground/bond container and receiving equipment. Use explosion-proof electrical/ventilating/lighting/equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Do not breathe dust/fume/gas/mist/vapors/spray. Wash skin thoroughly after handling. Do not eat, drink or smoke when using this product. Use only outdoors or in a well-ventilated area. Wear protective gloves/eye protection/face protection. Wear respiratory protection. Response: IF ON SKIN (or hair):Take off immediately all contaminated clothing. Rinse skin with water/shower. IF INHALED: Remove person to fresh air and keep comfortable for breathing. Immediately call a POISON CENTER or doctor/ physician. IF exposed or concerned: Call a POISON CENTER or doctor/ physician. If skin irritation occurs: Get medical advice/attention. Take off contaminated clothing and wash before reuse. In case of fire: Use dry sand, dry chemical or alcohol-resistant foam to extinguish. Storage: Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place. Keep cool. Store locked up. Disposal: Dispose of contents/container to an approved waste disposal plant. Other hazards None known. SECTION 3.COMPOSITION/INFORMATION ON INGREDIENTS Substance/Mixture Mixture Chemical nature Static Accumulator Hazardous components Chemical Name I CAS-No. Classification I Concentration ALUMINA 800986-5135P Not a hazardous >= 1.50-<5.00 substance or mixture. 2/21 Page:3 SAFETY DATA SHEET Revision Date: 05/25/2015 Print Date: 7/7/2015 SIDS Number: R0205917 IB WATER STOP Version: 1.1 602471 The identity of one or more component(s) is being withheld under business confidentiality. CALCIUM CARBONATE 471-34-1 50.00 PETROLEUM DISTILLATES 8052-41-3 Asp. Tox. 1; H304 14.99 (STODDARD TYPE) MAGNESIUM CARBONATE 546-93-0 9.99 KAOLIN 1332-58-7 This material is not 9.99 considered hazardous under the OSHA Hazard Communication Standard (HazCom 2012). LIMESTONE 1317-65-3 g.gg DISTILLATES (PETROLEUM), 64742-52-5 Not a hazardous 4.99 HYDROTREATED HEAVY substance or mixture. NAPHTA SILICA AMORPHOUS (SIO2) 7631-86-9 This material is not T99 considered hazardous under the OSHA Hazard Communication Standard (HazCom 2012). TITANIUM DIOXIDE (T1O2) 13463-67-7 This material is not 4.99 considered hazardous under the OSHA Hazard Communication Standard (HazCom 2012). SECTION 4. FIRST AID MEASURES General advice Move out of dangerous area. Consult a physician. 3/21 ASHLAP40. Page:4 SAFETY DATA SHEET Revision Date: 05/25/2015 Print Date: 7/7/2015 SIDS Number: R0205917 IB WATER STOP Version 1.1 602471 Show this safety data sheet to the doctor in attendance. Symptoms of poisoning may appear several hours later. Do not leave the victim unattended. If inhaled Move to fresh air. Call a physician or poison control centre immediately. Keep patient warm and at rest. If unconscious place in recovery position and seek medical advice. In case of skin contact Remove contaminated clothing. If irritation develops, get medical attention. If on skin, rinse well with water. Wash contaminated clothing before re-use. If on clothes, remove clothes. In case of eye contact Flush eyes with water as a precaution. Remove contact lenses. Protect unharmed eye. If eye irritation persists, consult a specialist. If swallowed Obtain medical attention. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Most important symptoms Ingestion of large amounts or other significant exposure to this and effects, both acute and material (or a component) may cause alkalosis. delayed Excessive calcium intake may cause gastrointestinal symptoms, hypertension, hypercalcemia, kidney stones, and may inhibit absorption of iron, zinc, and possibly other trace elements. Acute aspiration of large amounts of oil-laden material may produce a serious aspiration pneumonia. Patients who aspirate these oils should be followed for the development of long-term sequelae. Repeated aspiration of small quantities of mineral oil can produce chronic inflammation of the lungs (i.e. lipoid pneumonia)that may progress to pulmonary fibrosis. Symptoms are often subtle and radiological changes appear worse than clinical abnormalities. Occasionally, persistent cough, irritation of the upper respiratory tract, shortness of breath with exertion, fever, and bloody sputum occur. Inhalation exposure to oil mists below current workplace exposure limits is unlikely to cause pulmonary abnormalities. Signs and symptoms of exposure to this material through breathing,swallowing, and/or passage of the material through the skin may include: stomach or intestinal upset(nausea,vomiting, diarrhea) irritation (nose, throat, airways) Causes skin irritation. Fatal if inhaled. May cause damage to organs. 4/21 �w Page: 5 SAFETY DATA SHEET Revision Date: 05/25/2015 Print Date: 7/7/2015 SIDS Number: R0205917 IB WATER STOP Version 1.1 602471 Notes to physician No hazards which require special first aid measures. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media Use extinguishing measures that are appropriate to local circumstances and the surrounding environment. Water spray Foam Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical Unsuitable extinguishing High volume water jet media Specific hazards during Organic dusts at sufficient concentration can form explosive firefighting mixtures in air. Never use welding or cutting torch on or near drum (even empty) because product(even just residue) can ignite explosively. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Do not allow run-off from fire fighting to enter drains or water courses. Hazardous combustion calcium oxide products carbon dioxide and carbon monoxide Hydrocarbons metal oxides Aldehydes Ketones Nitrogen oxides (NOx) Sulphur oxides aluminum oxides Specific extinguishing methods Product is compatible with standard fire-fighting agents. Further information Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. Use a water spray to cool fully closed containers. Special protective equipment In the event of fire,wear self-contained breathing apparatus. for firefighters SECTION 6.ACCIDENTAL RELEASE MEASURES Personal precautions, Evacuate personnel to safe areas. 5/21 As"LAP413. Page:6 SAFETY DATA SHEET Revision Date: 0 5/2 512 0 1 5 Print Date: 7/7/2015 SOS Number: R0205917 IB WATER STOP Version: 1.1 602471 protective equipment and Remove all sources of ignition. emergency procedures Use personal protective equipment. Ensure adequate ventilation. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Persons not wearing protective equipment should be excluded from area of spill until clean-up has been completed. Environmental precautions Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials for Contain spillage, and then collect with non-combustible containment and cleaning up absorbent material, (e.g. sand,earth, diatomaceous earth, vermiculite) and place in container for disposal according to local/national regulations(see section 13). Other information Comply with all applicable federal, state, and local regulations. Suppress(knock down)gases/vapours/mists with a water spray jet. SECTION 7. HANDLING AND STORAGE Advice on safe handling Open drum carefully as content may be under pressure. Avoid formation of aerosol. Provide sufficient air exchange and/or exhaust in work rooms. Do not breathe vapours/dust. Do not smoke. Container hazardous when empty. Take precautionary measures against static discharges. Avoid contact with skin and eyes. Smoking, eating and drinking should be prohibited in the application area. For personal protection see section 8. Dispose of rinse water in accordance with local and national regulations. Secondary operations, such as grinding and sanding, may produce dust. Maintain good housekeeping. Do not permit dust layers to accumulate,for example, on floors, ledges, and equipment, in order to avoid any potential for dust explosion hazards. For further guidance on prevention of dust explosions, refer to National Fire Protection Association(NFPA)654:"Standard for the Prevention of Fire and Dust Explosions, from the Manufacturing, Processing and Handling of Combustible Particulate Solids". Conditions for safe storage Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and 6121 ASHLAN"'_ Page, 7 SAFETY DATA SHEET Revision Date: 05/25/2015 Print Date: 7/7/2015 SIDS Number: R0205917 IB WATER STOP Version. 1.1 602471 kept upright to prevent leakage. Observe label precautions. No smoking. Prevent unauthorized access. Electrical installations/working materials must comply with the technological safety standards. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters Components CAS-No Value type Control Basis (Form of parameters/ exposure) Permissible concentration ALUMINA 800986- TWA 1 m9/m3 ACGIH 5135P Respirable fraction. CALCIUM CARBONATE 471-34-1 PEL 5 mg/m3 OSHA_TRA Respirable NS fraction. PEL 15mg/m3 OSHA_TRA Total dust. NS REL 5 mg/m3 NIOSH/GUID Respirable. E REL 10 mg/m3 NIOSH/GUID Total E PETROLEUM DISTILLATES 8052-41-3 TWA 100 ppm ACGIH STODDARD TYPE REL 350 mg/m3 NIOSH/GUID E Ceil_Time 7800 mg/m3 NIOSH/GUID E PEL 500ppm OSHA_TRA 2,900 m /m3 NS MAGNESIUM CARBONATE 546-93-0 REL 5 mg/m3 NIOSH/GUID Respirable. E REL 10 mg/m3 NIOSH/GUID Total E PEL 15 mg/m3 OSHA_TRA Total dust. NS PEL 5mg/m3 OSHA_TRA Respirable NS fraction. TWA 15 mg/m3 Z1A Total dust. TWA 5 mg/m3 Z1A Respirable fraction. KAOLIN 1332-5877 TWA 2 mg/m3 ACGIH Respirable 7/21 HL ".