HomeMy WebLinkAboutCO2013-1803UNDER CONSTRUCTION
CORRECTION LETTER
PW OR LD NEEDED
TD NO LETTER
C/O CHECK LIST
C/O PERMIT # P13- 180
ADDRESS: -�40 .�- r1C�l>1 6Z I l�iC
BUSINESS NAME: C- decd L((—+s I -L,llC
BUSINESS /PROPERTY
CHANGE NAME /OWNER NEW CONST /ADDITION PERMIT #
NEW TENANT /OCCUPANT ::Z REMODEL /ALTERATION PERMIT #
ISSUE DATE
/ FINAL DATE
'1/ 1. APPLICATION FORM COMPLETED
V"2. ZONING MAP COPIED & WORKORDER FORM COMPLETED
V 3. ZONING CHECKED & COMPLETED ON APPLICATION m
V 4. BUILDING INSPECTION SCHEDULED: DATE 5I a.),'TIME �' I
5. FIRE DEPT. INSPECTION SCHEDULED: DATE 5 a� IJTIME
INSPECTOR
6. HEALTH INSPECTION: DATE TIME
7. PUBLIC WORKS INSPECTION: E -MAIL DATE
�- 8. LOT DRAINAGE INSPECTION: E -MAIL DATE
9. CORRECTION LETTER SENT: DATE
✓/10. BUILDING INSPECTORS SIGN OFF LETTER: YES / NO
11. FIRE DEPARTMENTS SIGN OFF LETTER: YES / NO
12. HEALTH DEPARTMENT SIGN OFF
13. PUBLIC WORKS SIGN OFF
114. LOT DRAINAGE SIGN OFF
15. LANDSCAPING SIGN OFF
�/. 16. BUILDING OFFICIALS SIGNATURE
/17. C/O ISSUED ELECTRIC RELEASE:
COPY: 111N .1.4,9@11 -
MAILED: JUN 172'-LUIJ
* CONDITIONS TO BE TYPED ON C /O: YES / NO
O;\FOR MS\)SCOINFORMATION\CKL IST
12130/04 \ Rev.11\11
DATE OF ISSUANCE:
Ull i 11�1e + 6— 00 5
'r E x ,t s PERMIT # I
MAY 2 U 2013
12 -nol
CERTIFICATE OF OCCUPANCY REO UEST
NO FEE REQUIRED IF CERTIFICATE OF OCCU NCY\IS ASSOCL4TED jWITH ANA TIVE CURRENT BUILDING PERMIT
ADDRESS OF OCCUPANCY-,' , A d00�\ cal '�� SUITE #
LOT: BLOCK: SUBDIVISION:
" "CERTIFICATE Q—C—C~CY N�H.L kOT BESUED WITHOUT LEGAL DESCRIPTION ""
1�0 NAME OF BUSINESS: `` roayC Qom, -
-� NEW OCCUPANT: YES NO ✓ NEW BUILDING/PROPERTY OWNER: YES NO
NEW BUILDING: YES NO 4 -� NAME CHANGE: BUSINESS YES — X NO
NUMBER OF EMPi.nv>RF.c :^ OQ I , FREIGHT FORWARDING: YES NO
-TwW BUSINESS OWNER: YES NO
TYPE OF BUSINESS:` ���1 1 �`�R�UZ+d2L SQUARE FOOTAGE:,
(Example: Retail, Office, Warehouse)
NAME OF TENANT:
CURRENT MAILI ADDRESS: c Xi \ �J lJ CZ y i \ 6� ^^\ ��`y� • Q r�
CITY /STATE /ZI • 'tJ �J PHONE NUMBER: Q - l0t l
PROPERTY OWNER: _4\ c—�E��e -,�\ �3 �� Q _
MAILING
CITY /STATE /ZIP?�p S�'�1`c,C9 11�� X `� �� PHONE NUMBER:E If1l - (A8t - ) 14-�
♦ IS YOUR BUSINESS SUBJIECT TO SALES TAX LAW? (if yes, provide copy of Sales Tax Certificate) - - - - YES �� NO
♦ WILL THERE BE ALCOHOLIC BEVERAGE SALES? (if yes, provide copy of Alcoholic Beverage Permit) -YES NO t�
♦ PERMITS ARE REQUIRED FOR SIGNS. WILL ANY SIGNS BE INSTALLED? - - - - - - - - - - - - - - - - - - - YES NO
♦ WILL BUSINESS GENERATE ANY INDUSTRIAL WASTE DISCHARGE TO SEWER SYSTEM? ----- YES NO4/
♦ WILL OUTSIDE REFUSE /RECYCLING /COMPACTING CONTAINERS BE NECESSARY?
(if yes, screening is required)---------------------------------------------------- - - - - -- -YES ENO
WILL THERE B ANY OUTSIDE STORAGE, DISPLAY, USE OR DINING: - - - - - - - - - - - - - - - - - - - - - YES NO
♦ WILL ANY ALTERATIONS BE MADE TO THE SITE OR BUILDING? - - - - - - - - - - - - - - - - - - - - - - - - - YES NO
♦ IS BUILDING SPRINKLERED? ------------------------------------------------------- YES ��NO � �1 _
♦ WILL BUSINESS STORE OR HANDLE HAZARDOUS MATERIALS OR LIQUIDS? Scar\1�,t6 it—)-6 rn i- 1Y�`F-�
(if yes, provide list of types & quantities, along with material safety data sheets) - - - - - - - - - - - - - - - - - - - - - - YES NO //
I HEREBY CERTIFY THAT THE FOREGOING IS CORRECT TO THE BEST OF MY KNOWLEDGE AND THE SAID
OCCUPANCY IS IN CONFORMANCE WITH THE INFORMATION HEREIN SET F
(If access to the building/space is not provided at the time of the scheduled inspection, $42.00 _i.spectiop f be charged)
FOR QUEST NS PLEAS CALL (8 1 0 -3
PRINT NAME: `�. SIGNATU
PHONE #: O '\� 1 EMAIL:
(OVER)
Development Services Department
The City of Grapevine * P.O. Box 95104 * Grapevine, Texas 76099 * (817) 410 -3165
Fax (817) 410 -3012 * www.grapevinetexas.gov
O :FYIRMSUD9AFFUCATIOM151CIOAppfica im
31n2(W11R,A.d51W, 5106, L07,4U09
TEXAS SALES TAX
Texas Sales Tag is charged and collected on sales within the State and City of Grapevine, Texas of "taxable items." Taxable
items include both tangible personal property, specified services. If you are in a business that will be selling "taxable items"
within the City of Grapevine, Texas you will be required to collect State and Local Sales Tax in the amount of 8.25 %.
A "Seller or Retailer" means a person engaged in the business of malting sales of "taxable items ", the receipts from which are
included in the measure of sales or use tax.
The term, "place of business" includes any location at which three or more orders are received by the "Seller or Retailer in
a calendar year. If an order is received at the place of business of a retailer in Texas, but delivery or shipment is made from a
location within the state other than the retailer's place of business. State and local sales tax is due and is allocated to the city
where the order was received.
I have read the above and I understand that I will be required to provide a copy of the Sales Tax Permit to the City of
Grapevine, Texas if the circumstance applies to my business.
ADDR
CITY,
xFOR OFFICE USE ONLY
TYPE OF CONSTRUCTION : OCCUPANCY: DIVISION:
ZONING DISTRICT: CONDITIONAL USE:
PERMITTED USE:
BUILDING DEPARTMENT:
ZONING APPROVAL: �(
FIRE DEPARTMENT:
LOT DRAINAGE INSPECTION:
PUBLIC WORKS DEPARTMENT:
HEALTH DEPARTMENT:
LANDSCAPING APPROVAL:
APPROVAL FOR ISSUANCE:
O: F:I RIILS\DSAPPLICATIONSICIOAppfic. iw
3 1=0011R,v6,a:4/e6, SAW% 2187,4(09
DATE: XJ 91
DATE:
DATE:
3 I
DATE:
DATE:
DATE:
DATE:
DATE:
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_ (R -07/17) TEXAS SALES AND USE TAX PERMIT
This permit is not transferable, and this side must be prominently displayed in your place of business,
Merchants Acopyof this permit does not replace a resale or exemption certificate. You will be responsible
for sales tax unless you have a valid resale,bxemption certificate on file.
TAXPAYER NAME, BUSINESS LOCATION NAME, and PHYSICAL LOCATION
GT PRODUCTS, INC.
GT PRODUCTS, INC.
501 INDUSTRIAL BLVD
GRAPEVINE TX 76051
NAICS CODE: 325211 DESCRIPTION ON NEXT LINE:
You must obtain a new permit if there is a change of
ownership, location, or business location name.
Type of permit
SALES AND USE TAX
Taxpayer number
1- 75- 2400178 -5
Location number
00002
First business date
to /o1/ 1gg6
Plastics Material and Resin MFG
WE SHOW THIS BUSINESS IN THE FOLLOWING LOCAL SALES TAX AUTHORITIES:
CITY: GRAPEVINE EFF: 10/01/1996
SPD: GRAPEVINE CRIME CONTROL EFF: 04/01 /2007 SUSAN COMBS
Comptroller of Public Accounts
YOU MAY NEED TO COLLECT SALES AND,OR USE TAXFOR OTHER LOCAL TAXING AUTHORITIES DEPENDING ON YOUR TYPE OF BUSINESS.
If you have any questions regarding sales tax, you may contact the Texas State Comptroller's field office
in your area or call 1- 800 - 252 -5555, toll free, nationwide. The Austin number is 512/463 -4600.
........................
DETACH HERE AND PROMINENTLY DISPLAY YOUR PERMIT ONLY
01- 300 -P4
IS THE INFORMATION PRINTED ON THIS PERMIT INCORRECT?
The information printed on your permit must be accurate and current. To make corrections, you may detach and complete ONLY the information in
the form below which is incorrect, and mail it to COMPTROLLER OF PUBLIC ACCOUNTS
111 E. 17th Street
Austin, TX 78774 -0100
MAKING CHANGES TO LOCAL TAXING AUTHORITIES OR BUSINESS DESCRIPTION LISTED ON THIS PERMIT
• You will need to contact us to correct the local taxing authorities for this business location. Contact your city /transit authority /county /special purpose
district if you are unsure if your business is located within that taxing jurisdiction. We can assist you in determining your local sales and use tax
responsibilities, and the appropriate rate for each local taxing authority. Publication 94 -105, "Guidelines for Collecting Local Sales and Use Tax" and
Publication 96 -132, "Texas Sales and Use Tax Rates" are available on the Comptroller's web. site at www.window.state.tx.us/taxinfo /local /.
• Visit us online at www. window. state. tx. us /taxinfo /sales /naics_coding.htmI if you need to correct the description of your business printed on the front of
this permit.
MORE INFORMATION ABOUT YOUR PERMIT
• You must prominently display this permit in your place of business.
• The information on your permit is public information.
• You cannot use this permit or a copy of it as a resale or exemption certificate.
• If the location specified on this permit is closed, return this permit to the Comptroller of Public Accounts and indicate the date of the last business
transaction.
• Depending on your type of business, you may need to collect sales and /or use tax for other local taxing authorities not listed on this permit.
TEXAS SALES AND USE TAX PERMIT
Taxpayer name shown on the permit
GT PRODUCTS, INC.
Taxpayer number shown on the permit
Location number shown on the permit
. 17524001785
00002
Correct business location name
Correct business location (no P.O. Box or directions accepted)
Change your mailing address and phone number,
•
add a business location, change a business address, or
close one or more business locations online at
City
State
ZIP code
https :lAvww. window. state. txus /accmaint fchangeaddress,html
Correct taxpayer name
Daytime phone (Area code and number)
Correct mailing address
•
City
•
State
ZIP code
Federal Employer Identification number
If you are no longer in business, enter the date of your last business transaction.
4S8F [' °jie
'� �a
Taxpayer or authorized agent
sign
here
Date
CERTIFICATE OF OCCUPANCY
WORKORDER
PERMIT # 13- 18 0 �)
ADDRESS OF INSPECTION: 1601 l i! ` t ( ' -b I lac`
DATE OF INSPECTION:
TIME OF INSPECTION:
NAME OF BUSINESS:
TYPE OF BUSINESS:
USE OF BUILDING AND /OR PREMISES: nLK46,c4u P.a Yom_
REASON FOR APPL
CONTACT PERSON:
TELEPHONE NUMBER: B 12 - � R) ' ( L I a�
COMMENTS/VIOLATIONS:
o�< SA, la -� s
* *TO BE FILLED OUT BY BUILDING OFFICIAL **
ZONING DISTRICT OF INSPECTION LOCATION: L_s^___
TYPE OF BUILDING: GROUP AND DIVISION:
ZONING RESTRICTIONS:
O. FORMS`DSCOINFORMATION,WORKORDER
12 30?(A Rev. 1 /1 712 00 6
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GT Products, Inc. - Primary Facility
501 Industrial Blvd,
Grapevine, Tx. 76051
May 20, 2013
Hazardous Chemical Inventory
Flammable material in less than or equal to S gallon containers located in NFPA -rated
flammable cabinets were omitted, Consult our Site Map submitted in the 2012 Tier II report
for area locations
Hazardous Material
Lbs
1- Ethynylcyclohexanol
1587
DC-CF-2403
10582
X5921
12582
X5835
14637
X6147
1472
Silbond Pure
�)
DF581
Ethyl Alcohol, Reagent Grade
3
Heptane
e
Hexane
�0 8
Toluene
b
VM &P Naptha
a7�L
Acetone
Xylene
L4410
Odorless Mineral Spirits
'2('6
Tetra -n -butyl titinate
X6068
281
OFS -2306 (� s e {, I fri one �A. ti/y„e
301/l/
Hexamethyldisilizane
3
Methy Ethyl Ketone
g S"
KBE -903
KBM -13
.2
Cata -check 860
'275—
Cata -check 820
' 9 x
Divinyltetramethyldisiloxane
S
Silbond 40
1-7,5'
2- methyl -3- butin -2 -ol
380
Tetra methyldisiloxane
12`1
Methoxytrimethylsilane
15- L
Ease Release
2 S- I
FC Ether
F50
Material in Staging Area
awaiting shipment to our sister
facility in Justin, Tx.
Materials are located in our
Flammable Storage Room. The
amounts listed are from our
inventory database.
SIGMA- ALDRICH
1. PRODUCT AND COMPANY IDENTIFICATION
Product name
Product Dumber
Brand
Supplier
Telephone
Fax
Emergency Phone # (For
both supplier and
manufacturer)
Preparation Information
2. HAZARDS IDENTIFICATION
Emergency Overview
OSHA Hazards
Flammable liquid
1.1,3,3- Tetramethy1disiloxane
92231
Aldrich
Sigma- Aldrich
3050 Spruce Street
SAINT LOUIS MO 63103
USA
+1 800 -325 -5832
+1 800- 325 -5052
(314) 776 -6555
Sigma Aldrich Corporation
Product Safety - Americas Region
1 -800- 521 -8956
GHS Classification
Flammable liquids (Category 2)
Acute toxicity, Oral (Category 5)
GHS Label elements, including precautionary statements
Pictogram
Signal word
Hazard statement(s)
H 225
H 303
Hanger
Highly flammable liquid and vapour.
May be harmful if swallowed.
sigma- aldr/ch.
Material Safety Data ShE
Version
Revision Date 10/08:.
Print Date 05120/:
Precautionary statement(s)
P210 Keep away from heat/sparks /open flameslhot surfaces. - No smoking.
HMIS Classification
Health hazard:
Flammability:
Physical hazards:
NFPA Rating
Health hazard:
Fire:
Reactivity Hazard:
Potential Health Effects
Inhalation
Skin
Eyes
1
3
0
0
3
0
May be harmful if inhaled. May cause respiratory tract irritation.
May be harmful if absorbed through skin. May cause skin irritation.
May cause eye irritation.
Ndrich - 9.2231 Pang 1 r
Ingestion
3. COMPOSITIONAINFORMATIO
Synonyms
Formula
Molecular Weight
May be harmful if swallowed.
V INGREDIENTS
Siloxane HSi2
C4H 14OSi2
134.32 gimol
Component Concentration
1,1,3,3- Tetramethyldisiloxane
CAS -No. 3277 -26 -7 _
EC-No. 221 - 906 -4 i
4. FIRST AID MEASURES
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance. Move out of dangerous area.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Flush eyes with water as a precaution.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult e
physician.
5. FIREFIGHTING MEASURES
Suitable extinguishing media
For small (incipient) fires, use media such as "alcohol" foam, dry chemical, or carbon dioxide. For large fires, apply we
from as far as possible. Use very large quantities (flooding) of water applied as a mist or spray; solid streams of water
may be ineffective. Cool all affected containers with flooding quantities of water.
Special protective equipment for firefighters
Wear self contained breathing apparatus for fire fighting if necessary.
Hazardous combustion products
Hazardous decomposition products formed under fire conditions. - Carbon oxides, silicon oxides
Further information
Use water spray to cool unopened containers.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions
Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove all
sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive
concentrations. Vapours can accumulate in low areas.
Environmental precautions
Prevent further leafage or spillage if safe to do so. Do not let product enter drains.
Methods and materials for containment and cleaning up
Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet - brushing and place in
container for disposal according to local regulations (see section 13).
7. HANDLING AND STORAGE
Precautions for safe handling
Avoid inhalation of vapour or mist.
Aldrirh - P22R1 Pan.
Use explosion -proof equipment, Keep away from sources of ignition -No smoking. Take measures to prevent the bull,
up of electrostatic charge.
Conditions for safe storage
Store in cool place. Keep container tightly closed in a dry and well - ventilated place. Containers which are opened mu:
be carefully resealed and kept upright to prevent leakage.
Store under inert gas. Moisture sensitive.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Contains no substances with occupational exposure limit values.
Personal protective equipment
Respiratory protection
Where risk assessment shows air - purifying respirators are appropriate use a full -face respirator with multi - purpose
combination (US) or type ABEK (EN 14387) respirator cartridges as a backup to engineering controls. If the
respirator is the sole means of protection, use a full -face supplied air respirator. Use respirators and components
tested and approved under appropriate government standards such as NIOSH (US) orCEN (EU).
Hand protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching
glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in
accordance with applicable laws and good laboratory practices. Wash and dry hands.
Eye protection
Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate
government standards such as NIOSH (US) or EN 166(EU).
Skin and body protection
impervious clothing, Flame retardant antistatic protective clothing, The type of protective equipment must be
selected according to the concentration and amount of the dangerous substance at the specific workplace.
Hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end
workday.
Appearance
Form
Colour
Safety data
pH
Melting
point/freezing point
Boiling point
clear, liquid
colourless
no data available
Melting point/range: < -78 'C (< -108 °F)
70-71 °C (158 -160 °F) -lit.
Flash point -26 'C ( -15 `F) - closed cup
Ignition temperature 240 'C (464 "F)
Autoignition no data available
temperature
Lower explosion limit 0.8 %(V)
Upper explosion limit 62.9 %(V)
Vapour pressure 500 hPa (375 mmHg) at 50 'C (122 -F)
150.0 hPa (112.5 mmHg) at 20 "C (68'F)
Density
Water solubility
0.76 g /mL at 25 °C (77 'F)
no data available
Adich - C12211 PanP'i r
Partition coefficient:
n -octa n of /water
Relative vapour
density
Odour
Odour Th reshold
Evaporation rate
no data available
no data available
no data available
no data available
no data available
10. STABILITY AND REACTIVITY
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
Vapours may form explosive mixture with air.
Conditions to avoid
Heat, flames and sparks. Extremes of temperature and direct sunlight.
Materials to avoid
Strong acids, Strong bases, Strong oxidizing agents
Hazardous decomposition products
Hazardous decomposition products formed under fire conditions. - Carbon oxides, silicon oxides
Other decomposition products -no data available
11. TOXICOLOGICAL INFORMATIO
Acute toxicity
Oral LD50
LD50 Oral - mouse - 3;000 mg /kg
Inhalation LC50
LC50 Inhalation - mouse - 2 h - 400,000 mg /m3
Dermal LD50
no data available
Other information on acute toxicity
no data available
Skin corrosionlirritation
no data available
Serious eye damage /eye irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
IARC: No component of this product present at levels greater than or equal to 0.1 % is identified as
probable, possible or confirmed human carcinogen by IARC.
ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by ACGIH.
NTP: No component of this product present at levels greater than or equal to 0.1 % is identified as a
known or anticipated carcinogen by NTP.
Addrirh - CO231 0— 4 ,
OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by OSHA.
Reproductive toxicity
no data available
Teratogeni city
no data available
Specific target organ toxicity - single exposure (Globally Harmonized System)
no data available
Specific target organ toxicity - repeated exposure (Globally Harmonized System)
no data available
Aspiration hazard
no data available
Potential health effects
Inhalation May be harmful if inhaled. May cause respiratory tract irritation.
Ingestion Maybe harmful if swallowed.
Skin May be harmful if absorbed through skin. May cause skin irritation.
Eyes May cause eye irritation.
Sighs and Symptoms of Exposure
Material may form a siloxane polymer on the skin, eyes, or in the lungs. In the event of direct contact of the liquid with
these tissues, seek medical attention., Dizziness. Headache, To the best of our knowledge, the chemical, physical, an
toxicological properties have not been thoroughly investigated.
Synergistic effects
no data available
Additional Information
RTECS: JN 1000000
12. ECOLOGICAL INFORMATION
Toxicity
no data available
Persistence and degradability
no data available
Bioaccumulabve potential
no data available
Mobility in soil
no data available
PBT and vPvB assessment
no data available
Other adverse effects
no data available
13. DISPOSAL CONSIDERATIONS
Product
Bum in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this mated
is highly flammable. Offer surplus and non - recyclable solutions to a licensed disposal company. Contact a licensed
professional waste disposal service to dispose of this material.
A drirh . P2211 PArla r
Contaminated packaging
Dispose of as unused product.
14. TRANSPORT INFORMATI
DOT (US)
UN number: 1993 Class: 3 Packing group: II
Proper sh ipping name: Flammable liquids, n.o.s. (1,1,3,3 - Tetramethyldisiloxane)
Marine pollutant: No
Poison Inhalation Hazard: No
IMDG
UN number: 1993 Class: 3 Packing group: II EMS -No: F -E, S -E
Proper shipping name: FLAMMABLE LIQUID, N.C.S. (1,1,3,3 - Tetramethyldisiloxane)
Marine pollutant: No
IATA
UN number: 1993 Class: 3 Packing group: II
Proper shipping name: Flammable liquid, n.o.s. (1,1,3,3 - Tetramethyldisiloxane)
15. REGULATORY INFORMATION!
OSHA Hazards
Flammable liquid
SARA 392 Components
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302.
SARA 313 Components
SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the thresl
(De Minimis) reporting levels established by SARA Title Ill, Section 313.
SARA 311/312 Hazards
Fire Hazard
Massachusetts Right To Know Components
No components are subject to the Massachusetts Right to Know Act.
Pennsylvania Right To Know Components
CAS -N o. Revision Date
1,1,3.3- Te tram eth yldisiloxane 3277 -26 -7
New Jersey Right To Know Components
CAS -N o. Revision Date
1,1,3,3- Tetramethyldisiloxane 3277 -26 -7
California Prop. 65 Components
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other
reproductive harm.
16, OTHER INFORMATION
Further information
Copyright 2012 Sigma - Aldrich Co. LLC. License granted to make unlimited paper copies for internal use only.
The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a
guide. The information in this document is based on the present state of our knowledge and is applicable to the
product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the
product. Sigma - Aldrich Corporation and its Affiliates shall not be held liable for any damage resulting from handling or
from contact with the above product. See www.sigma- aldrich.com and/or the reverse side of invoice or packing slip fo
additional terms and conditions of sale.
APdnrh - r{2211 0— r. ,
GT Products
1.
2.
PRODUCT GT Products° GT6147
PRODUCT AND COMPANY IDENTIFICATION
Manufactured by:
GT Products, Inc.
501 Industrial Blvd.
Grapevine, TX 76051
Date Prepared/ Revised:
Chemical Type/ Description:
HAZARDOUS INGREDIENTS
Telephone: (800) 221 -0866
(817) 481 -7113
Fax: (817) 421-1211
gtproducts.com
EMERGENCY (Chemtrec): (800) 424 -9300
06/15/11 by: Daniel Shaw
Silicone Water Repellent
Component
% (Approx.)
Exposure Limits
CAS No.
methoxy substituted
10 -20%
not established
Trade Secret
silicone resin
for methanol OSHA std is:
200 ppm, 8 hr. TWA
organotrimethoxysilan
5 -15%
not established
Trade Secret
e
for ethanol OSHA std is:
1000 ppm, 8 hr. TWA
titanium compound
.5 -3%
not established supplier recommends
Trade Secret
20 ppm, 8 hr. TWA
This product contains Methylpolysiloxanes, which can generate Formaldehyde at approximately 300 °F (150 °C)
and above, in atmospheres which contain oxygen. Formaldehyde is a skin, eye, and throat irritant, is toxic and a
potential cancer hazard.
HMIS RATING: FLAMMABILITY: 3
3. EFFECTS OF EXPOSURE
Potential Health Effects:
Ingestion:
Skin Contact:
Inhalation:
Eye Contact:
REACTIVITY:1 HEALTH:2
Ingestion will result in hydrolysis releasing methanol. Do not ingest.
May cause contact dermatitis on long exposure.
May irritate.
Will irritate.
GT6147 printed: 05/20/13 page 1 of 4
GT Products
4. FIRST AID MEASURES
Ingestion: Ingestion will result in hydrolysis producing methanol and ethanol.
Seek medical attention. Treat for methanol poisoning.
Skin: Remove with dry towel, then wash with soap and water.
Eyes: Rinse 15 minutes with running water. Seek medical attention if
irritation persists.
Inhalation: Seek fresh air if needed.
Other: Not applicable.
5. FIRE FIGHTING INFORMATION
Flash Point (Method):
<75 °F (Setaflash) Note: Flash point varies somewhat due to the
variable methanol content. Material burns poorly p[roducing significant
Si02 ash. Flame self- extinguishes when ignition source is removed.
However, the low flash of the alcohols (mainly methanol) typically
present make it a red -label flammable.
Flammability Class:
Flammable Liquid Class IB.
Flammability Limits in Air:
Not available.
Extinguishing Media:
All standard media for chemical fires.
Hazardous Combustion Products
CO, CO2, Si02, H2CO
Special Fire Fighting Notes:
Like all silicones or products containing them, GT Products° GT6147
can produce formaldehyde when strongly heated in air. Additionally,
GT Products`' GT6147 will generate methanol upon contact with water
or during improper storage.
6. ACCIDENTAL RELEASE MEASURES
Pick up spilled material with absorbent clay, then wash area thoroughly with water and detergent Scrubbing will
be required if the spilled material has been allowed to cure. Spilled material is very slippery.
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes and prolonged skin contact.
Storage: Store in cool (< 100 1F), closed and dry containers.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering Controls: Good general ventilation.
Personal Protective Equipment
Eyes: Safety glasses.
Skin: Rubber or plastic gloves as desired.
Inhalation: Respirator fitted with organic vapor cartridges if exposure causes
discomfort. This is not normally required.
GT6147 printed: 05/20/13 page 2 of 4
GT Products
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State:
Color:
Odor:
Boiling Point:
Vapor Density (air = 1):
Density:
Solubility in Water:
Clear low viscosity liquid.
Colorless.
Slight odor of methanol.
Will not boil, but rather begins decomposing at temperatures >60C.d.
All components are heavier than air. Any methanol present (or
formed) is also heavier than air though not by much (1.1x).
1.00±0.02
Negligible. Reacts with water.
10. STABILITY AND REACTIVITY
Chemical Stability:
Hazardous Polymerization:
Decomposition Products:
Materials to Avoid:
Conditions to Avoid:
Stable in the absence of contamination and moisture.
Will not occur.
Only in fire conditions or when contaminated - see section 5.
Water, acids, bases, oxidizing agents.
Keep tightly sealed to avoid contamination and exposure to
atmospheric moisture. Storage in the original container, in a cool dry
place will avoid problems.
11. TOXICOLOGICAL INFORMATION
No additional information is available. See Section 2 and Section 3.
12. ECOLOGICAL INFORMATION
None available
13. DISPOSAL CONSIDERATIONS
Disposal should be made in accordance with state and local regulations.
14. TRANSPORT INFORMATION
DOT SHIPPING NAME: "FLAMMABLE LIQUID N.O.S. — Silicone Mixture Contains and Methanol"
DOT HAZARD CLASS: Flammable Liquid.
UN /NA Number: UN1993.
GT6147 printed: 05/20/13 page 3 of 4
GT Products
15. REGULATORY INFORMATION
TSCA INVENTORY STATUS: These materials or all of their contents are listed on the Toxic
Substances Control Act (TSCA).
16. OTHER INFORMATION
We believe the above information is correct as of the date of this MSDS. However, as this information and the
conditions under which the product are used are beyond the control of GT PRODUCTS, INC., it is the user's
obligation to determine the conditions for the safe use of the product. No warranty, expressed or implied, is
hereby made.
GT6147 printed: 05/20/13 page 4 of 4
MAY /20/2013/MON 02:07 PM
MAY-09 -2013 THU 10:01 PM
FAX No,
P. 001 /001
P' 001
GT PRODUCTS PURCHASE ORDER
501 INDUSTRIAL- BLVD
&ZIP Inc. GRAPEVIN E, TX 76051
FAX 817-421 -1211
Phone: 817-481-7113
www.gtprodU0ts.00m
PLEASE CONFIRM
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R; CAR'. 1570 0pBN AVENUE.. :OX .
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Phone: 609- 695 -d." � 11
609••695 -0101 BAR
1'OI.YFILI, 301 ALUMINA T MYDRATE ALUMINA TRIHYDRA17d 8000,00 Lb .4480 LB 3584.00
8 SUMRSACKS 1000 POUNDS EACH
PLEASE coNFmK AO I THANK YOU
Number
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Date
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GE Silicones
FORMAT: USA MATERIAL SAFETY DATA SHEET
PRODUCT: DF581 SILANOL /STPD SILOXANE W /SILSESQXNS
1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION
--------------------------------------------------- --- ----- -- ------- -- --- - -- --
MANUFACTURED BY:
GE SILICONES
260 HUDSON RIVER ROAD
WATERFORD, NY 12188
EMERGENCY PHONE (24 ERS)
(518) 237 -3330
REVISED: 07/27/99
PREPARER: CE HANNI
CHEMICAL FAMILY /USE: SILICONE FLUID
FORMULA. CAS - MIXTURE
SUPPLIED BY:
GE SILICONES
260 HUDSON RIVER ROAD
WATERFORD, NY 12188
EMERGENCY PHONE (24 FIRS)
(518) 237 -3330
------------------------------------------------------------------------------
2. COMPOSITION /INFORMATION ON INGREDIENTS
----------------------------------------------- -- --- ----- ------- ----- ---- - ----
PRODUCT COMPOSITION/ APPROX. ACGIH TLV OSHA PEL
CAS REG NO_ WGT. % TWA STEL TWA STEL UNITS
- --- -- ---- -- ---- - --- - - ----- - - - --- --- - -- ---- -- ---- -- -- ---
HAZARDOUS
SILANOL /STPD SILOXANE W /ME SILSQXNS
68554 -67 -6 60 -80 NF NE NF NE NA
OCTAMETHYLCYCLOTETRASILOXANE
556 -67 -2 30 -60 5 PPM NE GE REC NE GUIDE
2. NON- HAZARDOUS
None Found
COPYRIGHT GENERAL ELECTRIC CO. page: 1
Aa
See Section 15 for description of any WHMIS Trade Secret(s).
3. HAZARDS IDENTIFICATION
EMERGENCY OVERVIEW:
WARNING!
Flammable liquid and vapor.
May be harmful if swallowed.
May irritate the skin.
May irritate the eyes.
May generate formaldehyde at temperatures greater than 150 C
(300 F). See Section 3 of MSDS for details.
Adverse liver and reproductive effects reported in animals.
Mild odor
Clear liquid
POTENTIAL HEALTH EFFECTS:
INGESTION:
May be harmful if swallowed.
SKIN CONTACT:
May cause mild skin irritation.
INHALATION:
None Known.
EYE CONTACT:
May cause mild eye irritation.
MEDICAL CONDITIONS AGGRAVATED:
None known.
SUBCHRONIC (TARGET ORGAN) EFFECTS:
Reproductive disorders.
May cause liver effects.
CHRONIC EFFECTS /CARCINOGENICITY:
This product or one of its ingredients present 0.13 or more
is NOT listed as a carcinogen or suspected carcinogen by
NTP, IARC, or OSHA_
COPYRIGHT GENERAL ELECTRIC CO. page: 2
PRODUCTS /INGREDIENTS
This space reserved for special use.
PRINCIPLE ROUTES OF EXPOSURE:
None known_
OTHER:
Ingestion: Rodents given large doses via oral gavage of
octamethylcyclotetrasiloxane (1600 mg /kg day,
14 days) developed increased liver weights
relative to unexposed control animals due to
hepatocellular hyperplasia (increased number
of liver cells which appeared normal) as well
as hypertrophy (increased cell size).
Inhalation: In inhalation studies, laboratory rodents exposed
to octamethylcyclotetrasiloxane (300 ppm five days
week, 90 days) developed increased liver weights
in female animals relative to unexposed control
animals. When the exposure was stopped, liver
weights returned to normal_ Microscopic exami-
nation of the liver cells did not show any evi-
dence of pathology. Inhalation studies utilizing
laboratory rabbits and guinea pigs showed no
effects on liver weights. Inhalation exposures
typical of industrial usage (5 -10 ppm) showed no
toxic effects in rodents.
Range finding reproductive studies were conducted
(whole body inhalation, 70 days prior to mating,
through mating, gestation and lactation)
with octamethylcyclotetrasiloxane (D4). Rats were
exposed to 70 and 700 ppm. In the 709 ppm group,
there was a statistically significant reduction in
mean litter size and in implantation sites. No D4
related clinical signs were observed in the pups and
no exposure related pathological findings were
found.
COPYRIGHT GENERAL ELECTRIC CO_ page: 3
Interim results from a two generation reproductive
study in rats exposed to 500 and 700 ppm D4
(whole body inhalation, 70 days prior to mating,
through mating, gestation and lactation) resulted
in a statically significant ecrease in live mean
litter size as well as extended periods of off-
spring delivery (dystocia). These results were
not observed at the 70 and 300 ppm dosing levels.
Preliminary results from an ongoing 24 -month
combined chronic /ongogenicity study in rats exposed
to 10, 30, 150, or 700 PPM D4 showed test - article
related effects in the kidney (male and female) and
uterus of rats exposed for 12 to 24 months. These
effects include increased kidney weight and
severity of chronic nephropathy, increased uterine
weight, increased incidence of endometrial cell
hyperplasia, and an increased incidence of
endometrial adenomas. All of these effects were
limited to the 700 PPM exposure group.
The relevance of these data to humans is unclear.
Further studies are ongoing.
In developmental toxicity studies, rats and rabbits
were exposed to octamethylcyclotetrasiloxane at
concentrations up to 700 ppm and 500 ppm
respectively. No teratogenic effects (birth
defects) were observed in either study.
Decamethylcylcopentasiloxane
Ingestion: Rodents given doses via oral gavage of decamethyl-
peatasiloxane (100 mg /kg /day for females, 400
mg /kg /day for males, 14 days) developed increased
liver weights relative to unexposed control
animals_
COPYRIGHT GENERAL ELECTRIC CO. page: 4
Inhalation: In inhalation studies, laboratory rodents exposed
to decamethylpentasiloxane (120 ppu. five days /week,
90 days) developed increased liver weights in
female animals relative to unexposed control
animals. When the exposure was stopped, iver
weights returned to normal. Microscopic
examination of the liver cells did not show any
evidence of pathology. Inhalation exposures
typical of industrial usage (5 -10 ppm) showed no
toxic effects in rodents.
Attention: Not for injection into humans.
This product contains methylpolysiloxanes which can generate
formaldehyde at approximately 300 degrees Fahrenheit (1501C)
and above, in atmospheres which contain oxygen_ Formaldehyde
is a skin and respiratory sensitizer, eye and throat irritant,
acute toxicant, and potential cancer hazard. An MSDS for
formaldehyde is available from GE Silicones.
4. FIRST AID MEASURES
INGESTION:
Do not induce vomiting. Slowly dilute with 1 -2 glasses of
water or milk and seek medical attention. Never give any-
thing by mouth to an unconscious person.
SKIN:
Wash with soap and water.
Get medical attention if irritation or symptoms from Section 3
develop.
INHALATION:
COPYRIGHT GENERAL ELECTRIC CO. page: 5
If inhaled, remove to fresh air. If not breathing give
artificial respiration using a barrier device. If breathing is
difficult give oxygen. Get medical attention.
EYES:
In case of contact, immediately flush eyes with plenty of water
for at least 15 minutes and get medical attention it irritation
persists.
NOTE TO PHYSICIAN:
None known.
5. FIRE FIGHTING MEASURES
FLASH POINT: 57 (C) 135 (F)
METHOD PMCC_
IGNITION TEMP UNK (C) UNK (F)
FLAMMABLE LIMITS IN AIR - LOWER W: NA
FLAMMABLE LIMITS IN AIR - UPPER (%-): NA
SENSITIVITY TO MECHANICAL IMPACT (YIN): NO
1- SENSITIVITY TO STATIC DISCHARGE:
Sensitivity to static discharge is expected; material has a
flash point below 200 F.
EXTINGUISHING MEDIA:
All standard firefighting media
SPECIAL FIREFIGHTING PROCEDURES:
Flammable.
Firefighters must wear NIOSH /MSHA approved positive pressure
self- contained breathing apparatus with full face mask and full
protective clothing.
6. ACCIDENTAL RELEASE MEASURES
COPYRIGHT GENERAL ELECTRIC CO. page: 6
ACTION TO BE TAKEN IF MATERIAL IS RELEASED OR SPILLED:
Wash walking surfaces with detergent and water to reduce slip-
ping hazard.
Wear proper protective equipment as specified in the protective
equipment section.
Wipe, scrape, or soak up in an inert material and put in a
container intended for flammable materials for disposal.
7. HANDLING AND STORAGE
PRECAUTIONS TO BE TAKEN IN HANDLING AND STORAGE:
Use ground strap and appropriate precautions for dispensing
flammable liquids.
Keep container closed when not in use.
Avoid breathing vapors.
Avoid contact with skin and eyes.
Store away from heat, sources of ignition, and incompatibles.
Keep away from children.
------------------------------------------------------------------------------
8. EXPOSURE CONTROLS /PERSONAL PROTECTION
ENGINEERING CONTROLS:
Showers and eyewash stations_ See 'Ventilation' below.
RESPIRATORY PROTECTION:
If exposure limits are exceeded or respiratory irritation is
experienced, NIOSR /MSHA approved respiratory protection should
be worn. Supplied air respirators may be required for
COPYRIGHT GENERAL ELECTRIC CO. page: 7
non - routine or emergency situations. Respiratory protection
must be provided in accordance with OSHA regulations (see 29
CPR 1910.134)_
PROTECTIVE GLOVES:
Polyvinylchloride.
r n1 ri e _
EYE AND FACE PROTECTION:
Safety glasses with side shields.
OTHER PROTECTIVE EQUIPMENT:
Wear eye protection and protective clothing.
VENTILATION:
Ventilation and other forms of engineering controls are
preferred for controlling exposures. Respiratory protection
may be needed for non - routine or emergency situations.
------------------------------------------------------------------------------
9. PHYSICAL AND CHEMICAL PROPERTIES
PRODUCT INFORMATION:
BOILING POINT
>135
(C) >275
(F)
VAPOR PRESSURE (20 C) (MM HG):
NEG
VAPOR DENSITY (AIR =1)
NEG
FREEZING POINT
NA
(C) NA
(F)
MELTING POINT
NA
(C) NA
(F)
PHYSICAL STATE
LIQUID
ODOR
ODORLESS
COLOR
CLEAR
ODOR THRESHOLD (PPM)
UNK
% VOLATILE BY VOLUME
<1
EVAP_ RATE(BDTYL ACETATE =1):
<1
SPECIFIC GRAVITY (WATER =1)
1.01
DENSITY (KG /M3)
1006
COPYRIGHT GENERAL ELECTRIC CO. page: 8
ACID /ALKALINITY (MEQ /G) -7
PH NA
VOC EXCL.H20 & EXEMPTS(G /L): 363
SOLUBILITY IN WATER (20 C) : INSOLUBLE
SOLUBILITY IN ORGANIC SOLVENT (STATE SOLVENT): YES IN TOLUENE
10. STABILITY AND REACTIVITY
STABILITY: STABLE
HAZARDOUS POLYMERIZATION: WILL NOT OCCUR
HAZARDOUS THERMAL DECOMPOSITION /COMBUSTION PRODUCTS:
Carbon monoxide.
Carbon dioxide.
Silicon dioxide.
Formaldehyde.
INCOMPATIBILITY (MATERIALS TO AVOID):
None known.
1` CONDITIONS TO AVOID:
Keep away from heat, sparks and flame_
Avoid any source of ignition.
11. TOXICOLOGICAL INFORMATION
PRODUCT INFORMATION:
ACUTE ORAL LD50 (MG /KG):
ACUTE DERMAL LD50 (MG /KG):
ACUTE I14HALATION LC50 (MG /L) :
>40,000 RAT,ESTM.
NONE FOUND
>535 MG /L ESTM.
COPYRIGHT GENERAL ELECTRIC CO. page: 9
OTHER:
None.
AMES TEST: UNKNOWN
--- ---- ----- ----------- ----------------------------------------------------- --
12. ECOLOGICAL INFORMATION
----------------------------------------------- ------ ----------- --- --- --- -- ---
ECOTOXICOLOGICAL INFORMATION: No data at this time
CHEMICAL FATE INFORMATION: No data at this time
------------------------------------------------------------------------------
13. DISPOSAL CONSIDERATIONS
------------------------------------------------ ----------- -- ---- ------- - --- --
DISPOSAL METHOD:
Disposal should be made in accordance with federal, state and
local regulations.
Incineration recommended in approved incinerator according to
federal, state, and local regulations.
------------------------------------------------------------------------------
14. TRANSPORT INFORMATION
----------------------------------------------- -- ------- ---- --- -- ------ -- -----
DOT SHIPPING NAME: FLAMMABLE LIQIIID N.O.S. (POLYDIMETHYLSILOXAKE)
DOT HAZARD CLASS: 3
DOT LABEL(S): FLAMMABLE LIQIIID
UN /NA NUMBER: UN1993
PLACARDS: FLAMMABLE LIQIIID
COPYRIGHT GENERAL ELECTRIC CO. page: 10
IATA:
FLAMMABLE LIQUID N.O.S. (POLYDIMETHYLSILOXANE), 3, UN1993,I1I.
IMO IMDG -code: 3
EMS No: EmS. No.3 -07
RID (OCTI): 3
ADR (ECE) 3
RAR (IATA) : 3
------------------------------------------------------------------------------
15. REGULATORY INFORMATION
SARA SECTION 302:
None Found
SARA (311,312) HAZARD CLASS:
CHRONIC HEALTH HAZARD
FIRE HAZARD
SARA (313) CHEMICALS:
NONE
CPSC CLASSIFICATION: NA
WHMIS HAZARD CLASS:
B3 COMBUSTIBLE LIQUIDS
D2A VERY TOXIC MATERIALS
WHMIS TRADE SECRET:
None
EXPORT:
SCHDLE B /HTSUS: 3910.00 Silicones in Primary Form
ECCN: EAR99
HAZARD RATING SYSTEMS
HMIS FLAMMABILITY 2 , REACTIVITY 0 HEALTH 0
NFPA HEALTH = 0, FT.AMMABILITY = 2, REACTIVITY = 0
CALIFORNIA PROPOSITION 65:
NONE
COPYRIGHT GENERAL ELECTRIC CO. page: 11
16. OTHER INFORMATION
This product or its components are on the European inventory of
existing commercial chemicals ( EINECS ) ...........................
................................. ...............................
These data are offered in good faith as typical values and not
as product specifications. No warranty, either expressed or
implied, is made. The recommended industrial hygiene and safe
handling procedures are believed to be generally applicable.
However, each user should review these recommendations in the
specific context of the intended use and determine whether they
are appropriate.
C = ceiling limit
EST= estimated
NA = not applicable
NE = none established
NO = none determined
By- product = reaction by-
product, TSCA inventory
status not required under
40 CFR part 720.30(h -2)
STEL = short term exposure
limit
NEGL =
NF =
UNKN =
REC =
V =
SKN =
TS =
R =
MST =
NT =
.................
negligible
none found
unknown
recommended
recomm. By vendor
skin
trade secret
recommended
mist
not tested
................................. ...............................
r
COPYRIGHT GENERAL ELECTRIC CO. page: 12
MATERIAL SAFETY DATA SHEET
1�'NEMf�AL. a
1. Product and Company Identification
Material name ALCOHOL, REAGENT (ACS)
Catalog # 1850
Version # 02
Revision date 04- Nov -2009
CAS # Mixture
Synonym(s) REAGENT ALCOHOL * ETHYL ALCOHOL * ETHANOL * DENATURED ALCOHOL
Manufacturer information GFS Chemicals, Inc.
P.O. Box 245
Powell, OH 43065 US
www.gfschemicals.com
Fax 740- 881 -5989
Phone 740 - 881 -5501
Toll Free 800 - 858 -9682
Emergency Assistance Chemtrec 800- 424 -8300
2. Hazards Identification
Emergency overviews FLAMMABLE LIQUID AND VAPOR.
Will be easily ignited by heat, spark or flames.
DANGER -- POISON
May be fatal or cause blindness if swallowed. Cannot be made nonpoisonous. Harmful in
contact with eyes. Harmful if inhaled or absorbed through skin. Cancer hazard. Causes skin
and eye irritation. May cause irritation to the respiratory system. Can cause adverse
reproductive effects - such as birth defects, miscarriages, or infertility. May cause central
nervous system effects. May cause damage to the liver. Prolonged exposure may cause
chronic effects.
OSHA regulatory status This product is considered hazardous under 29 CFR 1910.1200 (Hazard Communication).
Potential health effects
Routes of exposure Inhalation. Ingestion. Skin contact. Eye contact.
Eyes Contact may irritate or burn eyes. Eye contact may result in corneal injury. Do not get this
material in contact with eyes.
Skin Avoid contact with the skin. May irritate skin and mucous membranes. Frequent or prolonged
contact may defat and dry the skin, leading to discomfort and dermatitis.
Inhalation Toxic effects exerted upon nervous system, particularly the optic nerve. May cause cancer by
inhalation. Avoid breathing dust/fume /gas /mist/vapors /spray. Once absorbed into the body, it
is very slowly eliminated. Symptoms of overexposure may include headache, drowsiness,
nausea, vomiting, blurred vision, blindness, coma and death. A person may get better but then
worse again up to 30 hours later.
Ingestion Even small amounts (30 -250 ml methanol) may be fatal. Symptoms are stomach ache,
nausea, vomiting, dullness, visual disorder and blindness. Components of the product may be
absorbed into the body by ingestion. Do not ingest.
Target organs Blood. Eyes. Liver. Skin. Central nervous system. Gastro - intestinal tract. Respiratory system.
Chronic effects Unconsciousness. Conjunctiva. Jaundice. Cyanosis (blue tissue condition, nails, lips, and /or
skin). Sterility. Liver injury may occur. May cause central nervous system disorder (e.g.,
narcosis involving a loss of coordination, weakness, fatigue, mental confusion and blurred
vision) and /or damage. Pregnant women or women of child - bearing age should not be
exposed to this product. Can cause adverse reproductive effects - such as birth defects,
miscarriages, or infertility. Frequent or prolonged contact may defat and dry the skin, leading
to discomfort and dermatitis.
Signs and symptoms Unconsciousness. Corneal damage. Narcosis. Cyanosis (blue tissue condition, nails, lips, and /or
skin). Decrease in motor functions. Behavioral changes. Liver enlargement. Jaundice.
Conjunctivitis. De`ratting of the skin. Skin irritation. Rash. Birth defects. Sterility. Blindness
Potential environmental May cause long -term adverse effects in the environment
effects
Material name: ALCOHOL, REAGENT (ACS) Msos Us
Catalog # Version #: 02 Revision date: 11 -04 -2009 Print date: 11-04 -2009 1/9
1850
I Composition / Information on Ingredients
Components
CAS #
Percent
ETHYL ALCOHOL
64 -17 -5
80-90
ISOPROPYL ALCOHOL
67 -63 -0
2.5-10
METHYL ALCOHOL
67 -56 -1
2.5-10
4. First Aid Measures
First aid urocedures
Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if
present and easy to do. Continue rinsing. Get medical attention immediately.
Skin contact Take off immediately all contaminated clothing. Immediately flush skin with plenty of water.
Get medical attention if irritation develops and persists. For minor skin contact, avoid
spreading material on unaffected skin. Wash clothing separately before reuse.
Inhalation Move to fresh air. Oxygen or artificial respiration if needed. Do not use mouth-to -mouth
method if victim inhaled the substance. Induce artificial respiration with the aid of a pocket
mask equipped with a one -way valve or other proper respiratory medical device. Get medical
attention if symptoms occur.
Ingestion Rinse mouth. If swallowed, induce vomiting immediately as directed by medical personnel. Do
not use mouth -to -mouth method if victim ingested the substance. Induce artificial respiration
with the aid of a pocket mask equipped with a one -way valve or other proper respiratory
medical device. IF SWALLOWED: Immediately call a POISON CENTER or doctor /physician.
Rinse mouth thoroughly. If vomiting occurs, keep head low so that stomach content doesn't
get into the lungs.
Notes to physician In case of shortness of breath, give oxygen. Keep victim warm. Keep victim under observation.
Symptoms may be delayed.
General advice IF exposed or concerned: Get medical advice /attention. In case of shortness of breath, give
oxygen. Keep victim warm. Keep victim under observation. Ensure that medical personnel are
aware of the material(s) involved, and take precautions to protect themselves.
5. Fire Fighting Measures
Flammable properties Flammable by OSHA criteria. Heat may cause the containers to explode. Runoff to sewer may
cause fire or explosion hazard.
Extinguishing media
Suitable extinguishing Water. Foam. Dry powder. Carbon dioxide (CO2).
media
Unsuitable extinguishing Do not use a solid water stream as it may scatter and spread fire.
media
Protection of firefighters
Specific hazards arising Fire may produce irritating, corrosive and /or toxic gases.
from the chemical
Protective equipment and In case of fire and /or explosion do not breathe fumes. Firefighters must use standard
precautions for protective equipment including flame retardant coat, helmet with face shield, gloves, rubber
firefighters boots, and in enclosed spaces, SCBA. If tank, rail car or tank truck is involved in a fire,
ISOLATE for 800 meters (1/2 mile) in all directions; also consider initial evacuation for 800
meters (1/2 mile) in all directions. ALWAYS stay away from tanks engulfed in flame. Fight fire
from maximum distance or use unmanned hose holders or monitor nozzles. Withdraw
immediately in rase of rising sound from venting safety device or any discoloration of tanks
due to fire. Move containers from fire area if you can do so without risk. In the event of fire,
cool tanks with water spray. Use water spray to cool unopened containers. Cool containers
exposed to flames with water until well after the fire is out. For massive fire in cargo area, use
unmanned hose holder or monitor nozzles, if possible. If not, withdraw and let fire burn out.
Specific methods In the event of fire and /or explosion do not breathe fumes. In the event of fire, cool tanks
with water spray. Use water spray to cool unopened containers.
Material name: ALCOHOL, REAGENT (ACS) Msos us
Catalog # Version #: 02 Revision date: 11-04 -2009 Print date: 11 -04 -2009 2/9
1850
6. Accidental Release Measures
Personal precautions
Keep unnecessary personnel away. Keep upwind. Keep out of low areas. Keep people away
from and upwind of spill /leak. Ventilate closed spaces before entering them. Ensure adequate
ventilation. Do not touch damaged containers or spilled material unless wearing appropriate
protective clothing.
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not contaminate water.
Methods for containment
ELIMINATE all ignition sources (no smoking, flares, sparks or flames in immediate area). Stop
the flow of material, if this is without risk. Dike the spilled material, where this is possible.
S. Exposure Controls / Personal Protection
Prevent entry into waterways, sewer, basements or confined areas.
Methods for cleaning up
Should not be released into the environment.
Large Spills: Dike far ahead of spill for later disposal. Use a non - combustible material like
vermiculite, sand or earth to soak up the product and place into a container for later disposal.
Small Spills: Wipe up with absorbent material (e.g. cloth, fleece). Clean surface thoroughly to
remove residual contamination. Following product recovery, flush area with water.
Never return spills in original containers for re -use.
7. Handling and Storage
Handling Vapors may form explosive mixtures with air. DO NOT handle, store or open near an open
flame, sources of heat or sources of ignition. Protect material from direct sunlight. Do not
smoke. All equipment used when handling the product must be grounded. Do not get this
material in contact with eyes. Avoid breathing dust/fume /gas /mist/vapors /spray. Avoid contact
with skin. Use only in area provided with appropriate exhaust ventilation. Wear personal
protective equipment. Avoid prolonged exposure. Wash thoroughly after handling. Avoid
release to the environment.
Storage
The pressure in sealed containers can increase under the influence of heat Keep away from
heat, sparks and open flame. Keep away from heat and sources of ignition. This material can
accumulate static charge which may cause spark and become an ignition source. Prevent
electrostatic charge build -up by using common bonding and grounding techniques. Store in
cool place. Store in a well- ventilated place. Keep container tightly closed. Keep in an area
equipped with sprinklers. Keep away from food, drink and animal feedingstuffs. Keep out of
the reach of children. Use care in handling /storage.
S. Exposure Controls / Personal Protection
occupational exposure limits
ACGIH
Components
CAS # Type Value Form
ETHYL ALCOHOL
64 -17 -5 TWA 1000 ppm
ISOPROPYL ALCOHOL
67 -63 -0 STEL 400 ppm
TWA 200 ppm
METHYL ALCOHOL
67 -56 -1 STEL 250 ppm
TWA 200 ppm
Material name: ALCOHOL, REAGENT (ACS) Msos us
Catalog # Version #: 02 Revision date: 11 -04 -2009 Print date: 11-04 -2009 3/9
1850
U.S. - OSHA
Components CAS # Type Value Form
ETHYL ALCOHOL
64 -17 -5 PEL
1000 ppm
1900 mg /m3
TWA
1900 mg /m3
1000 ppm
ISOPROPYL ALCOHOL
67 -63 -0 PEL
400 ppm
980 mg /m3
STEL
1225 mg /m3
—
ppm
TWA
400 ppm
980 mg /m3
METHYL ALCOHOL
67 -56 -1 PEL
200 ppm
260 mg /m3
STEL
250 ppm
325 mg /m3
TWA
260 mg /m3
200 ppm
Engineering controls
Ensure adequate ventilation, especially in confined areas.
Personal protective equipment
Respiratory protection
In case of insufficient ventilation, wear suitable
respiratory equipment.
Hand protection
Rubber gloves.
Eye / face protection
Wear chemical goggles. Do not get in eyes.
Skin protection
Wear appropriate chemical resistant clothing. Chemical resistant gloves.
General hygeine
When using do not smoke. Do not get in eyes. Avoid contact with skin. Keep away from food
considerations
and drink. Handle in accordance with good industrial hygiene and safety practice.
9. Physical & Chemical Properties
Appearance
Clear.
Color
Colorless.
Odor
Similar to isopropyl alcohol.
Odor threshold
Not available.
Physical state
Liquid.
Form
Liquid.
pH
Not available.
Melting point
-169.6 °F ( -112.01 °C) estimated
Freezing point
Not available.
Boiling point
172.4 °F (78 °C)
Flash point
55.4 °F (13 °C)
Evaporation rate
Not available.
Flammability
Not available.
Flammability limits in air,
19%
upper, % by volume
Flammability limits in air,
3.3%
lower, % by volume
Vapor pressure
82.65 hPa estimated
Vapor density
1.6
Specific gravity
0.79
Relative density
0.79 g /cm3
Solubility (water)
Miscible.
Material name: ALCOHOL, REAGENT (ACS)
MsDS us
Catalog # Version #: 02 Revision date: 11 -04 -2009 Print date: 11 -04 -2009
4/9
1850
Partition coefficient
(n- octanol /water)
Auto - ignition temperature
Decomposition temperature
voc
Percent volatile
Not available.
676.4 OF (358 °C) estimated
Not available.
100 % estimated
100%
10. Chemical Stability & Reactivity Information
Chemical stability
Conditions-to avoid
Incompatible materials
Hazardous decomposition
products
Possibility of hazardous
reactions
Stable at normal conditions. Risk of ignition. Risk of explosion.
Heat-flames; and smirks. Avoid high temperatures.
Oxidizing materials.
No hazardous decomposition products are known.
Hazardous polymerization does not occur.
11. Toxicological Information
Sensitization
US ACGIH Threshold Limit Values: Skin designation
METHYL ALCOHOL 67 -56 -1 Can be absorbed through the skin.
Material name: ALCOHOL, REAGENT (ACS) MsDS us
Catalog # Version #: 02 Revision date: 11 -04 -2009 Print date: 11-04 -2009 5/9
1850
Acute effects
Acute Dermal: LD 50
ISOPROPYL ALCOHOL
67 -63 -0
Rabbit 5030 - 7900 mg /kg
ISOPROPYL ALCOHOL
67 -63 -0
Rabbit 12800 mg /kg
METHYL ALCOHOL
67 -56-1
Rabbit 15800 mg /kg
Acute Inhalation: LC 50
ETHYL ALCOHOL
64 -17 -5
Rat 20000 mg /1 10 h
ETHYL ALCOHOL
64 -17 -5
Mouse 0.039 mg /1 4 h
METHYL ALCOHOL
67 -56-1
Rat 87.5 mg /I 6 h
METHYL ALCOHOL
67 -56-1
Rat 64000 mg /I 4 h
METHYL ALCOHOL
67 -56 -1
Cat 43.68 mg /I 6 h
METHYL ALCOHOL
67 -56 -1
- - -- - -- - - -- -
Cat 85.41 mg /I 4.5 h
-- -- -- - - -- - - -- - -- - -- --
Acute Oral LD 50
ETHYL ALCOHOL
64 -17 -5
Guinea pig 5.6 g /kg
ETHYL ALCOHOL
64 -17 -5
Rat 10.6 g /kg
ETHYL ALCOHOL
64 -17 -5
Mouse 3450 mg /kg
ETHYL ALCOHOL
64 -17 -5
Rat 6.2 g /kg
ETHYL ALCOHOL
64 -17 -5
Rat 7060 mg /kg
ETHYL ALCOHOL
64 -17 -5
Rat 17.8 g /kg
ETHYL ALCOHOL
64 -17 -5
Rat 9.9 g/kg
ETHYL ALCOHOL
64 -17 -5
Dog 5.5 g /kg
ETHYL ALCOHOL
64 -17 -5
Rat 11.5 g /kg
ISOPROPYL ALCOHOL
67 -63 -0
Rat 5045 mg /kg
ISOPROPYL ALCOHOL
67 -63 -0
Rabbit 8000 mg /kg
ISOPROPYL ALCOHOL
67 -63 -0
Rat 4700 - 5800 mg /kg
ISOPROPYL ALCOHOL
67 -63 -0
Rabbit 6410 mg /kg
ISOPROPYL ALCOHOL
67 -63 -0
Mouse 3600 mg /kg
ISOPROPYL ALCOHOL
67 -63 -0
Dog 4797 mg /kg
METHYL ALCOHOL
67 -56-1
Rabbit 14.4 g /kg
METHYL ALCOHOL
67 -56-1
Mouse 7300 mg /kg
METHYL ALCOHOL
67 -56 -1
Monkey 2 g /kg
METHYL ALCOHOL
67 -56 -1
Dog 8000 mg /kg
METHYL ALCOHOL
67 -56 -1
Rat 5628 mg /kg
Acute Toxicity other routes: LD 50
ETHYL ALCOHOL
6417 -5
Rat 3750 mg /kg Intraperitoneal
ETHYL ALCOHOL
64 -17 -5
Rat 1440 mg/kg Intravenous
ETHYL ALCOHOL
6417 -5
Mouse 933 mg /kg Intraperitoneal
ETHYL ALCOHOL
64 -17 -5
Mouse 8285 mg /kg Subcutaneous
ETHYL ALCOHOL
64 -17 -5
Mouse 1973 mg /kg Intravenous
ISOPROPYL ALCOHOL
67 -63 -0
Rat 1099 mg /kg Intravenous
ISOPROPYL ALCOHOL
67 -63 -0
Mouse 1509 mg /kg Intravenous
METHYL ALCOHOL
67 -56 -1
Mouse 10765 mg /kg Intraperitoneal
METHYL ALCOHOL
67 -56-1
Rat 7529 mg /kg Intraperitoneal
METHYL ALCOHOL
67 -56 -1
Rat 2131 mg /kg Intravenous
METHYL ALCOHOL
67 -56-1
Monkey 3 g /kg Intraperitoneal
METHYL ALCOHOL
67 -56-1
Rabbit 8907 mg /kg Intravenous
METHYL ALCOHOL
67 -56 -1
Rabbit 1826 mg /kg Intraperitoneal
METHYL ALCOHOL
67 -56-1
Hamster 8555 mg /kg Intraperitoneal
METHYL ALCOHOL
67 -56-1
Mouse 4710 mg/kg Intravenous
METHYL ALCOHOL
67 -56-1
Mouse 4100 mg/kg Subcutaneous
METHYL ALCOHOL
67 -56 -1
Guinea pig 3556 mg /kg Intraperitoneal
Toxicology data for the preparation
Local effects
Components of the product may be absorbed into the body through the skin. Blood disorder
may occur after ingestion. Liver toxicity. Contact may irritate or burn eyes.
Chronic effects
Hazardous by OSHA criteria. Repeated absorption may cause disorder of central nervous
system, liver, kidneys and blood. Prolonged exposure may cause chronic effects.
Subchronic effects
Blood disorder
may occur after prolonged inhalation. Blood disorder may occur after ingestion.
Blood disorder
may occur after prolonged skin contact.
Carcinogenicity
Hazardous by OSHA criteria. Cancer hazard. Risk of cancer cannot be excluded with prolonged
exposure.
US ACGIH Threshold Limit Values: A3 carcinogen
ETHYL ALCOHOL
64 -17 -5
A3 Confirmed animal carcinogen with unknown relevance to humans.
US ACGIH Threshold Limit Values: A4 carcinogen
ISOPROPYL ALCOHOL
67 -63 -0
A4 Not classifiable as a human carcinogen.
Epidemiology
Hazardous by OSHA criteria.
Material name: ALCOHOL, REAGENT (ACS)
MSS US
Catalog # Version #: 02 Revision
date: 11-04 -2009
Print date: 11-04 -2009 6/9
1850
Neurological effects Hazardous by OSHA criteria.
Reproductive effects Hazardous by OSHA criteria. Possible reproductive hazard. Can cause adverse reproductive
effects - such as birth defects, miscarriages, or infertility.
Further information Reproductive toxicity. Symptoms may be delayed.
12. Ecological Information
Eeotoxicity
Contains a substance which causes risk of hazardous effects to the environment.
Invertebrate Toxicity: EC 50
ETHYL ALCOHOL
64 -17 -5
Water flea (Daphnia magna) 7.7 - 11.2 mg /I 48 h Static Intoxication
ETHYL ALCOHOL
64 -17 -5
Water flea (Daphnia magna) > 10000 mg /I 48 h Static Intoxication
---- ETtiYt AtCOHOL -- -
°17 5 — - - -
-- Water - lea- (Daphnia-obtusa)- 1 2300 - -13400 mg /1 24 -h Static-Intoxication----
ETHYL ALCOHOL
64 -17 -5
Water flea (Daphnia obtusa) 10100 - 11200 mg/I 48 h Static Intoxication
ETHYL ALCOHOL
64 -17 -5
Water flea (Daphnia magna) > 1.58 mg /I 24 h Static Intoxication
ETHYL ALCOHOL
64 -17 -5
Water flea (Daphnia magna) > 100 mg /I 2 h Static Intoxication
ETHYL ALCOHOL
64 -17 -5
Water flea (Daphnia magna) > 100 mg /I 24 h Static Intoxication
ETHYL ALCOHOL
64 -17 -5
Water flea (Daphnia magna) > 100 mg /I 4 h Static Intoxication
ETHYL ALCOHOL
64 -17 -5
Water flea (Daphnia magna) > 100 mg /I 6 h Static Intoxication
ETHYL ALCOHOL
64 -17 -5
Water flea (Daphnia magna) > 10000 mg /I 24 h Static Intoxication
METHYL ALCOHOL
67 -56-1
Water flea (Daphnia magna) 20450 - 29350 mg /I 48 h Static Intoxication
METHYL ALCOHOL
67 -56 -1
Water flea (Daphnia obtusa) 22800 - 24400 mg /I 24 h Static Intoxication
METHYL ALCOHOL
67 -56 -1
Water flea (Daphnia magna) > 10000 mg /I 48 h Static Intoxication
METHYL ALCOHOL
67 -56 -1
Water flea (Daphnia magna) > 10000 mg /I 24 h Static Intoxication
METHYL ALCOHOL
67 -56 -1
Water flea (Daphnia obtusa) 21100 - 23400 mg /I 48 h Static Intoxication
Micro- organisms Toxicity: LC
50
ETHYL ALCOHOL
64 -17 -5
Turbellarian, flatworm (Dugesia tigrina) > 100 mg /I 96 h Static Mortality
METHYL ALCOHOL
67 -56-1
Turbellarian, flatworm (Dugesia tigrina) > 100 mg /I 96 h Static Mortality
Environmental effects
An environmental hazard cannot be excluded in the event of unprofessional handling or
disposal.
Persistence and degradability
Not available.
13. Disposal Considerations
Waste codes
D001: Waste Flammable material with a flash point <140 F
US RCRA Hazardous Waste U
List: Reference
METHYL ALCOHOL
67 -56 -1
0154
Disposal instructions Dispose of this material and its container to hazardous or special waste collection point.
Incinerate the material under controlled conditions in an approved incinerator. Do not
incinerate sealed containers. Do not allow this material to drain into sewers /water supplies. If
discarded, this product is considered a RCRA ignitable waste, D001. Dispose in accordance
with all applicable regulations.
14. Transport Information
DOT
Basic shipping requirements:
Proper shipping name
Hazard class
UN number
Packing group
Additional information:
Special provisions
Packaging exceptions
Packaging non bulk
Packaging bulk
ERG number
Ethanol or Ethyl alcohol or Ethanol solutions or Ethyl
alcohol solutions
UN 1170
II
24, I62, T4, TP1
150
202
242
127
Material name: ALCOHOL, REAGENT (ACS) MSDS us
Catalog Version #: 02 Revision date: 11-04 -2009 Print date: 11-04 -2009 7/9
1850
15. Regulatory Information
US federal regulations
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication
Standard, 29 CFR 1910.1200.
All components are on the U.S. EPA TSCA Inventory List.
CERCLA/SARA Hazardous Substances - Not applicable.
US EPCRA (SARA Title III) Section 313 - Toxic Chemical: De minimis concentration
METHYL ALCOHOL
67 -56-1 1.0%
CERCLA (Superfund) reportable quantity
- - - -- -- None - -- - -- - —
— - - -- - - - - - - -- -- —_ . - --
- -
Superfund Amendments and Reauthorization Act of 1986 (SARA)
Hazard categories
Immediate Hazard - Yes
Delayed Hazard - Yes
Fire Hazard - Yes
Pressure Hazard - No
Reactivity Hazard - No
Section 302 extremely
No
hazardous substance
Section 311 hazardous
Yes
chemical
Inventory status
Country(s) or region
Inventory name On inventory (yes /no)*
Australia
Australian Inventory of Chemical Substances (AICS)
Yes
Canada
Domestic Substances List (DSL)
Yes
Canada
Non - Domestic Substances List (NDSL)
No
China
Inventory of Existing Chemical Substances in China (IECSC)
Yes
Europe
European Inventory of New and Existing Chemicals (EINECS)
Yes
Europe
European List of Notified Chemical Substances (ELINCS)
No
Japan
Inventory of Existing and New Chemical Substances (ENCS)
Yes
Korea
Existing Chemicals List (ECL)
Yes
New Zealand
New Zealand Inventory
Yes
Philippines
Philippine Inventory of Chemicals and Chemical Substances (PICCS)
Yes
United States & Puerto Rico
Toxic Substances Control Act (TSCA) Inventory
Yes
A "Yes" indicates that all components of this product comply with the inventory requirements administered by the governing country(s)
State regulations
WARNING: This product contains a chemical known to the State of California to cause cancer
and birth defects or other reproductive harm.
US - New Jersey Community RTK (EHS Survey): Reportable threshold
METHYL ALCOHOL
67 -56 -1 500 LBS
US - Pennsylvania RTK - Hazardous Substances: Listed substance
ETHYL ALCOHOL
64 -17 -5 Listed.
ISOPROPYL ALCOHOL
67 -63 -0 Listed.
METHYL ALCOHOL
67 -56 -1 Listed.
16. Other Information
Further information HMIS® is a registered trade and service mark of the NPCA.
HMIS® ratings Health: 2*
Flammability: 3
Physical hazard: 1
NFPA ratings Health: 2
Flammability: 3
Instability: 1
Material name: ALCOHOL, REAGENT (ACS) rtsos us
Cataloo # Version #: 02 Revision date: 11-04 -2009 Print date: 11-04 -2009 8/9
1850
Disclaimer The information in the sheet was written based on the best knowledge and experience
currently available. The information provided in this Safety Data Sheet is correct to the best of
our knowledge, information and belief at the date of its publication. The information given is
designed only as a guidance for safe handling, use, processing, storage, transportation,
disposal and release and is not to be considered a warranty or quality specification. The
information relates only to the specific material designated and may not be valid for such
material used in combination with any other materials or in any process, unless specified in
the text
Issue date
This data sheet contains
changes from the previous
— version in -section n(s): — — -
04- Nov -2009
This document has undergone significant changes and should be reviewed in its entirety.
Material name: ALCOHOL, REAGENT (ACS) Msos us
Catalog # Version #: 02 Revision date: 11 -04 -2009 Print date: 11-04 -2009 9/9
1850
L!tl.— l._'- 1.'... 1r.• � i,= rr•.Ln 1 \.'f'1Ll_C I _VL`JLI Y I e i i vd. ' _
INDUSTRIAL HYGIENE, TOXICOLOGY, AND MATERIAL
SAFETY DATA SHEET
�Ie
NOTE: REPRESENTATION � C Y c I
HEEREIN.SEE PAGE7 FOR CONOITIO UNDER WHICH DATA AR FURNISHED. �, (� 4L Lq
Trade Name and Synonyms
C5726 TE�X
—SOLVE C b�C p,.0
No.
manufacturer's Name i mergency Telephone
—Texacg Chemical Company 4 9 722 -8381
Address
4800 Fa rnace Place P.O. Box 430 B 11,aire Tx 77401
Chemical Name and /or Family or bascription
Commercial ne
THIS PRODUCT IS CLASSIFIED AS: NOT HAZARDOUS:
X— HAZARD U Y DEFINITI N N 1 2 ON TTACHPC EXPLANATI N NEETS
WARNING STATEMENT:
DANGER( EXTREMELY FLAMMABLE
CAUSES IRRITATION TO EYE$
MAY CAUSE IRRITATION TO SKIN
UG.GLII� `X IC3I�iA G�,3T ' ti TL PI�t CAD
M r
protective Equipment (Type)
Eyes: Chemical type goggles must be worn. Do not wear contact lenses.
Skirt Protective clothing such as uniforms, coveralls or lab coats
should be worn. Launder or dry clean when soiled. Gloves reAitl--
N.D. — Not Determined N.A, —(+lot Applicable
Less Than > — Greater Than 1
cv
r
,r
i i i . r
J�
1YQ. icy
4
Effects of Exposure
Acute:
Eyes: Believed to cause moderate eye irritation.
Skin: Believed to be moderately irritating; Believed to cause
redness, edema or drying of the skin.
Respiratory System: Overexposure to mist,vapors may cause dizziness, drowsiness,head-
ache,nausea.Massive overexposure may cause unconsciousness,death.
Chronic: Prolonged or repeated skin contact may cause drying or cracking
of skin.
Other: --See additional comments pg_ 6.
Sensitization Properties:
Skin: Yes — No -.—. Unknown X Respiratory: Ye: — No -- Unknown ?i
Median Lethal Dose (t p so LC ,o )(Species)
Believed to be > 5 A /kg (rat) ; practically non-toxic
Oral —
N.D.
inhalation
Believed to be > 3 R/k {rabbit); practically non -toxic
Dermal
N. D,
Other
irritation Index. Estimation of Irritation (Species)
Believed to be 3 -5/8 0 (rabbit) ; moderately irritating
Skin
Believed to be 25- 50/110 (rabbit); moderately rrritatin
Eyes --
5 m toms of Ex osur See above.
i "i Pi3C3T T, E C1R1'4Ai�C?[�1
Ignition Temp oF. 399 F Flash Point OF. (Method) 16 F
Flammable Limits { %) Lower 1 • {] Upper 7. 0
Products Evolved When Subjected to Heat or Combustion:
Carbon monoxide and carbon dioxide may be formed on burning in
Limited air supply.
Recommended Fire Extinguishing Agents And Special Procedures:
According to the National Fire Protection Association Guide 325M,
use dry chemical, foam or carbon dioxide. Water may be ineffec-
tive on the flames, but water should be used to keep fire - exposed
containers cool. If a leak or spill has not ignited, use Water
spray to disperse the vapors and to provide protection for the
persons attempting to stop the leak..
Unusual or Explosive Hazards:
Kay accumulate static electric charge and cause fire /explosion
if discharged in vapor air mixtures within flammable limits.
N'a - w petetmineo N,k - Not AppllUbl♦
< — Less Than y — Greater Than 2
I-NUM VRLLE'�' S0LIJEt1T, FTIAI, TO
4211211 P. 01/04
Avyi 1-~ A
W414
ION y l , i ', ✓/ ) /: >
.' 1NANl�4, . � f` .. SCl t � .rl �"^'�w
I
\ 4
Waste D sposal Method:
Re-evaluation of the product may be required by the user at the
time of disposal, since the product uses, transformations,
mixtures and processes may change classification to non--hazardous
or hazardous for reasons other than, or in addition to
_i-gnitab l_ity.__(See Remarksfor_ waste Classification.) _
Procedures in Case of Breakage or Leakage: ('transportation $pills Call CHEMTREC (S00) 424-9300)
Eliminate all ignition sources including internal combustion eng-
ines and power tools. Ventilate area: Avoid breathing vapor. Use
SCBA or supplied -air mask for lg spills or in confined areaz,Con-
tain spill. Remove with inert absorbant. Avoid contact with eyes.