> Page: 8 SAFETY DATA SHEET Revision Date: 05/25/2015 Print Date: 7/7/2015 SIDS Number: R0205917 IB WATER STOP Version 1.1 602471 fraction. REL 5 mg/m3 NIOSH/GUID Respirable. E REL 10 mg/m3 NIOSH/GUID Total E PEL 5 mg/m3 OSHA_TRA Respirable NS fraction. PEL 15 mg/m3 OSHA_TRA Total dust. NS TWA 10 mg/m3 TN OEL Total dust. TWA 5 mg/m3 TN DEL Respirable fraction. LIMESTONE 1317-65-3 REL 10 mg/m3 NIOSH/GUID Total E REL 5 mg/m3 NIOSH/GUID Respirable. E PEL 5 mg/m3 OSHA_TRA Respirable NS fraction. PEL 15mg/m3 OSHA_TRA Total dust. NS TWA 15 mg/m3 Z1A Total dust. TWA 5 mg/m3 Z1A Respirable fraction. DISTILLATES (PETROLEUM), 64742-52-5 PEL 500 ppm OSHA_TRA HYDROTREATED HEAVY 2,000 mg/m3 NS NAPHTA REL 5 mg/m3 NIOSH/GUID Mist. E STEL 10 mg/m3 NIOSH/GUID Mist. E PEL 5 mg/m3 OSHA_TRA Mist. NS SILICA AMORPHOUS (SI02) 7631-86-9 REL 6 mg/m3 NIOSH/GUID E TWA 0.8 m /m3 Z3 TWA 6 m /m3 TN DEL TITANIUM DIOXIDE (TI02 13463-67-7 TWA 10 m /m3 ACGIH PEL 15 mg/m3 OSHA_TRA Total dust. NS TWA 1 mg/m3 ACGIHLIS_P Respirable fraction. Engineering measures Provide sufficient mechanical (general and/or local exhaust) ventilation to maintain exposure below exposure guidelines (if applicable)or below levels that cause known, suspected or apparent adverse effects. 8/21 H �m Page:9 SAFETY DATA SHEET Revision Date: 05/25/2015 Print Date: 7/7/2015 SIDS Number: R0205917 IB WATER STOP Version: 1.1 602471 Provide appropriate exhaust ventilation at places where dust is formed. Personal protective equipment Respiratory protection In the case of vapour formation use a respirator with an approved filter. A NIOSH-approved air-purifying respirator with an appropriate cartridge and/or filter may be permissible under certain circumstances where airborne concentrations are expected to exceed exposure limits (if applicable) or if overexposure has otherwise been determined. Protection provided by air- purifying respirators is limited. Use a positive pressure, air- supplied respirator if there is any potential for uncontrolled release, exposure levels are not known or any other circumstances where an air-purifying respirator may not provide adequate protection. Hand protection Remarks The suitability for a specific workplace should be discussed with the producers of the protective gloves. Eye protection Not required under normal conditions of use. Wear splash- proof safety goggles if material could be misted or splashed into eyes. Skin and body protection Wear as appropriate: impervious clothing Safety shoes Flame-resistant clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place. Discard gloves that show tears, pinholes,or signs of wear. Wear resistant gloves (consult your safety equipment supplier). Hygiene measures Avoid contact with skin, eyes and clothing. Wash hands before breaks and immediately after handling the product. When using do not eat or drink. When using do not smoke. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance viscous Physical state liquid Colour grey Odour 9/21 A%SHLANN", Page: 10 SAFETY DATA SHEET Revision Date: 05/25/2015 Print Date: 7/7/2015 SDS Number: R0205917 IB WATER STOP Version: 1.1 602471 No data available Odour Threshold No data available pH No data available No data available Boiling point/boiling range 309.9-385.0°F/154.4- 196.1 °C Flash point 104°F 140°C Method:Tag closed cup Evaporation rate 0.1 n-butyl acetate=1 Flammability(solid, gas) Combustible Dust Upper explosion limit 6.0%(V) Lower explosion limit 0.5%(V) Vapour pressure 16 mmHg(20 °C) Relative vapour density 3.5 Relative density No data available Density 1.6 g/cm3(20°C) Solubility(ies) Water solubility No data available Solubility in other solvents No data available Partition coefficient: n- No data available octanol/water Thermal decomposition No data available Viscosity Viscosity, dynamic No data available Viscosity, kinematic No data available Oxidizing properties No data available SECTION 10. STABILITY AND REACTIVITY 10/21 m IPage: 11 SAFETY DATA SHEET Revision Date: 05/25/2015 Print Date: 7/7/2015 SIDS Number: R0205917 IB WATER STOP Version: 1.1 602471 Reactivity No decomposition if stared and applied as directed. Chemical stability Stable under recommended storage conditions. Possibility of hazardous Vapours may form explosive mixture with air. reactions This product does not present a dust explosion hazard as delivered. However, fine dust dispersed in air in sufficient concentrations, and in the presence of an ignition source, is a potential dust explosion hazard. Conditions to avoid Heat,flames and sparks. Incompatible materials Acids ammonium salts aluminum salts fluorides Fluorine formaldehyde-like strong bases Strong oxidizing agents Hazardous decomposition products aluminum oxides calcium oxide carbon dioxide and carbon monoxide Hydrocarbons metal oxides SECTION 11. TOXICOLOGICAL INFORMATION Information on likely routes of : Inhalation exposure Skin contact Eye Contact Ingestion Acute toxicity Fatal if inhaled. Product: Acute inhalation toxicity Assessment: The component/mixture is classified as acute inhalation toxicity, category 1. Components: ALUMINA: Acute oral toxicity LD 50(Rat): >5,000 mg/kg LD50(Rat,female): >2,000 mg/kg Method: OECD Test Guideline 423 GLP: yes Assessment: No adverse effect has been observed in acute oral toxicity tests. Components: 11 /21 As"UNN130 Page: 12 SAFETY DATA SHEET Revision Date: 05/25/2015 Print Date: 7/7/2015 SIDS Number: R0205917 IB WATER STOP Version: 1.1 602471 CALCIUM CARBONATE: Acute oral toxicity LID 50 (Rat): 6,450 mg/kg Acute inhalation toxicity LC 50 (Rat): >3 mg/I Exposure time: 4 In Method: OECD Test Guideline 403 Assessment: Not classified as acutely toxic by inhalation under GHS. Remarks:Aerosol Acute dermal toxicity LID 50 (Rat): >2,000 mg/kg Method: OECD Test Guideline 402 PETROLEUM DISTILLATES (STODDARD TYPE): Acute oral toxicity LID 50 (Rat): >5 g/kg Acute dermal toxicity LD 50(Rabbit): >3 g/kg Assessment: Not classified as acutely toxic by dermal absorption under GHS. MAGNESIUM CARBONATE: Acute oral toxicity LD50(Rat): >2,000 mg/kg Method: OECD Test Guideline 420 Assessment: No adverse effect has been observed in acute oral toxicity tests. KAOLIN: Acute oral toxicity LID 50 (Rat): >5,000 mg/kg Acute dermal toxicity LID 50 (Rat): >5,000 mg/kg LIMESTONE: Acute oral toxicity LID 50(Rat):6,450 mg/kg DISTILLATES (PETROLEUM), HYDROTREATED HEAVY NAPHTA: Acute oral toxicity LID 50 (Rat): >5 g/kg Acute inhalation toxicity LC50 (Rat): >5.53 mg/I Exposure time:4 h Test atmosphere: dust/mist Method: OECD Test Guideline 403 Assessment: Not classified as acutely toxic by inhalation under GHS. Acute dermal toxicity LID 50 (Rabbit): >2,000 mg/kg Assessment: Not classified as acutely toxic by dermal absorption under GHS. Remarks: No mortality observed at this dose. SILICA AMORPHOUS (SIO2): Acute oral toxicity LID 50 (Rat): >5,000 mg/kg Method: OECD Test Guideline 401 GLP: yes 12/21 Page: 13 SAFETY DATA SHEET Revision Date: 05/25/2015 Print Date: 7/7/2015 SDS Number: R0205917 IB WATER STOP Version. 1.1 602471 Acute inhalation toxicity LC 50 (Rat): >2,08 mg/I Exposure time:4 h Test atmosphere:dust/mist Method: OECD Test Guideline 403 GLP: yes Assessment: No adverse effect has been observed in acute inhalation toxicity tests. Acute dermal toxicity LID 50 (Rabbit): >5,000 mg/kg TITANIUM DIOXIDE (TIO2): Acute oral toxicity LD 50 (Rat): >24,000 mg/kg Acute inhalation toxicity LC 50 (Rat): >6,820 mg/m3 Exposure time:4 h Test atmosphere:dust/mist Acute dermal toxicity LID 50 (Rabbit): > 10,000 mg/kg Skin corrosion/irritation Causes skin irritation. Product: Result: Irritating to skin Result: Repeated exposure may cause skin dryness or cracking. Remarks: May cause skin irritation and/or dermatitis. Components: ALUMINA: Result: Not irritating to skin Species: Rabbit Method: OECD Test Guideline 404 Result: Not irritating to skin GLP: yes Components: CALCIUM CARBONATE: Result: Not irritating to skin PETROLEUM DISTILLATES (STODDARD TYPE): Result: Mildly irritating to skin Result: Repeated exposure may cause skin dryness or cracking. MAGNESIUM CARBONATE: Result: Mildly irritating to skin KAOLIN: Result: Not irritating to skin 13/21 Hl. ".i Page: 14 SAFETY DATA SHEET Revision Date: 05/25/2015 Print Date: 7/7/2015 SDS Number: R0205917 IB WATER STOP Version: 1.1 602471 LIMESTONE: Result: Possibly irritating to skin DISTILLATES (PETROLEUM), HYDROTREATED HEAVY NAPHTA: Species: Rabbit Result: Not irritating to skin SILICA AMORPHOUS (SI02): Result: Possibly irritating to skin TITANIUM DIOXIDE (TI02): Result: Possibly irritating to skin Serious eye damage/eye irritation Not classified based on available information. Product: Remarks:Vapours may cause irritation to the eyes, respiratory system and the skin. Components: ALUMINA: Result: Possibly irritating to eyes Remarks:Aluminum powder, uncoated Species: Rabbit Result: Not irritating to eyes Method: OECD Test Guideline 405 GLP: yes Components: CALCIUM CARBONATE: Result: Not irritating to eyes PETROLEUM DISTILLATES (STODDARD TYPE): Result: Mildly irritating to eyes MAGNESIUM CARBONATE: Result: Mildly irritating to eyes KAOLIN: Result: Not irritating to eyes LIMESTONE: Result: Possibly irritating to eyes DISTILLATES (PETROLEUM), HYDROTREATED HEAVY NAPHTA: Species: Rabbit Result: Mildly irritating to eyes SILICA AMORPHOUS (S102): Result: Possibly irritating to eyes TITANIUM DIOXIDE (TI02): Result: Possibly irritating to eyes 14/21 HL �' Page: 15 SAFETY DATA SHEET Revision Date: 05/25/2015 Print Date: 7/7/2015 SIDS Number: R0205917 IB WATER STOP Version: 1.1 602471 Respiratory or skin sensitisation Skin sensitisation: Not classified based on available information. Respiratory sensitisation: Not classified based on available information. Components: ALUMINA: Test Type: Maximisation Test(GPMT) Species: Guinea pig Method: OECD Test Guideline 406 Result: Did not cause sensitisation on laboratory animals. GLP: yes Components: DISTILLATES (PETROLEUM), HYDROTREATED HEAVY NAPHTA: Species: Guinea pig Assessment: Does not cause skin sensitisation. Method: OECD Test Guideline 406 Germ cell mutagenicity Not classified based on available information. Carcinogenicity Not classified based on available information. Reproductive toxicity Not classified based on available information. STOT-single exposure May cause damage to organs(Central nervous system). Product: Target Organs: Central nervous system Assessment: May cause damage to organs. STOT-repeated exposure Not classified based on available information. Aspiration toxicity Not classified based on available information. Product: No aspiration toxicity classification Components: PETROLEUM DISTILLATES (STODDARD TYPE): May be fatal if swallowed and enters airways. Further information Product: Remarks: Solvents may degrease the skin. Components: PETROLEUM DISTILLATES (STODDARD TYPE): Remarks: Kidney TITANIUM DIOXIDE (TI02): Remarks: Lung Carcinogenicity: IARC Group 213: Possibly carcinogenic to humans 15/21 A%S"LJNN130 Page: 16 SAFETY DATA SHEET Revision Date: 05/25/2015 Print Date: 7/7/2015 SIDS Number: R0205917 IB WATER STOP Version: 1.1 602471 TITANIUM DIOXIDE (T1O2) 13463-67-7 OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. NTP No component of this product present at levels greater than or equal to 0.1% is identified as a known or anticipated carcinogen by NTP. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Product: Ecotoxicology Assessment Acute aquatic toxicity Acute aquatic toxicity Category 3 Chronic aquatic toxicity Chronic aquatic toxicity Category 3 CALCIUM CARBONATE: Toxicity to fish LC 50 (Gambusia affinis (Mosquito fish)): >56,000 mg/I Exposure time: 96 h Test Type: static test DISTILLATES (PETROLEUM), HYDROTREATED HEAVY NAPHTA: Toxicity to fish LL50 (Pimephales promelas (fathead minnow)): > 100 mg/I Exposure time: 96 h Test Type: static test Test substance:WAF Method: OECD Test Guideline 203 Toxicity to daphnia and other EL50 (Daphnia magna(Water flea)): > 10,000 mg/I aquatic invertebrates Exposure time: 48 h Test Type: static test Test substance:WAF Method: OECD Test Guideline 202 Toxicity to algae NOEL(Pseudokirchneriella subcapitata (green algae)): >_ 100 mg/I End point: Growth inhibition Exposure time: 72 h Test Type: static test Test substance:WAF Method: OECD Test Guideline 201 Toxicity to daphnia and other NOEL(Daphnia (water flea)): 10 mg/I aquatic invertebrates Exposure time: 21 d (Chronic toxicity) Test Type: semi-static test Test substance:WAF 16/21 �m Page: 17 SAFETY DATA SHEET Revision Date: 05/25/2015 Print Date: 7/7/2015 SDS Number: R0205917 IB WATER STOP Version: 1.1 602471 Method: OECD Test Guideline 211 SILICA AMORPHOUS (SI02): Toxicity to fish LC 50 (Danio rerio(zebra fish)): > 10,000 mg/I Exposure time: 96 h Method: OECD Test Guideline 203 GLP: yes TITANIUM DIOXIDE (TI02): Toxicity to daphnia and other EC 50(Water flea (Daphnia magna)): > 1,000 mg/I aquatic invertebrates Exposure time:48 In Test Type: static test Persistence and degradability DISTILLATES (PETROLEUM), HYDROTREATED HEAVY NAPHTA: Biodegradability Result: Inherently biodegradable Biodegradation: 31 % Exposure time:28 d Method: OECD Test Guideline 301 F Bioaccumulative potential No data available Mobility in soil No data available Other adverse effects No data available Product: Additional ecological An environmental hazard cannot be excluded in the event of information unprofessional handling or disposal., Harmful to aquatic life with long lasting effects. SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods General advice The product should not be allowed to enter drains, water courses or the soil. Do not contaminate ponds,waterways or ditches with chemical or used container. Send to a licensed waste management company. Dispose of in accordance with all applicable local, state and federal regulations. Contaminated packaging Empty remaining contents. Dispose of as unused product. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum. 17/21 JASHL QJ, Page: 18 SAFETY DATA SHEET Revision Date: 05/25/2015 Print Date: 7/7/2015 SDS Number: R0205917 IB WATER STOP Version: 1.1 602471 SECTION 14. TRANSPORT INFORMATION International transport regulations REGULATION ID NUMBER PROPER SHIPPING NAME *HAZARD SUBSIDIARY PACKING MARINE CLASS HAZARDS GROUP POLLUTANT/ LTD. QTY. U.S. DOT-ROAD UN 1133 Adhesives 3 111 LIMITED QUANTITY U.S. DOT-RAIL UN 1133 Adhesives 3 III LIMITED QUANTITY U.S. DOT-INLAND WATERWAYS UN 1133 Adhesives 3 III LIMITED QUANTITY TRANSPORT CANADA -ROAD UN 1133 ADHESIVES 3 III LIMITED QUANTITY TRANSPORT CANADA-RAIL UN 1133 ADHESIVES 3 III LIMITED QUANTITY TRANSPORT CANADA -INLAND WATERWAYS UN 1133 ADHESIVES 3 III LIMITED n= QUANTITY INTERNATIONAL MARITIME DANGEROUS GOODS UN 1133 ADHESIVES 3 III LIMITED QUANTITY INTERNATIONAL AIR TRANSPORT ASSOCIATION -CARGO UN 1133 Adhesives 3 ill INTERNATIONAL AIR TRANSPORT ASSOCIATION -PASSENGER UN 1t33 Adhesives 3 III 18/21 JASH Page: 19 SAFETY DATA SHEET Revision Date: 05/25/2015 Print Date: 7/7/2015 SIDS Number: R0205917 IB WATER STOP Version. 1.1 602471 MEXICAN REGULATION FOR THE LAND TRANSPORT OF HAZARDOUS MATERIALS AND WASTES UN 1133 ADHESIVOS 3 III `ORM =ORM-D, CBL=COMBUSTIBLE LIQUID Marine pollutant yes Dangerous goods descriptions (if indicated above) may not reflect quantity, end-use or region-specific exceptions that can be applied. Consult shipping documents for descriptions that are specific to the shipment. SECTION 15. REGULATORY INFORMATION SARA 3111312 Hazards Fire Hazard Acute Health Hazard SARA 313 This material does not contain any chemical components with Component(s)SARA 313 known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. California Prop 65 WARNING!This product contains a chemical known to the State of California to cause cancer. QUARTZ/SAND 14808-60-7 The components of this product are reported in the following inventories: TSCA On the inventory, or in compliance with the inventory DSL On the inventory, or in compliance with the inventory AUSTR Not in compliance with the inventory ENCS Not in compliance with the inventory KECL Not in compliance with the inventory IECSC Not in compliance with the inventory PICCS Not in compliance with the inventory Inventories AICS (Australia), DSL(Canada), IECSC (China), REACH (European Union), ENCS (Japan), ISHL (Japan), KECI (Korea), NZIoC (New Zealand), PICCS (Philippines), TSCA(USA) Registration: Trade Secret Chemical Name Identification number ALUMINA 800986-5135P 19/21 Page: 20 SAFETY DATA SHEET Revision Date: 05/25/2015 Print Date: 7/7/2015 SDS Number: R0205917 IB WATER STOP Version: 1.1 602471 SECTION 16. OTHER INFORMATION Further information Revision Date: 05/25/2015 NFPA: HMIS III: Flammability HEALTH Zi 5 0 3 PHYSICAL HAZARD 0 0=not significant, 1=Slight, Special hazard. 2=Moderate,3=High 4=Extreme,`=Chronic NFPA Flammable and Combustible Liquids Classification Combustible Liquid Class II Full text of H-Statements referred to under sections 2 and 3. H304 May be fatal if swallowed and enters airways. Sources of key data used to compile the Safety Data Sheet Ashland internal data including own and sponsored test reports The UNECE administers regional agreements implementing harmonised classification for labelling (GHS)and transport. The information accumulated herein is believed to be accurate but is not warranted to be whether originating with the company or not. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This SDS has been prepared by Ashland's Environmental Health and Safety Department(1-800-325-3751). List of abbreviations and acronyms that could be, but not necessarily are, used in this safety data sheet : ACGIH : American Conference of Industrial Hygienists BEI : Biological Exposure Index CAS : Chemical Abstracts Service(Division of the American Chemical Society). CMR : Carcinogenic, Mutagenic or Toxic for Reproduction FG : Food grade GHS : Globally Harmonized System of Classification and Labeling of Chemicals. 