F7emarks: Waste Classification. Product (as presently constituted) has the
RCRA characteristic of ignitability and if discarded in its
purchased form would have the hazardous waste number D001.
PRECA : TI: NS
DANGER! EXTREMELY FLAMMAB'.E
CAUSES IRRITATION TO EYES
MAY CAUSE IRRITATION TO SKIN
Keep away from heat, sparks and flame. Keep container closed
Avoid contatt with eyes and prolonged contact with skin.
Use only in well - ventilated locations. Avoid prolonged
breathing of vapor or mist Keep head away from container
when opening or dispensing. Wash thoroughly after handling.
Requirements for 7ransportatlon. Handling ynd Storage:
Transport, handle, and store in accordance with OSHA Regulation 1910.106
and applicable DOT Regulations.
DOT Proper Shipping Name: Commercial heptane
DOT Hazard Class (f applicable); Flammable liquid, UN 1206
Boiling Point (OF) 190 -210 Vapor Pressure 53 @20 C - -- (mmHg)
Specific Gravity 0-717 (H20- 1) Vapor Den5ity_3 • 3 — (Air= 1)
Appearance and Odor. - Colorless liquid; mild odor
pH of undiluted product N. A. Solubility NeK. _
Percent Volatile by Volume 100 Evaporation N.D. ( )� 1
Viscosity N.D. Other _
Hazardous Polymerizntiona Occur X Do not occur
The Material Reacts Violently With: (If others is checked below, see additional comments on page 6 for futher details)
Air Water Hest Strong Oxidizers Others None of These
X
N,L). - Not Delerminect N.A. - Not AppOCaole
t - Less Than > Greater Than 3
DEU- I J - 1b: u . ( F-HUfl VHLLEY 'DI LIjEH I, F- I [A. 111
4-11--'11
U2 IL14
" lak
,4L#
vl\� 0
G MI(`.ALS, INC.
740 -8 01(Tel.) 740 - 881- 5989(Fax)
1 -800- 424- 9300(Chemtrec 24Hr. Info.)
MATERIAL SAFETY DATA SHEET
X S
CHEMICAL NAME -& SYNONYMS
Xvlenes;
FORMULA REPORTABLE QUANTITY
C6H4 (CHI) 2 45.4 kg
mixture of o - -, m -, p- isomers and ethylbenzene
1059
DOT -CLASS SARA -TITLE 313
3 /II Yes
TSCA listed - Yes
F. W. CAS#
106.17 1330 -20 -7
PHYSICAL DATA
Boiling range 137 -- 144 °C; Density 0.86; 100. volatile. Vapor pressure 6.7 mm at
21 °C. Vapor density 3.7. Insoluble in water, soluble in many organic solvents.
APPEARANCE & ODOR
Clear volatile liquid. Sweetish (benzene -like) odor.
REACTIVITY L, C. ,'J' iTTIONS TO AVOID
Stable. ?` <<- spo:itanecus self- reaction. Incompatible with oxidizers.
FIRE HAZARDS
.
Readily 1 air with sooty black smoke. Avoid inhalation of
f - _ . �
smoke. : [eis wear SCBA . NFPA # 2 -3 -0.
EXTINGUISHER
Dry chemical, CO,,foam or water spray.
FLASHPOINT LEL UEL
17 -26 °C 1. 7.
HEALTH HAZARDS
Irritant to skin, eyes and mucous membranes. Harmful by ingestion, inhalation
or skin absorption. Exposure may cause narcotic effects. Lung irritation, chest
pain, CNS depression, dermatitis, gastric d -i.sturbances. Chronic effects: liver
damage, kidney damage and blood effects. LD5. (oral -rat) 4300 mg /kg. LD5o
(inhl -rat) 5000 ppm /4H. OSHA PEL /ACGIH T-LV: TWA 100 ppm; STEL 150 ppm. Not
considered carcinogenic.
SPECIAL PRECAUTIONS
Use only with adequate ventilation or approved resnirat.or. Wear goggles and
rubber c.;loves while handling. Do not use near source of fire or spark. Store
with flammables and away from oxidizers.
FIRST AID
Wash skin or eyes thoroughly with water for 15 minutes. Remove contaminated
clothing and wash before re -use. For inhalation, remove to fresh air. If
breathing is difficult, give oxygen, if not breathing, use artificial
respiration. Get medical assisF_ance. if swallowed, give water or milk and induce
r_vomi ting. Call. a privsi cian.
SPILLS & LEAKS
Ventilate area. Rei toT :7-e ig%iir_ion sources. 'fake up spill in absorbent material.
Do not br..e_ t- vap >_ :-;:;- Disposal tC: i iciner.ator.
CATALOG # PREPARED BY DATE
1059 MDM February 15, 2005
GF ;� IEMICALS, INC.
245 Powe 65
74 -8 01(Tel.) 740 - 881- 5989(Fax)
1 -80 - 24- 9300(Chemtrec 24Hr. Info.)
MATERIAL SAFETY DATA SHEET
1 �METH�YLE�THYL KETONE
�J
959
CHEMICAL NAME & SYNONYMS DOT CLASS SARA TITLE 313
Methyl Ethyl Ketone; 2- Butanone; MEK 3 /II Yes
TSCA listed - Yes
FORMULA REPORTABLE QUANTITY F.W. CAS#
CH3COCH:('H,; 2270 kg 72.11 78 -93 -3
PHYSICAL DATA
Boiling point 79.6 °C; Vapor pressure 91 mm Hg at 25 °C; Density 0.807 at 20 °C;
Vapor density 2.42; 100. volatile; Water soluble; freezing point -87 °C.
APPEARANCE & ODOR
Clear, colorless oily liquid. Odor characteristic of ketones.
REACTIVITY & CONDITIONS TO AVOID
Stable. Protect from heat and sources of ignition. Incompatible with strong
oxidants, strong bases and many plastics.
FIRE HAZARDS
- mit toxic fi.imes in a fire. Fire"! raters wear SCBA.
NFPA J!. ? - 0 .
EXTINGUISHER FLASHPOINT LEL UEL
CO,, foam or dry chemical, water for cooling -9 °C 1.80 10.0.
HEALTH HAZARDS
Vapor irrit.a-.ing to eyes, dose and throat. Liquid is irritating to skin and
eyes. LDS, (oral- rat) 2737 mg /kg. Repeated contact may cause dermatitis. OSHA
PEL /ACGIH TLV: TWA 200 ppm; ACGIH STEL 300 ppm. Reproductive effects at high
concentration 1,3000 ppm). No evidence of carcinogenicity.
SPECIAL PRECAUTIONS
Use only with adequate ventilation. Explosion -proof electrical equipment. Use
goggles or face shield. and. rubber gloves while: handling.
FIRST AID
Inhalation - remove to fresh air. If breathing stops, use artificial respiration
and get medical attention. For skin or eye contact, wash thoroughly with water.
If irritation persists, get medical attention. Wash clothing before re -use. If
large quantities are swallowed, get immediate medical attention. Do NOT induce
jTomit.ing unless directed by a physician.
SPILLS & LEAKS
Eliminate scurcc- of ignition. Ventilate area. Contain spill to prevent liquid
from entering sewer. Absorb spill into organic base absorbent and dispose to
incinerator (_ -,r other suitable hazardous waste method. Recovery of spill by
pumping and reprocessing may be possible. Small amounts in water may be
disposable to sanitary drain. Check local regulations.
CATALOG # PREPARED BY DATE
9S9 MDM November 6, 2003
MSDS NO:EU -06- 05300037
.., S
PRODUCT NAME: KBE -903
MATERIAL SAFETY DATA SHEET
SECTION I. COMPANY IDENTIFICATION
COMPANY IDENTIFICATION
MANUFACTURER'S NAME: Shin -Etsu Silicones of America, Inc.
ADDRESS: 1150 Damar Drive, Akron, Ohio 44305
EMERGENCY TELEPHONE NUMBER:
330 - 630- 9860(Shin -Etsu Silicones of America, Inc.)
800 -424- 9300 (CHEMTREC)(24hrs)(Washington, D.C_ USA)
TELEPHONE NUMBER FOR INFORMATION:
979- 230 -9595 (Shin -Etsu Silicones of America, Inc. Manufacturing)
330- 630 -9860 (Shin -Etsu Silicones of America, Inc.)
OL
DATA PREPARED
01/19/1994
LAST REVISION
: 05/08/2003
DATA ISSUED
05/21/2003
ISSUE NO 200305001681
BASE NO 10
PRODUCT NAME
KBE -903
PRODUCT CLASSIFICATION:
Silane Coupling Agent
SECTION 2. COMPOSITION
SINGLE OR MIXTURE:
Single
CHEMICAL IDENTIFICATION:
3- Aminopropyltriethoxysilane
HAZARDOUS COMPONENT (S) No.):
No hazardous materials present
(See Section 8 of this MSDS for Exposure Guideline)
SECTION 3. HAZARDS IDENTIFICATION
HAZARDS CLASSIFICATION:
None (based on IMO), Irritant (based on OSHA)
None (based on DOT)
FIRE AND EXPLOSION:
Not considered flammable nor combustible, but will burn if
involved in a fire.
POTENTIAL HEALTH EFFECT:
INHALATION ; May cause irritation to mucous membranes and
(C)
G
1/7
MSDS NO: EU -06- 05300037 2/7
PRODUCT NAME: KBE -903
upper respiratory tract.
SKIN contact May cause severe skin irritation, prolonged
and extensive contact may result in skin
burns.
Kidney injury could occur by skin absorption.
EYES contact..__; Cause _severe eyes irritation, with burn of
cornea.
INGESTION Harmful
SECTION 4. FIRST AID MEASURES
INHALATION Remove to fresh air.
SKIN contact Remove product from skin with dry cloth or
towel, and wash exposed area with detergent.
EYES contact Immediately flush with plenty of water for at
least 15 minutes and promptly call a
physician.
INGESTION Wash out mouth with water provided person is
conscious. Never give anything by mouth to an
unconscious person. Call a physician
immediately.
SECTION 5. FIRE FIGHTING MEASURES
FLASH POINT(method used):
98 degrees C (Open cup)
95 degrees C (Closed cup)
FLAMMABLE LIMITS:
LOWER: Not measured UPPER: Not measured
EXTINGUISHING MEDIA:
Foam, dry chemical or carbon dioxide
SPECIAL FIRE FIGHTING PROCEDURE:
Wear eye /face protection and protective clothing.
UNUSUAL FIRE AND EXPLOSION HAZARD:
Burning can produce nitrogen oxides, a toxic and corrosive
gas.
SECTION 6. ACCIDENTAL RELEASE MEASURES
STEP TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
Shut off all ignition sources.
Wear appropriate protective equipment.
Contain the spill or leak.
Scrape up with rag or other absorbent material and place in
container.
SECTION 7. HANDLING AND STORAGE
kmMSDS NO:EU -06- 05300037 3/7
v PRODUCT DAME: KBE -903
PRECAUTION TO BE TAKEN IN HANDLING AND STORING:
Keep container closed when not in use.
Store in a cool place.
Keep away from heat, sparks and flame.
- - - -Do- not - -lay the container on its side. - - - -.
Use with adequate ventilation.
Avoid breathing vapor.
Avoid contact with eyes, skin and clothing.
Wear suitable gloves and eye /face protection.
Avoid contact with water or moisture.
Keep out of reach of children.
* * * * * Information about the emptied container
Do not re -use this container.
This container will be very hazardous when emptied.
Residues will be explosive or flammable.
Keep away from heat, sparks and flame.
Do not puncture or cut this container, and do not weld on or
near this container.
SECTION S. EXPOSURE CONTROLS /PERSONAL PROTECTION
EXPOSURE GUIDELINES:
ACGIH TLV -TWA : Not established,
OSHA PEL : Not established [3- Aminopropyltriethoxysilane]
ACGIH TLV -TWA ; 1000ppm,
OSHA PEL : 8H TWA 1000ppm
[Ethanol decomposed product]
RESPIRATORY PROTECTION(specify type);
Not required
VENTILATION:
LOCAL EXHAUST: Recommended
MECHANICAL(general): Adequate ventilation system
SPECIAL: Unknown
OTHER: Unknown
PROTECTIVE GLOVES:
Plastic film or rubber gloves
EYE PROTECTION:
Face shield or protective goggles
OTHER PROTECTIVE CLOTHING OR EQUIPMENT:
Safety shower and eyewash equipment
WORK /HYGIENIC PRACTICES:
Keep away from heat, sparks and flame.
Avoid breathing vapor.
Avoid contact with eyes and skin.
Wear suitable gloves and eye /face protection.
Wash hands and gargle after handling.
MSDS NO: EU- 06- 05300037 4/7
PRODUCT NAME: KBE -903
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
BOILING POINT:
217 degrees C
VAPOR-PRESSURE: - -.
<10mmHg (25 degrees C)
VAPOR DENSITY(air =1):
7.6
SPECIFIC GRAVITY:
0.94 (25 degrees C)
MELTING POINT:
Not measured
EVAPORATION RATE:
<1 (Butyl Acetate =l)
SOLUBILITY IN WATER:
Soluble
APPEARANCE(color):
Light yellow, transparent
APPEAP.ANCE (form) :
Liquid
ODOR:
Amine odor
SECTION 10. STABILITY AND REACTIVITY
STABILITY:
Stable
CONDITION TO AVOID:
Hydrolyzed with water, but no hazard.
INCOMPATIBILITY(material to avoid):
Mineral acids and water.
HAZARDOUS DECOMPOSITION OR BY- PRODUCT:
Water, acids or alkalis can cause ethanol.
Thermal breakdown of this product during fire or very
high heat condition may evolve the following hazardous
decomposition product: Carbon oxides and traces of
incompletely burned carbon compounds. Silicon dioxide.
Nitrogen oxides.
HAZARDOUS POLYMERIZATION:
Will not occur
CONDITION TO AVOID:
None
SECTION 11. TOXICOLOGICAL INFORMATION
SKIN IRRITATION:
i-- MSDS NO: EU -06- 05300037 5/7
nim
SKIN - RABBIT 5mg /24Hr SEVERE
EYE IRRITATION:
EYE - RABBIT : 0.75mg /24Hr SEVERE
ACUTE TOXICITY(LD50):
LD50(Oral /Rat) : 1.789 /kg
May cause _acute kidney injury
_(renal cortical. tubular necrosis)
by massive peroral overdose or sustained skin contact.
ACUTE TOXICITY(LC50):
No information is available.
CHRONIC TOXICITY:
No information is available.
MUTAGENICITY:
Negative(Bacteria)
CARCINOGENICITY:
NTP: Not listed, IARC: Not listed, OSHA REGULATED: Not listed
OTHER INFORMATION:
None
SECTION 12. ECOLOGICAL INFORMATION
BIODEGRADATION:
No information is available.
BIOACCUMULATION:
No information is available.
AQUATIC TOXICITY:
No information is available.
OTHER INFORMATION:
Causes easily hydrolysis in water or atmosphere.
SECTION 13. DISPOSAL CONSIDERATIONS
Can be burned in a chemical incinerator equipped with an
afterburner and scrubber.
Do not dispose of the emptied container unless the contents
have been completely removed and container has been flushed
with a clean neutral solvent and then dried up.
Do not dispose the emptied container unlawfully.
Observe all federal, state, and local laws.
SECTION 14. TRANSPORT INFORMATION
<IMO INFORMATION>
ID No.:
None
CLASSIFICATION AND CLASS:
None
PACKAGING GROUP:
Sh* MSDS NO:EU -06- 05300037 617
PRODUCT NAME: KBE -903
None
PROPER SHIPPING NAME:
None
TECHNICAL SHIPPING NAME:
None
MARINE --POLLUTANT: ..._
None
<DOT INFORMATION>
ID No.(49CFR 172.101):
None
HAZARD CLASS(49CFR 172.101):
None
PACKING GROUP(49CFR 172.101):
None
PROPER SHIPPING NAME(49CFR 172.101):
None
TECHNICAL SHIPPING NAME:
None
DOT REPORTABLE QUANTITY(49CFR 172.101, APP.)
HAZARD SUBSTANCE(S) NAME / (CAS No.), CONTENTS AND RQ
Not applicable
SECTION 15. REGULATORY INFORMATION
TOXIC SUBSTANCES CONTROL ACT(TSCA) STATUS:
Listed on the TSCA Inventory.
EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES
(EINECS) STATUS:
Listed on the EINECS.
LABELING ACCORDING TO EC- REGULATIONS REQUIRED:
SYMBOL : C
R- PHRASE (R -22) Harmful if swallowed.
(R -34) Causes burns.
S- PHRASE (S -26) In case of contact with eyes, rinse
immediately with plenty of water and seek
medical advice.
(S- 36/37/39) Wear suitable protective clothing,
gloves and eye /face protection.
(S -45) In case of accident or you feel unwell
seek medical advice immediately
(show the label where possible).
CONTAINS Alkoxysilane ca.100%
WGK CLASSIFICATION (Water Resources Act in Germany):
WGK =1
Rr MSDS NO:EU -06- 05300037 7/7
PRODUCT NAME: KBE -903
SUPERFUND AMENDMENTS AND REAUTHORIZAITION ACT OF 1986(SARA)
TITLE III SECTION 313 SUPPLIER NOTIFICATION:
This regulation requires submission of annual reports of toxic
chemicals) that appear in section 313 of the emergency planning
and community Right -To -Know Act of 1986_an.d_40 CFR_372.
This information must be included in all MSDS's that are copied
and distributed for the material.
The toxic chemical(s) contained in this product are:
CHEMICAL NAME /(CAS No.) AND CONTENTS
** None **
CALIFORNIA PROPOSITION 65:
This regulation requires a warning for California Proposition 65 Chemical(s)
under the statute.
The California Proposition 65 Chemical(s) contained in this product are:
CHEMICAL NAME /(CAS No.) AND CONTENTS
** None **
SECTION 16. OTHER INFORMATION
For Industrial Use Only
* * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * * *
This materials safety data sheet is offered solely for your
information, consideration and investigation.
The data described in this MSDS consist of data on literature,
our acquisitional data and analogical inference by data of
similar chemical substance or product.
Shin -Etsu Silicones of America, Inc. provides no warranties, either
express or implied, and assumes no responsibility for the
accuracy or completeness of the data contained herein.
Mrcc 2
PAGE 01/06
MATERIAL SAFETY DATA SHEET
SECTION 1. COMPANY IDENTIFICATION
COMPANY IDENTIFICATION
MANUFACTURER'S NAME: Shin -Etsu Chemical Co., Ltd.
ADDRESS: 6 -1, 2- Chome, Ohtemachi, Chiyodaku, Tokyo, JAPAN
EMERGENCY TELEPHONE NUMBER:
330 - 630- 9860(Shin -Etsu Silicones of America, Inc.)
800 - 424- 9300(CHEMTREC) (24hrs) (Washington, D.C. USA)
TELEPHONE NUMBER FOR INFORMATION:
03- 3246 -5121 (Tokyo,JAPAN)
330 - 630- 9860(Shin -Etsu Silicones of America, Inc.)
DATA PREPARED :05/24/1994
LAST REVISION :04/17/1995
DATA ISSUED :01/26/1999
ISSUE NO 0041999010223
MSDS NO 0530109502GBR
BASE NO 02 -02
PRODUCT NAME:
KBM -1 3
PRODUCT CLASSIFICATION:
Silane
SECTION 2. COMPOSITION
SINGLE OR MIXTURE:
Single
CHEMICAL IDENTIFICATION:
Methyltrimethoxysilane
HAZARDOUS COMPONENTS) /(CAS No.):
Methyltrimethoxysilane /(1185 -55 -3) [Flammable Liquid] : 100%
(See Section 8 of this MSDS for Exposure Guideline)
SECTION 3. HAZARDS IDENTIFICATION
HAZARDS CLASSIFICATION:
Flammable Liquids (based on IMO)
FIRE AND EXPLOSION:
Highly flammable and explosive hazard
POTENTIAL HEALTH EFFECT:
INHALATION ; May cause slight irritation to mucous
membranes and upper respiratory tract.
SKIN contact; May cause slight skin irritation.
PRODUCT NAME: KBM -13
EYES contact; Causes eyes irritation.
INGESTION ; Low - harmful
SECTION 4. FIRST AID MEASURES
ISSUE NO.0041999010223 PAGE 02/06
INHALATION ; Remove to fresh air.
SKIN contact; Remove product from skin with dry cloth or
towel, and wash exposed area with detergent.
EYES contact; Immediately flush with plenty of water for at
least 15 minutes and promptly call a
physician.
INGESTION ; Wash out mouth with water provided person is
conscious. Never give anything by mouth to an
unconscious person. Call a physician
immediately.
SECTION 5. FIRE FIGHTING MEASURES
FLASH POINT(method used):
8 degrees C (Closed cup)
FLAMMABLE LIMITS:
LOWER: Not measured UPPER: Not measured
EXTINGUISHING MEDIA:
Foam, dry chemical or carbon dioxide
SPECIAL FIRE FIGHTING PROCEDURE:
None
UNUSUAL FIRE AND EXPLOSION HAZARD:
Vapors form explosive mixtures with air.
Vapors may travel considerable distance to source of ignition and flash back.
SECTION 6. ACCIDENTAL RELEASE MEASURES
STEP TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED:
Shut off all ignition sources.
Contain the spill or leak.
Scrape up with rag and place in container.
SECTION 7. HANDLING AND STORAGE
PRECAUTION TO BE TAKEN IN HANDLING AND STORING:
Keep container closed when not in use.
Store in a cool place.
Keep away from heat, sparks and flame.
Do not lay the container on its side.
Avoid prolonged breathing vapor.
Use with adequate ventilation.
Ai, ;A Ai-h 1 cLin
PRODUCT NAME: KBM -13
ISSUE N0.0041999010223 PAGE 03/06
Avoid contact with water or moisture.
Static electricity may accumulate and cause a fire hazard.
Keep out of reach of children.
* * * * * Information about the emptied container
Do not re -use this container.
This container will be very hazardous when emptied.
Residues will be explosive or flammable.
Keep away from heat, sparks and flame.
Do not puncture or cut this container, and do not weld on or near this container.
SECTION 8. EXPOSURE CONTROLS /PERSONAL PROTECTION
EXPOSURE GUIDELINES:
ACGIH TLV -TWA : Not established,
OSHA PEL : Not established [Methyltrimethoxysilane]
ACGIH TLV -TWA : 200ppm ; STEL 250ppm(SKIN),
OSHA PEL : 8H TWA 200ppm [Methanol; decomposed product]
RESPIRATORY PROTECTION (specify type):
Recommended
VENTILATION:
LOCAL EXHAUST: Required
MECHANICAL(general): Adequate ventilation system
SPECIAL: Unknown
OTHER: Unknown
PROTECTIVE GLOVES:
Plastic film or rubber gloves
EYE PROTECTION:
Safety glasses
OTHER PROTECTIVE CLOTHING OR EQUIPMENT:
Safety shower and eyewash equipment
WORK /HYGIENIC PRACTICES:
Keep away from heat, sparks and flame.
Avoid breathing vapor.
Avoid contact with eyes and skin.
Wash hands and gargle after handling.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
BOILING POINT:
102 degrees C
VAPOR PRESSURE:
45mmHg (25 degrees C)
VAPOR DENSITY(air =1):
4.7
SPECIFIC GRAVITY:
0.95 (25 degrees C)
PRODUCT NAME: KBM -13
MELTING POINT:
-78 degrees C
EVAPORATION RATE:
>1 (Butyl Acetate =1)
SOLUBILITY IN WATER:
Not soluble (Hydrolyzed with water)
APPEARANCE (color):
Colorless, transparent
APPEARANCE(form) :
Liquid
ODOR.
Slight odor
SECTION 10. STABILITY AND REACTIVITY
STABILITY:
ISSUE NO.0041999010223 PAGE 04/06
Unstable(But it will not vigorously polymerize, decompose,
condense, or will not become self - reactive under conditions
of shocks pressure or temperature.)
CONDITION TO AVOID:
Hydrolyzed %Ajith water, but no hazard.
INCOMPATIRILITY(material to avoid):
Water, acids or alkalis
HAZARDOUS DECOMPOSITION OR BY- PRODUCT:
Methanol (Flammable and Poisonous Liquid)
HAZARDOUS POLYMERIZATION:
Will not occur
CONDITION TO AVOID:
None
SECTION 11. TOXICOLOGICAL MFORMATION
SKIN IRRITATION:
SKIN-RABBIT: 500mg(Open) MILD
EYE IRRITATION:
EYE-RABBIT: 500mg /24Hr MILD
ACUTE TOXICITY (LD50):
LD50(Oral /Rat) : 12.5g /kg
LD50(Oral /Rat) : 5.628g/kg [Methanol; decomposed product]
ACUTE TOXICITY(LC50) :
LC50(lnhalation /Rat) : 64000ppm /4Hr
[Methanol; decomposed product]
CHRONIC TOXICITY:
May cause conjunctivitis, dizziness, sleeplessness, and
gastrointestinal and optical disturbances
[Methanol ; decomposed product].
PRODUCT NAME: KBM -13
ISSUE N0.0041999010223 PAGE 05/06
CARCINOGENICITY:
NTP:Not listed, IARC:Not listed, OSHA REGULATED:Not listed
MUTAGENICITY:
Negative (Bacteria)
OTHER INFORMATION:
None
SECTION 12. ECOLOGICAL INFORMATION
1. 0119 1r -.r 21 A
No information is available.
BIOACCUMULATiON:
No information is available.
AQUATIC TOXICITY:
No information is available.
OTHER INFORMATION:
Causes easily hydrolysis in water or atmosphere.
SECTION 13. DISPOSAL CONSIDERATIONS
Can be burned in chemical incinerator equipped with
afterburner and scrubber but exert extra care in igniting
as this product is very flammable.
Do not dispose of the emptied container unless the contents
have been completely removed and container has been flushed
with a clean neutral solvent and then dried up.
Do not dispose the emptied container unlawfully.
Observe all federal, state, and local laws.
SECTION 14. TRANSPORT INFORMATION
UN No.:
UN 1993
IMO CLASSIFICATION AND CLASS:
Flammable Liquids / Class 3.2
PACKAGING GROUP:
11
PROPER SHIPPING NAME:
Flammable Liquids, N.O.S.
TECHNICAL SHIPPING NAME:
Organosilane
MARINE POLLUTANT:
None
DOT REPORTABLE QUANTITY (RQ) :
HAZARD SUBSTANCE(S) NAME / (CAS No.), CONTENTS AND RQ
Not applicable
PRODUCT NAME: KBM -13 ISSUE NO.0041999010223 PAGE 06/06
SECTION 15. REGULATORY INFORMATION
TOXIC SUBSTANCES CONTROL ACT(TSCA) STATUS:
Listed on the TSCA Inventory.
EUROPEAN INVENTORY OF EXISTING COMMERCIAL CHEMICAL SUBSTANCES(EINECS) STATUS:
Listed on the EINECS.
LABELING ACCORDING TO EC- REGULATIONS REQUIRED:
SYMBOL : F
R- PHRASE : (R -11) Highly flammable
S- PHRASE : (S -9) Keep container in a well - ventilated place.
(S -16) Keep away from sources of
ignition -No smoking.
(S -51) Use only in well- ventilated areas.
CONTAINS: Methyltrimethoxysilane 100%
SUPERFUND AMENDMENTS AND REAUTHORIZAITION ACT OF 1986 (SARA) TITLE III SECTION
313 SUPPLIER NOTIFICATION:
This regulation requires submission of annual reports of toxic chemical (s) that
appear in section 313 of the emergency planning and community Right -To -Know Act
of 1986 and 40 CFR 372. This information must be included in all MSDS's that are
copied and distributed for the material.
The toxic chemical (s) contained in this product are:
CHEMICAL NAMU(CAS No.) AND CONTENTS
** None **
CALIFORNIA PROPOSITION 65:This regulation requires a warning for California
Proposition 65 Chemical (s) under the statute.
The California Proposition 65 Chemical(s) contained in this product are:
CHEMICAL NAMEACAS No.) AND CONTENTS
** None **
SECTION 16. OTHER INFORMATION
For Industrial Use Only
This materials safety data sheet is offered solely for your information,
consideration and investigation. The data described in this MSDS consist of data
on literature, our acquisitional data and analogical inference by data of
similar chemical substance or product. Shin -Etsu Chemical Co., Ltd. provides no
warranties, either express or implied, and assumes no responsibility for the
accuracy or completeness of the data contained herein.
.rX UVvnn
Material Safetv Data Sheet
NFPA
OSHA HCS Risk Phrases
Personal Protective
Equipment
CLASS: Irritating substance.
C/1�
Section 1
Chemical Product: and Company Identification
Common Name/ Cata -Chek® 860
Trade Name I VA5
Manufacturer
Ferro Corporation, Polymer Additives Division
Walton Hills Operation
7050 Krick Road
Walton Hills, Ohio 44146 -4494 USA
Emergency Phone Numbers
CHEMTREC: 1- 800 - 424 -9300
24 Hour Information: 1- 216 - 641 -5324
Plant -Wr4/10/2002. 16- 750 -6708
Issued
Chemical Name
Stannous Octoate
Chemical Family Polymer Additive
Synonym
Hexanoic acid, 2- ethyl -, tin(2 +) salt
CAS#
301 -10 -0
Section .2
Composition and Information on Ingredients
INGREDIENTS
CAS #
% Weight
OSHA (PEL) ACGIH (TLV)
1) Tin (organic
compounds, as Sri)
7440 -31 -5
25 -30
TWA: 0.1 (mg /m3) from OSHA (PEL) [United States]
TWA: 0.1 (mg /m') from ACGIH (TLV) [United States]
Section 3
Hazards Identification
Emergency Overview
CAUTION!
Color : Yellow.
Physical state : Liquid. (Clear)
Odor : Bland.
MAY CAUSE EYE AND SKIN IRRITATION. HARMFUL IF ABSORBED THROUGH SKIN. MAY BE HARMFUL IF
SWALLOWED OR INHALED.
Potential Health Effects
Acute May cause mild irritation with direct contact. Harmful if absorbed through the skin. Can cause
gastrointestinal irritation.
Chronic
There is no known effect from chronic exposure to this product. Not listed as carcinogen by OSHA, NTP
or IARC.
Section .4
First Aid Measures
....................
Eye
Flush with plenty of water for at least 15 minutes, occasionally lifting the upper and lower eyelids. If
irritation persists, seek medical attention.
Skin
Gently and thoroughly wash the contaminated skin with running water and non- abrasive soap. If irritation
persists, seek medical attention.
Inhalation
Allow the victim to rest in a well ventilated area. Oxygen may be administered if breathing is difficult.
Seek medical attention.
Ingestion
Do not induce vomiting. Drink two large glasses of water. Seek immediate medical attention.
Section 5
Fire and Explosion Data
Flash Point
CLOSED CUP: 140 °C (284 °F). (Pensky- Martens.)
Flammability
Non- flammable.
Fire Fighting Media Use DRY chemicals, CO2, water spray or foam. Use extinguishing media suitable for surrounding materials. Fire fighters
and Instructions should wear proper protective equipment. A self contained breathing apparatus should be used to avoid inhalation of the product.
Combustion Products Tin Oxide. Products of combustion, carbon oxides (CO, CO2).
Fire Hazards
When heated to decomposition it emits toxic fumes (oxides of tin).
Continued on Next Page
Cata -Ch&C 860 Ferro Corporation, Polymer Additives Division Page Number 2
Section 6
Accidental Release Measures
Small Spill
Absorb with an inert material and place in an appropriate waste disposal container.
Large Spill
Absorb with DRY earth, sand or other non - combustible material. Dike spill area and do not allow product
to reach sewage system and surface or ground water. Wear suitable protective clothing, gloves and
eye /face protection.
Personal Protection
y
Small Spill Safety glasses. Gloves.
Large Spill
Splash goggles. Protective clothing. Gloves. Boots. Wear appropriate respirator when ventilation is
inadequate.
Section 7
Handling:and Storage
Precaution
Avoid contact with eyes, skin, and clothing. Wear suitable gloves and eye /face protection. Do not ingest.
Use only in well - ventilated areas.
Storage
Keep container tightly closed. Keep container in a cool, well - ventilated area. Store away from
incompatible materials.
Section 8
Exposure Controls/Personal Protection
Engineering Controls Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of
vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers
are close to the work - station location.
Personal Protection Safety glasses. Gloves.
Exposure Limits
See Section 2
Section 9.
Physical and Chemical Properties
Physical state
Liquid. (Clear)
Odor Bland.
pH (1% saWwater)
Not applicable.
Color Yellow.
Boiling Point
Not available.
SpeciBcGravity 1.273 (Water = 1)
Vapor Pressure
Not available.
Vapor Density Not available.
Volatility
Not available.
Viscosity Not available.
Evaporation rate
<1 compared to Butyl acetate.
Solubility Insoluble in cold water, hot water.
Section 10
Stability and Reactivity Data
Instability
The product is stable.
Will material polymerize? Will not occur.
Incompatibiles
Reactive with oxidizing agents.
Corrosivity
Non- corrosive in presence of glass, of steel.
Section 11
Toxicological Information
Routes of Entry
Absorbed through skin. Eye contact.
Toxicity to
Animals
Acute oral toxicity (LD50): >2000 mg /kg [Rabbit].
Acute Effects
May cause mild irritation with direct contact. Harmful if absorbed through the skin. Can cause
gastrointestinal irritation.
Chronic Effects
There is no known effect from chronic exposure to this product. Not listed as carcinogen by OSHA, NTP
or IARC.
Continued on Next Page
Cata-ChekCk 860
Ferro Corporation, Polymer Additives Division Page Number: 3
Section 1.2
Ecological Information
Ecotoxicity
Not available.
Biodegradation
Not available.
Section 13
Disposal Considerations
Waste Disposal
Recycle, if possible. Dispose of according to all federal, state and local applicable regulations. This
product is a nonhazardous waste when disposed of, as defined in Resource Conservation Recovery Act
(RCRA) regulations (40 CFR 261).
Section 14
Transport information
DOT Classification Not a DOT controlled material (United States).
Reportable Quantity CERCLA: Hazardous substances.: No products were found.
Marine Pollutant
Not applicable.
Special Provisions for No additional remark.
Transport
Canada
Not controlled under TDG (Canada).
TDC Classification
WHMIS
Not WHIvIIS controlled material.
Section 15
Other Regulatory fnformation
State Regulations
Rhode Island RTK hazardous substances: Tin (organic compounds, as Sn)
Pennsylvania RTK: Tin (organic compounds, as Sn)
Florida: Tin (organic compounds, as Sn)
Minnesota: Tin (organic compounds, as Sn)
Massachusetts RTK: Tin (organic compounds, as Sn)
New Jersey: Tin (organic compounds, as Sn)
California prop. 65: No products were found.
Reportable Quantity
CERCLA: Hazardous substances.: No products were found.
SARA 313
SARA 313 toxic chemical notification and release reporting: No products were found.
HMIS (U.S.A.)
`Health :Hazard >Fiie;Hazard Q Reactivity Q- Personal Protection B
TSCA 8(b)
TSCA (Toxic Substance Control Act): This product is listed on the TSCA Inventory.
Canadian environmental protection act (CEPA): This product is on the Domestic Substances List (DSL)
inventory
CEPA
EINECS: This product is on the European Inventory of Existing Commercial Chemical Substances.
EINECS Status
Section 1!6
Other Information
References
Not available.
Issued on 4/10/2002.
M_u wti Cata -Chek
Notice to Reader
The information and recommendations contained in this Material Safety Data Sheet have been compiled from sources
believed to be reliable and to represent the most reasonable current opinion on the subject when the MSDS was prepared.
No warranty, guaranty or representation is made as to the correctness or sufficiency of the information. The user of this
product must decide what safety measures are necessary to safely use this product, either alone or in combination with other
products, and determine its environmental regulatory compliance obligations under any applicable federal or state laws.
Instructions to the customer /purchaser.
This MSDS contains important environmental, safety and health information for your employees who will be using this product. Please give
this information to them. If you resell this product, give a copy of this MSDS to the buyer.
fL.(A- v . i X. v , lfl"L ncc. to lSO/DI""I 4 recut
Printing date 0313012004 Reviewed on
11dentification of r r
•Product details
Trade name 1,3 Div* Itetrametlh 1- disilox _ —
-�
Application " t e substance /the preparation General purpose
Manufacturer /Supplier:
B.R.B. International B. V
- •A
Branskamp 10 — ---- ---- --
6014 CB Ittervoort, Holland
Tel. 0031475560306
Fax.0031475560323
Information department: Research & Development
CompositionlData on components
Chemical characterization:
CAS No. Description
1627 -95 -4 1,1,3,3- tetramethyl- 1,3- divinylsiloxane
Identification number(s) Einecs number 220 -099 -6
Hazards
Hazard description:
=. Irritant
//
`' �` a ' lr
Information pertaining to particular dangers for man and environment:
Flammable.
i! `/
Irritating to skin.
Classification system:
NFPA ratings (scale 0 - 4)
Health = 2
Fire = 3
Reactivity = 0
HMIS- ratings (scale 0 - 4)
2 Health = 2
3 Fire = 3
REACTIVITYrO Reactivity = 0
4 First aid r
• After inhalation: In case of unconsciousness place patient stably inside position for transportation.