20/21 HPage: 21 SAFETY DATA SHEET Revision Date: 05/25/2015 Print Date: 7/7/2015 SDS Number: R0205917 IB WATER STOP Version: 1.1 602471 H-statement: Hazard Statement IATA : International Air Transport Association. IATA-DGR: Dangerous Goods Regulation by the"International Air Transport Association" (IATA). ICAO : International Civil Aviation Organization ICAO-TI (ICAO) :Technical Instructions by the"International Civil Aviation Organization" IMDG : International Maritime Code for Dangerous Goods ISO : International Organization for Standardization IogPow: octanol-water partition coefficient LCxx : Lethal Concentration,for xx percent of test population LDxx : Lethal Dose,for xx percent of test population. ICxx : Inhibitory Concentration for xx of a substance Ecxx : Effective Concentration of xx N.O.S.: Not Otherwise Specified OECD : Organization for Economic Co-operation and Development OEL : Occupational Exposure Limit P-Statement: Precautionary Statement PBT : Persistent, Bioaccumulative and Toxic PPE : Personal Protective Equipment STEL : Short-term exposure limit STOT : Specific Target Organ Toxicity TLV: Threshold Limit Value TWA :Time-weighted average vPvB :Very Persistent and Very Bioaccumulative WEL : Workplace Exposure Level CERCLA : Comprehensive Environmental Response, Compensation, and Liability Act DOT : Department of Transportation FIFRA: Federal Insecticide, Fungicide, and Rodenticide Act HMIRC : Hazardous Materials Information Review Commission HMIS : Hazardous Materials Identification System NFPA : National Fire Protection Association NIOSH : National Institute for Occupational Safety and Health OSHA : Occupational Safety and Health Administration PMRA: Health Canada Pest Management Regulatory Agency RTK : Right to Know WHMIS :Workplace Hazardous Materials Information System 21 /21 SAFETY DATA SHEET 31ne. 1920 Colored Sealants Issue date: 05/01/2015 1. Product and Company Identification Product Name: Solar Seal-All Colors-VOC Compliant Sealant Product Type: Elastomeric Sealant, non-chemically curing Product Number: 900 Series Company Address: Contact Information: NPC Sealants Telephone: 708-681-1040 M-F 8-5 1208 S. 8th Ave. Medical emergency: Contact local poison control center Maywood, III. 60153 USA After hours Transport Emergency Phone: 1-800-424-9300 (toll free) 1-703-527-3887 2. Hazards identification Emergency Overview HMIS Physical State: Paste Health 2 Color: On box or tube Flammability 3 Odor: Solvent Physical Hazard 0 Personal Protection See Section 8 SIGNAL WORD: DANGER H225 HIGHLY FLAMMABLE LIQUID AND VAPOR H315 CAUSES SKIN IRRITATION H319 CAUSES SERIOUS EYE IRRITATION H302 + H332 HARMFUL IF SWALLOWED OR INHALED H336 MAY CAUSE DROWSINESS OR DIZZINESS GHS HAZARD CLASS: FLAMMABLE LIQUID: HAZARD CATEGORY 2. SKIN IRRITATION: HAZARD CATEGORY 2. EYE IRRITATION: HAZARD CATEGORY 2A. STOT-SE: HAZARD: CATEGORY 3 PICTOGRAMS: Precautionary statements. PREVENTION. Keep away from heat, sparks, open flames and hot surfaces [P210]. Keep container tightly closed [P233]. Use only non-sparking tools [P242]. Take precautionary measures against static discharge [P243] Wear protective gloves, protective clothing, eye protection and face protection [P280]. Wash hands thoroughly after A C T o 7 2020 handling [P264]. Avoid breathing fumes, mist, vapors, or spray[P261]. Use only outdoors or in a well-ventilated area [P271]. RESPONSE. If on skin or hair: Take off immediately all contaminated clothing. Rinse skin with water/shower [P303+P361+P353]. If skin irritation occurs:/Get medical advice/attention [P332+313]. If inhaled: Remove person to fresh air and keep comfortable for breathing [P304+P340]. If(uncured product)swallowed: Immediately call a POISON center or doctor/physician. Do not induce vomiting [P301+P310+P331]. If in eyes: Rinse cautiously with water for several minutes. Remove contact lens, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical attention/attention. [P305+P337+P338+351+313]. In case of fire: Use dry chemicals, CO2, water fog or foam to extinguish [P370+ P378]. STORAGE: Store in a well ventilated place. Keep cool [P403+235]. Keep container tightly closed [P233]. Store locked up and out of reach of children [P405 +P102] DISPOSAL: Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations[P401]. 3. Composition/information on ingredients Components CAS# Percent* Limestone 1317-65-3 10-30 t-But I Acetate 540-88-5 2-20 PCBTF 98-56-6 2-25 Aromatic Petroleum Distillates 64742-94-6 2-3.9 Quartz Si02 ** 14808-60-7 0.1 - 1.5 Trimeth (benzenes*** 95-63-6 0.64— 1.25 X lenes**** 1330-20-7 0-0.09 Cumene**** 100-41-4 0-0.04 *Exact percentage is a trade secret. Range is provided to assist user in selecting appropriate protections.**naturally occurring minor constituent of 1317-65-3. ***constituent of 64742-94-6. ****may be constituents of 64742-94-6. All other ingredients, including proprietary (trade secret) hydrocarbon resins and elastomers, are considered non hazardous. The main hazard of limestone (&quartz) is dust inhalation. Because of incorporation into sealant, exposure by inhalation is unlikely. 4. Firc}-girl maacureS Skin Contact: Rinse with running water and soap. If symptoms develop and persist, seek medical attention. Inhalation: If inhaled, remove the affected person to fresh air. If breathing is difficult, give oxygen. If symptoms develop and persist, seek medical attention. Eye contact: Flush eyes with water for 15 minutes, and seek immediate medical attention. Ingestion: If uncured sealant is ingested, do not induce vomiting. Seek medical attention immediately. Notes to physician: Treat symptomatically and supportively. 5. Fire-fighting measures Extinguishing Media: Dry Chemical, Foam, Carbon Dioxide, Water Fog or Spray, In case of fire, keep containers cool with water spray. Special Firefighting Procedure: Under fire emergency conditions, it is recommended that full protection equipment be used, including NIOSH approved self-contained breathing apparatus to protect fire fighters from any hazardous combustion products. Wear full protective clothing. Unusual Fire & Explosion Hazards: During emergency conditions, over exposure to combustion products such as smoke and carbon monoxide may cause a health hazard. General Fire Hazards Caution: Flammable vapors. Vapors are heavier than air and may travel to distant ignition sources. Keep containers closed. Use with adequate ventilation. Hazardous Combustion Products: Carbon dioxide. Carbon Monoxide. 6. Accidental release measures Use personal protection recommended in section 8 as required to maintain exposure below applicable exposure limit. Restrict area access to necessary personnel. Environmental precautions: Ventilate area. Keep upwind of spill. Prevent further leakage or spillage if safe to do so. Do not allow product to enter sewer or waterways. Clean up methods: Remove all sources of ignition. Cover material in inert absorbent and place into a appropriate closed container. Waste Disposal Method: Dispose of contents and/or container according to Federal, State/Provincial and local governmental regulations. 7. Handling and Storage: When handling uncontained material, use protective equipment as described in Section 8 to maintain exposure below the applicable exposure limit. Use only in well ventilated areas. This product is intended for exterior use only. Store in a cool, dry well ventilated area. Store away from sources of ignition. Do not heat or pressurize containers. Keep out of reach of children. Do not reuse empty containers. 8. Exposure controls/personal protection: Employers should complete an assessment of all workplaces to determine the need for and selection of proper exposure controls and protective equipment for each task performed. Hazardous Components ACGIH TLV OSHA PEL AIHA WEEL t-But I Acetate 200 ppm TWA 950 m /m3 none PCBTF none none none Aromatic Petroleum Distillates 100 ppm TWA 100 m TWA none 5 mg/m3 TWA respirable fraction 10 mg/m3 TWA 15 mg/m3 TWA Limestone total dust total dust none 0.1 mg/m3 TWA respirable fraction 0.025 mg/m3 TWA 0.3 mg/m3 TWA Quartz (Si02)* respirable fraction total dust none 50 ppm (245 Trimeth (benzenes 251pPm TWA m /m3 TWA none 100 ppm TWA 100 ppm (435 X lenes** 150 ppm STEL m /m3)TWA none 50 ppm (245 Cumene** 50 ppm m /m3)TWA none * Naturally occurring constituent of limestone**May be low level constituents of petroleum distillates Engineering controls: Intended for outdoor use, or unoccupied dwellings having forced fresh air ventilation. Local exhaust ventilation is recommended when general ventilation is not sufficient to control airborne contamination below occupational exposure limits. Respiratory Protection: Not needed under expected exterior conditions of use, but avoid concentrating vapors in any closed area. Use a NIOSH approved air purifying respirator if the potential to exceed established limits exists. When required, a respirator program following 29CFR 1910.134 should be followed. NIOSH approved organic vapor purifying respirator may be used for the voluntary reduction of nuisance odors. Detection (50%) limit threshold is 10 ppb for TBAc. Eye/face protection: Safety goggles or safety glasses with side shields are prudent practices. Skin Protection: Use impermeable gloves and protective clothing as necessary to prevent skin contact. 9. Physical and chemical properties Physical State: Solid paste Color: List on box and tube. Solubility: Not available. Not water soluble. Specific Gravity (20 °C): 1.14 Relative Vapor Density(air=1): Not available, heavier than air. Vapor Pressure (20 °C): Not available. Evaporation rate: Not available. Slower than ether. Odor: Strong solvent odor. Relevant components: TBAc is detectable at 71 ppb (10 ppb 50%threshold)with a sweet ester/camphor solvent odor. PCBTF and aromatic petroleum distillates have an aromatic solvent odor. Odor Threshold: No available. Flash Point (°C): Not available. Product is a solid paste. Burn rate unknown. [Flammable components: TBAc solvent has a flash point of 40OF(4.4°C). It is a flammable liquid as defined under SARA Title III, section 311/312 hazard category but is not subject to the reporting requirements of SARA Title III, section 313. PCBTF solvent exhibits a flash point of 109' F (42.8° C), but is a non-regulated material under the DOT Hazardous Material Regulations and the IMDG Code because it does not sustain combustion.] Flammable/explosion Limits-lower: Not available Flammable/explosion Limits-upper: Not available Autoignition Temperature(°C): Not available Melting Point/Range (°C): Not available Boiling Point/Range (°C): Not available pH: Not applicable Partition Coefficient[Oct/water]: Not available VOC (w/w%): <4% Decomposition temperature: Not available 10. Stability and reactivity Chemical stability: This material is thermally stable when stored and used as directed. Hazardous polymerization will not occur. Conditions to avoid: Avoid high temperatures, flame, sparks and other ignition sources. Incompatible Materials: None known. It is prudent to avoid strong oxidizing agents with carbon based systems. Hazardous decomposition products: Oxides of carbon, smoke and other toxic fumes. Hazardous reactions: None known. Unlikely to occur. 