After skin contact. Immediately wash with water and soap and rinse thoroughly.
After eye contact. Rinse opened eye for several minutes under running water.
After swallowing: Ifsymptoms persist consult doctor.
5 Firefighting ineasures
Suitable extinguishing agents: CO2, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
Protective equipment. No special measures required.
r Accidental release ineasures
Person- related safety precautions: Wear protective equipment. Keep unprotected persons away.
Measures for environmental protection: No special measures required.
(Contd. on page 2)
LV.&g4M1 LILT UIIJGIy ""t" UIMC9
acc. to ISO /DIS 11014
Printing date 0313012004
Reviewed on 0911112002
Trade name: 1,3 Divinyltetrametllyl- disiloxa»e
(Contd. of page 1)
• Measures for cleaning /collecting: Absorb with liquid- binding material (sand, diatomite, acid binders, universal binders, sawdust).
Handling and storage
• Handling:
Information for safe handling:
Keep receptacles tightly sealed.
Use only in well ventilated areas.
Information about protection against explosions and fires:
Keep ignition sources away - Do not smoke.
Protect against electrostatic charges.
Storage:
Requirements to be met by storerooms and receptacles. Store only in the original receptacle.
Information about storage in one common storage facility: Not required.
Further information about storage conditions:
Store receptacle in a well ventilated area.
Keep receptacle tightly sealed.
Exposure / andpersonal
• Additional information about design of technical systems: No further data; see item 7.
Components with limit values that require monitoring at the workplace: Not required.
Additional information: The lists that were valid during the creation were used as basis.
Personal protective equipment:
General protective and hygienic measures:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing.
Wash hands before breaks and at the end of work.
Avoid contact with the skin.
Avoid contact with the eyes and skin.
Breathing equipment: Not required.
Protection of hands:
() Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/ the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the degradation
Material ofgloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality and varies from
manufacturer to manufacturer.
Penetration time ofglove material
The exact break trough time has to be found out by the manufacturer of the protective gloves and has to be observed.
Eye protection:
i Tightly sealed goggles
9 Physical and chenticalproperfies
General Information
Form: Liquid
Color: Colorless
Odor: Weak, characteristic
Change in condition
Melting point/Melting range: Undetermined.
Boiling poindBoiling range: 139 °C (282 °F)
Flash point: 26 °C (79 °F)
(Contd. on page 3)
tl /J I V i I \t L) il lYl ULGIIUL UUf GLy LULU JrIrGL
acc. to ISO/DIS 11014
Printing date 0313012004 Reviewed on 0911112002
Trade name: 1,3 Divinyltetranrethyl- disiloxane
(Contd. of Dace 2)
Danger of explosion:
Product is not explosive. However, formation of explosive air /vapor mixtures are possible.
Density:
Not determined.
Bulk density at 20 °C (68 °F):
810 kg /m'
Solubility in I Miscibility with
Water:
Slightly soluble.
/ -Stability
Thermal decomposition /conditions to be avoided. No decomposition if used according to specifications.
Dangerous reactions No dangerous reactions known.
Dangerous products of decomposition: No dangerous decomposition products known.
1.1 Toxicological information
Acute toxicity:
Primary irritant effect:
on the skin: Irritant to skin and mucous membranes.
on the eye: No irritating effect.
Sensitization: No sensitizing effects known.
Ecological i
General notes: Not known to be hazardous to water.
13 Disposal considerations
Product.
Recommendation: Must not be disposed of together with household garbage. Do not allow product to reach sewage system.
Uncleaned packagings.
Recommendation: Disposal must be made according to official regulations.
Transport
• DOT regulations:
i.
Hazard class: 3
Identification number: UN1993
Packing group: III
Proper shipping name (technical name): FLAMMABLE LIQUID, N.O.S. (1,1,3,3- tetromethyl- 1,3- divinylsiloxane)
Label 3
• Land transport ADRIRID (cross- border):
ADRIRID class. 3 Flammable liquids
Danger code (Kemler): 30
UN- Number: 1993
Packaging group: III
(Contd. on page 4)
✓ 11 \1 ✓ 1rl KL[./ 1•K[ LJ NJ GLy LWLK ✓ /LGGL
ace. to ISO/DIS 11014
,Printing date 0313012004
Reviewed on 0911112002
Trade name: 1,3 Divinyltetramethyl- disiloxane
(Contd. of pagc 3)
Description ofgoods: 1993 FLAMMABLE LIQUID, N.O.S., special provision 640E (1,1,3,3- tetramethyl-1,3-
divinylsiloxane)
Maritime transport IMDG.
4
1
IMDG Class: 3
UN Number: 1993
Label 3
Packaging group: III
EMS Number. F -ES-E
Propper shipping name: FLAMMABLE LIQUID, N.O.S. (1,1,3,3- letr-aniethvl -1,3- divinylsiloxane)
Air transport ICAO -TI and IATA -DGR:
4
ICAO11ATA Class: 3
UN/ID Number: 1993
Label 3
Packaging group: III
Propper shipping name: FLAMMABLE LIQUID, N.O.S. (1,1,3,3- tet)-amethyl -1,3- divinylsiloxane)
Sara
Section 355 (extremely hazardous substances): Substance is not listed.
Section 313 (Specific toxic chemical listings): Substance is not listed.
TSCA (Toxic Substances Control Act): Substance is listed.
Proposition 65
Chemicals known to cause cancer: Substance is not listed.
Chemicals known to cause reproductive toxicity: Substance is not listed.
Cancerogenity categories
EPA (Environmental Protection Agency) Substance is not listed.
IARC (International Agency for Research on Cancer) Substance is not listed.
NIP (National Toxicology Program) Substance is not listed.
TL (Threshold Limit Value established by ACGIH) Substance is not listed.
MAK (German Maximum Workplace Concentration) Substance is not listed.
NIOSH - -Ca (National Institute for Occupational Safety and Health) Substance is not listed.
OSHA -Ca (Occupational Safety & Health Administration) Substance is not listed.
Product related hazard informations:
The product has been classified and marked in accordance with directives on hazardous materials.
Hazard symbols:
Irritant
Risk phrases:
Flammable.
Irritating to skin.
- Safety phrases:
Wear suitable gloves.
Other information
This information is based on our present knowledge. However, this shall not constitute a guarantee for any specific product features and
shall not establish a legally valid contractual relationship.
Department issuing MSDS: Research and Development
Contact: Ing. R.J.H. Houben
Or-4-90
DATE OF PREPARAT 0
PREPARED BY. ._ MATERIAL SAFETY DATA SHEET 1117
To the Purchaser: This MSDS contains important environmental, safety and health information for your employees who will be using this
product. Please be sure this information is given to them. If you resell this product, a copy of the MSDS should be given to the
buyer.
MANUFACTURER'S NAME:
BEDFORD C:HENICAL DIVISION — Ferro Corporation
ADDRESS (Number, Street, City, State & Zip Code)
7050 }; r i r-- k: Road, Walton Hills, Ohio 44146-4494
TRADE NAME:
CATA -cam $zo
CHEMICAL & COMMON NAME(S):
Dibutyl tin dilaurate.
SECTION I
SECTION II
OSHA POTENTIAL HAZARDOUS INGREDIENT(S)
COMPONENT CAS # PCT.
TIN (ORGANIC Cpds. - as Tin) 77 -58-7 100.0
Emergencu Telephone Numbers:
CHEMTREC: (800)424 -9300
24 -HR INFO: (216)641 -5324
Plant: (216) 641 -8580
DOT CLASSlID NUMBER:
Not regulated.
FORMULA:
C32H64O4Sn
EXPOSURE LIMIT
ACGIH -TLU OSHA -PEL
0.1 mglm3* 0. 1 mglm3f NF
313
OTHER MATL.
This product contains a USEPA Section 313 chemical subject to the reporting requirements of Title III of SARA and 40 CFR
Part 372 Yes_ N0 -X
dDOITIONAL INFORMATION:
* SKIN.
VA = NOT APPLICABLE NF = NOT FOUND
PAGE I OF 3
NO
CATA —CWK(9 820
BOILING POINT ( °C): NA
VAPOR PRESSURE (mm Hg): NF
VAPOR DENSITY (AIR =1): NF
SOLUBILITY IN PATER: Insoluble
APPEARANCE: Yellow liquid
FEE 2 OF 3
4 -4-90
SECTION III - PHYSICAL DATA
SPECIFIC GRAVITY 020 =1): 1.65
VOLATILES BY VOLUME ('1.): NA
EVAPORATION RATE (BUTYL ACETATE =1)
NA
MELTING POINT ( °C): NF
ODOR: MILD FATTY ACID
SECTION I U - FINE & EXPLOSION HUAND DATA
FLASH POINT (Method Used): )43 C (PMCC)
FLAMMABLE LIMITS LEL NF UEL NF
EXTINGUISHING MEDIA:
Carbon dioxide, foam, dry chemical. (National Fire Protection Assoc. CIass B extinguishers).
SPECIAL FIRE FIGHTING PROCEDURES:
pater spray may be ineffective. Use water to cool closed containers. Emergency response personnel
should wear protective clothing and use self— contained breathing apparatus.
UNUSUAL FIRE 5 EXPLOSION HAZARDS (See Reactivity Section for other physical hazards):
Closed containers may explode when exposed to extreme heat or fire. If burned,
material could give off Toxic Fumes!
SECTION D - NEACT I D I TY DATA
UNSTABLE CONDITIONS TO AVOID:
STABILITY: X STABLE Not Applicable
INCOMPATIBILITY (Materials to Avoid):
Strong oxidizing agents.
HAZARDOUS DECOMPOSITION PRODUCTS:
Oxides of tin.
HAZARDOUS _.May Occur CONDITIONS TO AVOID:
POLYMERIZATION X pill Not Occur Not Applicable
SECTION DI - HEALTH HKAND DATA
PRIMARY ROUTES OF ENTRY:
Inhalation, ingestion.
LISTED AS A CARCINOGEN? Yes No X
SYMPTOMS AND EFFECTS OF OVEREXPOSURE:
NF
EMERGENCY AND FIRST AID PROCEDURES:
In case of skin or eye contact, flush with lukewarm water.
If swallowed, call a physician immediately.
If inhaled, move patient to fresh air.
PAGE 2 OF 3
tunnnTnur.nrr nnnr n rnn nrnro nrurnn
CATA— CHE%—,, $ 0
SECTION U I I - SPILL OR LEAK PROCEDURES
STEPS TO BE TAKEN IN CASE MATERIAL IS RELEASED OR SPILLED
When liquid spills may occur, wear apron, rubber gloves and chemical eye goggles.
Cover with inert, absorbent material (sawdust, etc.) and remove to disposal con-
tainers. Nash clothing before reuse.
WASTE DISPOSAL METHOD:
Dispose of in accordance with Federal, state and local regulations.
SECTION U I I I - RECOMMENDED CONTROL MEASURES
RESPIRATORY PROTECTION:
If concentration exceeds TLV, use NIOSHIMSHA approved respirator as necessary.
LOCAL EXHAUST: As necessary to control fume or mist. SPECIAL:
VENTILATION: MECHANICAL (General): Normally adequate. pP
Not Applicable
PROTECTIVE GLOVES: EYE PROTECTION:
Use gloves impervious to oils. Use chemical goggles.
OTHER PROTECTIVE EQUIPMENT:
Rubber apron
SPECIAL PROTECTIVE MEASURES FOR REPAIR AND MAINTENANCE OF CONTAMINATED EQUIPMENT:
Emergency personnel should wear protective clothing and assure adequate air for breathing.
SECTION I - SPECIAL PRECAUTIONS
PRECAUTIONS TO BE TAKEN IN HANDLING & STORING (Including appropriate hggenic practices):
Store in cool areas. Keep containers tightly closed. Keep away from sparks and
open flame. Keep away from feed or food products. Prevent water contamination.
PAGE 3 OF 3
4 -4 -90
Judgments as to the suitability of information herein for the purchaser's purposes are necessarily the
purchaser's responsibility. Reasonable care has been taken in the preparation of this information, but
FERRO EXTENDS NO WARRANTIES, MAKES NO REPRESENTATIONS AND ASSUMES NO RESPONSIBILITY AS TO THE ACCURACY
OR SUITABILITY OF THIS INFORMATION FOR ANY PURCHASER'S USE OR FOR ANY CONSEQUENCE OF ITS USE.
PAGE 3 OF 3
GFS '$EMICALS, INC.
we 1, 065
740 - 881- 5501(Tel.) 740 - 881- 5989(Fax)
1- 800 - 424- 9300(Chemtrec 24Hr. Info.)
MATERIAL SAFETY DATA SHEET
/ 'TOLUENE
CHEMICAL .NAME & SYNONYMS
Toluene, Methvl Benzene; Toluol
FORMU LiZ:.
C6HSCF=1;
REPORTABLE (UAII T Y
IT
454 kg
�� S15 �
DOT CLASS
3 /II
TSCA listed
F.W.
92.14
2493
SARA TITLE 313
Yes
- Yes
CAS#
108 -88 -3
PHYSICAL_ _DATA
Density ' � ` ?6 ?; w; = ... a ?oi..n.- 950C; Boiling point 110 °C.; �Tapor pressure 36.7 mm
tt:c at _;e' ';'; . j� _: A _isity 3 . 14; Odor threshold 2 ppm. S� _)lu , _1ity in water 0.05
9/100 ml .a -F,, .Taporation rate. 2.4
APPEARANCE & ODOR_
Clear ccl:?-rl(_;s liquid. Characteristic aromatic odor.
RFAC'TI'VITY _f<_CONDITIONS TO AVOID
Stable. 1.�: n ?.t:�ble. No hazardous self - reaction. IncoT- mDaLt.J_b1.e with oxidizers.
i IRE FIT .T ''DS
c: ; s 7 ^oiirces . Emits sooty smoke. Avoi c., inhalation of smoke.
Firefi :,. _t ;2 dFPA # 2 -3 -0.
EXTINGUISHER F LASHPOI_NT LEL UEL
4 °C CO-,, f )qtr. .-0 7.1.
HEALTil HAZARDS
Irritating to s:;ii., eyes, and. mucous membranes. OSHA PEL: TWA 200 ppm; Ceiling
300 ppm. A':'C .T T I'r,V: TWA: 50 ppm. . Symptoms of over exposure are headache,
nausea., eye irritation, loss of appetite, bad taste in mouth and lassitude.
Extreme: e«}?osure may lead to narcosis, intoxication or coma. Chronic exposure
may lead to anemia and bone marrow damage. Toxicities LD50 (oral -rat) 636 mg /kg;
TCL,, (ihl -rat) 1000 mg/ m3/24 hrs 0 -14 day preg.) . Suspect carcinogen, mutagen,
t.eratoger . ng: This product contains a chemical :mown to the state of
Califr.lni:=I t., b:i.rth deiecct.s or other reproductive harm.
SPEC TAi
Wear , g: _j ,.i : a -, :--, biDe gloves while handling. Use only with good ventilation
or sl�litab.lc- respirator. Wash clothing before re-use.
FIRST 2-0!;
Wash co�.it. =a ic:.ot.g:h1_,T with water. For eyes or if irritation persists, get
medical as ,i;.: In.inalation: remove to fresh air. If breathing is difficult,
give oxygen. If breathing stops, give artificial respiration. Get medical
assistance. if swallowed, d.0 not. induce vomiting. Get medical attention
immediately.
SPILLS & LEAKS
Remove possible ignition :-sot_: rces . Coiita:i"t i spi 1. . Ta.: <_.e up spill in suitable
absorb(---r C _r11:' ?1. 3tc !Dc not al .'i ow sp -1.1_ t. c. L -ez ch sewer system.
PREPARED BY DATE
"4 93 . _ n- 1DI1 February 5, 2003
The Chemical Comrqqny
Safety data sheet
2- Methyl -3- butyn -2 -ol
Revision date: 2006/05/12 Page: 116
Version: 1.0 (30042498/MDS GEN US /EN)
1. Substance /preparation and company identification
Company 24 Hour Emergency Response Information
BASF CORPORATION CHEMTREC: 1- 800 - 424 -9300
100 Campus Drive BASF HOTLINE: 1- 800 - 832 -HELP
Florham Park, NJ 07932
Molecular formula: (CH3)2C(OH)CCH
Chemical family: alcohols, unsaturated
Synonyms: 2- Methyl -3- butyn -2 -ol
2. Composition /information on ingredients
CAS Number Content (WM) Chemical name
115 -19 -5 99.0% 2- methylbut- 3- in -2 -ol
3. Hazard identification
Emerciency overview
DANGER: FLAMMABLE LIQUID. MAY BE HARMFUL IF SWALLOWED.
MAY BE HARMFUL IF INHALED.
CAUSES EYE IRRITATION.
RISK OF SERIOUS DAMAGE TO EYES.
INGESTION MAY CAUSE GASTRIC DISTURBANCES.
Has a narcotic effect.
Avoid contact with the skin, eyes and clothing.
Avoid inhalation of mists /vapours.
Use with local exhaust ventilation.
Wear a NIOSH - certified (or equivalent) organic vapour /particulate respirator.
Wear NIOSH - certified chemical goggles.
Wear full face shield if splashing hazard exists.
Wear chemical resistant protective gloves.
Wear protective clothing.
Eye wash fountains and safety showers must be easily accessible.
Potential health effects
Primary routes of exposure
Routes of entry for solids and liquids include eye and skin contact, ingestion and inhalation. Routes of entry
for gases include inhalation and eye contact. Skin contact may be a route of entry for liquified gases.
Medical conditions aggravated by overexposure:
Data available do not indicate that there are medical conditions that are generally recognized as being
aggravated by exposure to this substance /product.
Safety data sheet
2- Methyl -3- butyn -2 -ol
Revision date: 2006/05/12 Page: 2/6
Version: 1.0 (30042498/MDS GEN MEN)
See MSDS section 11 - Toxicological information.
4. First -aid measures
General advice:
Remove contaminated clothing.
If inhaled:
Remove the affected individual into fresh air and keep the person calm. Assist in breathing if necessary.
Immediate medical attention required.
If on skin:
Wash affected areas thoroughly with soap and water. Remove contaminated clothing. Wash soiled clothing
immediately. Immediate medical attention required.
If in eyes:
In case of contact with the eyes, rinse immediately for at least 15 minutes with plenty of water. Immediate
medical attention required.
If swallowed:
Rinse mouth and then drink plenty of water. Do not induce vomiting. Never induce vomiting or give anything
by mouth if the victim is unconscious or having convulsions. Immediate medical attention required.
5. Fire - fighting measures
Flash point: 22 °C (DIN 51755)
Autoignition: 350 °C (DIN 51794)
Lower explosion limit: 1.8 %(V)
Upper explosion limit: 16.0 %(V)
Suitable extinguishing media:
water fog, foam, carbon dioxide, dry extinguishing media
Unsuitable extinguishing media for safety reasons:
water
Hazards during fire - fighting:
Substance /product is dangerous when exposed to heat or flames.
Protective equipment for fire- fighting:
Firefighters should be equipped with self - contained breathing apparatus and turn -out gear.
Further information:
If exposed to fire, keep containers cool by spraying with water.
NFPA Hazard codes:
Health : 3 Fire: 3 Reactivity: 0 Special:
6. Accidental release measures
Personal precautions:
Ensure adequate ventilation.
Environmental precautions:
Substance /product is RCRA hazardous due to its properties.
Safety data sheet
2- Methyl -3- butyn -2 -ol
Revision date : 2006/05/12 Page: 3/6
Version: 1.0 (30042498/MDS GEN US /EN)
Cleanup:
Spills should be contained, solidified, and placed in suitable containers for disposal.
7. Handling and storage
Handling
General advice:
Ensure thorough ventilation of stores and work areas.
Protection against fire and explosion:
See MSDS section 5 - Fire fighting measures.
Storage
General advice:
Avoid all sources of ignition: heat, sparks, open flame.
8. Exposure controls and personal protection
Advice on system design:
Provide local exhaust ventilation to control vapours /mists.
Personal protective eauioment
Respiratory protection:
Wear a NIOSH - certified (or equivalent) organic vapour/particulate respirator. Do not exceed the maximum
use concentration for the respirator facepiece /cartridge combination. For emergency or non - routine, high
exposure situations, use a NIOSH - certified full facepiece pressure demand self- contained breathing
apparatus (SCBA) or a full facepiece pressure demand supplied -air respirator (SAR) with escape provisions
Observe OSHA regulations for respirator use (29 CFR 1910.134).
Hand protection:
Chemical resistant protective gloves, Consult with glove manufacturer for testing data.
Eye protection:
Tightly fitting safety goggles (chemical goggles). Wear face shield if splashing hazard exists.
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g. head protection, apron,
protective boots, chemical- protection suit.
General safety and hygiene measures:
Eye wash fountains and safety showers must be easily accessible. Wear protective clothing as necessary to
prevent contact.
9. Physical and chemical properties
Form:
liquid
Odour:
pleasant
Colour:
colourless to yellow
pH value:
No data available.
Melting point:
3 °C
Boiling point:
102 - 105 °C
Vapour pressure:
20 mbar ( 20 °C)
Density:
0.8608 g /cm3 ( 20 °C)
Safety data sheet
2- Methyl -3- butyn -2 -ol
Revision date: 2006/05/12 Page: 4/6
Version: 1.0 (30042498/MDS GEN US /EN)
Partitioning coefficient n- 0.32
octanol /water (log Pow):
Viscosity, dynamic: 3.02 mPa.s
Solubility in water:
10. Stability and reactivity
Conditions to avoid:
Avoid all sources of ignition: heat, sparks, open flame.
Substances to avoid:
oxidizing agent
Hazardous reactions:
The product is chemically stable.
Reacts with oxidizing agents.
Corrosion to metals:
No corrosive effect on metal.
11. Toxicological information
Acute toxicity
Oral:
LD50 /rat: 1,420 mg /kg
Inhalation:
LC50 /rat: > 21.3 mg /I / 4 h
Skin irritation:
rabbit: non - irritant (BASF -Test)
Eye irritation :
rabbit: Irritant. (BASF -Test)
Risk of serious damage to eyes.
Chronic toxicity
Experiences in humans:
High concentrations have a narcotizing effect.
(20 °C)
( 20 °C) miscible
Other information:
No experimental evidence available for genotoxicity in vitro (Ames test negative).
12. Ecological information
Environmental fate and transport
Bioaccumulation:
Safety data sheet
2- Methv1-3- butvn -2 -o1
Revision date: 2006/05/12 Page: 5/6
Version: 1.0 (30042498 /MDS_GEN US /EN)
Because of the n- octanol /water distribution coefficient (log Pow) accumulation in organisms is not to be
expected.
Chemical oxygen demand (COD):
2,390 mg /g
Biochemical oxygen demand (BOD):
: 20 mg /g
13. Disposal considerations
Waste disposal of substance:
Dispose of in a RCRA - licensed facility.
Do not discharge into waterways or sewer systems without proper authorization.
Dispose of in accordance with national, state and local regulations.
Container disposal:
Empty containers with less than 1 inch of residue may be landfilled at a licensed facility. Recommend
crushing, puncturing or other means to prevent unauthorized use of used containers. If containers are not
empty, they must be disposed of in a RCRA - licensed facility.
RCRA: D001
14. Transport information
Land transport
USDOT
Proper shipping name: ALCOHOLS, N.O.S. (contains 2- METHYLBUT- 3- YN -2 -OL)
Hazard class: 3
ID- number: LIN 1987
Packing group: li
Sea transport
IMDG
Proper shipping name:
ALCOHOLS, N.O.S. (contains 2- METHYLBUT- 3- YN -2 -OL)
Hazard class:
3
ID- number:
UN 1987
Packing group:
II
Marine pollutant:
NO
Air transport
IATA/ICAO
Proper shipping name:
ALCOHOLS, N.O.S. contains (2- METHYLBUT- 3- YN -2 -OL)
Hazard class:
3
ID- number:
UN 1987
Packing group:
11
Safety data sheet
2- Methyl -3- butyn -2 -ol
Revision date : 2006/05/12 Page: 6/6
Version: 1.0 (30042498 /MDS_GEN US /EN)
15. Regulatory information
Federal Regulations
Registration status:
TSCA, US released / listed
OSHA hazard category: Flammable Liquid, Acute target organ effects reported
SARA hazard categories (EPCRA 3111312): Fire, Acute
State regulations
State RTK
CAS Number Chemical name State RTK
115 -19 -5 2- methylbut- 3- in -2 -ol MA, NJ, PA
16. Other information
HMIS III rating
Health: 3 Flammability: 3 Physical hazard: 0
HMIS uses a numbering scale ranging from 0 to 4 to indicate the degree of hazard. A value of zero means that the
substance possesses essentially no hazard; a rating of four indicates high hazard.
Local contact information
prod_reg @basf.com
IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN
ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR
GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION /USE,
WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR
YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER
EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A
PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR
INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE
USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE
SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A
PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND
AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY BASF
HEREUNDER ARE GIVEN GRATIS AND BASF ASSUMES NO OBLIGATION OR LIABILITY FOR THE
DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH
BEING GIVEN AND ACCEPTED AT YOUR RISK.
END OF DATA SHEET
COMPANY IDENTITY: SolvChem, Inc. DATE: 03/23/11
PRODUCT IDENTITY: ACETONE PAGE: 1 OF 8
SDS NUMBER: ACETONE
SAFETY DATA SHEET
This Safety Data Sheet conforms to ANSI Z400.5, and to the format requirements
and the International Chemical Safety Cards of the Global Harmonizing System.
THIS SDS COMPLIES WITH 29 CFR 1910.1200 (HAZARD COMMUNICATION STANDARD)
IMPORTANT: Read this SDS before handling & disposing of this product.
Pass this information on to employees, customers, & users of this product.
SECTION 1. IDENTIFICATION OF THE SUBSTANCE OR MIXTURE AND OF THE SUPPLIER
PRODUCT IDENTITY: ACETONE
NEW MSDS DATE: 03/23/2011
COMPANY IDENTITY: SolvChem, Inc.
COMPANY ADDRESS: 1904 Mykawa Road
COMPANY CITY: Pearland, TX 77581 -0490
COMPANY PHONE: 1 -281- 485 -5377
EMERGENCY PHONES: CHEMTREC: 1- 800 - 424 -9300 (USA)
CANUTEC: 1- 613 - 996 -6666 (CANADA)
SECTION 2. HAZARDS IDENTIFICATION '
DANGER!!
RISK STATEMENTS:
R36/37/38 Irritating to eyes, respiratory system and skin.
R12 Extremely Flammable.
R66 Repeated exposure may cause skin dryness or cracking.
R67 Vapors may cause drowsiness and dizziness.
SAFETY STATEMENTS:
S9 Keep container in a well - ventilated place.
S16 Keep away from sources of ignition. No smoking.
SEE SECTIONS 8, 11 & 12 FOR TOXICOLOGICAL INFORMATION.
COMPANY IDENTITY: SolvChem, Inc. DATE: 03/23/11
PRODUCT IDENTITY: ACETONE PAGE: 2 OF 8
SDS NUMBER: ACETONE
SECTION 3. COMPOSITION /INFORMATION ON INGREDIENTS
MATERIAL CAS# EINECS# WT
Acetone 67 -64 -1 200 -662 -2 100
SECTION 4. FIRST AID MEASURES
EYE CONTACT:
For eyes, flush with plenty of water for 15 minutes & get medical attention.
SKIN CONTACT:
In case of contact with skin immediately remove contaminated clothing.
Wash thoroughly with soap & water. Wash contaminated clothing before reuse.
INHALATION:
After high vapor exposure, remove to fresh air. If breathing is difficult, give
oxygen. If breathing has stopped, trained personnel should immediately begin
artificial respiration. If the heart has stopped, trained personnel
should immediately begin cardiopulmonary resuscitation (CPR).
SWALLOWING:
Rinse mouth. GET MEDICAL ATTENTION IMMEDIATELY. Do NOT give liquids
to an unconscious or convulsing person.
SECTION S. FIRE FIGHTING MEASURES
FIRE & EXPLOSION PREVENTIVE MEASURES
NO open flames, NO sparks, & NO smoking. Use a closed system, ventilation,
explosion -proof electrical equipment, lighting.
Do NOT use compressed air for filling, discharging, or handling.
EXTINGUISHING MEDIA
Use dry powder, carbon dioxide.
SPECIAL FIRE FIGHTING PROCEDURES
Water spray may be ineffective on fire but can protect fire - fighters
& cool closed containers. Use fog nozzles if water is used.
Do not enter confined fire -space without full bunker gear.
(Helmet with face shield, bunker coats, gloves & rubber boots).
Use NIOSH approved positive- pressure self- contained breathing apparatus.
COMPANY IDENTITY: SolvChem, Inc. DATE: 03/23/11
PRODUCT IDENTITY: ACETONE PAGE: 3 OF 8
SDS NUMBER: ACETONE
SECTION 5. FIRE FIGHTING MEASURES (CONTINUED)
UNUSUAL EXPLOSION AND FIRE PROCEDURES
EXTREMELY FLAMMABLE!! VAPORS CAN CAUSE FLASH FIRE
Isolate from oxidizers, heat, sparks, electric equipment & open flame.
Closed containers may explode if exposed to extreme heat.
Applying to hot surfaces requires special precautions.
Empty container very hazardous! Continue all label precautions!
SECTION 6. ACCIDENTAL RELEASE MEASURES
PERSONAL PROTECTIVE MEASURES:
Vapors may ignite explosively & spread long distances. Prevent vapor buildup.
Keep unprotected personnel away. Ventilate spill area. Remove all ignition sources.
Use self- contained breathing apparatus.
ENVIRONMENTAL PRECAUTIONS:
Keep from entering storm sewers and ditches which lead to waterways.
CONTAINMENT AND CLEAN -UP MEASURES:
Stop spill at source. Dike and contain. Collect leaking liquid in sealable containers.
Absorb remaining liquid in sand or inert absorbent. Remove to safe place.
SECTION 7. HANDLING AND STORAGE
HANDLING
Isolate from oxidizers, heat, sparks, electric equipment & open flame.
Use only with adequate ventilation. Avoid breathing of vapor or spray mist.
Avoid contact with skin & eyes.
Wear OSHA Standard goggles or face shield. Consult Safety Equipment Supplier. Wear
gloves, apron & footwear impervious to this material. Wash clothing before reuse.
Avoid free fall of liquid. Ground containers when transferring. Do not flame cut, saw,
drill, braze, or weld. Empty container very hazardous! Continue all label precautions!
To minimize static discharge when transferring, ensure electrical continuity
by bonding and grounding all equipment. Use an inlet line diameter of at
least 3.5 inches (8.9 centimeters) with a maximum flow rate of 1 meter /second.
STORAGE
Vapors may ignite explosively & spread long distances. Prevent vapor buildup. Put out
pilot lights & turn off heaters, electric equipment & other
ignition sources during use & until all vapors are gone. Isolate from strong oxidants.
Do not store above 49 C/120 F. Keep container tightly closed
& upright when not in use to prevent leakage.
COMPANY IDENTITY: SolvChem, Inc.
PRODUCT IDENTITY: ACETONE
SDS NUMBER: ACETONE
MATERIAL
Acetone
MATERIAL
Acetone
SECTION 8. EXPOSURE CONTROLS /PERSONAL PROTECTION
CAS# EINECS# TWA (OSHA)
67 -64 -1 200 -662 -2 1000 ppm
DATE: 03/23/11
PAGE: 4 OF 8
TLV (ACGIH)
500 ppm A4
CAS# EINECS# CEILING STEL(OSHA /ACGIH) HAP
67 -64 -1 200 -662 -2 None Known 750 ppm No
This product contains no EPA Hazardous Air Pollutants (HAP) in amounts > 0.1 %.
RESPIRATORY EXPOSURE CONTROLS
A respiratory protection program that meets OSHA 29 CFR 1910.134 and
ANSI Z86.2 requirements or European Standard EN 149 must be followed
whenever workplace conditions warrant a respirator's use.
VENTILATION
LOCAL EXHAUST: Necessary MECHANICAL (GENERAL): Acceptable
SPECIAL: None OTHER: None
Please refer to ACGIH document, "Industrial Ventilation, A Manual of
Recommended Practices ", most recent edition, for details.
PERSONAL PROTECTIONS:
Wear OSHA Standard goggles or face shield. Consult Safety Equipment Supplier. Wear
gloves, apron & footwear impervious to this material. Wash clothing before reuse.
WORK & HYGIENIC PRACTICES:
Provide readily accessible eye wash stations & safety showers.
Wash at end of each workshift & before eating, smoking or using the toilet.
Promptly remove clothing that becomes contaminated. Destroy contaminated
leather articles. Launder or discard contaminated clothing.
COMPANY IDENTITY: SolvChem, Inc.
PRODUCT IDENTITY: ACETONE
SOS NUMBER: ACETONE
SECTION 9. PHYSICAL & CHEMICAL PROPERTIES
APPEARANCE:
ODOR:
ODOR THRESHOLD:
pH (Neutrality):
MELTING POINT /FREEZING POINT:
BOILING RANGE (IBP,50 %,Dry Point):
FLASH POINT (TEST METHOD):
EVAPORATION RATE (n -BUTYL ACETATE =1):
FLAMMABILITY CLASSIFICATION:
LOWER FLAMMABLE LIMIT IN AIR (% by vol):
UPPER FLAMMABLE LIMIT IN AIR (% by vol):
VAPOR PRESSURE (mm of Hg) @20 C
VAPOR DENSITY (air =1):
GRAVITY @ 68/68 F / 20/20 C:
SPECIFIC GRAVITY (Water =l):
POUNDS /GALLON:
WATER SOLUBILITY:
PARTITION COEFFICIENT (n- Octane /Water):
AUTO IGNITION TEMPERATURE:
DECOMPOSITION TEMPERATURE:
REFRACTIVE INDEX:
VOC'S (>0.44 Lbs /Sq In)
TOTAL VOC'S (TVOC) *:
NONEXEMPT VOC'S (CVOC) *:
HAZARDOUS AIR POLLUTANTS (RAPS):
NONEXEMPT VOC PARTIAL PRESSURE (mm of Hg @ 20 C)
DATE: 03/23/11
PAGE: 5 OF 8
Liquid, Water -White
Ketone
Not Available
Not Applicable
Not Available
56 56 57 C / 133 134 135 F
-16 C / 2 F (TCC)
5.1
Class I B
2.6
12.8
186.0
2.0
0.792
6.597
Complete
Not Available
537 C / 1000 F
Not Available
1.358
100.0 Vol% / 792.0 g/L / 6.5 Lbs /Gal
100.0 Vol% / 792.0 g/L / 6.5 Lbs /Gal
0.0 Vol% /0.0 g/L / 0.000 Lbs /Gal
0.0 Wt% /0.0 g/L / 0.000 Lbs /Gal
0.0
* Using California South Coast Air Quality Management District (SCAQMD) Rule 443.1.
SECTION 10. STABILITY & REACTIVITY
STABILITY
Stable under normal conditions.
CONDITIONS TO AVOID
Isolate from oxidizers, heat, sparks, electric equipment & open flame.
MATERIALS TO AVOID
Reacts with strong oxidants, causing fire & explosion hazard.
HAZARDOUS DECOMPOSITION PRODUCTS
Carbon Monoxide, Carbon Dioxide from burning.
HAZARDOUS POLYMERIZATION
Will not occur.
COMPANY IDENTITY: SolvChem, Inc.
PRODUCT IDENTITY: ACETONE
SDS NUMBER: ACETONE
SECTION 11. TOXICOLOGICAL INFORMATION
ACUTE HAZARDS
EYE & SKIN CONTACT:
Primary irritation to skin, defatting, dermatitis.
Primary irritation to eyes, redness, tearing, blurred vision.
Liquid can cause eye irritation. Wash thoroughly after handling.
INHALATION:
Anesthetic. Irritates respiratory tract. Acute overexposure
can cause serious nervous system depression. Vapor harmful.
SWALLOWING:
Swallowing can cause abdominal irritation, nausea, vomiting & diarrhea.
SUBCHRONIC HAZARDS /CONDITIONS AGGRAVATED
CONDITIONS AGGRAVATED
Persons with severe skin, liver or kidney problems should avoid use.
CHRONIC HAZARDS
CANCER, REPRODUCTIVE & OTHER CHRONIC HAZARDS:
This product has no carcinogens listed by IARC, NTP, NIOSH,
OSHA or ACGIH, as of this date, greater or equal to 0.1%.
MAMMALIAN TOXICITY INFORMATION
MATERIAL CAS# EINECS#
Acetone 67 -64 -1 200 -662 -2
Acetone 67 -64 -1 200 -662 -2
Acetone 67 -64 -1 200 -662 -2
DATE: 03/23/11
PAGE: 6 OF 8
LOWEST KNOWN LETHAL DOSE DATA
LOWEST KNOWN LD50 (ORAL)
5340.0 mg /kg(Rabbits)
LOWEST KNOWN LC50 (VAPORS)
2100 ppm (Cats)
LOWEST KNOWN LD50 (SKIN)
20000.0 mg /kg (Rabbits)
COMPANY IDENTITY: SolvChem, Inc. DATE: 03/23/11
PRODUCT IDENTITY: ACETONE PAGE: 7 OF 8
SDS NUMBER: ACETONE
SECTION 12. ECOLOGICAL INFORMATION
AQUATIC ANIMAL INFORMATION:
The most sensitive known aquatic group to any component of this product is:
Mosquito Fish 13000 ppm or mg /L (48 hour exposure).
MOBILITY IN SOIL
This material is a mobile liquid.
DEGRADABILITY
This product is completely biodegradable.
ACCUMULATION
This product does not accumulate or biomagnify in the environment.
SECTION 13. DISPOSAL CONSIDERATIONS
Processing, use or contamination may change the waste management options.
Recycle / dispose of observing national, regional, state, provincial and local
health, safety & pollution laws. If in doubt, contact appropriate agencies.
SECTION 14. TRANSPORT INFORMATION
DOT SHIPPING NAME: UN1090, Acetone, 3, PG -II
DRUM LABEL: (FLAMMABLE LIQUID)
IATA / ICAO: UN1090, Acetone, 3, PG -II
IMO / IMDG: UN1090, Acetone, 3, PG -II
EMERGENCY RESPONSE GUIDEBOOK NUMBER: 127 '
> 5000 LB / 2272 KG OF THIS PRODUCT IN 1 CONTAINEF
EXCEEDS THE "RQ" OF ACETONE.
SECTION 15. REGULATORY INFORMATION
EPA REGULATION:
SARA SECTION 311/312 HAZARDS: Acute Health, Fire
All components of this product are on the TSCA list.
This material contains no known products restricted under SARA Title III,
Section 313 in amounts greater or equal to 1 %.
SARA TITLE III INGREDIENTS CAS# EINECS# WT% (REG.SECTION) RQ(LBS)
Acetone 67 -64 -1 200 -662 -2 95 -100 (311,312) 5000
COMPANY IDENTITY: SolvChem, Inc. DATE: 03/23/11
PRODUCT IDENTITY: ACETONE PAGE: 8 OF 8
SDS NUMBER: ACETONE
SECTION 15. REGULATORY INFORMATION (CONTINUED)
> 5000 LB / 2272 KG OF THIS PRODUCT IN 1 CONTAINER EXCEEDS THE "RQ" OF ACETONE.
Any release equal to or exceeding the RQ must be reported to the National
Response Center (800- 424 -8802) and appropriate state and local regulatory
agencies as described in 40 CFR 302.6 and 40 CFR 355.40 respectively.
Failure to report may result in substantial civil and criminal penalties.
State & local regulations may be more restrictive than federal regulations.
STATE REGULATIONS:
THIS PRODUCT MEETS REQUIREMENTS OF SOUTHERN
CALIFORNIA AQMD RULE 443.1 & SIMILAR REGULATIONS
CALIFORNIA PROPOSITION 65: This product contains no chemicals
known to the State of California to cause cancer & reproductive toxicity.
INTERNATIONAL REGULATIONS
The components of this product are listed on the chemical inventories of the
following countries:
Australia (AICS), Canada (DSL, NDSL), China (IECSC), Europe (EINECS, ELINCS),
Japan (METI /CSCL, MHLW /ISHL), South Korea (KECI), New Zealand (NZIoC),
Philippines (PICCS), Switzerland (SWISS), Taiwan (NECSI), USA (TSCA).
CANADA: WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS)
B2: Flammable Liquid.
SECTION 16. OTHER INFORMATION
HAZARD RATINGS:
HEALTH (NFPA): 1, HEALTH (HMIS): 2, FLAMMABILITY: 3, REACTIVITY: 0
(Personal Protection Rating to be supplied by user based on use conditions.)
This information is intended solely for the use of individuals
trained in the NFPA & HMIS hazard rating systems.
EMPLOYEE TRAINING
See Section 2 for Risk & Safety Statements. Employees should be made aware
of all hazards of this material (as stated in this SDS) before handling it.
NOTICE
The supplier disclaims all expressed or implied warranties of merchantability or fitness
for a specific use, with respect to the product or the information provided herein,
except for conformation to contracted specifications. All information appearing herein
is based upon data obtained from manufacturers and /or recognized technical sources.
While the information is believed to be accurate, we make no representations as to its
accuracy or sufficiency.
Conditions of use are beyond our control, and therefore users are responsible for
verifying the data under their own operating conditions to determine whether the product
is suitable for their particular purposes and they assume all risks of their handling,
and disposal of the product. Users also assume all risks in regards to the publication
or use of, or reliance upon information contained herein.
This information relates only to the product designated herein, and does not relate to
its use in combination with any other material or process.
Unless updated, the Safety Data Sheet is valid until 03/23/2014.
XIAMETER(R)
Jinm DOW CORNING Material Safety Data Sheet
XIAMETER(R) RSN -2403 RESIN
1 1. PRODUCT AND COMPANY IDENTIFICATION
Dow Coming Corporation
South Saginaw Road
Midland, Michigan 48686
MSDS No.: 04108118
Generic Description: Silicone resin.
Physical Form: Liquid
Color: Colorless
Odor: Alcoholic odor
NFPA = National Fire
2.
Page: 1 of 9
Version: 1.0
Revision Date: 2011/11/07
24 Hour Emergency Telephone: (989) 496 -5900
Customer Service: (989) 496 -4430
Product Disposal Information: (989) 496 -6315
CHEMTREC: (800) 424 -9300
Revision Date: 2011/11107 1
NFPA Profile: Health 0 Flammability 3 Instability /Reactivity 0
POTENTIAL HEALTH EFFECTS
Acute Effects
Eye: Direct contact may cause mild irritation.
Skin: May cause mild irritation.
Inhalation: Vapor may irritate nose and throat.
Oral: Low ingestion hazard in normal use.
Prolonged /Repeated Exposure Effects
Skin: No known applicable information.
Inhalation: No known applicable information.
Oral: No known applicable information.
Signs and Symptoms of Overexposure
No known applicable information.
Medical Conditions Aggravated by Exposure
No known applicable information.
The above listed potential effects of overexposure are based on actual data, results of studies performed upon similar compositions,
component data and /or expert review of the product. Please refer to Section 11 for the detailed toxicology information.
XIAMETER(R)
from DOW CORNING Material Safety Data Sheet
Page: 2 of 9
Version: 1.0
Revision Date: 2011/11/07
XIAMETER(R) RSN -2403 RESIN
3. COMPOSITION /INFORMATION ON INGREDIENTS
CAS Number Wt % Component Name
68037 -85-4 85.0-100.0 Methylmethoxy siloxane with methyl silsesquioxane
The above components are hazardous as defined in 29 CFR 1910.1200.
4. FIRST AID MEASURES
Eye: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 5 minutes
while holding the eyelid(s) open. Obtain medical attention.
Skin: No health effects expected. If irritation does occur flush with lukewarm, gently flowing water
for 5 minutes. If irritation persists, obtain medical advice.
Inhalation: Remove from the source of contamination or move to fresh air. Obtain medical attention.
Oral: If irritation or discomfort occur, obtain medical advice.
Notes to Physician: Treat according to person's condition and specifics of exposure.
5. FIRE FIGHTING MEASURES
Flash Point: 96.8 OF / 36 °C (Pensky- Martens Closed Cup)
Autoignition Temperature: Not determined.
Flammability Limits in Air: Not determined.
Extinguishing Media: On large fires use dry chemical, foam or water spray. On small fires use carbon dioxide
(CO2), dry chemical or water spray. Water can be used to cool fire exposed containers.
Fire Fighting Measures: Self- contained breathing apparatus and protective clothing should be wom in fighting large
fires involving chemicals. Determine the need to evacuate or isolate the area according to
your local emergency plan. Use water spray to keep fire exposed containers cool.
Unusual Fire Hazards: Vapors are heavier than air and may travel to a source of ignition and flash back. Static
electricity will accumulate and may ignite vapors. Prevent a possible fire hazard by bonding
and grounding or inert gas purge.
6. ACCIDENTAL RELEASE MEASURES
XIAMETER(R)
fin„= DOW CORNING Material Safety Data Sheet
Page: 3 of 9
Version: 1.0
Revision Date: 2011/11/07
XIAMETER(R) RSN -2403 RESIN
Containment/Clean up: Remove possible ignition sources. Determine whether to evacuate or isolate the area
according to your local emergency plan. Observe all personal protection equipment
recommendations described in Sections 5 and 8. For large spills, provide diking or other
appropriate containment to keep material from spreading. If diked material can be pumped,
store recovered material in appropriate container. Clean up remaining materials from spill
with suitable absorbant. Clean area as appropriate since spilled materials, even in small
quantities, may present a slip hazard. Final cleaning may require use of steam, solvents or
detergents. Dispose of saturated absorbant or cleaning materials appropriately, since
spontaneous heating may occur. Local, state and federal laws and regulations may apply to
releases and disposal of this material, as well as those materials and items employed in the
cleanup of releases. You will need to determine which federal, state and local laws and
regulations are applicable. Sections 13 and 15 of this MSDS provide information regarding
certain federal and state requirements.
Note: See Section 8 for Personal Protective Equipment for Spills.
1 7. HANDLING AND STORAGE
Use with adequate ventilation. Product evolves flammable methyl alcohol when exposed to water or humid air. Provide
ventilation during use to control exposure within Section 8 guidelines or use air - supplied or self - contained breathing
apparatus. Avoid eye contact. Avoid skin contact. Avoid breathing vapor. Keep container closed.
Static electricity will accumulate and may ignite vapors. Prevent a possible fire hazard by bonding and grounding or inert
gas purge. Keep container closed and away from heat, sparks, and flame. Keep container closed and store away from
water or moisture.
1 8. EXPOSURE CONTROLS / PERSONAL PROTECTION ___1
Component Exposure Limits
CAS Number Component Name Exposure Limits
68037 -85-4 Methylmethoxy siloxane with methyl See methyl alcohol comments.
silsesquioxane
Methyl alcohol forms on contact with water or humid air. Provide adequate ventilation to control exposures within
guidelines of OSHA PEL: TWA 200 ppm and ACGIH TLV -skin: TWA 200 ppm, STEL 250 ppm.
Engineerinq Controls
Local Ventilation: Recommended.
General Ventilation: Recommended.
Personal Protective Equipment for Routine Handling
Eyes: Use proper protection - safety glasses as a minimum.
XIAMETER(R)
from DOWCORNINC Material Safety Data Sheet
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XIAMETER(R) RSN -2403 RESIN
Skin: Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed as
soon as practical and thoroughly cleaned before reuse. Chemical protective gloves are
recommended.
Suitable Gloves: Handle in accordance with good industrial hygiene and safety practices.
Inhalation: Use respiratory protection unless adequate local exhaust ventilation is provided or exposure
assessment demonstrates that exposures are within recommended exposure guidelines. IH
personnel can assist in judging the adequacy of existing engineering controls.
Suitable Respirator: General and local exhaust ventilation is recommended to maintain vapor exposures below
recommended limits. Where concentrations are above recommended limits or are unknown,
appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29
CFR 1910.134) and use NIOSH /MSHA approved respirators.
Personal Protective Equipment for Spills
Eyes: Use full face respirator.
Skin: Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed as
soon as practical and thoroughly cleaned before reuse. Chemical protective gloves are
recommended.
Inhalation /Suitable Respiratory protection recommended. Follow OSHA Respirator Regulations (29 CFR
Respirator: 1910.134) and use NIOSH /MHSA approved respirators. Protection provided by air purifying
respirators against exposure to any hazardous chemical is limited. Use a positive pressure air
supplied respirator if there is any potential for uncontrolled release, exposure levels are
unknown, or any other circumstance where air purifying respirators may not provide adequate
protection.
Precautionary Measures: Avoid eye contact. Avoid skin contact. Avoid breathing vapor. Keep container closed. Use
reasonable care.
Comments: Product evolves flammable methyl alcohol when exposed to water or humid air. Provide
ventilation during use to control exposure within Section 8 guidelines or use air - supplied or
self- contained breathing apparatus.
When heated to temperatures above 150 °C (300 °F) in the presence of air, product can form
formaldehyde vapors. Formaldehyde is a potential cancer hazard and a known skin and
respiratory sensitizer. Vapors irritate eyes, nose, and throat. Safe handling conditions may be
maintained by keeping vapor conditions within the OSHA permissible exposure limit for
formaldehyde.
Note: These precautions are for room temperature handling. Use at elevated temperature or aerosol /spray applications may require
added precautions. For further information regarding aerosol inhalation toxicity, please refer to the guidance document regarding the
use of silicone -based materials in aerosol applications that has been developed by the silicone industry (www.SEHSC.com) or contact
the Dow Corning customer service group.
9. PHYSICAL AND CHEMICAL PROPERTIES
XIAMETER(R)
from DOWCORNINC Material Safety Data Sheet
Page: 5 of 9
Version: 1.0
Revision Date: 2011/11/07
Physical Form:
Color:
Odor:
Specific Gravity @ 25 °C:
Viscosity:
Freezing /Melting Point:
Boiling Point:
Vapor Pressure @ 25 °C:
Vapor Density:
Solubility in Water:
pH:
Volatile Content:
Flash Point:
Autoignition Temperature:
Flammability Limits in Air:
XIAMETER(R) RSN -2403 RESIN
Liquid
Colorless
Alcoholic odor
1.155
25 mm2 /s
Not determined.
>35 °C
Not determined.
Not determined.
Not determined.
Not determined.
Not determined.
96.8 °F / 36 °C (Pensky- Martens Closed Cup)
Not determined.
Not determined.
The above information is not intended for use in
1 10. STABILITY AND REACTIVITY
Chemical Stability: Stable.
Hazardous Hazardous polymerization will not occur.
Polymerization:
Conditions to Avoid: None.
Materials to Avoid: Oxidizing material can cause a reaction. Water, moisture, or humid air can cause hazardous
vapors to form as described in Section 8.
Hazardous Decomposition Products
Thermal breakdown of this product during fire or very high heat conditions may evolve the following decomposition
products: Carbon oxides and traces of incompletely burned carbon compounds. Silicon dioxide. Formaldehyde.
Component Toxicology Information
This material may liberate methanol upon exposure to moisture or humid air. Overexposure to methanol can result in
blindness and nervous system effects.
Special Hazard Information on Components
No known applicable information.
XIAMETER(R)
f�m DOW CORNING Material Safety Data Sheet
Page: 6 of 9
Version: 1.0
Revision Date: 2011/11/07
XIAMETER(R) RSN -2403 RESIN
12. ECOLOGICAL INFORMATION
Environmental Fate and Distribution
Complete information is not yet available.
Environmental Effects
Complete information is not yet available.
Fate and Effects in Waste Water Treatment Plants
Complete information is not yet available.
Ecotoxicity Classification Criteria
Hazard Parameters (LC50 or EC50)
High
Medium
Low
Acute Aquatic Toxicity (mg /L)
1<=100
< =1
>1 and < =100
>100
Acute Terrestrial Toxicity
>100 and <= 2000
>2000
This table is adapted from "Environmental Toxicology and Risk Assessment', ASTM STP 1179, p.34,1993.
This table can be used to classify the ecotoxicity of this product when ecotoxicity data is listed above. Please read the other information presented in the
section concerning the overall ecological safety of this material.
13. DISPOSAL CONSIDERATIONS
RCRA Hazard Class (40 CFR 261)
When a decision is made to discard this material, as received, is it classified as a hazardous waste? Yes
Characteristic Waste:
Ignitable: D001
State or local laws may impose additional regulatory requirements regarding disposal.
14. TRANSPORT INFORMATION
DOT Road Shipment Information (49 CFR 172.101)
Proper Shipping Name: Flammable liquids, n.o.s.
Hazard Technical Name: Polysiloxane
Hazard Class: 3
UN /NA Number: UN 1993
Packing Group: iii
XIAMETER(R)
/)om DOW CORNING Material Safety Data Sheet
Page: 7 of 9
Version: 1.0
Revision Date: 2011/11/07
XIAMETER(R) RSN -2403 RESIN
Hazard Label(s):
Flammable Liquid
Ocean Shipment (IMDG)
Proper Shipping Name:
FLAMMABLE LIQUID, N.O.S.
Hazard Technical Name:
Polysiloxane
Hazard Class:
3
UN /NA Number:
UN 1993
Packing Group:
III
Hazard Label(s):
flammable liquid
Air Shipment (IATA)
Proper Shipping Name:
Flammable liquid, n.o.s.
Hazard Technical Name:
Polysiloxane
Hazard Class:
3
UN /NA Number:
UN 1993
Packing Group:
III
Hazard Label(s):
Flammable Liquid
15. REGULATORY INFORMATION
Contents of this MSDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
TSCA Status: All chemical substances in this material are included on or exempted from listing on the TSCA
Inventory of Chemical Substances.
EPA SARA Title III Chemical Listings
Section 302 Extremely Hazardous Substances (40 CFR 355):
None.
Section 304 CERCLA Hazardous Substances (40 CFR 302):
None.
Section 311/312 Hazard Class (40 CFR 370):
Acute: No
XIAMETER(R)
from DOW CORNING Material Safety Data Sheet
XIAMETER(R) RSN -2403 RESIN
Chronic: No
Fire: Yes
Pressure: No
Reactive: No
Page: 8 of 9
Version: 1.0
Revision Date: 2011/11/07
Section 313 Toxic Chemicals (40 CFR 372):
None present or none present in regulated quantities.
Note: Chemicals are listed under the 313 Toxic Chemicals section only if they meet or exceed a reporting threshold.
Supplemental State Compliance Information
California
Warning: This product contains the following chemical(s) listed by the State of California under the Safe Drinking Water
and Toxic Enforcement Act of 1986 (Proposition 65) as being known to cause cancer, birth defects or other
reproductive harm.
None known.
Massachusetts
No ingredient regulated by MA Right -to -Know Law present.
New Jersey
CAS Number Wt % Component Name
I
68037 -85 -4 85.0-100.0 Methylmethoxy siloxane with methyl silsesquioxane
Pennsylvania
CAS Number Wt % Component Name
68037 -85 -4 85.0-100.0 Methylmethoxy siloxane with methyl silsesquioxane
XIAMETER(R)
from DOW CORNING Material Safety Data Sheet
Page: 9 of 9
Version: 1.0
Revision Date: 2011/11/07
XIAMETER(R) RSN -2403 RESIN
16. OTHER INFORMA
Prepared by: Dow Corning Corporation
These data are offered in good faith as typical values and not as product specifications. No warranty, either expressed or
implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally
applicable. However, each user should review these recommendations in the specific context of the intended use and
determine whether they are appropriate.
XIAMETER(R) is a trademark of Dow Coming Corporation
http: / /www.xiameter.com
I Mann
Release Technologies
Material Safety Data Sheet
Ease Release 200 Aerosol
Date of Preparation: April 4, 2012
MSDS No. 7002
Revision: 0011
Section 1 - Chemical Product and Comoanv Identification
Product /Chemical Name: Ease Release 200 Aerosol
General Use: Mold Release Agent
Manufacturer: Mann Release Technologies Inc., 2000 St. John St.,
Phone (610) 252 -5800, Fax (610) 252 -6200
Emergency Contact: Chem -Tel
Domestic 800 - 255 -3924
International 813- 248 -0585
Easton PA 18042
Section 2- Hazards Identification
Non Flammable aerosol, as determined by ASTM D 3065 -77 and FSHA sec. 1500.45 HMIs
However, this product contains components which may be ignited under certain
circumstances. Do not use near sources such as sparks or open flames.
R 0
Section 3 - Composition / Information on Ingredients
Component
ACGIH TWA
OSHA PEL
Hazard
Weight
Designation
Percent
Dimethyl Ether
None
None
50 -60
CAS Number: 115 -10 -6
Established
Established
EINECS Number: 204 -065 -8
+F+
I Section 4 - First Aid Measures 1
Inhalation: Remove source(s) of contamination and move victim to fresh air. If breathing has
stopped, give artificial respiration, then oxygen if needed. Contact physician immediately.
Eye Contact: Flush eyes with plenty of water. If irritation persists, seek medical attention.
Skin Contact: In case of skin contact, wash thoroughly with soap and water.
Ingestion: Ingestion is unlikely route of exposure. Do not induce vomiting unless instructed by
a physician.
After first aid, get appropriate in- plant, paramedic, or community medical support.
Note to Physicians:
Because of possible disturbance of cardiac rhythm, catecholamine drugs, such as epinephrine,
should be used only in situations of emergency life support.
Page 1 of 4
MSDS No. 7002 Ease Release 200 Aerosol Revision: 0011
Section 5 - Fire-Fighting Measures
Fire and Explosion Hazards: Vapors confined in a poorly ventilated area may NFPA
be ignited by a spark or flame. Vapors may travel considerable distances to
source of ignition. Vapors are heavier than air and may accumulate in low
areas. Containers may rupture or explode under fire conditions. Hazardous 0
decomposition products may be formed. Material can accumulate static
charges which can cause an incendiary electrical discharge. Empty 0
containers retain product residue and can be dangerous. 4
Flammability Classification: Non Flammable aerosol, as determined by ASTM D 3065 -77 and
FSHA sec. 1500.45 However, this product contains components which may be ignited under
certain circumstances. Do not use near sources such as sparks or open flames.
Fire - Fighting Instructions: Use dry chemical, foam or CO2; water may be ineffective but
should be used to keep containers cool.
Fire - Fighting Equipment: Because fire may produce toxic thermal decomposition products,
wear a self- contained breathing apparatus (SCBA) with a full face piece operated in pressure -
demand or positive - pressure mode.
Section 6 - Accidental Release Measures
Spill /Leak Procedures: Avoid breathing vapors. Evacuate area until vapor has been
dispersed. Remove all sources of ignition. Stop or reduce discharge if it can be done safely.
Section 7 - Handling and Storage
Handling Precautions: Minimize breathing of vapors and avoid prolonged or repeated contact
with skin. Wear proper protective equipment. If ventilation is not sufficient, wear proper
respiratory equipment. Do not use near ignition sources. Contents under pressure, do not
puncture or incinerate.
Storage Requirements: Store in cool dry, well ventilated area away from all sources of ignition.
Empty container may contain residues which are hazardous. Do not store at temperature
above 120 °F.
Section 8 - Exposure Controls / Personal Protection
Respiratory Protection: Follow OSHA respirator regulations 29 CFR 1910.134 and European
Standards EN 141, 143 and 371; wear an MSHA/NIOSH or European Standards EN 141, 143 and
371 approved respirators. Warning!Air- purifying respirators do not protect workers in oxygen -
deficient atmospheres. If respirators are used, OSHA requires a written respiratory protection
program that includes at least: medical certification, training, fit - testing, periodic environmental
monitoring, maintenance, inspection, cleaning, and convenient, sanitary storage areas.
Protective Clothing /Equipment: Wear chemically protective gloves, boots, and aprons to
prevent prolonged or repeated skin contact. Wear protective eyeglasses or chemical safety
goggles, per OSHA eye- and face - protection regulations 29 CFR 1910.133 and European
Standard EN 166. Contact lenses are not eye protective devices. Appropriate eye protection
must be worn instead of, or in conjunction with contact lenses.
4D w
Page 2 of 4
MSDS No. 7002 Ease Release 200 Aerosol RP- nni i
Section 8 - Exposure Controls / Personal Protection
Comments: Never eat, drink, or smoke in work areas. Practice good personal hygiene after
using this material, especially before eating, drinking, smoking, using the toilet, or applying
cosmetics.
Section 9 - Physical and Chemical Properties
Product Form: Aerosol Can Vapor Density (Air -1): -4
Appearance and Odor: Clear, Slight ethereal odor Water Solubility: Negligible
Vapor Pressure: 10.02 psia @ 70 OF Boiling Point: N/A
Specific Gravity: N/A Evaporation Rate: (butyl acetate =1) >1
Volatile Organic
Compounds (grams /Liter): 497
Section 10 - Stability and Reactivity
Stability: This product is stable at room temperature in closed containers under normal storage
and handling conditions.
Polymerization: Hazardous polymerization cannot occur.
Hazardous Decomposition Products: Thermal oxidative decomposition can produce
hydrochloric and hydrofluoric acids, carbonyl halides such as phosgene, silicon dioxide, carbon
oxides and traces of incompletely burned carbon compounds, formaldehyde.
Section 11- Toxicological Information
None established
Section 12 - Ecological Information
None Established
Section 13 - Disposal Considerations
Disposal: Contact your supplier or a licensed contractor for detailed recommendations. Follow
applicable Federal, state, and local regulations.
Section 14 - Transport Information
DOT IATA IMDG
Shipping Name: N/A Shipping Name Shipping Name:
UN #: N/A Consumer Commodity Aerosols
Hazard Class: ORM -D ID #: 8000 UN #: UN 1950
Label: N/A Hazard Class: 9 Hazard Class: 2.2
Label: Non - Required Label: Limited Quantity
Page 3 of 4
MSDS No. 7002 Ease Release 200 Aerosol Revision: 0011
Section 15 - Regulatory Information
United States EPA Regulations:
TSCA Inventory Status (40 CFR710): All components of this formulation are listed in the TSCA
Inventory.
California Proposition 65: This product contains no chemicals which in the State of California
has found to cause cancer, birth defects or other reproductive harm
Canadian Regulations;
WHMIS Identification: None/ Consumer Commodity
Labeling according to EEC Directive
Risk Phrases Symbol(s) Re uired for EU Label Safety Phrases
R12: Extremely flammable. S2: Keep out of reach of
children.
S9: Keep container in a well
ventilated place.
16 - Other Information
Disclaimer: The information contained in this MSDS is considered accurate as of the version
date. However, no warranty is expressed or implied regarding the accuracy of the data. Since
the use of this product is not within the control of Smooth -On Inc., it is the user's obligation to
determine the suitability of the product for its intended application and assumes all risk and
liability for its safe use.
This Material Safety Data Sheet is prepared to comply with the United States Occupational
Safety and Health Administration (OSHA)Hazard Communication Standard (29 CFR
1910.1200), the Canadian Workplace Hazardous Materials Information System (WHMIS), and
European Union Directive 1907 /2006 /EEC (REACH). Hazard symbols and risk phrases are
based on maximum listed concentration of each hazardous ingredient. Unlisted ingredients are
not "hazardous" per the OSHA Hazard Communication Standard (29 CFR 1910.1200), the
Canadian Workplace Hazardous Materials Information System (WHMIS) or the European
Union (EU /EEC) directive 1907/2006/EEC and are considered trade secrets under US Federal
Law (29CFR and 40CFR), Canadian Law (Health Canada Legislation), and European Union
Directives.
Page 4 of 4
S16: Keep away from
+F+ � Extremely Flammable
sources of ignition. -No
Smoking.
S33: Take precautionary
measures against static
discharges.
Page 4 of 4
On F
The Chemical Company
Safety data sheet
1- Ethynyl- 1- cyclohexanol
Revision date: 2006/10/16 Page: 1/7
Version: 1.2 (30036635 /MDS_GEN US /EN)
1. Substance /preparation and company identification
Company 24 Hour Emergency Response Information
BASF CORPORATION CHEMTREC: 1- 800 - 424 -9300
100 Campus Drive BASF HOTLINE: 1- 800 - 832 -HELP
Florham Park, NJ 07932
Molecular formula: C(8)H(12)0
Synonyms: 1- Ethynylcyclohexanol
2. Composition /information on ingredients
CAS Number Content (WM) Chemical name
78 -27 -3 1- ethynylcyclohexa nol
3. Hazard identification
Emergency overview
WARNING: COMBUSTIBLE SOLID. HARMFUL IF SWALLOWED.
PROLONGED OR REPEATED CONTACT MAY DRY SKIN AND CAUSE IRRITATION.
CAUSES EYE, SKIN AND RESPIRATORY TRACT IRRITATION.
Has a narcotic effect.
Avoid contact with the skin, eyes and clothing.
Avoid inhalation of dusts.
Use with local exhaust ventilation.
Wear a NIOSH - certified (or equivalent) particulate respirator.
Wear NIOSH- certified chemical goggles.
Wear chemical resistant protective gloves.
Wear protective clothing.
Eye wash fountains and safety showers must be easily accessible.
Potential health effects
Primary routes of exposure
Routes of entry for solids and liquids include eye and skin contact, ingestion and inhalation. Routes of entry
for gases include inhalation and eye contact. Skin contact may be a route of entry for liquified gases.
Medical conditions aggravated by overexposure:
Data available do not indicate that there are medical conditions that are generally recognized as being
aggravated by exposure to this substance /product.
See MSDS section 11 - Toxicological information.
Potential environmental effects
Safety data sheet
1- Ethynyl- 1- cyclohexanol
Revision date: 2006/10/16 Page: 2/7
Version: 1.2 (30036635/MDS GEN US /EN)
Aquatic toxicity:
There is a high probability that the product is not acutely harmful to aquatic organisms.
Inhibition of degradation activity in activated sludge is not to be anticipated during correct introduction of low
concentrations.
4. First -aid measures
General advice:
Remove contaminated clothing.
If inhaled:
Remove the affected individual into fresh air and keep the person calm. Assist in breathing if necessary
Immediate medical attention required.
If on skin:
Wash affected areas thoroughly with soap and water. Remove contaminated clothing. Seek medical
attention.
If in eyes:
In case of contact with the eyes, rinse immediately for at least 15 minutes with plenty of water. Seek medical
attention.
If swallowed:
Rinse mouth and then drink plenty of water. Induce vomiting. Never induce vomiting or give anything by
mouth if the victim is unconscious or having convulsions. Immediate medical attention required.
5. Fire - fighting measures
Flash point: 73 °C (DIN 51758)
Autoignition: 365 °C (DIN 51794)
Lower explosion limit: 1.3 %(V) (66 °C)
Upper explosion limit: 8.7 %(V) ( 130.5 °C)
Suitable extinguishing media:
water, dry extinguishing media, carbon dioxide, foam
Hazards during fire- fighting:
No particular hazards known.
Protective equipment for fire - fighting:
Firefighters should be equipped with self - contained breathing apparatus and tum -out gear.
Further information:
Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems.
6. Accidental release measures
Personal precautions:
Wear appropriate respiratory protection. Use personal protective clothing. Ensure adequate ventilation.
Environmental precautions:
This product is not regulated by RCRA. This product is not regulated by CERCLA ('Superfund').
Safety data sheet
1 -Ethynyl-1 -cyclohexanol
Revision date: 2006/10/16 Page: 3/7
Version: 12 (30036635 /MDS_GEN US /EN)
Cleanup:
Spills should be contained, solidified, and placed in suitable containers for disposal.
7. Handling and storage
Handling
General advice:
See MSDS section 10 - Stability and reactivity. See MSDS section 5 - Fire fighting measures.
Protection against fire and explosion:
See MSDS section 5 - Fire fighting measures.
Storage
General advice:
Avoid extreme heat. Keep away from sources of ignition - No smoking.
Storage incompatibility:
General: Segregate from alkalies and alkalizing substances.
Storage stability:
Storage duration: 24 Months
8. Exposure controls and personal protection
Advice on system design:
Provide local exhaust ventilation to control dust.
Personal protective equipment
Respiratory protection:
Wear a NIOSH - certified (or equivalent) particulate respirator. Observe OSHA regulations for respirator use
(29 CFR 1910.134).
Hand protection:
Chemical resistant protective gloves, Consult with glove manufacturer for testing data.
Eye protection:
Tightly fitting safety goggles (chemical goggles).
Body protection:
Body protection must be chosen depending on activity and possible exposure, e.g, head protection, apron,
protective boots, chemical - protection suit.
General safety and hygiene measures:
Eye wash fountains and safety showers must be easily accessible. Avoid inhalation of dust. Wear protective
clothing as necessary to minimize contact.
9. Physical and chemical properties
Form:
solid
Odour:
faint odour
Colour:
colourless
pH value:
7 ( 1 g /I)
Melting point:
30 °C
Safety data sheet
1 -Ethynyl-1 -cyclohexanol
Revision date: 2006/10/16 Page: 4/7
Version: 1.2 (30036635/MDS GEN US /EN)
Boiling point: 180 °C
Vapour pressure: 1 mbar ( 50 °C)
Density: 0.9763 g /cm3 ( 20 °C)
Partitioning coefficient n- 1.81 (calculated)
octanol /water (log Pow):
Solubility in water: 10 g/I ( 20 °C)
10. Stability and reactivity
Substances to avoid:
oxidizing agent
Hazardous reactions:
Reacts with strong bases and heavy -metal salts. Exothermic reaction.
The product is chemically stable.
Decomposition products:
Possible thermal decomposition products: acetylene
Thermal decomposition:
approx. 190 - 200 °C
Thermal decomposition above the indicated temperature is possible.
Corrosion to metals:
No corrosive effect on metal.
11. Toxicological information
Acute toxicity
Oral:
LD50 /rat: 590 mg /kg
Moderately toxic.
Inhalation:
Inhalation -risk test (IRT): No mortality within 8 hours as shown in animal studies. The inhalation of a highly
saturated vapor -air mixture represents no acute hazard. Literature data.
Dermal:
LD50 /rabbit: 980 mg /kg
Literature data.
Skin irritation:
rabbit: non - irritant (OECD Guideline 404)
Prolonged contact with the product can result in skin irritation
Eye irritation :
rabbit: Irritating.
Chronic toxicity
Genetic toxicity:
The substance was not mutagenic in bacteria.
Safety data sheet
1- Ethynyl- 1- cyclohexanol
Revision date : 2006/10/16 Page: 5/7
Version: 1.2 (30036635 /MDS_GEN US /EN)
Experiences in humans:
High concentrations have a narcotizing effect.
12. Ecological information
Environmental fate and transport
Biodegradation:
Test method:
Method of analysis:
Degree of elimination
Evaluation:
Bioaccumulation:
OECD Guideline 302 B
DOC reduction
20 -70%
Moderately /partially eliminated from water.
Moderately /partially biodegradable.
Moderately /partially eliminated from water.
No significant accumulation in organisms is expected as a result of the distribution coefficient of n-
octanol /water (log Pow).
Chemical oxygen demand (COD):
2,750 mg /I
Biochemical oxygen demand (BOD):
Incubation period 5 d: 3 mg /I
Environmental toxici
Acute and prolonged toxicity to fish:
golden orfe /LC50 (96 h): > 220 - < 460 mg /I
Acute toxicity to aquatic invertebrates:
Daphnia magna /EC50 (48 h): 160 mg /I
Toxicity to aquatic plants:
DIN 38412 Part 9 green algae /EC50 (72 h): > 500 mg /I
Toxicity to microorganisms:
DIN 38412 Part 8 bacterium /EC50 (17 h): 1,800 mg /I
Inhibition of degradation activity in activated sludge is not to be anticipated during correct introduction of low
concentrations.
13. Disposal considerations
Waste disposal of substance:
Do not discharge substance /product into sewer system.
Dispose of in accordance with national, state and local regulations.
Container disposal:
Dispose of in a licensed facility. Recommend crushing, puncturing or other means to prevent unauthorized
use of used containers.
14. Transport information
Land transport
Safety data sheet
1- Ethvnv1- 1- cvc1ohexanol
Revision date : 2006/10/16 Page: 6/7
Version: 1.2 (30036635 /MDS_GEN US /EN)
USDOT
Proper shipping name: TOXIC SOLID, ORGANIC, N.O.S. (contains 1-
Air transport
IATA/ICA0
Proper shipping name: TOXIC SOLID, ORGANIC, N.O.S. contains (1-
ETHINYLCYCLOHEXANOL)
Hazard class: 6.1
ID number: UN 2811
Packing group: III
15. Regulatory information
Federal Regulations
Registration status:
TSCA, US released / listed
OSHA hazard category: Chronic target organ effects reported, Acute target organ effects reported,
Toxic - dermal
CERCLA RO CAS Number Chemical name
5,000 LBS 108 -94 -1 cyclohexanone
SARA hazard categories (EPCRA 311/312): Acute, Fire
16. Other information
HMIS III rating
Health: 2 Flammability: 2 Physical hazard: 0
HMIS uses a numbering scale ranging from 0 to 4 to indicate the degree of hazard. A value of zero means that the
substance possesses essentially no hazard; a rating of four indicates high hazard.
Local contact information
prod_reg @basf.com
ETHI NYLCYCLOHEXANOL)
Hazard class:
6.1
ID number:
UN 2811
Packing group:
III
Sea transport
IMDG
Proper shipping name:
TOXIC SOLID, ORGANIC, N.O.S. contains (1-
ETH I NYLCYCLOH EXANOL)
Hazard Gass:
6.1
ID number:
UN 2811
Packing group:
III
Marine pollutant:
NO
Air transport
IATA/ICA0
Proper shipping name: TOXIC SOLID, ORGANIC, N.O.S. contains (1-
ETHINYLCYCLOHEXANOL)
Hazard class: 6.1
ID number: UN 2811
Packing group: III
15. Regulatory information
Federal Regulations
Registration status:
TSCA, US released / listed
OSHA hazard category: Chronic target organ effects reported, Acute target organ effects reported,
Toxic - dermal
CERCLA RO CAS Number Chemical name
5,000 LBS 108 -94 -1 cyclohexanone
SARA hazard categories (EPCRA 311/312): Acute, Fire
16. Other information
HMIS III rating
Health: 2 Flammability: 2 Physical hazard: 0
HMIS uses a numbering scale ranging from 0 to 4 to indicate the degree of hazard. A value of zero means that the
substance possesses essentially no hazard; a rating of four indicates high hazard.
Local contact information
prod_reg @basf.com
Safety data sheet
1- Ethynyl -1- cyclohexanol
Revision date: 2006/10/16 Page: 7/7
Version: 1.2 (30036635/MDS GEN US /EN)
IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN
ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR
GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION /USE,
WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR
YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER
EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A
PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR
INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE
USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE
SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A
PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND
AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY BASF
HEREUNDER ARE GIVEN GRATIS AND BASF ASSUMES NO OBLIGATION OR LIABILITY FOR THE
DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH
BEING GIVEN AND ACCEPTED AT YOUR RISK.