11. Toxicological information Relevant Routes of exposure: Skin, Inhalation Potential health effects Skin Contact: Repeated or prolonged skin contact may cause skin irritation and or dermatitis in sensitive persons. Inhalation: Over exposure to vapors may cause dizziness, headaches and respiratory tract irritation. Exposure to high doses may cause central nervous system depression. People with a history of chemical sensitivity should be advised this product contains petroleum solvents. Reports have associated prolonged and repeated overexposure to solvents with permanent brain and nervous system damage. Intentional misuse by deliberately inhaling concentrated fumes may be harmful or fatal. Eye contact: Direct contact symptoms can include significant irritation, redness and tearing. Ingestion: Ingestion can cause gastrointestinal irritation, nausea, vomiting and diarrhea. No available information regarding existing conditions aggravated by exposure. ARC OSHA Carcinogen Hazardous Components NTP Carcinogen Carcinogen (Specifically Regulated) t-But I Acetate No No No PCBTF No No No Aromatic Petroleum Distillates No No No Limestone No No No Known human Quartz SiO2 carcinogen I Group 1 1 No Trimeth (benzenes No No No Cumene** Suspect Group 2B No X lenes** No No No naturally occurring constituent of limestone**may be low level constituents of petroleum distillates Hazardous Components Health Effects/Target Organs t-But I Acetate Irritant, Central Nervous System Adrenals, Blood, CNS, Immune system, Irritant, Kidney, Liver, PCBTF Lung, Skin, Thyroid Aromatic Petroleum Distillates Irritant, Central Nervous System Limestone Nuisance dust Quartz Si02 Immune system, Lung, Some evidence of carcino enicit Trimeth (benzenes Irritant, Central Nervous System Cumene Irritant, Central Nervous System X lenes Irritant, Central Nervous Sy stem Sensitization: None known. Chronic: Possible skin and eye irritant. Carcinogenicity: NTP: No, IARC: No, OSHA: No. Mutagenicity: None known. Medical Conditions Aggravated by Exposure: None known. Reproductive Toxicity: None known. Acute Toxicity Values: Not determined. 12. Ecological information No data are available on the adverse effects of this material on the environment. TBAc solvent has been shown to biodegrade in standard closed-bottle laboratory tests using acclimated and non-acclimated microorganisms. 28-day biological oxygen demand (BOD)expressed as %of chemical oxygen demand (COD) ranged from 28%with EPA-approved Polyseed to 75%with acclimated Delcora sludge typically found in Publicly-Owned Treatment Works (POTW). Chemicals with BOD greater than 60%of their COD are generally considered to be"readily biodegradable". PCBTF has neither COD nor BOD data available. Volatility, and relative environmental partitioning characteristics, makes it unlikely that PCBTF represents a significant threat to aquatic or terrestrial environments. Based on the chemical composition of this product it is assumed that the mixture can be treated in an acclimatized biological waste treatment plant system in limited quantities. However, such treatment should be evaluated and approved for each specific biological system. Additional ingredients have neither COD nor BOD data available. None of the ingredients in this mixture are classified as a Marine Pollutant. Avoid contaminating waterways. Ecotoxicity: No information available. Persistence and degradability: No information available. Mobility: No information available. Based on the chemical composition, volatile substances are likely to enter the atmosphere. No accumulation is expected. TBAc and PCBTF are approved as exempted non-VOC solvents. 13. Disposal considerations All waste must be disposed in accordance with Federal, State, and Local Regulations (see 40 CFR Part 268). It is the responsibility of the user to determine at time of disposal whether a material containing the product or derived from the product should be classified as a solid or hazardous waste. US EPA waste number: D001, Ignitable waste. 14. Transport information Multi-modal shipping descriptions are provided for informational purposes and do not consider container sizes. The presence of a shipping description for a particular mode of transport(ocean, air, etc.), does not indicate that the product is packaged suitably for that mode of transport. All packaging must be reviewed for suitability prior to shipment, and compliance with the applicable regulations is the sole responsibility of the person offering the product for transport. US Ground (DOT) Flammability Classification: OSHA: Class IB Viscous mixture with Flash Point: <110°F, TCC DOT: 173.150 (c) "Consumer Commodity", Class ORM-D Material. 173.121, Class 3(b) E 173.150 DOT(Dept of Transportation) Hazardous Substances & Reportable Quantities: Xylenes, Proper shipping name Adhesives Hazard Class 3 Identification number UN 1133 Packing group III Canada (TDG) Proper shipping name Adhesives Hazard Class 3 Identification number UN 1133 Packing group III QUANTITY, (ERG#160) International or Air Shipments in non-bulk containers, 172,101 Flammable Liquid, n.o.s. UN1993, Packaging Group III. 15. Regulatory information United States Regulatory information: All components comprising this product are listed on the TSCA 8(b) inventory. TSCA Export notification 12(b) list: Solvent(CAS#98-56-6) CERCLA/SARA Section 302 EHS None above reporting limits CERCLA/SARA Section 311/312 EHS Immediate Health, Delayed Health, Fire CERCLA/SARA Section 313 EHS Xylenes (CAS#1330-20-7) Trimethylbenzene(95-63-6) CA Proposition 65: This product contains a chemical known to the state of California to cause cancer, birth defects or other reproductive harm. Canadian Regulatory: CEPA DSL/NDSL Status : All components comprising this product are listed on the Canadian DSL. WHMIS hazard Class: B.2, D.2a. D.2b 16. Other information Prepared by: NPC Technical Staff Disclaimer: The data contained herein are furnished in good faith for information only and are believed to be reliable on the effective issue date. However NuPuttie Corp and its subsidiaries or suppliers do not assume responsibility for any results obtained by persons whose methods are not controlled by NPC and its affiliates or suppliers. It is the user's responsibility to determine the suitability of NPC's products for a specific use, and to adopt such precautions as may be advisable for the protection of property and persons against any hazards that may be involved in the handling and use of NPC products. NPC and its suppliers specifically disclaim all warranties,express or implied, including merchantability and fitness for a particular purpose or location, arising from the sale or use of NPC's products. NPC disclaims any liability for consequential or incidental damages of any kind, including lost profits. It is the users responsibility to ensure its activities comply with Federal, State,provincial and local laws. r RoolSystems SAFETY DATA SHEET 1, Identification Product identifier Rapid set insulation Adhesive Part A Other means of identification Not available. Recommended use Adhesive. Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Manufacturer/Supplier: IB Roof Systems 2877 Chad Drive Eugene, Oregon 97408 UE General Information: 800-426-1626 Emergency: 2. Hazard(s) identification Physical hazards Not classified. Health hazards Acute toxicity,inhalation Category 4 Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2A Sensitization, respiratory Category 1 Sensitization,skin Category 1 Specific target organ toxicity,single exposure Category 3 respiratory tract irritation Specific target organ toxicity, repeated Category 2 exposure OSHA defined hazards Not classified. Label elements 4 Signal word Danger Hazard statement Causes skin irritation. May cause an allergic skin reaction.Causes serious eye irritation.Harmful if inhaled.May cause allergy or asthma symptoms or breathing difficulties if inhaled.May cause respiratory irritation. May cause damage to organs through prolonged or repeated exposure. Precautionary statement Prevention Do not breathe mist or vapor.Wash thoroughly after handling.Wear protective gloves/protective clothing/eye protection/face protection.In case of inadequate ventilation wear respiratory protection.Use only outdoors or in a well-ventilated area.Contaminated work clothing should not be allowed out of the workplace. Response If on skin:Wash with plenty of water. If skin irritation or rash occurs:Get medical advice/attention. Take off contaminated clothing and wash before reuse. If inhaled:Remove person to fresh air and keep comfortable for breathing.Call a poison center/doctor if you feel unwell. If experiencing respiratory symptoms:Call a POISON CENTER or doctor/physician. If in eyes:Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do.Continue rinsing. If eye irritation persists: Get medical advice/attention.Wash contaminated clothing before reuse. Storage Store in a well-ventilated place.Keep container tightly closed.Store locked up. Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s)not otherwise Not classified. classified(HNOC) Supplemental information None. 3. Composition/information on ingredients Mixtures Rapid set insulation Adhesive Part A SDS US 914047 Version#:01 Revision date:- Issue date: 10-September-2013 1 /7 Chemical name CAS number % Polymethylene polyphenyl 9016-87-9 30-60 isocyanate Methylene Biphenyl 101-68-8 20-40 diisocyanate Diisocyanate 26447-40-5 0-15 methylenediphenyl Composition comments All concentrations are in percent by weight unless ingredient is a gas.Gas concentrations are in percent by volume. 4. First-aid measures Inhalation Immediately remove from further exposure.Get immediate medical assistance. For those providing assistance,avoid exposure to yourself or others.Use adequate respiratory protection. Give supplemental oxygen, if available. If breathing has stopped,assist ventilation with a mechanical device or use mouth-to-mouth resuscitation. Skin contact Remove contaminated clothing.Wash immediately with soap and water for at least 15 minutes. Get medical attention promptly if symptoms persist or occur after washing.Discard contaminated shoes and clothing. Eye contact Immediately flush with plenty of water for up to 15 minutes. Remove any contact lenses and open eyelids wide apart.Get medical attention. Ingestion Get medical attention if any discomfort occurs. Most important Irritation of eyes and mucous membranes.Skin irritation.Sensitization. Wheezing. Difficulty in symptoms/effects,acute and breathing. Ingestion may cause irritation and malaise. delayed Indication of immediate Provide general supportive measures and treat symptomatically. medical attention and special treatment needed General information Ensure that medical personnel are aware of the material(s)involved,and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Dry chemical powder.Carbon dioxide(CO2).Foam. Unsuitable extinguishing None known. media Specific hazards arising from During fire,gases hazardous to health may be formed. the chemical Special protective equipment Self-contained breathing apparatus,operated in positive pressure mode and full protective clothing and precautions for firefighters must be worn in case of fire. Fire-fighting Move containers from fire area if you can do so without risk. equipmentli nstructions 6.Accidental release measures Personal precautions, Avoid inhalation of vapors and contact with skin and eyes.Do not touch damaged containers or protective equipment and spilled material unless wearing appropriate protective clothing. For personal protection,see emergency procedures section 8 of the SDS. Methods and materials for Collect and dispose of spillage as indicated in section 13 of the SDS.Stop the flow of material,if containment and cleaning up this is without risk.Dike the spilled material,where this is possible.Wipe up with absorbent material(e.g.cloth,fleece).Should not be released into the environment. Never return spills in original containers for re-use.Prevent product from entering drains. Environmental precautions Prevent entry into waterways,sewer, basements or confined areas.Environmental manager must be informed of all major spillages. 7. Handling and storage Precautions for safe handling Avoid inhalation of vapors and contact with skin and eyes.Wear personal protective equipment. Wash hands thoroughly after handling.Observe good industrial hygiene practices. Conditions for safe storage, Store in tightly closed original container.Store in a cool and well-ventilated place.Store away from including any incompatibilities incompatible materials. Rapid set insulation Adhesive Part A SDS us 914047 Version#:01 Revision date:- Issue date:10-September-2013 2/7 8. Exposure controls/personal protection Occupational exposure limits US.OSHA Table Z-1 Limits for Air Contaminants(29 CFR 1910.1000) Components Type Value Methylene diphenyl Ceiling 0.2 mg/m3 diisocyanate(CAS 101-68-8) 0.02 ppm Polymethylene polyphenyl Ceiling 0.2 mg/m3 isocyanate(CAS 9016-87-9) 0.02 ppm US.ACGIH Threshold Limit Values Components Type Value Methylene diphenyl TWA 0.005 ppm diisocyanate(CAS 101-68-8) Polymethylene polyphenyl TWA 0.005 ppm isocyanate(CAS 9016-87-9) US NIOSH Pocket Guide to Chemical Hazards:Ceiling Limit Value and Time Period(if specified) Components Type Value Methylene diphenyl Ceiling 0.2 mg/m3 diisocyanate(CAS 101-68-8) 0.02 ppm Polymethylene polyphenyl Ceiling 0.2 mg/m3 isocyanate(CAS 9016-87-9) 0.02 ppm US NIOSH Pocket Guide to Chemical Hazards:Recommended exposure limit(REL) Components Type Value Methylene diphenyl TWA 0.05 mg/m3 diisocyanate(CAS 101-68-8) 0.005 ppm Polymethylene polyphenyl TWA 0.05 mg/m3 isocyanate(CAS 9016-87-9) 0.005 ppm Biological limit values No biological exposure limits noted for the ingredient(s). Exposure guidelines No exposure standards allocated. Appropriate engineering General ventilation normally adequate.Ensure adequate ventilation,especially in confined areas. controls Provide easy access to water supply and eye wash facilities. Individual protection measures,such as personal protective equipment Eye/face protection Wear approved chemical safety goggles. Use face shield in case of splash risk. Skin protection Hand protection Wear appropriate chemical resistant gloves.Suitable gloves can be recommended by the glove supplier.Be aware that the liquid may penetrate the gloves.Frequent change is advisable. Other Wear chemical-resistant gloves,footwear and protective clothing appropriate for risk of exposure. Contact chemical protective clothing manufacturer for specific information. Respiratory protection If engineering controls do not maintain airborne concentrations below recommended exposure limits(where applicable)or to an acceptable level(in countries where exposure limits have not been established),an approved respirator must be wom.In the United States of America, if respirators are used, a program should be instituted to assure compliance with OSHA 29 CFR 1910.134. Respirator type:Air-purifying respirator with an appropriate,government approved (where applicable),air-purifying filter,cartridge or canister. Thermal hazards Wear appropriate thermal protective clothing,when necessary. General hygiene Always observe good personal hygiene measures,such as washing after handling the material considerations and before eating,drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Rapid set insulation Adhesive Part A SDS US 914047 Version#:01 Revision date:- Issue date: 10-September-2013 3/7 9. Physical and chemical properties Appearance Tan viscous liquid. Physical state Liquid. Form Liquid. Color Tan. Odor Faint aromatic. Odor threshold Not available. pH Not available. Melting point/freezing point Not available. Initial boiling point and boiling Not available. range Flash point >350.0`F(> 176.7'C)Pensky-Martens Closed Cup Evaporation rate Not available. Flammability(solid,gas) Not available. Upper/lower flammability or explosive limits Flammability limit-lower Not available. N Flammability limit-upper Not available. 1�) Explosive limit-lower(%) Not available. Explosive limit-upper(%) Not available. Vapor pressure Not available. Vapor density Not available. Relative density 1.12 Solubility(ies) Reacts with water. Partition coefficient Not available. (n-octanol/water) Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity 3200-11000 cP 75'F) Other information Percent volatile <0.15 10. Stability and reactivity Reactivity The product is stable and non reactive under normal conditions of use,storage and transport. Chemical stability The product is stable under normal conditions of use,storage and transport. Possibility of.hazardous Hazardous polymerization does not occur. reactions Conditions to avoid Exposure to heat and contact with sources of ignition. Contact with incompatible materials. Incompatible materials Strong oxidizing agents. Hazardous decomposition During combustion:Carbon oxides.Nitrogen oxides. products 11. Toxicological information Information on likely routes of exposure Ingestion Ingestion may cause irritation and malaise. Inhalation Causes respiratory tract irritation. May cause allergic respiratory reaction. Skin contact Causes skin irritation.May cause sensitization by skin contact. Eye contact Causes eye irritation. Symptoms related to the Sensitization. Wheezing. Difficulty in breathing. Irritation of eyes and mucous membranes.Skin physical,chemical and irritation. Ingestion may cause irritation and malaise. toxicological characteristics Information on toxicological effects Rapid set insulation Adhesive Part A SDS US 914047 Version#:01 Revision date:- Issue date: 10-September-2013 4/7 Acute toxicity Ingestion may cause irritation and malaise. Components Species Test Results Methylene diphenyl diisocyanate(CAS 101-68-8) Acute Inhalation LC50 Rat >2.24 mg/I, 1 Hours Polymethylene polyphenyl isocyanate(CAS 9016-87-9) Acute Inhalation LC50 Rat 0,369 mg/I,4 Hours Skin corrosion/irritation Causes skin irritation. Serious eye damageleye Causes serious eye irritation. irritation Respiratory sensitization May cause allergy or asthma symptoms or breathing difficulties if inhaled. Skin sensitization May cause sensitization by skin contact. Germ cell mutagenicity Not classified. Carcinogenicity Not classified. IARC Monographs.Overall Evaluation of Carcinogenicity Diisocyanate methylenediphenyl(CAS 26447-40-5) 3 Not classifiable as to carcinogenicity to humans. Methylene diphenyl diisocyanate(CAS 101-68-8) 3 Not classifiable as to carcinogenicity to humans. Polymethylene polyphenyl isocyanate(CAS 9016-87-9) 3 Not classifiable as to carcinogenicity to humans. Reproductive toxicity Not classified. Specific target organ toxicity- May cause respiratory tract irritation. single exposure Specific target organ toxicity- May cause damage to the following organs through prolonged or repeated exposure:Respiratory repeated exposure system. Aspiration hazard Not classified. Chronic effects May cause allergic respiratory and skin reactions. 