END OF DATA SHEET
1.
2.
GT Products, Inc.
MATERIAL SAFETY DATA SHEET
PRODUCT
PRODUCT AND COMPANY IDENTIFICATION
Manufactured by:
GT Products, Inc.
501 Industrial Blvd.
Grapevine, TX 76051
Date Prepared/ Revised:
Chemical Type/ Description:
INGREDIENTS
GT Products® GT -6068
Release Coating
Telephone: (800) 221 -0866
(817) 481 -7113
Fax: (817) 421 -1211
gtproducts.com
EMERGENCY (Chemtrec): (800) 424 -9300
06/15/11 by: Daniel Shaw
Silicone Release coating solution in petroleum solvent
This product contains Methylpolysiloxanes, which can generate Formaldehyde at approximately 300 °F (150 °C)
and above, in atmospheres which contain oxygen. Formaldehyde is a skin, eye, and throat irritant, is toxic and a
potential cancer hazard.
HMIS RATING: FLAMMABILITY: 3 REACTIVITY: 0 HEALTH: 2
3. EFFECTS OF EXPOSURE
Potential Health Effects:
Ingestion: May irritate exposed tissue.
Skin Contact: May cause irritation or skin freezing.
Inhalation: None expected due to very low vapor pressure.
Eye Contact: May irritate.
4. FIRST AID MEASURES
Ingestion: Seek medical attention.
Skin: Remove with dry towel, then wash with soap and water.
Eyes: Rinse 15 minutes with running water. Seek medical attention if
irritation persists.
Inhalation: Seek fresh air if needed.
Other: Not applicable.
GT -6068 printed: 6/20/2011 page 1 of 3
(Approx.)
Exposure Limits
CAS No.
petroleum solvent
90 -95% by weight
none established
64741 -66 -8
silicone oil blend
5 -10% by weight
none established
Trade Secret
This product contains Methylpolysiloxanes, which can generate Formaldehyde at approximately 300 °F (150 °C)
and above, in atmospheres which contain oxygen. Formaldehyde is a skin, eye, and throat irritant, is toxic and a
potential cancer hazard.
HMIS RATING: FLAMMABILITY: 3 REACTIVITY: 0 HEALTH: 2
3. EFFECTS OF EXPOSURE
Potential Health Effects:
Ingestion: May irritate exposed tissue.
Skin Contact: May cause irritation or skin freezing.
Inhalation: None expected due to very low vapor pressure.
Eye Contact: May irritate.
4. FIRST AID MEASURES
Ingestion: Seek medical attention.
Skin: Remove with dry towel, then wash with soap and water.
Eyes: Rinse 15 minutes with running water. Seek medical attention if
irritation persists.
Inhalation: Seek fresh air if needed.
Other: Not applicable.
GT -6068 printed: 6/20/2011 page 1 of 3
GT Products
5. FIRE FIGHTING INFORMATION
Flash Point (Method):
Flammability Class:
Flammability Limits in Air:
Extinguishing Media:
Hazardous Combustion Products
Special Fire Fighting Notes:
-10C Setaflash
I -B flammable liquid.
Approximate LEL 0.9 %, UEL 6.3% @ 77 (for petroleum solvent).
All standard media for chemical fires. Use water spray to cool.
CO, COZ, Si02, HZCO
Like all silicones, GT Productsc' X6068 can produce formaldehyde
when strongly heated in air.
6. ACCIDENTAL RELEASE MEASURES
Shut off or remove all sources of ignition. Pick up spilled material with absorbent clay, then wash area
thoroughly with water and detergent. Spilled material is very slippery.
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes and prolonged skin contact.
Storage: Store in cool (<40C) closed and dry containers.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering Controls: Good general ventilation.
Personal Protective Equipment
Eyes: Safety glasses.
Skin: Rubber or plastic gloves as desired.
Inhalation: Not normally required.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical State:
Color:
Odor:
Boiling Point:
Vapor Density (air = 1):
Specific Gravity:
Solubility in Water:
Clear, low- viscosity liquid.
None.
Petroleum.
208 -219F for solvent — silicone fraction is non - volatile.
>>1
0.71
None.
10, STABILITY AND REACTIVITY
Chemical Stability: Stable.
Hazardous Polymerization: Will not occur.
Decomposition Products: Only in fire conditions, see section 5.
Materials to Avoid: None.
Conditions to Avoid: None — keep tightly sealed to avoid contamination.
GT -6068 printed: 6/20/2011 page 2 of 3
GT Products
11. TOXICOLOGICAL INFORMATION
See section 3.
12. ECOLOGICAL INFORMATION
None available.
13. DISPOSAL CONSIDERATIONS
Disposal should be made in accordance with state and local regulations.
14. TRANSPORT INFORMATION
DOT SHIPPING NAME: Flammable Liquid N.O.S. contains mineral spirits and silicones
DOT HAZARD CLASS: 3
UN /NA Number: UN 1993
15. REGULATORY INFORMATION
TSCA INVENTORY STATUS: These materials or all of their contents are listed on the Toxic
Substances Control Act (TSCA).
16. OTHER INFORMATION
We believe the above information is correct as of the date of this data sheet. However, as this information and
the conditions under which the product are used are beyond the control of GT PRODUCTS, INC., it is the user's
obligation to determine the conditions for the safe use of the product. No warranty, expressed or implied, is
hereby made.
GT -6068 printed: 6/20/2011 page 3 of 3
V nIVAR 8
Univar USA Inc Material Safety Data Sheet
MSDS No:
ICZ68259
Version No:
1008 2012 -03 -27
Order No:
Univar USA Inc., 17425 NE Union Hill Rd., Redmond WA 98052
(425) 889 3400
Emergency Assistance
For emergency assistance involving chemicals call
Chemtrec - (800) 424 -9300
UNIVAR USA INC.
ISSUE DATE:201 1 -11 -01
Annotation:
± E,Wbfi,hW m re81
McI &al MW les 11mMed
.Material Safety Data for: Hexane
1. PRODUCT INDENTIFICATION
MSDS NO:CZ68259
VERSION:008 2012 -03 -27
2221 Ninth Line ! Oakville, ON LGH 7G7
Phone: 905- 337 -7411 i Fax: 905- 337 -1686
megaloid.ca
Name
hexane
Synonyms
normal hexane, n- hexane
CAS#
110 -54-3
ECM
203 -777 -6
Product Uses
solvent — oil extraction from oilseed, rubber cement, reagent, gasoline component
2.
INGREDIENTS % TWAEV / TLV Mu (mg /kg) L%(j (Mg/kg) LCsu ppm
Mg/M3 ORAL, SKIN INHALATION
Hexane
100 50 / 176 (skin) 15,800 >3300 42,600
3. (a) HAZARDS SUMMARY
Hazards, Quick Guide: highly flammable liquid, heavy vapour travels, distant ignition & flashback possible; nervous system
toxin
Canada — WHMIS B 3, D 2B
Key: B 2 — Flash Point <38 °C, B 3 — Flash Point >38°C & 93 °C
D I — Immediately Toxic, D 2 — Chronic Toxicity
C — Oxidising Substance, E - Corrosive
U.S.A. — HMIS Health — 1, Fire — 4, Reactivity — 0
Key: 0= minimal, I= slight, 2= moderate, 3= serious, 4= severe
3. (b) HAZARDS — TOXICITY
Effects, Acute Exposure
Skin Contact
Skin Absorption
Eye Contact
Inhalation
Ingestion
Effects, Chronic Exposure
General
Sensitising
Carcinogen /Tum origen
Reproductive Effect
Mutagen
Synergistic With
LD50 (oral)
LD50 (skin)
LC50 (inhalation)
drying, mild irritant — rapid evaporation limits exposure
some; no toxic effects likely by this route due to low general toxicity
mildly irritating — rapid evaporation limits exposure
5000ppm causes headache, dizziness, drowsiness, intoxication, anaesthesia
A high vapour concentration is readily achieved due to the high vapour pressure of Hexane.
poorly absorbed, low toxicity; nervous system symptoms possible; nausea may result — vomiting
could cause inhalation into the lungs and serious lung damage
prolonged exposure may cause dermatitis; prolonged exposure to as little as 30ppm, up to 2500ppm
by inhalation may cause peripheral neuropathy (numbness /tingling of hands & feet); blurred vision,
poor colour discrimination & visual field constriction associated with S yr exposure to 425- 1280ppm
not a sensitizer in humans or animals
not considered a tumorigen or a carcinogen in humans or animals
no known effect in humans; testicular damage in rats at doses also producing other clear symptoms
no known effect on humans or animals
effects of hexane enhanced by exposure to methyl ethyl ketone & lead acetate
15,800, 28,670 & 32,290mg /kg (rat); 20,000mg/kg (mouse)
>3300mg/kg (rabbit)
42,600ppm (mouse), 48,000 & 74,000ppm (rat)
UNIVAR USA INC.
ISSUE DATE:201 1 -11 -01
Annotation:
+i din 1961
mall"1o1 limited
(Hexane, cont'd)
4. FIRST AID
MSDS NO:CZ68259
VERSION:008 2012 -03 -27
2221 Ninth Line i Oakville, ON 1-61-1 7G7
Phone: 905-337-7411 1 Fax: 905- 337 -1686
megaloid.ca
page 2
SKIN: Evaporates rapidly. Wash with plenty of water. If exposed to pure hexane, remove clothing & allow to dry. If
hexane is contaminated with other substances, remove wet clothing & do not reuse until thoroughly cleaned.
EYES: Wash eyes with plenty of water, holding eyelids open. Seek medical assistance promptly if there is
irritation.
INHALATION: Remove from contaminated area promptly. CAUTION. • Rescuer must not endanger himsel./I If breathing
stops, administer artificial respiration and seek medical aid promptly.
INGESTION: Give plenty of water to dilute product. Do not induce vomiting (NOTE below). Keep victim quiet. If vomiting
occurs, lower victim's head below hips to prevent inhalation of vomited material. Seek medical help promptly.
Inadvertent inhalation of vomited material may seriously damage the lungs. The danger of this is greater than the risk ofpoisoning through absorption of this
relatively low- toxicity substance. The stomach should only be emptied under medical supervision, and after the installation of an airway to protect the lungs.
5. PHYSICAL PROPERTIES
Odour & Appearance
clear, colourless liquid with pleasant gasoline odour
Odour Threshold
>60ppm — above TWAEV / TLV,• odour poor guide to presence of harmful concentrations
Vapour Pressure
120mmHg / 16kPa (20 °C / 68 °F)
Evaporation Rate (Butyl Acetate =1)
8
Vapour Density (air = 1)
3
Boiling Range
60 -70 °C / 140 -158 °F
Freezing Point
-95 °C /-1400F
Specific Gravity
0.67 (20/20 °C)
Water Solubility
10 milligrams per litre (20 °C / 68 °F)
Also soluble in
most organic solvents
Viscosity
0.3centipoise (25 °C / 77 °F)
pH
none — (does not liberate hydrogen ions when dissolved)
Conversion Factor
Ippm = 3.52g/m3
Molecular Weight
86grams per mole
NOTE. Physical properties may vary depending on the presence of hexane isomers.
6. FLAMMABILITY & FIRE FIGHTING
Flash Point
-22 °C / -7°F (closed cup); also -26 °C / -15 °F (closed cup)
Autoignition Temperature
225 °C / 437 °F
Flammable Limits
1.1 % - 7.5%
Combustion Products
carbon monoxide, nitrogen oxides, smoke, part oxidised hydrocarbon fragments
Fire Fighting Precautions
CO2, foam, dry chemical, water fog or spray only to cool, product floats on water — water jet
spreads flames; fire fighters must wear SCBA
Static Charge Accumulation
readily accumulates a static charge on agitation or pumping; easily ignited by static
discharge
7. STABILITY / REACTIVITY
Dangerously Reactive With strong oxidising agents; chlorine, fluorine, NO2 & N204 can cause ignition or explosion
Also Reactive With damages certain plastics — check your equipment for its ability to resist hexane
Stability stable; will not polymerize
Decomposes in Presence of not known
Decomposition Products none apart from Hazardous Combustion Products
Sensitive to Mechanical Impact no
UNIVAR USA INC.
ISSUE DATE:2011 -11 -01
Annotation:
MSDS NO:CZ68259
VERSION:008 2012 -03 -27
¢ewbll<n „ r�sr = 2221 Ninth Line Oakville, ON L6H 7G7
� 1 �'O'� — Phone: 905- 337 -7411 j Fax: 905- 337 -1686
`_— Ilr f d fT1Ef,TdIGICLCd
`7 �ai�
(Hexane, cont'd) Page 3
8. PROTECTIVE EQUIPMENT/ EXPOSURE CONTROL
ACGIH TLV 50ppm / 176mg/m3 (skin)
OSHA PEL 500ppm / 1800mg/m3
STEL not listed
Ventilation hexane is highly volatile — use in enclosed equipment, mechanical ventilation (explosion - proof) may be
required to control airborne titre to regulated limits; depending on handling procedures; respirators with
organic vapour cartridges must be available for "escape" purposes should ventilation fail; store respirators in
air -tight containers (eg: "Tupperware ", 'ZipLock') to preserve cartridge `freshness"
Hands nitrite or "Viton" gloves may be used – other types may also protect; consult supplier to confirm suitability
Eyes safety glasses with side shields – always protect the eyes
Clothing no special protective clothing required
9. HANDLING & STORAGE
Store in a cool, dry environment, away from sources of ignition, heat and oxidising agents. Always use non - sparking
bronze or aluminium hand tools. All electrical and mechanical equipment (including lighting, switchgear and forklift
trucks) used with or around this product must be explosion proof.
Ground or electrically bond the source container and the receiving container, & pump before transferring contents.
Avoid splashing by ensuring that the product nozzle is below the surface in the receiving container.
Avoid breathing product vapour. Use with adequate ventilation. If dealing with a spill, and ventilation is impossible or
impractical, wear a suitable respirator with organic vapour cartridge..
Never cut, drill, weld or grind on or near this container. Avoid contact with skin and wash work clothes frequently. An
eye bath and safety shower must be available near the workplace.
Hexane has a mild, pleasant odour, which does not warn of intoxication hazard — which the victim may be unaware off
WHEN FILLING STORAGE TANKS WITH HEXANE IN ADDITION TO NORMAL GROUNDING PROCEDURES READ THE FOLLOWING:
This product may form an explosive mixture inside a bulk storage tank. Prior to filling a bulk storage tank with this product, consider ventilating
the headspace with nitrogen. In addition, consider asking the supplier to put an anti - static additive in the product when you order. If the bulk tank
has a floating product level indicator, this should be inspected reaularly. The float MUST HAVE a firmly fixed around wire connecting it to its
support cable. This connection must be free of corrosion.
Consult NFPA 77, 2007: "Recommended Practice on Static Electricity"
10. SPILL PROCEDURES
Serious Fire Potential: blanket spill with foam as a precaution against accidental ignition. Take extreme care
to avoid sparks – do not operate (turn on OR off) electrical appliances near spill, unless
Leak Precaution dyke to control spillage and prevent environmental contamination
Handling Spill ventilate contaminated area; recover free liquid with explosion -proof pumps; absorb residue (much of this will
evaporate) on an inert sorbent, sweep & pick up using plastic or aluminium shovel, & store in closed
containers for recycling or disposal
11. DISPOSAL
Waste Disposal do not flush to sewer, recycle solvent if possible, may be incinerated in approved facility
Containers Drums should be reused. Recondition and pressure test by a licensed reconditioner prior to re -use.
Pails must be vented and thoroughly dried prior to crushing and recycling.
IBCs (intermediate bulk containers): polyethylene bottle must be pressure tested & recertified at 30 months.
Replace at 60 months (5yrs). Steel containers must be inspected, pressure tested & recertified every 5 years.
Never cut, drill, weld or grind on or near this container, even if empty
Please eiistire that this JISDS is gireit to, and explained to people using this product.
UNIVAR USA INC.
ISSUE DATE:201 1 -11 -01
Annotation:
nee t9aloid
�IiN1'aIM'I!S Ilmited
v +rrl�ri7
(Hexane, cont'd)
12. ENVIRONMENTAL INFORMATION
MSDS NO:CZ68259
VERSION:008 2012 -03 -27
2221 Ninth Line ; Oakville, ON L6H 7G7
Phone: 905 -337 -7411 I Fax: 905- 337 -1686
megaloid.ca
page 4
Bioaccumulation in the hexane is a bioaccumulator; very rapid volatilisation & low water solubility limit this
Biodegradation hexane degrades readily in the presence of oxygen: 17% in 72 hours (closed incubation); in well -
aerated sewage treatment facility: 99% in 24 hours — much volatilised; % biodegraded unknown
Abiotic Degradation reacts with atmospheric hydroxyl radicals; estimated half -life in air is 5hours; photodegradation in
aquatic medium 50% in 24 hours
Mobility in soil, water water insoluble and cannot move in soil or water; volatilisation from soil or water is rapid, limiting
the likelihood of contamination of soil or ground water
Aquatic Toxicity
LCso (Fish, 96hr) 4mg /litre (Carassius auratus)
EC50 (Crustacea, 24hr) 50mg/litre (Dapnia magna) — this concentration must be emulsified into water
EC5o (Algae) not known, but 500mg/litre was toxic to bacteria in sewage sludge ...
13. TRANSPORT REGULATIONS
Canada TDG PIN UN -1208
AND Shipping Name hexanes
U.S.A. 49 CFR Class 3
Packing Group II
Marine Pollutant not a marine pollutant
EMF,RGENCY INFORMATION
Canada Call CANUTEC (collect) (613) 996 -6666
U.S.A. Call CHEMTREC (800) 424 -9300
IL REGULATIONS
Canada DSL on inventory
U.S.A. TSCA on inventory
Europe EINECS on inventory
Immediately Dangerous to Life or Health: 1100 ppm (Based on 109/o of the lower explosion limit for safety considerations even though the rclevant toxicological data indicated that irreversible health efects or
unpairrnent of escape existed only at higher eoncentmtions.) IREF -291
OSHA Standards: Permissible Exposure Limit: Table Z•1 8-hr Time Weighted Avg: 500 ppm (1800 mg /cum). Vacated 1999 OSHA PEL TWA 50 ppm (180 mg /cum) is still enforced in some statese.
N10SH Recommendations: Recommended Exposure Limit: 10 Hr Twe- Weighted Avg: 50 ppm (180 mg/cu m).
Threshold Limit Values: 8 hr Time Weighted Avg (TWA): 50 ppm, skin. Excursion Limit Recommendation: Excursions in worker exposure levels may exceed 3 times the TLV -TWA for no more than a total of30
minutes during a work day, and under no circumstances should they exceed 5 times the TLV -TWA, provided that the TLV -TWA is not exceeded. Biological Exposure Index (BEI): Determinant: 2„ -hexanedion
(without hydrolysis) in urine; Sampling Tune: end of shift at end of wwkwcelc, BEL 0.4 mg/L.
Atmospheric Standards: Listed as a hazardous au pollutant (HAP) generally (mown or suspected to cause serious health problems. The Clean Ain Act, as amended in 1990, directs EPA to set standards requiring
major sources to sharply reduce routine emissions of toxic pollutants. EPA is required to establish and phase in specific performance based standards for all air emission sources that emit one or more of the listed
pollutants. Hexane is included on this list.
State Drinking Water Standards: New Jersey 30 ug/L
State Drinking Water Guidelines: Arizona 4000 ug/l, Florida 10 ug/l, Maine 420 ug/l, Minnesota 400 ug/l, Nmv Jersey 30 ug/L. Wisconsin 600 uga
CERCLA Reportable Quantities: Persons in charge ofyessels or facilities am required to notify the National Response Center (NRC) immediately, when there is a release of this designated hazardous substance, in
an amount equal to or greater than its reportable quantiq of 500016 or 2270 kg. The toll fmc number ofthe NRC is (800) 424 -8802; In the Washington D.C. metropolitan area (202) 426 -2675. The role for determining
when notification is required is stated in 40 CFR 3024 (section W. D.31).
FDA Requirements: Hexane is an indirect food additive for use only as a component of adhesives.
16. PREPARATION INFORMATION
Prepared for Megaloid Laboratories by Peter Bursztyn, (705) 734 -1577
With data from RTF,CS, Ham Substance Data Base, Cheminfo (CCOHS), IUCLID Datasheets (European Chem. Substance Info. System), & others, as available
Preparation Date: November 2003Revision Date: July 2006, November 2008, November 2011
Univar USA Inc Material Safety Data Sheet
For Additional Information contact MSDS Coordinator during business hours, Pacific time: (425) 889 -3400
Notice
Univar USA Inc. ( "Univar ") expressly disclaims all express or implied warranties of merchantability and fitness for
a particular purpose, with respect to the product or information provided herein, and shall under no
circumstances be liable for incidental or consequential damages.
Do not use ingredient information and /or ingredient percentages in this MSDS as a product specification. For
product specification information refer to a product specification sheet and /or a certificate of analysis. These
can be obtained from your local Univar sales office.
All information appearing herein is based upon data obtained from the manufacturer and /or recognized
technical sources. While the information is believed to be accurate, Univar makes no representations as to its
accuracy or sufficiency. Conditions of use are beyond Univar's control and therefore users are responsible to
verify this data under their own operating conditions to determine whether the product is suitable for their
particular purposes and they assume all risks of their use, handling, and disposal of the product, or from the
publication or use of, or reliance upon, information contained herein.
This information relates only to the product designated herein, and does not relate to its use in combination
with any other material or in any other process
Material Safety Data Sheet
Hexamethyldisilazane (HMDS)
1. Product and company identification
::: iVance
Product name
: Hexamethyldisilazane (HMDS)
Supplier /Manufacturer
SiVance LLC
P.O. Box 1466
Emergency overview
Gainesville, FL 32602 -1466
Telephone No.: +1 352 - 376 -8246
Code
17178600000
Validation date
3/21/2011.
Responsible name
SiVance LLC ESHA (sivance.msds @sivancellc.com)
2. Hazards identification
Physical state :
Liquid.
OSHA/HCS status
This material is considered hazardous by the OSHA Hazard Communication Standard
(29 CFR 1910.1200).
Emergency overview
DANGER!
FLAMMABLE LIQUID AND VAPOR. CAUSES RESPIRATORY TRACT, EYE AND
SKIN BURNS. HARMFUL IF ABSORBED THROUGH SKIN. MAY BE HARMFUL IF
SWALLOWED. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN
DAMAGE, BASED ON ANIMAL DATA.
Keep away from heat, sparks and flame. Do not breathe vapor or mist. Do not ingest.
Do not get in eyes or on skin or clothing. Use only with adequate ventilation. Keep
container tightly closed and sealed until ready for use. Wash thoroughly after handling.
Routes of entry
Dermal contact. Eye contact. Inhalation. Ingestion.
Potential acute health effects
Inhalation :
Corrosive to the respiratory system. Exposure to decomposition products may cause a
health hazard. Serious effects may be delayed following exposure.
Ingestion
Harmful if swallowed. May cause burns to mouth, throat and stomach.
Skin
Corrosive to the skin. Causes burns. Toxic in contact with skin.
Eyes
Corrosive to eyes. Causes burns.
Potential chronic health effects
Chronic effects
Contains material that may cause target organ damage, based on animal data.
Target organs
Contains material which may cause damage to the following organs: blood, kidneys,
liver, eyes, central nervous system (CNS).
Over - exposure signs /symptoms
Inhalation
Adverse symptoms may include the following:
respiratory tract irritation
coughing
Ingestion
Adverse symptoms may include the following:
stomach pains
Skin
Adverse symptoms may include the following:
pain or irritation
redness
blistering may occur
Eyes
Adverse symptoms may include the following:
pain
watering
redness
3/21/2011.
17178600000 119
Hexamethyldisilazane (HMDS)
2. Hazards identification
Medical conditions Pre - existing disorders involving any target organs mentioned in this MSDS as being at
aggravated by over- risk may be aggravated by over - exposure to this product.
exposure
See toxicological information (Section 11)
3. Composition /information on ingredients
Name
1 ,1,1,3,3,3- hexamethyldisilazane
hexamethyldisiloxane
hydroxytrimethylsilane
4. First aid measures
CAS number
%
999 -97 -3
98-100
107 -46 -0
0.1 -2
1066 -40 -6
0.1 -1
Eye contact Check for and remove any contact lenses. Immediately flush eyes with plenty of water
for at least 15 minutes, occasionally lifting the upper and lower eyelids. Get medical
attention immediately.
Skin contact In case of contact, immediately flush skin with plenty of water for at least 15 minutes
while removing contaminated clothing and shoes. Wash clothing before reuse. Clean
shoes thoroughly before reuse. Get medical attention immediately.
Inhalation
Move exposed person to fresh air. If not breathing, if breathing is irregular or if
respiratory arrest occurs, provide artificial respiration or oxygen by trained personnel.
Loosen tight clothing such as a collar, tie, belt or waistband. Get medical attention
immediately.
Ingestion
Wash out mouth with water. Do not induce vomiting unless directed to do so by medical
personnel. Never give anything by mouth to an unconscious person. Get medical
attention immediately.
Protection of first - aiders
: No action shall be taken involving any personal risk or without suitable training. If it is
suspected that fumes are still present, the rescuer should wear an appropriate mask or
self- contained breathing apparatus. It may be dangerous to the person providing aid to
give mouth -to -mouth resuscitation. Wash contaminated clothing thoroughly with water
before removing it, or wear gloves.
Notes to physician
In case of inhalation of decomposition products in afire, symptoms maybe delayed.
The exposed person may need to be kept under medical surveillance for 48 hours.
5. Fire - fighting measures
Flammability of the product Flammable liquid. In a fire or if heated, a pressure increase will occur and the container
may burst, with the risk of a subsequent explosion. The vapor /gas is heavier than air
and will spread along the ground. Vapors may accumulate in low or confined areas or
travel a considerable distance to a source of ignition and flash back. Runoff to sewer
may create fire or explosion hazard.
Flash point Closed cup: 17.8 °C (64 °F)
Flammable limits Not available.
Auto - ignition temperature 330 °C (626 °F)
Suitable Apply Alcohol Resistant - Aqueous Film Forming Foam (AR- AFFF). Water fog may be
used to knock down vapor cloud. Use dry chemical, COz, water spray (fog) or foam.
Not suitable Do not use water jet.
Special exposure hazards Promptly isolate the scene by removing all persons from the vicinity of the incident if
there is a fire. No action shall be taken involving any personal risk or without suitable
training. Move containers from fire area if this can be done without risk. Use water
spray to keep fire- exposed containers cool.
3/21/2011. 17178600000 219
Hexamethyldisilazane (HMDS)
5. Fire - fighting measures
Hazardous thermal Decomposition products may include the following materials:
decomposition products carbon dioxide
carbon monoxide
nitrogen oxides
Silicon dioxide
metal oxide /oxides
Special protective : Fire - fighters should wear appropriate protective equipment and self- contained breathing
equipment for fire - fighters apparatus (SCBA) with a full face -piece operated in positive pressure mode.
6. Accidental release measures
Personal precautions No action shall be taken involving any personal risk or without suitable training.
Evacuate surrounding areas. Keep unnecessary and unprotected personnel from
entering. Do not touch or walk through spilled material. Shut off all ignition sources. No
flares, smoking or flames in hazard area. Do not breathe vapor or mist. Provide
adequate ventilation. Wear appropriate respirator when ventilation is inadequate. Put
on appropriate personal protective equipment (see Section 8).
Environmental precautions Avoid dispersal of spilled material and runoff and contact with soil, waterways, drains
and sewers. Inform the relevant authorities if the product has caused environmental
pollution (sewers, waterways, soil or air).
7. Handling and storage
Handling : Put on appropriate personal protective equipment (see Section 8). Eating, drinking and
smoking should be prohibited in areas where this material is handled, stored and
processed. Workers should wash hands and face before eating, drinking and smoking.
Remove contaminated clothing and protective equipment before entering eating areas.
Do not get in eyes or on skin or clothing. Do not breathe vapor or mist. Do not ingest.
Use only with adequate ventilation. Wear appropriate respirator when ventilation is
inadequate. Do not enter storage areas and confined spaces unless adequately
ventilated. Keep in the original container or an approved alternative made from a
compatible material, kept tightly closed when not in use. Store and use away from heat,
sparks, open flame or any other ignition source. Use explosion -proof electrical
(ventilating, lighting and material handling) equipment. Use non - sparking tools. Take
precautionary measures against electrostatic discharges. To avoid fire or explosion,
dissipate static electricity during transfer by grounding and bonding containers and
equipment before transferring material. Empty containers retain product residue and
can be hazardous. Do not reuse container.
Storage Store in accordance with local regulations. Store in a segregated and approved area.
Store in original container protected from direct sunlight in a dry, cool and well - ventilated
area, away from incompatible materials (see section 10) and food and drink. Eliminate
all ignition sources. Separate from oxidizing materials. Keep container tightly closed
and sealed until ready for use. Containers that have been opened must be carefully
resealed and kept upright to prevent leakage. Do not store in unlabeled containers. Use
appropriate containment to avoid environmental contamination.
8. Exposure controls /personal protection
Specific exposure standards are not available for all silazanes. It is recommended that the 25 ppm ceiling exposure limit
for Ammonia be utilized.
Consult local authorities for acceptable exposure limits.
Recommended monitoring If this product contains ingredients with exposure limits, personal, workplace atmosphere
procedures or biological monitoring may be required to determine the effectiveness of the ventilation
or other control measures and /or the necessity to use respiratory protective equipment.
3/21/2011. 17178600000 319
Hexamethyldisilazane (HMDS)
8. Exposure controls /personal protection
Engineering measures
Use only with adequate ventilation. Use process enclosures, local exhaust ventilation or
other engineering controls to keep worker exposure to airborne contaminants below any
recommended or statutory limits. The engineering controls also need to keep gas, vapor
or dust concentrations below any lower explosive limits. Use explosion -proof ventilation
equipment.
Hygiene measures
Wash hands, forearms and face thoroughly after handling chemical products, before
eating, smoking and using the lavatory and at the end of the working period. Appropriate
techniques should be used to remove potentially contaminated clothing. Wash
contaminated clothing before reusing. Ensure that eyewash stations and safety showers
are close to the workstation location.
Personal protection
Respiratory
Use a properly fitted, air - purifying or air -fed respirator complying with an approved
standard if a risk assessment indicates this is necessary. Respirator selection must be
based on known or anticipated exposure levels, the hazards of the product and the safe
working limits of the selected respirator.
Hands
Chemical- resistant, impervious gloves complying with an approved standard should be
worn at all times when handling chemical products if a risk assessment indicates this is
necessary. >8 hours (breakthrough time): Recommended: butyl rubber, neoprene
Eyes
: Safety eyewear complying with an approved standard should be used when a risk
assessment indicates this is necessary to avoid exposure to liquid splashes, mists or
dusts. Recommended: splash goggles, face shield
Skin
Personal protective equipment for the body should be selected based on the task being
performed and the risks involved and should be approved by a specialist before handling
this product.
Recommended: Wear suitable protective clothing.
Environmental exposure
Emissions from ventilation or work process equipment should be checked to ensure they
controls
comply with the requirements of environmental protection legislation. In some cases,
fume scrubbers, filters or engineering modifications to the process equipment will be
necessary to reduce emissions to acceptable levels.
9. Physical and chemical properties
Physical state
Flash point
Auto - ignition temperature
Flammable limits
Odor
pH
Boiling /condensation point
Melting /freezing point
Relative density
Density
Vapor pressure
Vapor density
Odor threshold
Evaporation rate
Solubility
Liquid.
Closed cup: 17.8 °C (64 °F)
330 °C (626 °F)
: Not available.
Not available.
Not available.
126 °C (258.8 °F)
Not available.
Not available.
0.777 g /cm3 [25 °C]
1.3 kPa (10 mm Hg) [20 °C]
5.5 [Air= 1]
Not available.
Not available.
Reacts
3/21/2011. 17178600000 419
Hexamethyldisilazane (HMDS)
10. Stability and reactivity
Chemical stability
Conditions to avoid
Materials to avoid
Hazardous decomposition
products
Possibility of hazardous
reactions
Special remarks on
reactivity
The product is stable.
Avoid all possible sources of ignition (spark or flame). Do not pressurize, cut, weld,
braze, solder, drill, grind or expose containers to heat or sources of ignition. Do not
allow vapor to accumulate in low or confined areas.
Reactive or incompatible with the following materials:
oxidizing materials
Contact with water liberates toxic gas. Ammonia.
: Under normal conditions of storage and use, hazardous reactions will not occur.
Reactive or incompatible with the following materials: oxidizing materials, acids, alkalis
and moisture.
REACTS WITH WATER TO RELEASE TOXIC GAS. Ammonia.
11. Toxicological information
Acute toxicity
Product/ingredient name
Result
Species
Dose
Exposure
1,1,1,3,3,3-
LC50 Inhalation Vapor
Rat
8700 mg /m3
4 hours
hexamethyldisilazane
Conclusion /Summary
Not available.
Carcinogenicity
LD50 Dermal
Rabbit
544 mg /kg
-
Conclusion /Summary
LD50 Oral
Rat
850 mg /kg
-
hexamethyldisiloxane
LC50 Inhalation Gas.
Rat
15956 ppm
4 hours
Conclusion /Summary
Not available.
Chronic toxicity
Conclusion /Summary
Not available.
Irritation /Corrosion
Conclusion /Summary
Not available.
Sensitizer
Conclusion /Summary
Not available.
Carcinogenicity
Conclusion /Summary
Not available.
Mutagenicity
Conclusion /Summary
Not available.
Teratogenicity
Conclusion /Summary
Not available.
Reproductive toxicity
Conclusion /Summary
Not available.
Synergistic products
Pre - existing respiratory and skin disorders may be aggravated by over - exposure to this
product.
3/21/2011. 17178600000 519
Hexamethyldisilazane (HMDS)
12. Ecological information
Ecotoxicity
Aquatic ecotoxicity
Conclusion /Summary
Persistence /degradability
Conclusion /Summary
Partition coefficient: n-
octanol /water
Bioconcentration factor
This product shows a low bioaccumulation potential.
Not available.
Not available.
2.62
Not available.
13. Disposal considerations
Waste disposal The generation of waste should be avoided or minimized wherever possible. Significant
quantities of waste product residues should not be disposed of via the foul sewer but
processed in a suitable effluent treatment plant. Dispose of surplus and non - recyclable
products via a licensed waste disposal contractor. Disposal of this product, solutions
and any by- products should at all times comply with the requirements of environmental
protection and waste disposal legislation and any regional local authority requirements.
Waste packaging should be recycled. Incineration or landfill should only be considered
when recycling is not feasible. This material and its container must be disposed of in a
safe way. Care should be taken when handling emptied containers that have not been
cleaned or rinsed out. Empty containers or liners may retain some product residues.
Vapor from product residues may create a highly flammable or explosive atmosphere
inside the container. Do not cut, weld or grind used containers unless they have been
cleaned thoroughly internally. Avoid dispersal of spilled material and runoff and contact
with soil, waterways, drains and sewers.
Disposal should be in accordance with applicable regional, national and local laws and regulations.
Refer to Section 7: HANDLING AND STORAGE and Section 8: EXPOSURE CONTROLS /PERSONAL PROTECTION
for additional handling information and protection of employees.
14. Transport information
Regulatory
UN number
Proper shipping
Classes
PG*
Label
Additional
information
name
information
DOT Classification
UN3286
Flammable liquid,
3 (6.1, 8)
li
Limited quantity
toxic, corrosive, n.o.s.
Yes.
(1,1,1,3,3,3 -
hexamethyldisilazane)
Packaging
instruction
>>
Passenger aircraft
.�
Quantity limitation: 1 L
o
Cargo aircraft
Quantity limitation: 5 L
Suecial provisions
I132, T11, TP2, TP13,
TP27
3/21/2011. 17178600000 619
Hexamethyldisilazane (HMDS)
14. Transport information
TDG Classification
UN3286
FLAMMABLE LIQUID,
3 (6.1, 8)
II
Explosive Limit and
TOXIC, CORROSIVE,
Limited Quantity
N.O.S. (1,1,1,3,3,3-
Index
hexamethyldisilazane)
1
Passenger Carrying
Road or Rail Index
1
Special provisions
16
IMDG Class
UN3286
FLAMMABLE LIQUID,
3 (6.1, 8)
II
Emergency
TOXIC, CORROSIVE,
schedules (EmS)
N.O.S.(1,1,1,3,3,3-
F -E, S -C
hexamethyldisilazane)
IATA -DGR Class
UN3286
Flammable liquid,
3 (6.1, 8)
II
Passenger and
toxic, corrosive, n.o.s.
Carao Aircraft
(1,1,1,3,3,3-
Quantity limitation: 1 L
hexamethyldisilazane)
Packaging
instructions: 352
<\
Cargo Aircraft Only
Quantity limitation: 5 L
Packaging
instructions: 363
Limited Quantities -
Passenger Aircraft
Quantity limitation:
0.5 L
Packaging
instructions: Y340
North America Emergency 131 PG*: Packing group
Response Guide
15. Regulatory information
HCS Classification Flammable liquid
Toxic material
Corrosive material
Target organ effects
U.S. Federal regulations TSCA 8(a) IUR Exempt/Partial exemption: Not determined
United States inventory (TSCA 8b): All components are listed or exempted.