12. Ecological information Ecotoxicity The product is not classified as environmentally hazardous.However,this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Persistence and degradability Expected to be persistent. Bioaccumulative potential The product is not expected to bioaccumulate. Mobility in soil Not available. Other adverse effects No other adverse environmental effects(e.g.ozone depletion, photochemical ozone creation potential,endocrine disruption,global warning potential)are expected from this component. 13. Disposal considerations Disposal instructions Dispose in accordance with all applicable regulations.Do not allow runoff to sewer,waterway or ground. Hazardous waste code The waste code should be assigned in discussion between the user,the producer and the waste disposal company. Waste from residues I unused Dispose of in accordance with local regulations. products Contaminated packaging Since emptied containers may retain product residue,follow label warnings even after container is emptied. 14.Transport information DOT Not regulated as a hazardous material by DOT. IATA Not regulated as a dangerous good. IMDG Not regulated as a dangerous good. Transport in bulk according to Not applicable. Annex II of MARPOL 73178 and the IBC Code Rapid set insulation Adhesive Part A SDS US 914047 Version#:01 Revision date:- Issue date: 10-September-2013 517 General information The transportation information provided represents the regulatory transport classification of the product without consideration to packaging,quantity,or modal restrictions and exceptions. It is the user's responsibility to determine the appropriate packaging and modal requirements and/or limitations for the product quantity being shipped. 15. Regulatory information US federal regulations This product is a"Hazardous Chemical'as defined by the OSHA Hazard Communication Standard,29 CFR 1910.1200. TSCA Section 12(b)Export Notification(40 CFR 707,Subpt.D) Not regulated. US.OSHA Specifically Regulated Substances(29 CFR 1910.1001-1050) Not listed. CERCLA Hazardous Substance List(40 CFR 302.4) Methylene diphenyl diisocyanate(CAS 101-68-8) LISTED Polymethylene polyphenyl isocyanate(CAS 9016-87-9) LISTED Superfund Amendments and Reauthorization Act of 1986(SARA) Hazard categories Immediate Hazard-Yes Delayed Hazard-Yes Fire Hazard-No Pressure Hazard-No Reactivity Hazard-No SARA 302 Extremely No hazardous substance SARA 3111312 Hazardous Yes chemical SARA 313(TRI reporting) Chemical name CAS number %by wt. Polymethylene polyphenyl isocyanate 9016-87-9 30-60 Methylene diphenyl diisocyanate 101-68-8 20-40 Other federal regulations Clean Air Act(CAA)Section 112 Hazardous Air Pollutants(HAPs)List Methylene diphenyl diisocyanate(CAS 101-68-8) Polymethylene polyphenyl isocyanate(CAS 9016-87-9) Clean Air Act(CAA)Section 112(r)Accidental Release Prevention(40 CFR 68.130) Not regulated. Safe Drinking Water Act Not regulated. (SDWA) Food and Drug Not regulated. Administration(FDA) US state regulations WARNING: This product contains chemicals known to the State of California to cause cancer. US.Massachusetts RTK-Substance List Methylene diphenyl diisocyanate(CAS 101-68-8) Polymethylene polyphenyl isocyanate(CAS 9016-87-9) US.New Jersey Worker and Community Right-to-Know Act Methylene diphenyl diisocyanate(CAS 101-68-8) 500 Ibs Polymethylene polyphenyl isocyanate(CAS 500 Ibs 9016-87-9) US,Pennsylvania RTK-Hazardous Substances Methylene diphenyl diisocyanate(CAS 101-68-8) Polymethylene polyphenyl isocyanate(CAS 9016-87-9) US.Rhode Island RTK Methylene diphenyl diisocyanate(CAS 101-68-8) Polymethylene polyphenyl isocyanate(CAS 9016-87-9) US.California Proposition 65 US-California Proposition 65-Carcinogens&Reproductive Toxicity(CRT): Listed substance Acetaldehyde(CAS 75-07-0) Cobalt(CAS 7440-48-4) Furan(CAS 110-00-9) Propylene oxide(CAS 75-56-9) International Inventories Country(s)or region Inventory name On inventory(yes/no)" Australia Australian Inventory of Chemical Substances(AICS) Yes Rapid set insulation Adhesive Part A SDS US 914047 Version#:01 Revision date:- Issue date:10-September-2013 6/7 Country(s)or region Inventory name On inventory(yes/no)- Canada Domestic Substances List(DSL) Yes Canada Non-Domestic Substances List(NDSL) No China Inventory of Existing Chemical Substances in China(IECSC) Yes Europe European Inventory of Existing Commercial Chemical Yes Substances(EINECS) Europe European List of Notified Chemical Substances(ELINCS) No Japan Inventory of Existing and New Chemical Substances(ENCS) Yes Korea Existing Chemicals List(ECL) Yes New Zealand New Zealand Inventory Yes Philippines Philippine Inventory of Chemicals and Chemical Substances Yes (PICCS) United States&Puerto Rico Toxic Substances Control Act(TSCA)Inventory Yes 'A"Yes"indicates this product complies with the inventory requirements administered by the governing country(s). A"No'indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 10-September-2013 Revision date - Version# 01 Further information I-Safety Glasses, Gloves, Dust,Vapor Respirator NFPA Ratings 0 References ACGIH EPA:Acquire database NLM: Hazardous Substances Data Base US. IARC Monographs on Occupational Exposures to Chemical Agents National Toxicology Program(NTP)Report on Carcinogens ACGIH Documentation of the Threshold Limit Values and Biological Exposure Indices ESIS(European chemical Substances Information System) HSDB®-Hazardous Substances Data Bank IARC Monographs.Overall Evaluation of Carcinogenicity Disclaimer The information in the sheet was written based on the best knowledge and experience currently available. Rapid set insulation Adhesive Part A SDS US 914047 Version#:01 Revision date:- Issue date:10-September-2013 7/7 0 SAFETY DATA SHEET 1. Identification Product identifier Rapid set insulation Adhesive Part B Other means of identification Not available. Recommended use Industrial use. Recommended restrictions None known. Manufacturer/Importer I Supplier/Distributor information Manufacturer/Supplier: IB Roof Systems 2877 Chad Drive Eugene,Oregon 97408 UE General Information: 800-426-1626 Emergency: 2. Hazard(s) identification Physical hazards Not classified. Health hazards Sensitization,skin Category 1 OSHA defined hazards Not classified. Label elements Signal word Warning Hazard statement May cause an allergic skin reaction. Precautionary statement Prevention Avoid breathing mist or vapor.Contaminated work clothing should not be allowed out of the workplace.Wear protective gloves/protective clothing/eye protection/face protection. Response If on skin:Wash with plenty of water. If skin irritation or rash occurs:Get medical advice/attention. Wash contaminated clothing before reuse. Storage Stare away from incompatible materials. Disposal Dispose of contents/container in accordance with local/regional/national/intemational regulations. Hazard(s)not otherwise Not classified. classified(HNOC) 3. Composition/information on ingredients Mixtures Chemical name CAS number % Dimethyl silicone polymer with 67762-90-7 1 -<3 silica Dipropylene glycol 25265-71-8 1 -<3 N-(3-(trimethoxysilyl)propyl)e 1760-24-3 1 -<3 thylenediamine Composition comments The components are not hazardous or are below required disclosure limits.All concentrations are in percent by weight unless ingredient is a gas.Gas concentrations are in percent by volume. 4. First-aid measures Inhalation If symptomatic,move to fresh air. Get medical attention if symptoms persist. Skin contact Wash skin with soap and water.Get medical attention promptly if symptoms occur after washing. Eye contact Any material that contacts the eye should be washed out immediately with water.If easy to do, remove contact lenses.Get medical attention promptly if symptoms occur after washing. Ingestion Seek medical advice. Rapid set insulation Adhesive Part B SIDS US 914049 Version#:01 Revision date:- Issue date: 10-September-2013 1 /6 Most important Sensitization. symptoms/effects,acute and delayed Indication of immediate Treat symptomatically. medical attention and special treatment needed General information In the case of accident or if you feel unwell,seek medical advice immediately(show the label where possible). 5. Fire-fighting measures Suitable extinguishing media Water.Water fog.Foam. Dry chemical powder.Carbon dioxide(CO2). Unsuitable extinguishing No restrictions known. media Specific hazards arising from Combustion products include:Carbon oxides. Nitrogen Oxides(NOx).Cyanides.Organic acid the chemical vapors. Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire. and precautions for firefighters Fire-fighting Move container from fire area if it can be done without risk. equipmentlinstructions 6.Accidental release measures Personal precautions, Wear appropriate personal protective equipment(See Section 8). protective equipment and emergency procedures Methods and materials for Absorb spill with vermiculite or other inert material,then place in a container far chemical waste for containment and cleaning up proper disposal.Flush area with water. Prevent runoff from entering drains,sewers,or streams. Dike for later disposal. Environmental precautions Avoid discharge into drains,water courses or onto the ground. 