3/21/2011. 17178600000 719
Hexamethyldisilazane (HMDS)
15. Regulatory information
Clean Air Act Section
112(b) Hazardous Air
Pollutants (HAPs)
Clean Air Act Section 602
Class I Substances
Clean Air Act Section 602
Class II Substances
State regulations
Massachusetts
New York
New Jersey
Pennsylvania
Canada
WHMIS (Canada)
Canadian lists
Canadian NPRI
CEPA Toxic substances
Canada inventory
International reaulations
SARA 302/304/311/312 extremely hazardous substances: No products were found.
SARA 302/304 emergency planning and notification: No products were found.
SARA 302/304/311/312 hazardous chemicals: 1, 1,1,3,3,3 - hexamethyldisilazane;
hexamethyldisiloxane
SARA 311/312 MSDS distribution - chemical inventory - hazard identification:
1, 1,1,3,3,3 - hexamethyldisilazane: Fire hazard, Immediate (acute) health hazard,
Delayed (chronic) health hazard; hexamethyldisiloxane: Fire hazard
Not listed
Not listed
Not listed
None of the components are listed.
None of the components are listed.
The following components are listed: HEXAMETHYLDISILAZANE; SILANAMINE, 1,1,1 -
TRIMETHYL- N -(TRI METHYLSI LYL)-
None of the components are listed.
Class B -2: Flammable liquid
Class D -113: Material causing immediate and serious toxic effects (Toxic).
Class E: Corrosive material
None of the components are listed.
None of the components are listed.
All components are listed or exempted.
International lists Australia inventory (AICS): All components are listed or exempted.
China inventory (IECSC): All components are listed or exempted.
Japan inventory: All components are listed or exempted.
Korea inventory: All components are listed or exempted.
New Zealand Inventory of Chemicals (NZIoC): All components are listed or exempted.
Philippines inventory (PICCS): All components are listed or exempted.
16. Other information
Label requirements FLAMMABLE LIQUID AND VAPOR. CAUSES RESPIRATORY TRACT, EYE AND
SKIN BURNS. HARMFUL IF ABSORBED THROUGH SKIN. MAY BE HARMFUL IF
SWALLOWED. CONTAINS MATERIAL THAT MAY CAUSE TARGET ORGAN
DAMAGE, BASED ON ANIMAL DATA.
Hazardous Material
Information System (U.S.A.)
Health 3
3
3/21/2011. 17178600000 819
Hexamefhyldisilazane (HMDS)
116. Other information
Personal protective equipment X
The customer is responsible for determining the PPE code for this material.
National Fire Protection
Association (U.S.A.)
Flammability
Health
40 1 Instability /Reactivity
Special
Date of printing 3/21/2011.
Date of issue 3121/2011.
Date of previous issue 9/20/2010.
Version 2.02
F Indicates information that has changed from previously issued version.
Notice to reader
To the best of our knowledge, the information contained herein is accurate. However, neither the above -named
supplier, nor any of its subsidiaries, assumes any liability whatsoever for the accuracy or completeness of the
information contained herein.
Final determination of suitability of any material is the sole responsibility of the user. All materials may present
unknown hazards and should be used with caution. Although certain hazards are described herein, we cannot
guarantee that these are the only hazards that exist.
3/21/2011. 17178600000 919
XIAMETER(R)
,from DOW CORNING Material Safety Data Sheet
Page: 1 of 9
Version: 2.1
Revision Date: 2011/12/15
XIAMETER(R) OFS -2306 SILANE
1. PRODUCT AND COMPANY IDENTIFICATION
Dow Corning Corporation
24 Hour Emergency Telephone:
(989) 496 -5900
South Saginaw Road
Customer Service:
(989) 496 -4430
Midland, Michigan 48686
Product Disposal Information:
(989) 496 -6315
CHEMTREC:
(800) 424 -9300
MSDS No.: 04099647
Revision Date: 2011/12/15
Generic Description:
Alkoxysilane
Physical Form:
Liquid
Color:
Colorless
Odor:
Some odor
NFPA Profile: Health 1 Flammability 2 Instability /Reactivity 0
Note: NFPA = National Fire Protection Association
2. HAZARDS IDENTIFICATION
POTENTIAL HEALTH EFFECTS
Acute Effects
Eye: Direct contact may cause mild irritation.
Skin: May cause mild irritation.
Inhalation: Vapor may irritate nose and throat. Overexposure by inhalation may cause drowsiness,
dizziness, confusion or loss of coordination.
Oral: Low ingestion hazard in normal use.
Prolonged /Repeated Exposure Effects
Skin: No known applicable information.
Inhalation: No known applicable information.
Oral: No known applicable information.
Signs and Symptoms of Overexposure
No known applicable information.
Medical Conditions Aggravated by Exposure
No known applicable information.
The above listed potential effects of overexposure are based on actual data, results of studies performed upon similar compositions,
XIAMETER(R)
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Version: 2.1
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XIAMETER(R) OFS -2306 SILANE
component data and /or expert review of the product. Please refer to Section 11 for the detailed toxicology information
3. COMPOSITION /INFORMATION ON INGREDIENTS
CAS Number Wt % Component Name
18395 -30 -7 85.0-100.0 Isobutyl trimethoxysilane
67 -56 -1 <1.0 Methyl alcohol
The above components are hazardous as defined in 29 CFR 1910.1200.
4. FIRST AID MEASURES
Eye: Immediately flush the contaminated eye(s) with lukewarm, gently flowing water for 5 minutes
while holding the eyelid(s) open. Obtain medical attention.
Skin: No health effects expected. If irritation does occur flush with lukewarm, gently flowing water
for 5 minutes. If irritation persists, obtain medical advice.
Inhalation: Remove from the source of contamination or move to fresh air. Obtain medical attention.
Oral: If irritation or discomfort occur, obtain medical advice.
Notes to Physician: Treat according to person's condition and specifics of exposure.
5. FIRE FIGHTING MEASURES
Flash Point: 129.2 OF / 54 °C (Tag Closed Cup)
Autoignition Temperature: 512.6 OF / 267 °C
Flammability Limits in Air: Lower Limit: 0.92 % Upper Limit: 16.0 %
Extinguishing Media: On large fires use dry chemical, foam or water spray. On small fires use carbon dioxide
(CO2), dry chemical or water spray. Water can be used to cool fire exposed containers.
Fire Fighting Measures: Self- contained breathing apparatus and protective clothing should be worn in fighting large
fires involving chemicals. Determine the need to evacuate or isolate the area according to
your local emergency plan. Use water spray to keep fire exposed containers cool.
Unusual Fire Hazards: Static electricity will accumulate and may ignite vapors. Prevent a possible fire hazard by
bonding and grounding or inert gas purge.
6. ACCIDENTAL RELEASE MEASURES
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XIAMETER(R) OFS -2306 SILANE
Containment/Clean up: Remove possible ignition sources. Determine whether to evacuate or isolate the area
according to your local emergency plan. Observe all personal protection equipment
recommendations described in Sections 5 and 8. For large spills, provide diking or other
appropriate containment to keep material from spreading. If diked material can be pumped,
store recovered material in appropriate container. Clean up remaining materials from spill
with suitable absorbant. Clean area as appropriate since spilled materials, even in small
quantities, may present a slip hazard. Final cleaning may require use of steam, solvents or
detergents. Dispose of saturated absorbant or cleaning materials appropriately, since
spontaneous heating may occur. Local, state and federal laws and regulations may apply to
releases and disposal of this material, as well as those materials and items employed in the
cleanup of releases. You will need to determine which federal, state and local laws and
regulations are applicable. Sections 13 and 15 of this MSDS provide information regarding
certain federal and state requirements.
Note: See Section 8 for Personal Protective Equipment for Spills.
AND
Use with adequate ventilation. Product evolves flammable methyl alcohol when exposed to water or humid air. Provide
ventilation during use to control exposure within Section 8 guidelines or use air - supplied or self- contained breathing
apparatus. Avoid eye contact. Avoid skin contact. Avoid breathing vapor, mist, dust, or fumes. Keep container closed.
Static electricity will accumulate and may ignite vapors. Prevent a possible fire hazard by bonding and grounding or inert
gas purge. Keep container closed and away from heat, sparks, and flame. Keep container closed and store away from
water or moisture.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Component Exposure Limits
CAS Number Component Name Exposure Limits
18395 -30 -7 Isobutyl trimethoxysilane See methyl alcohol comments.
Methyl alcohol forms on contact with water or humid air. Provide adequate ventilation to control exposures within
guidelines of OSHA PEL: TWA 200 ppm and ACGIH TLV- skin: TWA 200 ppm, STEL 250 ppm.
Engineering Controls
Local Ventilation: Recommended.
General Ventilation: Recommended.
Personal Protective Equipment for Routine Handling
Eyes: Use proper protection - safety glasses as a minimum.
XIAMETER(R)
fro,» DOW CORNING Material Safety Data Sheet
Page: 4 of 9
Version: 2.1
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XIAMETER(R) OFS -2306 SILANE
Skin: Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed as
soon as practical and thoroughly cleaned before reuse. Chemical protective gloves are
recommended.
Suitable Gloves: Handle in accordance with good industrial hygiene and safety practices.
Inhalation: Use respiratory protection unless adequate local exhaust ventilation is provided or exposure
assessment demonstrates that exposures are within recommended exposure guidelines. IH
personnel can assist in judging the adequacy of existing engineering controls.
Suitable Respirator: General and local exhaust ventilation is recommended to maintain vapor exposures below
recommended limits. Where concentrations are above recommended limits or are unknown,
appropriate respiratory protection should be worn. Follow OSHA respirator regulations (29
CFR 1910.134) and use NIOSH /MSHA approved respirators.
Personal Protective Equipment for Spills
Eyes: Use full face respirator.
Skin: Wash at mealtime and end of shift. Contaminated clothing and shoes should be removed as
soon as practical and thoroughly cleaned before reuse. Chemical protective gloves are
recommended.
Inhalation /Suitable Respiratory protection recommended. Follow OSHA Respirator Regulations (29 CFR
Respirator: 1910.134) and use NIOSH /MHSA approved respirators. Protection provided by air purifying
respirators against exposure to any hazardous chemical is limited. Use a positive pressure air
supplied respirator if there is any potential for uncontrolled release, exposure levels are
unknown, or any other circumstance where air purifying respirators may not provide adequate
protection.
Precautionary Measures: Avoid eye contact. Avoid skin contact. Avoid breathing vapor, mist, dust, or fumes. Keep
container closed. Use reasonable care.
Comments: Product evolves flammable methyl alcohol when exposed to water or humid air. Provide
ventilation during use to control exposure within Section 8 guidelines or use air - supplied or
self- contained breathing apparatus.
Note: These precautions are for room temperature handling. Use at elevated temperature or aerosol /spray applications may require
added precautions. For further information regarding aerosol inhalation toxicity, please refer to the guidance document regarding the
use of silicone -based materials in aerosol applications that has been developed by the silicone industry (www.SEHSC.com) or contact
the Dow Corning customer service group.
9. PHYSICAL AND CHEMICAL PROPERTIES
Physical Form:
Liquid
Color:
Colorless
Odor:
Some odor
Specific Gravity @ 25 °C:
0.92
Viscosity:
1 cSt
XIAMETER(R)
,;n. DOW CORNING Material Safety Data Sheet
Freezing /Melting Point:
Boiling Point:
Vapor Pressure @ 25 °C:
Vapor Density:
Solubility in Water:
pH:
Volatile Content:
Flash Point:
Autoignition Temperature:
Flammability Limits in Air:
Note: The above
10. STABILITY AND
Page: 5 of 9
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XIAMETER(R) OFS -2306 SILANE
Not determined.
155.5 °C
Not determined.
Not determined.
Not determined.
Not determined.
Not determined.
129.2 °F / 54 °C (Tag Closed Cup)
512.6 °F / 267 °C
Lower Limit: 0.92 % Upper Limit: 16.0 %
is not intended for use in
Chemical Stability: Stable.
Hazardous Hazardous polymerization will not occur.
Polymerization:
Conditions to Avoid: None.
Materials to Avoid: Oxidizing material can cause a reaction. Water, moisture, or humid air can cause hazardous
vapors to form as described in Section 8.
Hazardous Decomposition Products
Thermal breakdown of this product during fire or very high heat conditions may evolve the following decomposition
products: Carbon oxides and traces of incompletely burned carbon compounds. Silicon dioxide. Formaldehyde.
11. TOXICOLOGICAL INFORMATION
Acute Toxicology Data for Product
Species Test Results Type of Test
Oral LD50: Rat 10,000 mg /kg
Inhalation LC50: Rat >1525 PPM 4hr vapor
Component Toxicology Information
This material may liberate methanol upon exposure to moisture or humid air. Overexposure to methanol can result in
blindness and nervous system effects.
The toxicity of methanol varies greatly between species, depending upon the ability to metabolize formate. Non - primates
metabolize formate more efficiently than humans and other primates following high level methanol exposure. Therefore,
the acute animal test data shown above does not necessarily reflect the known human toxicity.
XIAMETER(R)
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XIAMETER(R) OFS -2306 SILANE
Special Hazard Information on Components
No known applicable information.
12. ECOLOGICAL INFORMATION
Environmental Fate and Distribution
Complete information is not yet available.
Environmental Effects
Complete information is not yet available.
Fate and Effects in Waste Water Treatment Plants
Complete information is not yet available.
Ecotoxicity Classification Criteria
Hazard Parameters (LC50 or EC50)
High
Medium
Low
Acute Aquatic Toxicity (mg /L)
< =1
>1 and < =100
>100
Acute Terrestrial Toxicity
< =100
>100 and <= 2000
>2000
This table is adapted from "Environmental Toxicology and Risk Assessment', ASTM STP 1179, p.34,1993.
This table can be used to classify the ecotoxicity of this product when ecotoxicity data is listed above. Please read the other information presented in the
section concerning the overall ecological safety of this material.
13. DISPOSAL CONSIDERATIONS
RCRA Hazard Class (40 CFR 261)
When a decision is made to discard this material, as received, is it classified as a hazardous waste? Yes
Characteristic Waste:
Ignitable: D001
State or local laws may impose additional regulatory requirements regarding disposal.
1 14. TRANSPORT INFORMATION I
DOT Road Shipment Information (49 CFR 172.101)
Proper Shipping Name: Combustible liquid, n.o.s.
Hazard Technical Name: Isobutyltrimethoxysilane / Methanol
Hazard Class: C
XIAMETER(R)
from DOW CORNING Material Safety Data Sheet
Page: 7 of 9
Version: 2.1
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XIAMETER(R) OFS -2306 SILANE
UN /NA Number:
NA 1993
Packing Group:
III
Hazard Label(s):
None
Remarks:
Above applies only to containers over 119 gallons or 450 liters.
Ocean Shipment (IMDG)
Proper Shipping Name:
FLAMMABLE LIQUID, N.O.S.
Hazard Technical Name:
Isobutyltrimethoxysilane / Methanol
Hazard Class:
3
UN /NA Number:
UN 1993
Packing Group:
III
Hazard Label(s):
flammable liquid
Air Shipment (IATA)
Proper Shipping Name:
Flammable liquid, n.o.s.
Hazard Technical Name:
Isobutyltrimethoxysilane / Methanol
Hazard Class:
3
UN /NA Number:
UN 1993
Packing Group:
III
Hazard Label(s):
Flammable Liquid
15. REGULATORY INFORMATION
Contents of this MSDS comply with the OSHA Hazard Communication Standard 29 CFR 1910.1200.
TSCA Status: All chemical substances in this material are included on or exempted from listing on the TSCA
Inventory of Chemical Substances.
EPA SARA Title III Chemical Listings
Section 302 Extremely Hazardous Substances (40 CFR 355):
None.
XIAMETER(R)
,mm DOWCORNPNG Material Safety Data Sheet
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XIAMETER(R) OFS -2306 SILANE
Section 304 CERCLA Hazardous Substances (40 CFR 302):
None.
Section 311/312 Hazard Class (40 CFR 370):
Acute:
Yes
Chronic:
No
Fire:
Yes
Pressure:
No
Reactive:
No
Section 313 Toxic Chemicals (40 CFR 372):
None present or none present in regulated quantities.
Note: Chemicals are listed under the 313 Toxic Chemicals section only if they meet or exceed a reporting threshold.
Supplemental State Compliance Information
California
Warning: This product contains the following chemical(s) listed by the State of California under the Safe Drinking Water
and Toxic Enforcement Act of 1986 (Proposition 65) as being known to cause cancer, birth defects or other
reproductive harm.
None known.
Massachusetts
No ingredient regulated by MA Right -to -Know Law present.
New Jersey
CAS Number Wt % Component Name
18395 -30 -7 85.0-100.0 Isobutyl trimethoxysi lane
Pennsylvania
CAS Number Wt % Component Name
18395 -30 -7 85.0 - 100.0 Isobutyl trimethoxysilane
XIAMETER(R)
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XIAMETER(R) OFS -2306 SILANE
16. OTHER IN
Prepared by: Dow Coming Corporation
These data are offered in good faith as typical values and not as product specifications. No warranty, either expressed or
implied, is hereby made. The recommended industrial hygiene and safe handling procedures are believed to be generally
applicable. However, each user should review these recommendations in the specific context of the intended use and
determine whether they are appropriate.
XIAMETER(R) is a trademark of Dow Corning Corporation
http: / /www.xiameter.com
COMPANY IDENTITY: SolvChem, Inc. DATE: 09/13/10
PRODUCT IDENTITY: ODORLESS MINERAL SPIRITS PAGE: 1 OF 7
SDS NUMBER: OMS
SAFETY DATA SHEET
This Safety Data Sheet conforms to ANSI Z400.5, and to the format requirements
and the International Chemical Safety Cards of the Global Harmonizing System.
THIS SDS COMPLIES WITH 29 CFR 1910.1200 (HAZARD COMMUNICATION STANDARD)
IMPORTANT: Read this SDS before handling & disposing of this product.
Pass this information on to employees, customers, & users of this product.
SECTION 1. IDENTIFICATION OF THE SUBSTANCE OR MIXTURE AND OF THE SUPPLIER
PRODUCT IDENTITY:
NEW MSDS DATE:
COMPANY IDENTITY:
COMPANY ADDRESS:
COMPANY CITY:
COMPANY PHONE:
EMERGENCY PHONES:
ODORLESS MINERAL SPIRITS
09/13/2010
SolvChem, Inc.
1904 Mykawa Road
Pearland, TX 77581 -0490
1- 281 -485 -5377
CHEMTREC: 1 -800- 424 -9300 (USA)
CANUTEC: 1- 613 - 996 -6666 (CANADA)
SECTION 2. HAZARDS IDENTIFICATION
WARNING!
RISK STATEMENTS:
R36/37/38 Irritating to eyes, respiratory system and skin.
R65 Harmful: may cause lung damage if swallowed.
SAFETY STATEMENTS:
S2 Keep out of the reach of children.
S23 Do not breathe gas, fumes, vapor, or spray.
524 Avoid contact with skin.
S62 If swallowed, do not induce vomiting; seek medical advice
immediately and show this container or label.
SEE SECTION 11 FOR OTHER TOXICOLOGICAL INFORMATION (ACUTE & CHRONIC HAZARDS)
SECTION 3. COMPOSITION /INFORMATION ON INGREDIENTS
MATERIAL CAS# EINECS# WT% TWA (OSHA) TLV (ACGIH)
Odorless Mineral Spirits 64741 -65 -7 265 -200 -4 95 -100 500 ppm 100 ppm
This product contains no EPA Hazardous Air Pollutants (HAP) in amounts > 0.1 %.
COMPANY IDENTITY: SolvChem, Inc. DATE: 09/13/10
PRODUCT IDENTITY: ODORLESS MINERAL SPIRITS PAGE: 2 OF 7
SDS NUMBER: OMS
SECTION 4. FIRST AID MEASURES
EYE CONTACT:
For eyes, flush with plenty of water for 15 minutes & get medical attention.
SKIN CONTACT:
In case of contact with skin immediately remove contaminated clothing.
Wash thoroughly with soap & water. Wash contaminated clothing before reuse.
INHALATION:
After high vapor exposure, remove to fresh air. If breathing is difficult, give
oxygen. If breathing has stopped, trained personnel should immediately begin
artificial respiration. If the heart has stopped, trained personnel
should immediately begin cardiopulmonary resuscitation (CPR).
SWALLOWING:
Rinse mouth. Do NOT induce vomiting. GET MEDICAL ATTENTION IMMEDIATELY.
Do NOT give liquids to an unconscious or convulsing person.
SECTION 5. FIRE FIGHTING MEASURES
FIRE & EXPLOSION PREVENTIVE MEASURES
NO open flames, NO sparks, & NO smoking. Above flash point, use
a closed system, ventilation, explosion -proof electrical equipment, lighting.
EXTINGUISHING MEDIA
Use dry powder, AFFF, carbon dioxide.
SPECIAL FIRE FIGHTING PROCEDURES
Water spray may be ineffective on fire but can protect fire - fighters
& cool closed containers. Use fog nozzles if water is used.
Do not enter confined fire -space without full bunker gear.
(Helmet with face shield, bunker coats, gloves & rubber boots).
Use NIOSH approved positive- pressure self- contained breathing apparatus.
UNUSUAL EXPLOSION AND FIRE PROCEDURES
COMBUSTIBLE!
Isolate from oxidizers, heat, & open flame.
Closed containers may explode if exposed to extreme heat.
Applying to hot surfaces requires special precautions.
Empty container very hazardous! Continue all label precautions!
COMPANY IDENTITY: SolvChem, Inc. DATE: 09/13/10
PRODUCT IDENTITY: ODORLESS MINERAL SPIRITS PAGE: 3 OF 7
SDS NUMBER: OMS
SECTION 6. ACCIDENTAL RELEASE MEASURES
PERSONAL PROTECTIVE MEASURES:
Keep unprotected personnel away. Ventilate spill area. Remove all ignition sources.
Filter respirator for organic vapors.
ENVIRONMENTAL PRECAUTIONS:
Keep from entering storm sewers and ditches which lead to waterways.
CONTAINMENT AND CLEAN -UP MEASURES:
Stop spill at source. Dike and contain.
Absorb remaining liquid in sand or inert absorbent.
SECTION 7. HANDLING AND STORAGE
HANDLING
Isolate from oxidizers, heat, & open flame.
Use only with adequate ventilation. Avoid breathing of vapor or spray mist.
Avoid prolonged or repeated contact with skin.
Wear OSHA Standard goggles or face shield. Consult Safety Equipment Supplier. Wear
gloves, apron & footwear impervious to this material. Wash clothing before reuse.
Avoid free fall of liquid. Ground containers when transferring. Do not flame cut,
braze, or weld. Empty container very hazardous! Continue all label precautions!
To minimize static discharge when transferring, ensure electrical continuity
by bonding and grounding all equipment. Use an inlet line diameter of at
least 3.5 inches (8.9 centimeters) with a maximum flow rate of 1 meter /second.
STORAGE
Isolate from strong oxidants. Keep container tightly closed
& upright when not in use to prevent leakage.
SECTION 8. EXPOSURE CONTROLS /PERSONAL PROTECTION
RESPIRATORY EXPOSURE CONTROLS
A respiratory protection program that meets OSHA 29 CFR 1910.134 and
ANSI Z86.2 requirements or European Standard EN 149 must be followed
whenever workplace conditions warrant a respirator's use.
VENTILATION
LOCAL EXHAUST: Necessary MECHANICAL (GENERAL): Acceptable
SPECIAL: None OTHER: None
Please refer to ACGIH document, "Industrial Ventilation, A Manual of
Recommended Practices ", most recent edition, for details.
PERSONAL PROTECTIONS:
Wear OSHA Standard goggles or face shield. Consult Safety Equipment Supplier. Wear
gloves, apron & footwear impervious to this material. Wash clothing before reuse.
COMPANY IDENTITY: SolvChem, Inc. DATE: 09/13/10
PRODUCT IDENTITY: ODORLESS MINERAL SPIRITS PAGE: 4 OF 7
SOS NUMBER: OMS
SECTION 8. EXPOSURE CONTROLS /PERSONAL PROTECTION (CONTINUED)
WORK & HYGIENIC PRACTICES:
Provide readily accessible eye wash stations & safety showers.
Wash at end of each workshift & before eating, smoking or using the toilet.
Promptly remove clothing that becomes contaminated. Destroy contaminated
leather articles. Launder or discard contaminated clothing.
SECTION 9. PHYSICAL & CHEMICAL PROPERTIES
APPEARANCE:
ODOR:
ODOR THRESHOLD:
pH (Neutrality):
MELTING POINT /FREEZING POINT:
BOILING RANGE (IBP,50 %,Dry Point):
FLASH POINT (TEST METHOD):
EVAPORATION RATE (n -BUTYL ACETATE =1):
FLAMMABILITY CLASSIFICATION:
LOWER FLAMMABLE LIMIT IN AIR (% by vol):
UPPER FLAMMABLE LIMIT IN AIR (% by vol):
VAPOR PRESSURE (mm of Hg) @20 C
VAPOR DENSITY (air =1):
GRAVITY @ 68/68 F / 20/20 C:
SPECIFIC GRAVITY (Water =1):
POUNDS /GALLON:
WATER SOLUBILITY:
PARTITION COEFFICIENT (n- Octane /Water):
AUTO IGNITION TEMPERATURE:
DECOMPOSITION TEMPERATURE:
REFRACTIVE INDEX:
VOC'S (>0.44 Lbs /Sq In)
TOTAL VOC'S (TVOC) *:
NONEXEMPT VOC'S (CVOC) *:
HAZARDOUS AIR POLLUTANTS (HAPS):
NONEXEMPT VOC PARTIAL PRESSURE (mm of Hg @ 20 C)
Liquid, Water -White
Mild
Not Available
Not Applicable
Not Available
171 191 204 C / 340 376 400 F
52 C / 127 F (TCC)
0.177
Class II
0.95
6.0
0.849
5.2
0.770
6.414
Negligible
Not Available
260 C / 500 F
Not Available
1.426
0.0 Vol% /0.0 g/L / 0.000 Lbs /Gal
100.0 Vol% / 770.0 g/L / 6.4 Lbs /Gal
100.0 Vol% / 770.0 g/L / 6.4 Lbs /Gal
0.0 Wt% /0.0 g/L / 0.000 Lbs /Gal
0.849
* Using California South Coast Air Quality Management District (SCAQMD) Rule 443.1.
SECTION 10. STABILITY & REACTIVITY
STABILITY
Stable under normal conditions.
CONDITIONS TO AVOID
Isolate from oxidizers, heat, & open flame.
MATERIALS TO AVOID
Reacts with strong oxidants, causing fire & explosion hazard.
HAZARDOUS DECOMPOSITION PRODUCTS
Carbon Monoxide, Carbon Dioxide from burning.
HAZARDOUS POLYMERIZATION
Will not occur.
COMPANY IDENTITY: SolvChem, Inc.
PRODUCT IDENTITY: ODORLESS MINERAL SPIRITS
SDS NUMBER: OMS
SECTION 11. TOXICOLOGICAL INFORMATION
ACUTE HAZARDS
EYE & SKIN CONTACT:
Primary irritation to skin, defatting, dermatitis.
Primary irritation to eyes, redness, tearing, blurred vision.
Liquid can cause eye irritation. Wash thoroughly after handling.
INHALATION:
Anesthetic. Irritates respiratory tract. Acute overexposure
can cause serious nervous system depression. Vapor harmful.
SWALLOWING:
Harmful or fatal if swallowed.
Swallowing can cause abdominal irritation, nausea, vomiting & diarrhea.
The symptoms of chemical pneumonitis may not show up for a few days.
SUBCHRONIC HAZARDS /CONDITIONS AGGRAVATED
CONDITIONS AGGRAVATED
Persons with severe skin, liver or kidney problems should avoid use.
CHRONIC HAZARDS
CANCER, REPRODUCTIVE & OTHER CHRONIC HAZARDS:
This product has no carcinogens listed by IARC, NTP, NIOSH,
OSHA or ACGIH, as of this date, greater or equal to 0.1 %.
MAMMALIAN TOXICITY INFORMATION
No mammalian information is available on this product.
DATE: 09/13/10
PAGE: 5 OF 7
COMPANY IDENTITY: SolvChem, Inc. DATE: 09/13/10
PRODUCT IDENTITY: ODORLESS MINERAL SPIRITS PAGE: 6 OF 7
SDS NUMBER: OMS
SECTION 12. ECOLOGICAL INFORMATION
AQUATIC ANIMAL INFORMATION:
No aquatic environmental information is available on this product.
Environmental effects of the substance have not been investigated adequately.
MOBILITY IN SOIL
This material is a mobile liquid.
DEGRADABILITY
This product is nonbiodegradable.
ACCUMULATION
This product does not accumulate or biomagnify in the environment.
SECTION 13. DISPOSAL CONSIDERATIONS
Processing, use or contamination may change the waste management options.
Recycle / dispose of observing national, regional, state, provincial and local
health, safety & pollution laws. If in doubt, contact appropriate agencies.
SECTION 14. TRANSPORT INFORMATION
DOT SHIPPING NAME: NONBULK: None
BULK: UN1268, Petroleum Distillates, n.o.s.
Combustible liquid, PG -III
Combustible liquid. Not DOT regulated on trucks in containers of < 119 gallons.
DRUM LABEL: None (Combustible Liquid)
IATA / ICAO: UN1268, Petroleum Distillates, n.o.s., 3, PG -III
IMO / IMDG: UN1268, Petroleum Distillates, n.o.s., 3, PG -III
EMERGENCY RESPONSE GUIDEBOOK NUMBER: 128
SECTION 15. REGULATORY INFORMATION
EPA REGULATION:
SARA SECTION 311/312 HAZARDS: Acute Health, Fire
All components of this product are on the TSCA list.
This material contains no known products restricted under SARA Title III,
Section 313 in amounts greater or equal to 1 %.
COMPANY IDENTITY: SolvChem, Inc.
PRODUCT IDENTITY: ODORLESS MINERAL SPIRITS
SDS NUMBER: OMS
SECTION 15. REGULATORY INFORMATION (CONTINUED)
INTERNATIONAL REGULATIONS
The components of this product are listed on the chemical
inventories of the following countries:
Australia, Canada, China, Europe (EINECS), Japan, Korea, United Kingdom.
CANADA: WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS)
B3: Combustible Liquid.
D2B: Irritating to skin / eyes.
SECTION 16. OTHER INFORMATION
HAZARD RATINGS:
DATE: 09/13/10
PAGE: 7 OF 7
HEALTH (NFPA): 0, HEALTH (HMIS): 1, FLAMMABILITY: 2, REACTIVITY: 0
(Personal Protection Rating to be supplied by user based on use conditions.)
This information is intended solely for the use of individuals
trained in the NFPA & HMIS hazard rating systems.
EMPLOYEE TRAINING
See Section 2 for Risk & Safety Statements. Employees should be made aware
of all hazards of this material (as stated in this SDS) before handling it.
NOTICE
The supplier disclaims all expressed or implied warranties of merchantability or fitness
for a specific use, with respect to the product or the information provided herein,
except for conformation to contracted specifications. All information appearing herein
is based upon data obtained from manufacturers and /or recognized technical sources.
While the information is believed to be accurate, we make no representations as to its
accuracy or sufficiency.
Conditions of use are beyond our control, and therefore users are responsible for
verifying the data under their own operating conditions to determine whether the product
is suitable for their particular purposes and they assume all risks of their handling,
and disposal of the product. Users also assume all risks in regards to the publication
or use of, or reliance upon information contained herein.
This information relates only to the product designated herein, and does not relate to
its use in combination with any other material or process.
Unless updated, the Safety Data Sheet is valid until 09/13/2013.
ORDER NO:DA465623 MATERIAL SAFETY DATA SHEET MSDS NO:DW04108
CUST:GT PRODUCTS VERSION:012 10/08/10
"I
`�
Material Safety Data Sheet
The Dow Chemical Company
Product Name: METHOCEL* 40 -0101 Personal Care Grade Issue Date: 10/01/2010
Hydroxypropyl Methylcellulose
Print Date: 05 Oct 2010
The Dow Chemical Company encourages and expects you to read and understand the entire (M)SDS,
as there is important information throughout the document. We expect you to follow the precautions
identified in this document unless your use conditions would necessitate other appropriate methods or
actions.
11. Product and Company Identification I
Product Name
METHOCEL* 40 -0101 Personal Care Grade Hydroxypropyl Methylcellulose
COMPANY IDENTIFICATION
The Dow Chemical Company
2030 Willard H. Dow Center
Midland, MI 48674
USA
Customer Information Number:
EMERGENCY TELEPHONE NUMBER
24 -Hour Emergency Contact:
Local Emergency Contact:
800 - 258 -2436
989- 636 -4400
989 - 636 -4400
12. Hazards Identification I
Emergency Overview
Color: White to off -white
Physical State: Powder
Odor: Mild
Hazar
Is of product:
WARNING! May cause allergic skin reaction. May form explosive dust -air mixture.
Slipping hazard. Avoid temperatures above 130 °C 266 °F
OSHA Hazard Communication Standard
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29
CFR 1910.1200.
Potential Health Effects
Eye Contact: Solid or dust may cause irritation or corneal injury due to mechanical action.
Skin Contact: Essentially nonirritating to skin.
Skin Absorption: No adverse effects anticipated by skin absorption.
Skin Sensitization: For the minor component(s): Skin contact may cause an allergic skin reaction.
®(TM) *Trademark of The Dow Chemical Company ( "Dow ") or an affiliated company of Dow
Page 1 of 8
ORDER NO:DA465623 MATERIAL SAFETY DATA SHEET MSDS NO:DW04108
CUST:GT PRODUCTS VERSION:012 10/08/10
Product Name: METHOCEL* 40 -0101 Personal Care Grade Issue Date: 10/01/2010
Hydroxypropyl Methylcellulose
Inhalation: No adverse effects are anticipated from single exposure to dust.
Ingestion: Very low toxicity if swallowed. Harmful effects not anticipated from swallowing small
amounts.
Aspiration hazard: Based on physical properties not likely to be an aspiration hazard
13. Composition Information
This product is a pure chemical.
Component
CAS #
Amount
Hydroxypropyl methyl cellulose
9004 -65 -3
>= 85.0 - <= 95.0
Water
7732 -18 -5
>= 1.0 - <= 10.0
Sodium chloride
7647 -14 -5
>= 0.5 - <= 5.0
Ethanedial
107 -22 -2
< 1.0
Polyglycol and carboxylic acid
Trade secret
<= 4.0
4. First -aid measures
Eye Contact: Flush eyes with plenty of water; remove contact lenses after the first 1 -2 minutes then
continue flushing for several minutes. Only mechanical effects expected. If effects occur, consult a
physician, preferably an ophthalmologist.
Skin Contact: Remove material from skin immediately by washing with soap and plenty of water.
Remove contaminated clothing and shoes while washing. Seek medical attention if irritation persists.
Wash clothing before reuse. Discard items which cannot be decontaminated, including leather articles
such as shoes, belts and watchbands.
Inhalation: Move person to fresh air; if effects occur, consult a physician.
Ingestion: No emergency medical treatment necessary.
Notes to Physician: No specific antidote. Treatment of exposure should be directed at the control of
symptoms and the clinical condition of the patient.
Emergency Personnel Protection: First Aid responders should pay attention to self - protection and
use the recommended protective clothing (chemical resistant gloves, splash protection). If potential for
exposure exists refer to Section 8 for specific personal protective equipment.
15. Fire Fighting Measures
Extinguishing Media: Water. Dry chemical fire extinguishers. Carbon dioxide fire extinguishers.
Fire Fighting Procedures: Keep people away. Isolate fire and deny unnecessary entry. Soak
thoroughly with water to cool and prevent re- ignition. Cool surroundings with water to localize fire
zone. Hand held dry chemical or carbon dioxide extinguishers may be used for small fires. Dust
explosion hazard may result from forceful application of fire extinguishing agents.
Special Protective Equipment for Firefighters: Wear positive - pressure self- contained breathing
apparatus (SCBA) and protective fire fighting clothing (includes fire fighting helmet, coat, trousers,
boots, and gloves). If protective equipment is not available or not used, fight fire from a protected
location or safe distance.
Unusual Fire and Explosion Hazards: Do not permit dust to accumulate. When suspended in air
dust can pose an explosion hazard. Minimize ignition sources. If dust layers are exposed to elevated
temperatures, spontaneous combustion may occur. Pneumatic conveying and other mechanical
handling operations can generate combustible dust. To reduce the potential for dust explosions,
electrically bond and ground equipment and do not permit dust to accumulate. Dust can be ignited by
static discharge.
Hazardous Combustion Products: During a fire, smoke may contain the original material in addition
to combustion products of varying composition which may be toxic and /or irritating. Combustion
products may include and are not limited to: Carbon monoxide. Carbon dioxide.
Page 2 of 8
ORDER NO:DA465623 MATERIAL SAFETY DATA SHEET MSDS NO:DW04108
CUST:GT PRODUCTS VERSION:012 10/08/10
Product Name: METHOCEL' 40 -0101 Personal Care Grade Issue Date: 10/01/2010
Hydroxypropyl Methylcellulose
6. Accidental Release Measures
Steps to be Taken if Material is Released or Spilled: Contain spilled material if possible. Sweep up.
Use care to minimize generation of airborne dust. Do not use water for cleanup. Collect in suitable
and properly labeled containers. See Section 13, Disposal Considerations, for additional information.
Personal Precautions: Spilled material may cause a slipping hazard. Use appropriate safety
equipment. For additional information, refer to Section 8, Exposure Controls and Personal Protection.