7. Handling and storage Precautions for safe handling Observe good industrial hygiene practices.Wear appropriate personal protective equipment(See Section 8). Conditions for safe storage, Keep container closed.Keep away from incompatible material. including any incompatibilities 8. Exposure controls/personal protection Occupational exposure limits No exposure limits noted for ingredient(s). Biological limit values No biological exposure limits noted for the ingredient(s). Exposure guidelines No exposure standards allocated. Appropriate engineering Ensure adequate ventilation,especially in confined areas. controls Individual protection measures,such as personal protective equipment Eye/face protection If contact with material may occur,safety glasses and face shield are recommended. Skin protection Hard protection Chemical resistant gloves are recommended. Be aware that the liquid may penetrate the gloves. Frequent change is advisable. Other Wear chemical-resistant gloves,footwear and protective clothing appropriate for risk of exposure. Contact glove manufacturer for specific information. Respiratory protection Not normally needed. In case of inadequate ventilation or risk of inhalation of vapors,use suitable respiratory equipment. Thermal hazards Wear appropriate thermal protective clothing,when necessary. General hygiene Always observe good personal hygiene measures, such as washing after handling the material considerations and before eating,drinking,and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Colorless viscous liquid. Physical state Liquid. Form Liquid. Color Colorless, Odor Polyether. Rapid set insulation Adhesive Part B SDS US 914049 Version#:01 Revision date:- Issue date:10-September-2013 2/6 Odor threshold Not available. PH 9-10 Melting point/freezing point Not available. Initial boiling point and boiling Not available. range Flash point >350.0°F(> 176.7`C)Pensky-Martens Closed Cup Evaporation rate Not available. Flammability(solid,gas) Not available. Upper/lower flammability or explosive limits Flammability limit-lower Not available. (°yo) Flammability limit-upper Notavailable. N Explosive limit-lower I%) Not available. Explosive limit-upper(%,) Not available. Vapor pressure Not available. Vapor density Not available. Relative density 0.98 Solubility(ies) Not available. Partition coefficient Not available. (n-octanol/water) Auto-ignition temperature Not available. Decomposition temperature Not available. Viscosity 3200-11800 cP Other information Percent volatile <0.15 10. Stability and reactivity Reactivity The product is stable and non reactive under normal conditions of storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous Hazardous polymerization does not occur. reactions Conditions to avoid Contact with incompatible materials. Elevated temperatures. Moisture. Incompatible materials Strong oxidizing agents.Isocyanates.Water.Aluminum.Brass.Copper.Galvanized metals.Tin. Zinc. Hazardous decomposition No hazardous decomposition products are known. products 11. Toxicological information Information on likely routes of exposure Ingestion No harmful effects expected in amounts likely to be ingested by accident. Inhalation Under normal conditions of intended use,this material is not expected to be an inhalation hazard. Skin contact Prolonged or repeated contact may dry skin and cause irritation.May cause sensitization by skin contact. Eye contact May cause temporary eye irritation. Symptoms related to the Sensitization. physical,chemical and toxicological characteristics Information on toxicological effects Acute toxicity Direct contact with eyes may cause temporary irritation. Rapid set insulation Adhesive Part B SDS us 914049 Version#:01 Revision date:- Issue date: 10-September-2013 3/6 Components Species Test Results Dipropylene glycol(CAS 25265-71-8) Acute Other LD50 Rat 10.56 g/kg Skin corrosionlirritation Not classified. Serious eye damage/eye Not classified. irritation Respiratory sensitization Not classified. Skin sensitization May cause an allergic skin reaction. Germ cell mutagenicity Not classified. Carcinogenicity Not available. Reproductive toxicity Not classified. Specific target organ toxicity- Not classified. single exposure Specific target organ toxicity- Not classified. repeated exposure Aspiration hazard Not applicable. Chronic effects Not classified. 12. Ecological information Ecotoxicity The product is not classed as environmentally hazardous.However,this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Components Species Test Results Dipropylene glycol(CAS 25265-71-8) Aquatic Fish LC50 Goldfish(Carassius auratus) >=5000 mg/I,24 hours Persistence and degradability No data available. Bioaccumulative potential No data available. Mobility in soil Not available. Other adverse effects No other adverse environmental effects(e.g.ozone deplefion, photochemical ozone creation potential,endocrine disruption,global warming potential)are expected from this component. 13. Disposal considerations Disposal instructions Dispose of contents/container in accordance with local/regionaUnational/intemational regulations. When this product as supplied is to be discarded as waste,it does not meet the definition of a RCRA waste under 40 CFR 261. Hazardous waste code The waste code should be assigned in discussion between the user,the producer and the waste disposal company. Waste from residues/unused Dispose of in accordance with local regulations. products Contaminated packaging Since emptied containers may retain product residue,follow label warnings even after container is emptied. 14. Transport information DOT Not regulated as a hazardous material by DOT. IATA Not regulated as a dangerous good. IMDG Not regulated as a dangerous good. Transport in bulk according to This substance/mixture is not intended to be transported in bulk. Annex II of MARPOL 73/78 and the IBC Code 15. Regulatory information US federal regulations This product is hazardous according to OSHA 29 CFR 1910.1200. All components are on the U.S.EPA TSCA Inventory List. Rapid set insulation Adhesive Part B SDS US 914049 Version#:01 Revision date:- Issue date: 10.September-2013 4/6 TSCA Section 12(b)Export Notification(40 CFR 707,Subpt.D) Not regulated. US.OSHA Specifically Regulated Substances(29 CFR 1910.1001-1050) Not listed. CERCLA Hazardous Substance List(40 CFR 302.4) Not listed. Superfund Amendments and Reauthorization Act of 1986(SARA) Hazard categories Immediate Hazard-Yes Delayed Hazard-No Fire Hazard-No Pressure Hazard-No Reactivity Hazard-No SARA 302 Extremely No hazardous substance SARA 311/312 Hazardous Yes chemical SARA 313(TRI reporting) Not regulated. Other federal regulations Clean Air Act(CAA)Section 112 Hazardous Air Pollutants(HAPs)List Not regulated. Clean Air Act(CAA)Section 112(r)Accidental Release Prevention(40 CFR 68.130) Not regulated. Safe Drinking Water Act Not regulated. (SDWA) Food and Drug Not regulated. Administration(FDA) US state regulations WARNING:This product contains a chemical known to the State of California to cause cancer. US.Massachusetts RTK-Substance List Not regulated. US.New Jersey Worker and Community Right-to-Know Act Not regulated. US.Pennsylvania RTK-Hazardous Substances Dipropylene glycol(CAS 25265-71-8) US.Rhode Island RTK Not regulated. US.California Proposition 65 US-California Proposition 65-Carcinogens&Reproductive Toxicity(CRT): Listed substance Acetaldehyde(CAS 75-07-0) Cobalt(CAS 7440-484) Furan(CAS 110-00-9) Propylene oxide(CAS 75-56-9) International Inventories Country(s)or region Inventory name On inventory(yes/no)* Canada Domestic Substances List(DSL) No Canada Non-Domestic Substances List(NDSL) Yes United States&Puerto Rico Toxic Substances Control Act(TSCA)Inventory Yes "A"Yes"indicates this product complies with the inventory requirements administered by the governing country(s). A"No"indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 10-September-2013 Revision date - Version# 01 Further information I-Safety Glasses, Gloves, Dust,Vapor Respirator Rapid set insulation Adhesive Part B SDS US 914049 Version#:01 Revision date:- Issue date:10-September-2013 6/6 NFPA Ratings 0 References ACGIH EPA:Acquire database NLM: Hazardous Substances Data Base US.IARC Monographs on Occupational Exposures to Chemical Agents National Toxicology Program(NTP)Report on Carcinogens ACGIH Documentation of the Threshold Limit Values and Biological Exposure Indices ESIS(European chemical Substances Information System) HSDB®-Hazardous Substances Data Bank [ARC Monographs.Overall Evaluation of Carcinogenicity Disclaimer To the best of our knowledge,the information contained herein is accurate.However, neither the above named supplier nor any of its subsidiaries assumes any liability whatsoever for completeness of the information contained herein.Final determination of suitability of any material is the sole responsibility of the user.All materials may present unknown hazards and should be used with caution.Although certain hazards are described herein,we cannot guarantee that these are the only hazards that exist. Rapid set insulation Adhesive Part B SDS US 914049 Version#:01 Revision date:- Issue date:10-September-2013 616