Environmental Precautions: Prevent from entering into soil, ditches, sewers, waterways and /or
groundwater. See Section 12, Ecological Information.
7. Handling and Storage
Handling
General Handling: Keep away from heat, sparks and flame. No smoking, open flames or sources of
ignition in handling and storage area. Electrically ground and bond all equipment. Good
housekeeping and controlling of dusts are necessary for safe handling of product. See Section 8,
EXPOSURE CONTROLS AND PERSONAL PROTECTION.
Storage
Store in a dry place. See Section 10 for more specific information.
Storage temperature: 5 - 35 °C
8. Exposure Controls / Personal Protection
Exposure Limits
Component List Type Value
Hydroxypropyl methyl Dow IHG TWA Total 10 mg /m3
cellulose dust
Ethanedial AIHA WEEL TWA 0.1 mg /m3 0.042 ppm D -SEN
Inhalable
fraction and
vapor. -
ACGIH TWA 0.1 mg /m3 SEN
Inhalable
fraction and
vapor.
A "SEN" notation following the exposure guideline refers to the potential to produce sensitization, as
confirmed by human or animal data.
A D -SEN notation following the exposure guideline refers to the potential to produce dermal
sensitization, as confirmed by human or animal data.
Personal Protection
Eye /Face Protection: Use safety glasses (with side shields). If there is a potential for exposure to
particles which could cause eye discomfort, wear chemical goggles.
Skin Protection: Use protective clothing chemically resistant to this material. Selection of specific
items such as face shield, boots, apron, or full body suit will depend on the task.
Hand protection: Use gloves chemically resistant to this material. Examples of preferred
glove barrier materials include: Neoprene. Nitrile /butadiene rubber ( "nitrile" or "NBR ").
Polyvinyl chloride ( "PVC" or "vinyl "). NOTICE: The selection of a specific glove for a particular
application and duration of use in a workplace should also take into account all relevant
workplace factors such as, but not limited to: Other chemicals which may be handled, physical
Page 3 of 8
ORDER NO:DA465623 MATERIAL SAFETY DATA SHEET MSDS NO:DW04108
CUST:GT PRODUCTS VERSION:012 10/08/10
Product Name: METHOCEL' 40 -0101 Personal Care Grade Issue Date: 1010112010
Hydroxypropyl Methylcellulose
requirements (cut/puncture protection, dexterity, thermal protection), potential body reactions
to glove materials, as well as the instructions /specifications provided by the glove supplier.
Respiratory Protection: Respiratory protection should be worn when there is a potential to exceed
the exposure limit requirements or guidelines. If there are no applicable exposure limit requirements
or guidelines, wear respiratory protection when adverse effects, such as respiratory irritation or
discomfort have been experienced, or where indicated by your risk assessment process. For most
conditions, no respiratory protection should be needed; however, in dusty atmospheres, use an
approved particulate respirator. The following should be effective types of air - purifying respirators:
Particulate filter.
Ingestion: Use good personal hygiene. Do not consume or store food in the work area. Wash hands
before smoking or eating.
Engineering Controls
Ventilation: Use local exhaust ventilation, or other engineering controls to maintain airborne levels
below exposure limit requirements or guidelines. If there are no applicable exposure limit
requirements or guidelines, general ventilation should be sufficient for most operations. Local exhaust
ventilation may be necessary for some operations.
9. Physical and Chemical Properties
Physical State
Color
Odor
Odor Threshold
Flash Point - Closed Cup
Flammability (solid, gas)
Flammable Limits In Air
Autoignition Temperature
Vapor Pressure
Boiling Point (760 mmHg)
Vapor Density (air = 1)
Specific Gravity (H20 = 1)
Freezing Point
Melting Point
Solubility in water (by
weight)
pH
Decomposition
Temperature
Partition coefficient, n-
octanol /water (log Pow)
Evaporation Rate (Butyl
Acetate =1)
Powder
White to off -white
Mild
No test data available
No test data available
No
Lower: No test data available
Upper: No test data available
No test data available
Not applicable
Not applicable.
Not applicable
No test data available
Not applicable
No test data available
completely soluble in water
Not applicable
No test data available
No data available for this product.
No test data available
110. Stabilitv and Reactivity
Stab i I ity /Instability
Stable under recommended storage conditions. See Storage, Section 7.
Conditions to Avoid: Avoid temperatures above 130 °C (266 °F). Exposure to elevated temperatures
can cause product to decompose. Avoid static discharge.
Incompatible Materials: Avoid contact with oxidizing materials. Avoid contact with: Strong acids.
Strong bases.
Hazardous Polymerization
Page 4 of 8
ORDER NO:DA465623 MATERIAL SAFETY DATA SHEET MSDS NO:DW04108
CUST:GT PRODUCTS VERSION:012 10/08/10
Product Name: METHOCEL* 40 -0101 Personal Care Grade Issue Date: 10/01/2010
Hydroxypropyl Methylcellulose
Will not occur.
Decomposition Thermal
Decomposition -products . -• -n• upon temp-orature. air supply and the . - -i - Qf Qlher materials.
11. Toxicological Information
Acute Toxicity
Ingestion
Single dose oral LD50 has not been determined.
For the major component(s): LD50, Rat > 5,000 mg/kg
Dermal
The dermal LD50 has not been determined.
For the major component(s): LD50, Rabbit > 5,000 mg/kg
Inhalation
The LC50 has not been determined.
Eye damage /eye irritation
Solid or dust may cause irritation or corneal injury due to mechanical action.
Skin corrosion /irritation
Essentially nonirritating to skin.
Sensitization
Skin
For the minor component(s): Skin contact may cause an allergic skin reaction.
Respiratory
No relevant information found.
Repeated Dose Toxicity
Repeated ingestion of similar cellulosics by humans has not resulted in known significant adverse
effects.
Chronic Toxicity and Carcinogenicity
Similar cellulosics did not cause cancer in long -term animal studies.
Developmental Toxicity
Similar cellulosics did not cause birth defects or other toxic effects to the fetus in laboratory animal
studies.
Reproductive Toxicity
In animal studies, a similar cellulosic has been shown not to interfere with reproduction.
Genetic Toxicology
Similar cellulosics were negative in both in vitro and animal genetic toxicity studies.
12. Ecological Information
ENVIRONMENTAL FATE
Movement & Partitioning
No bioconcentration is expected because of the relatively high molecular weight (MW greater than
1000).
Persistence and Degradability
No appreciable biodegradation is expected.
Biological oxygen demand (BOD):
BOD 5 BOD 10 BOD 20 BOD 28
0%
ECOTOXICITY
Not expected to be acutely toxic to aquatic organisms
Page 5 of 8
ORDER NO:DA465623 MATERIAL SAFETY DATA SHEET MSDS NO:DW04108
CUST:GT PRODUCTS VERSION:012 10/08/10
Product Name: METHOCEL' 40 -0101 Personal Care Grade Issue Date: 10/01/2010
Hydroxypropyl Methylcellulose
DO NOT DUMP INTO ANY SEWERS, ON THE GROUND, OR INTO ANY BODY OF WATER. All
disposal practices must be in compliance with all Federal, State /Provincial and local laws and
regulations. Regulations may vary in different locations. Waste characterizations and compliance with
applicable laws are the responsibility solely of the waste generator. AS YOUR SUPPLIER, WE HAVE
NO CONTROL OVER THE MANAGEMENT PRACTICES OR MANUFACTURING PROCESSES OF
PARTIES HANDLING OR USING THIS MATERIAL. THE INFORMATION PRESENTED HERE
PERTAINS ONLY TO THE PRODUCT AS SHIPPED IN ITS INTENDED CONDITION AS
DESCRIBED IN MSDS SECTION: Composition Information. FOR UNUSED & UNCONTAMINATED
PRODUCT, the preferred options include sending to a licensed, permitted: Recycler. Reclaimer.
Incinerator or other thermal destruction device. Landfill.
14. Transport Information
DOT Non -Bulk
NOT REGULATED
DOT Bulk
NOT REGULATED
IMDG
NOT REGULATED
ICAO /IATA
NOT REGULATED
This information is not intended to convey all specific regulatory or operational
requirements /information relating to this product. Additional transportation system information can be
obtained through an authorized sales or customer service representative. It is the responsibility of the
transporting organization to follow all applicable laws, regulations and rules relating to the
transportation of the material.
115. Regulatory Information
OSHA Hazard Communication Standard
This product is a "Hazardous Chemical" as defined by the OSHA Hazard Communication Standard, 29
CFR 1910.1200.
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning
and Community Right- to-Know Act of 1986) Sections 311 and 312
Immediate (Acute) Health Hazard Yes
Delayed (Chronic) Health Hazard No
Fire Hazard No
Reactive Hazard No
Sudden Release of Pressure Hazard No
Superfund Amendments and Reauthorization Act of 1986 Title III (Emergency Planning and
Community Right -to -Know Act of 1986) Section 313
To the best of our knowledge, this product does not contain chemicals at levels which require reporting
under this statute.
Pennsylvania (Worker and Community Right -To -Know Act): Pennsylvania Hazardous
Substances List and /or Pennsylvania Environmental Hazardous Substance List:
Page 6 of 8
ORDER NO:DA465623 MATERIAL SAFETY DATA SHEET MSDS NO:DW04108
CUST:GT PRODUCTS VERSION:012 10/08/10
Product Name: METHOCEL` 40 -0101 Personal Care Grade Issue Date: 10/01/2010
Hydroxypropyl Methylcellulose
To the best of our knowledge, this product does not contain chemicals at levels which require reporting
under this statute.
Pennsylvania (Worker and Community Bight- To-Know Act): Pennsylvania Special Hazardous
Substances List:
To the best of our knowledge, this product does not contain chemicals at levels which require reporting
under this statute.
California Proposition 65 (Safe Drinking Water and Toxic Enforcement Act of 1986)
This product contains no listed substances known to the State of California to cause cancer, birth
defects or other reproductive harm, at levels which would require a warning under the statute.
US. Toxic Substances Control Act
All components of this product are on the TSCA Inventory or are exempt from TSCA Inventory
requirements under 40 CFFI 720.30
CEPA - Domestic Substances List (DSL)
All substances contained in this product are listed on the Canadian Domestic Substances List (DSL) or
are not required to be listed.
16. Other Information
Recommended Uses and Restrictions
Thickener. Binder. Film former. Processing aid. We recommend that you use this product in a
manner consistent with the listed use. If your intended use is not consistent with the stated use, please
contact your sales or technical service representative.
Revision
Identification Number: 79555 / 1001 / Issue Date 10/01/2010 / Version: 6.0
Most recent revision(s) are noted by the bold, double bars in left -hand margin throughout this
document.
Leaend
N/A
Not available
W/W
Weight/Weight
OEL
Occupational Exposure Limit
STEL
Short Term Exposure Limit
TWA
Time Weighted Average
ACGIH
American Conference of Governmental Industrial Hygienists, Inc.
DOW IHG
Dow Industrial Hygiene Guideline
WEEL
Workplace Environmental Exposure Level
HAZ_DES
Hazard Designation
Action Level
A value set by OSHA that is lower than the PEL which will trigger the need for
activities such as exposure monitoring and medical surveillance if exceeded.
The Dow Chemical Company urges each customer or recipient of this (M)SDS to study it carefully and
consult appropriate expertise, as necessary or appropriate, to become aware of and understand the
data contained in this (M)SDS and any hazards associated with the product. The information herein is
provided in good faith and believed to be accurate as of the effective date shown above. However, no
warranty, express or implied, is given. Regulatory requirements are subject to change and may differ
between various locations. It is the buyer's /user's responsibility to ensure that his activities comply with
all federal, state, provincial or local laws. The information presented here pertains only to the product
as shipped. Since conditions for use of the product are not under the control of the manufacturer, it is
file buyersiuser's duly to determine the conditions necessary fGr Llle Jale IJJe VI t hi0 prvUUU1. Due tv
the proliferation of sources for information such as manufacturer - specific (M)SDSs, we are not and
cannot be responsible for (M)SDSs obtained from any source other than ourselves. If you have
Page 7 of 8
MSDS NO:DW04108
IDER NO:DA465623 MATERIAL SAFETY DATA SHEET CUST.:GT PRODUCTS VERSION :012 10/08/10
product Name: METHOCEL* 40 -0101 Personal Care Grade
Issue Date: 10/01/2010
Hy drox roov, Meth Iceilulose
obtained an (M)SDS from another source or if you are not sure that the (M)SDS you have is current,
,.,,.,fact us for the most current version.
page 8 of 8
SIGMA- ALDRICH
sigma- a(drlch.
Material Safety Data ShE
Versior
Revision Date 12,1041:
Print Date 05/201,
1. PRODUCT AND COMPANY IDENTIFICATION
Product Number
Brand
Supplier
Telephone
Fax
Emergency Phone # (For
both supplier and
manufacturer)
Preparation Information
2. HAZARDS IDENTIFICATION
Emergency Overview
OSHA Hazards
Flammable liquid, Irritant
253006
Aldrich
Sigma- Aldrich
3050 Spruce Street
SAINT LOUIS MO 63103
USA
+1 800 - 325 -5832
+1 800 - 325 -5052
(314) 776 -6555
Sigma Aldrich Corporation
Product Safety - Americas Region
1- 800 -521 -8956
GHS Classification
Flammable liquids (Category 2)
Eye irritation (Category 2A)
GHS Label elements, including precautionary statements
Pictogram
Signal word
Hazard statement(s)
H225
H319
Precautionary statement(s)
P210
P305 + P351 + P338
HMIS Classification
Health hazard:
Flammability:
Physical hazards:
NFPA Rating
Health hazard:
Fire:
Reactivity Hazard
Potential Health Effects
Inhalation
g dri rh - 25 100FN
i
Danger
Highly flammable liquid and vapour.
Causes serious eye irritation.
Deep away from heat'sparks /open flames /hot surfaces. - No smoking.
IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses,
present and easy to do. Continue rinsing.
2
3
0
2
3
0
May be harmful if inhaled. Causes respiratory tract irritation.
PanP 1 r
Skin May be harmful if absorbed through skin. Causes skin irritation.
Eyes Causes eye irritation.
Ingestion May be harmful if swallowed.
3. COMPOSITIONIINFORMATION ON INGREDIENTS
Synonyms
Methyl trimethylsilyl ether
Trimethylmethoxysilane
Molecular Weight 104.22 g /mol
Comi)onent
I Concentration
)xytrimethylsilane
CAS -No.
EC-No.
FIRST AID MEASURES
1825 -61 -2
217 -369 -0
General advice
Consult a physician. Show this safety data sheet to the doctor in attendance.Move out of dangerous area.
If inhaled
If breathed in, move person into fresh air. If not breathing, give artificial respiration. Consult a physician.
In case of skin contact
Wash off with soap and plenty of water. Consult a physician.
In case of eye contact
Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician.
If swallowed
Do NOT induce vomiting. Never give anything by mouth to an unconscious person. Rinse mouth with water. Consult c
physician.
5. FIREFIGHTING MEASURES
Suitable extinguishing media
For small (incipient) fires, use media such as "alcohol" foam, dry chemical, or carbon dioxide. For large fires, apply we
from as far as possible. Use very large quantities (flooding) of water applied as a mist or spray; solid streams of water
may be ineffective. Cool all affected containers with flooding quantities of water.
Special protective equipment for firefighters
Wear self contained breathing apparatus for fire fighting if necessary
Hazardous combustion products
Hazardous decomposition products formed under fire conditions. - Carbon oxides, silicon oxides
Further information
Use water spray to cool unopened containers.
6. ACCIDENTAL RELEASE MEASURES
Personal precautions
Use personal protective equipment. Avoid breathing vapors, mist or gas. Ensure adequate ventilation. Remove all
sources of ignition. Evacuate personnel to safe areas, Beware of vapours accumulating to form explosive
concentrations. Vapours can accumulate in low areas.
Environmental precautions
Prevent further leakage or spillage if safe to do so. Do not let product enter drains.
Methods and materials for containment and cleaning up
Contain spillage, and then collect with an electrically protected vacuum cleaner or by wet - brushing and place in
container for disposal according to local regulations (see section 13).
7. HANDLING AND STORAGE
Alririeh - �`,.' >(inh panP 2 t
Precautions for safe handling
,ovoid contact with skin and eyes. Avoid inhalation of vapour or mist.
Use explosion -proof equipment. Keep away from sources of ignition - No smoking. Take measures to prevent the buil
up of electrostatic charge.
Conditions for safe storage
Store in cool place. Keep container tightly closed in a dry and well - ventilated place. Containers which are opened mus
be carefully resealed and kept upright to prevent leakage.
Moisture sensitive.
8. EXPOSURE CONTROLS/PERSONAL PROTECTION
Contains no substances with occupational exposure limitvalues.
Personal protective equipment
Respiratory protection
Where risk assessment shows air - purifying respirators are appropriate use a full -face respiratorwith multi - purpose
combination (US) or type AXBEK (EN 14387) respirator cartridges as a backup to engineering controls. If the
respirator is the sole means of protection, use a full -face supplied air respirator. Use respirators and components
tested and approved under appropriate government standards such as NIOSH (US)orCEN (EU).
Hand protection
Handle with gloves. Gloves must be inspected prior to use. Use proper glove removal technique (without touching
glove's outer surface) to avoid skin contact with this product. Dispose of contaminated gloves after use in
accordance with applicable laws and good laboratory practices. Wash and dry hands.
Eye protection
Face shield and safety glasses Use equipment for eye protection tested and approved under appropriate
government standards such as NIOSH (US) or EN 166(EU).
Skin and body protection
impervious clothing, Flame retardant antistatic protective clothing, The type of protective equipment must be
selected according to the concentration and amount of the dangerous substance at the specific workplace.
Hygiene measures
Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end
workday.
9. PHYSICAL AND CHEMICAL PROPERTIES
Appearance
Form
Colour
Safety data
pH
Melting
point/freezing point
Boiling point
Flash point
Ignition temperature
Auto - ignition
temperature
Louver explosion limit
Upper explosion limit
liquid
no data available
no data available
no data available
57 - 58 -C (135 -136 °F) -lit.
-20 °C (-4'F) - closed cup
no data available
no data available
no data available
no data available
Vapour pressure 101 h'Pa (76 mmHg) at 25 °C (77 °F)
Density 0.756 g /cm3 at 25 °C (77 °F)
Ndrieh - 25300 Pan� 3 r
Water solubility
Partition coefficient
n- octanollwater
Relative vapor
density
Odour
Odour Threshold
Evaporation rate
no data available
no data available
no data available
no data available
no data available
no data available
10. STABILITY AND REACTIVITY
Chemical stability
Stable under recommended storage conditions.
Possibility of hazardous reactions
Vapours may form explosive mixture with air.
Conditions to avoid
Heat, flames and sparks. Extremes of temperature and direct sunlight.
Materials to avoid
Strong oxidizing agents, Strong acids
Hazardous decomposition products
Hazardous decomposition products formed under fire conditions. - Carbon oxides, silicon oxides
Other decomposition products - no data available
11. TOXICOLOGICAL INFORMATION
Acute toxicity
Oral LD50
no data available
Inhalation LC50
no data available
Dermal LC50
no data available
Other information on acute toxicity
no data available
Skin corrosion /irritation
no data available
Serious eye damage /eye irritation
no data available
Respiratory or skin sensitization
no data available
Germ cell mutagenicity
no data available
Carcinogenicity
[ARC: No component of this product present at levels greater than or equal to 0.1% is identified as
�n,rnhahla �nnccihle nr confirmed human carcinogen by IARC.
ACGIH: No component of this product present at levels greater than or equal to 0.1 % is identified as a
carcinogen or potential carcinogen by ACGIH.
NTP: No component of this product present at levels greater than or equal to 0.1% is identified as a
known or anticipated carcinogen by NTP.
Al(irirh - 25300 Pang 4 c
OSHA: No component of this product present at levels greater than or equal to 0.1% is identified as a
carcinogen or potential carcinogen by OSHA.
Reproductive toxicity
no data available
Teratogenicity
no data available
Specific target organ toxicity - single exposure (Globally Harmonized System)
no data available
Specific target organ toxicity - repeated exposure (Globally Harmonized System)
no data available
Aspiration hazard
no data available
Potential health effects
Inhalation May be harmful if inhaled. Causes respiratory tract irritation.
Ingestion May be harmful if swallowed.
Skin Maybe harmful if absorbed through skin. Causes skin irritation.
Eyes Causes eye irritation.
Signs and Symptoms of Exposure
To the best of our knowledge, the chemical, physical, and toxicological properties have not been thoroughly investigat
Synergistic effects
no data available
Additional Information
RTECS: Not available
42. ECOLOGICAL INFORMATION
Toxicity
no data available
Persistence and degradability
no data available
Bioaccumulative potential
no data available
Mobility in soil
no data available
PBT and vPvB assessment
no data available
Other adverse effects
no data available
13. DISPOSAL CONSIDERATIONS
Product
Bum in a chemical incinerator equipped with an afterburner and scrubber but exert extra care in igniting as this materi
is highly flammable. Offer surplus and non - recyclable solutions to a licensed disposal company. Contact a licensed
professional waste disposal service to dispose of this material.
Contaminated packaging
Dispose of as unused product.
Raf3P. F t
Aldrich - 253006
14. TRANSPORT INFORMATION
DOT (US)
UN number: 1993 Class: 3 Packing group: II
Proper shipping name: Flammable liquids, n.o.s. (Methoxytrimethylsilane)
Marine Pollutant: No
Poison Inhalation Hazard: No
1MDG
UN number: 1993 Class: 3 Packing group: II EMS -No: F -E, S -E
ropershipping name: et oxytnme y si ane
Marine Pollutant: No
IATA
UN number: 1993 Class: 3 Packing group: II
Proper shipping name: Flammable liquid, n.o.s. (Methoxytrimethylsilane)
15. REGULATORY INFORMATION
OSHA Hazards
Flammable liquid, Irritant
SARA 302 Components
SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title Ill, Section 302.
SARA 313 Components
SARA 313: This material does not contain any chemical components with Known CAS numbers that exceed the thresl
(De Minimis) reporting levels established by SARA Title III, Section 313.
SARA 3111312 Hazards
Fire Hazard, Acute Health Hazard
Massachusetts Right To Know Components
No components are subject to the Massachusetts Right to Know Act.
Pennsylvania Right To Know Components
CAS -N o. Revision Date
Meth oxytdm ethylsilane 1825 -61 -2
New Jersey Right To Know Components
CAS -N o. Revision Date
Meth oxytrimethylsilane 1825 -61 -2
California Prop. 65 Components
This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other
reproductive harm.
16. OTHER INFORMATION
Further information
Copyright 2012 Sigma Aldrich Co. LLC. License granted to make unlimited paper copies for internal use only.
The above information is believed to be correct but does not purport to be all inclusive and shall be used only as a
guide. The information in this document is based on the present state of our knowledge and is applicable to the
product with regard to appropriate safety precautions. It does not represent any guarantee of the properties of the
product. Sigma - Aldrich Corporation and its Affiliates shall not be held liable for any damage resulting from handling or
from contact with the above product. See www.sigma- aldrich.com andlor the reverse side of invoice or packing slip fo
additional terms and conditions of sale.
Aldrich - 2510W Pane 6 r
Material Safety Data Sheet
PAGE 1
MSDSNO. 004
SECTION 1. CHEMICAL PRODUCT & COMPANY INFORMATION
PRODUCT NAME CHEMICAL NAME
SILBOND"' 40 Alkyl Silicate
SYNONYM
Alkyl silicate binding material
CAS# MIXTURE
PRODUCT USE
Binding agent
MANUFACTURERS NAME
Silbond Corporation
EMERGENCY CONTACT
Carl McLaughlin
EMERGENCY TELEPHONE #1
1- 517 - 436 -3171
ISSUE DATE
01/01/2007
CHEMICAL FORMULA
Mixture
CHEMICAL FAMILY
Alkyl Silicate
ADDRESS
9901 Sand Creek Highway
Weston. MI 49289
COUNTRY
USA
EMERGENCY TELEPHONE #2
CHEMTREC USA 1- 8001324 -9300
OUTSIDE USA 703 -527 -3887
SECTION 2 COMPOSITION /INFORMATION ON INGREDIENTS
SUBSTANCE DESCRIPTION PERCENT CAS#
Ethyl Silicate - 20.000 78 -10-4
Ethanol <3.000 64 -17 -5
Ethyl Polysilicates - 77.000 11099 -06 -2
SECTION 3. HAZARDS IDENTIFICATION
APPEARANCE a ODOR
Clear liquid with a sweet odor.
STATEMENT OF HAZARDS
WARNING!
FLAMMABLE LIQUID AND VAPOR
KEEP AWAY FROM HEAT SPARKS AND FLAME
KEEP CONTAINER CLOSED
USE ADEQUATE VENTILATION
FIRE AND EXPLOSION HAZARDS
This product is a flammable liquid. Vapors are heavierthan air and may travel to a source of ignition and
flash back. Vapor mixtures are explosive above the flash point. Drums have nylon closures and should
vent during fires.
Cyrncfa-
a,
.. f .. ._.• r•.i V" .' �•
Sllbond Corporation • 9991 Sand Creek Highway • P.O. Box:' • Weston, Mi 49289 • (517)436 -3171 • silbond@sllbond.com
NbtLi d SafetN, Jkm Sheet
DATE PRINTED aj912607
SILSOND 40
PRIMARY ROUTE OF EXPOSURE
Skin contact and inhalation are the principal routes of exposure to this product
INHALATIONACUTE EXPOSURE EFFECTS
Inhalation of vapor may irritatethe respiratory tract and may cause central nervous system depression
with dizziness, headache, or confusion.
SKIN CONTACT ACUTE EXPOSURE EFFECTS
Skin contact is not expected to cause irritation.
EYE CONTACTACUTE EXPOSURE EFFECTS
Eye contact is not expected to cause irritation.
INGESTIONACUTE EXPOSURE EFFECTS
This pt cxluct has a low order of toxicity. No significant toxic effects are expected
NFPA HEALTH RATING
I
NFPA FLAMMABILITY RATING
3
NFPA REACTIVITY RATING
0
NFPA OTHER
NFL
SECTION4. FIRST AID MEASURES
INHALATION
Remove to fresh air. If breathing becomes difficult. oxygen maybe given; preferably with a physician's
advice. If not breathing, give artificial respiration Get medical attention.
SKIN CONTACT
Remove contaminated clothing and equipment. Wash all affected areas with plenty of soap and water.
Do not attemptto neutralizewith chemical agents. Wash any contaminated clothing and shoes before
reuse. Obtain medicaladvice if irritation occurs.
EYE CONTACT
Flush eyeswith large quantities of ninningwaterfor a minimum of 15 minutes. If the victim iswearing
contact lenses. removethem. Holdthe eyelids apart during flushing to ensure rinsing of the entire surface
of the eye and lids with water. DO NOT let victim rub eye(s). Do not attempt
to neutralizewith chemical agents. Oils or ointments should not be used at this time. Get medical
attention, if eye irritation occurs.
INGESTION
Give several glasses of water. DO NOT induce vomiting. If vomiting occurs keep head below hips to
reduce risk of aspiration. Give fluids again. Seek medical attention if health effects occur. Never give
anything by mouth to a person who is unconscious or convulsing. If victim is unconscious, monitor pulse.
breathing, and airway. If breathing stops, begin artificial respiration immediately. If the heart has stopped,
give cardiopulmonary resuscitation (CPR). Get medicalattentionimmediately.
Material Safety Data Sheet
DATE PRINTED 319;2007 PAGE t
SILSOND 40 MSDS NO. 004
I SECTION 4. FIRST AID MEASURES (Continued)
MEDICAL CONDITIONS AGGRAVATED
Personswith preexisting kidney or liver disease may be at an increased risk from exposure to this
material.
NOTETO PHYSICIAN
No specific antidote is known. Based on the individual reactions of the patient, the physician'sjudgment
should be used to control symptoms and clinical conditions.
{ SECTION 5. FIREFIGHTING MEASURES 1
FLASH POINT
81.00 OF 27.22 °C
FLASH METHOD
Tagliabue Closed Cup
AUTO IGNITION TEMPERATURE
685.00 OF 362.77 °C (for ethyl alcohol)
UPPER EXPLOSION LIMIT
19% (For ethyl alcohol)
LOWER EXPLOSION LIMIT
3.3 % (For ethyl alcohol)
EXTINGUISHING METHOD
Usewater dry chemical powder. "alcohol resistant' foam or carbon dioxide extinguishing agents.
FIRE FIGHTING PROCEDURES
As in any fire, prevent human exposure to fire, smoke. fumes or products of combustion. Only properly
trained personnel should be involved in firefighting. Evacuate nonessential personnel from the fire area.
Firefightersshould wear full- face.. self- contained breathing apparatus and impervious protective clothing.
D' possible, move containers from the fire area. High pressurewater may spread productfrom broken
containers increasing contamination of fire hazard. Dike fire water for later disposal. Do not allow
contaminated water to enter waterways.
FIREAND EXPLOSION HAZARDS
This product is a volatile. flammable liquid. Vapors may travel to a source of ignition and flash back.
OTHER FIRE AND EXPLOSION HAZARDS
Decomposes under fire conditionsto give off oxides or silicon and carbon.
HAZARDOUS PRODUCTSICOMBUSTION
Oxides of silicon and carbon may be produced by the combustion of this product.
SECTION 6. ACCIDENTAL RELEASE MEASURES
CLEAN -UP
A comprehensive spill response plan should be developed. If material is spilled, all ignition sources in the
area should be extinguished and the leak stopped at the source. For large spills dike ahead of spill to
contain. For small spllis. absorb with sand, clay or ether Inert absorbent. Place Inc nt Inersfor
o a disposal.
Personnel involved in spill control and cleanup should follow the recommended exposure controls in
SECTION 8 of this MSDS. . %I] non- essential personnel should be evacuated from the immediatespill
area
Material Safety Data Sheet
LATE PRINTED 3194007 PAGE 4
SILBOND40 MSDS NO. 004
SECS .. ..., ,{ ......
WASTE DISPOSAL
The characteristic of ignitability per RCRAcuuiu apply w u lc Ur IU�u product if ii wecornes a waste
material. The EPA hazardous waste number D001 could apply. It is the responsibility of the waste
generatorto evaluate whether his wastes are hazardous by characteristics or listing.
CONTAINER DISPOSAL
Containers should be cleaned of residual product before disposal Empty containers should be disposed
of in ac-cr,1ance with all applicable laws and regulations.
SECTION 7. HANDLINGISTORAGEi TRANSPORTATION
HANDLING
Electrically groundedtanks and containers should always be used as should non - sparking, electrically
grounded hand tools and appliances. Ground or bond to ground all vessels when transferring to prevent
the accurnulation of static electricity. See National Electric Code.
STORAGE
Because the product is a flammable liquid. storage should meet the requirement of 29 CFR 1910.106.
Flammableand Combustible Liquids Code. Store in a cool, dry; well - ventilated area away from sources of
heat, ignition. direct sunlight. oxidizers and alkalis. Keep container closed when not in use. Remove
closures carefully, internal pressure may be present
MAXIMUM STORAGE TEMPERATURE
Store below flashpoint if possible
SECTION 8. EXPOSURE CONTROLS /PERSONAL PROTECTION
GENERAL COMMENTS
This product may be slightly acidic and may attack certain plastics and corrode carbon steel over
extended periods of time.
RESPIRATORY PROTECTION
Use NIOSH - approved organic vapor respiratorswith dust, mist and fume filters to reduce potentialfor
inhalation exposure if use conditions generate vapor, rnist or aerosol and adequate ventilation (e.g.
outdoor or well ventilated area) is not available. Where exposure potential necessitates a higher level of
protection, use a NIOSH - approved: positive - pressure /pressure - demand, air - supplied respirator. When
using respirator cartridges or canisters, they must be changed frequently ( following each use or at the
end of the workshift ) to assure breakthrough exposure does not occur.
SKIN PROTECTION
Skin contactwith liquid or its aerosol should be prevented through the use of suitable protective clothing,
gloves and footwear selected with regard for use condition exposure potential. Viton® gloves and boots
are not recommended.
EYE PROTECTION
If the possibility of splashing or spraying of this material exists chemical goggles and /or a full face shield
should be worn.
VENTILATION PROTECTION
Local exhaust ventilation, enclosed system design. continuous monitoring devices, process isolation and
remote control are traditional exposure control techniques which may be used to effectively minimize
employee exposure.
Material Safety Data Sheet
DATE PRINTED 3!912007 PAGE 5
SIL80ND 40 MSDS NO. 00.4
SECTION 8. EXPOSURE CONTROILS!PE OVAL PRO E;,TION (Continued, �
OTHER PROTECTION
All food and smoking materials should be kept in a separate area away from the storageluse location.
Eating, drinking and smoking should be prohibited in areas where there is a potential for exposure to this
material. Before eating, drinking or smoking, hands and face should be thoroughly washed.
APPLICABLE EXPOSURE LIMITS
Other than any exposure limits which may be displayed in Section 15, there are no other known exposure
limits applicable for this product or its components.
VAPOR PRESSURE (mm Hg)
21
@ 50 °F 10"C
EVAPORATION RATE
N!0
BOILING POINT
172 OF 78 °C
(at 760 mm Hg)
SPECIFIC GRAVITY
1.06
@ 68 OF 20 °C
SOLUBILITY IN WATER
Hydrolyzes in water
COEFFICIENTOF OILM/ATER
NID
MELTING POINT
-130 OF -90 nC
CLOUD POINT
NID
VAPOR DENSITY (Air = 1.0)
NID
VOLATILE %
-34 (ASTM D- 2369 -93)
ODOR THRESHOLD (ppm)
AP 85
ppm (ethanol& ethyl silicate)
BULK DENSITY
NID
S0LUBILITY IN OTHER SOLVENTS
Misciblewith organic solvents
POUR POINT
N/D F NIDC
PH FACTOR
NID
OTHER
Viscosity 5.0 -6.5 @ 68 OF 20 °C
SECTION10. STABILITY AND REACTMTY
STABILITY
This product is stable at ambienttemperatures and atmospheric pressures. It is not self- reactive and is
not sensitiveto physical impact
INCOMPATIBILITIES
This product hydrolyzes slowly and nonviolently under moist alkaline or acidic conditions at ambient
temperatures and atmospheric pressuresto form silicon dioxide and ethanol. It reacts with oxidizing
agents such as nitrates and hypochlorites. The product may attack certain plastics and corrode carbon
steel over extended periods d time.
POLYMERIZATION
Hazardous polynnerization is not expected to occur.
Material Safety Data Sheet
DATE PRINTED 3/9/2007 PAGE 6
SILBOND 40 MSDS NO. 004
- -
SECTION % STABILITY AND REACTIVITY (continued) 1
DECOMPOSITION
Thermal decomposition products include oxides of carbon and silicon.
CONDITIONS TO AVOID
Underwet alkaline or acidic conditions, prolonged storage at elevated temperatures should be avoided to
assure product integrity.Store away from foodstuffs, animalfeed and incompatibles such as oxidizers,
acids and alkalis.
SECTION 11. TOXICOLOGICAL.. INFORMATION
INHALATION EFFECTS
The acute inhalation LC50 is greater than 4.8 mg /L in both male and female rats. A single4 -hour
inhalation exposure of 4.8 mg /L (greaterthan 95 percent respirable) produced a 4 to 7 percent decrease
in body weights in male and female rats. No mortality was observed.
INHALATION CHRONIC EXPOSURE EFFECTS
Prolonged and/or repeated inhalation may cause severe respiratory irritation, pulmonary edema and
possible kidney and liver damage.
DERMAL EFFECTS
The acute dermal LD50 is greater than 1000 mg/kg in rabbits. A single dermal application of 4640 mg/kg
did not produce signs of toxicity in rabbits. Local effects included mild edema.
This product was non - irritating to rabbit skin following a 4 -hr. exposure.
SKIN CONTACT CHRONIC EXPOSURE EFFECTS
Chronic dermal exposure effects for this product are not known.
EYE EFFECTS
This product did not produce irritationwhen tested in rabbits eyes.
EYE CONTACT CHRONIC EXPOSURE EFFECTS
Chronic eye exposure effects for this product are not known.
INGESTION EFFECTS
The oral LD50for this material is >5000 mg/kg in rats. A single oral dose of 5000 mglkg did not produce
signs of toxicity in male rats.
INGESTION CHRONIC EXPOSURE EFFECTS
Health effects as a result of chronic ingestion are not known.
CARCINOGENICITYIMUTAGENICITY
Neitherthis product nor its components have been classified as a carcinogen by [ARC, NTP, OSHA, or
ACGIH.
REPRODUCTIVE EFFECTS
The reproductive toxicity of this product is not known. Reproductive toxicity of the components of this
product are as follows:
ETHYLALCOHOL
Ethyl alcohol has been shown to affect male fertility. It is not clear from the literature if
exposures which are solely occupational and clearly within the exposure limits are
sufficient to be a reproductive risk.
Material Safety Data Sheet
DATE PRINTED 3/912007 PAGE 7
SILSOND 40 MSDS NO. 004
I SECTION 11. a'OKCOLOGICAL INFORMATION (Continued) I
NEUROTOXICITY
The neu rotoxic effects of this product are not known.
OTHER EFFECTS
No other toxic effects for this product are known.
TARGET ORGANS
Overexposure to this product may affect the skin and respiratory system. Overexposure to ethyl silicate
may cause damage to the liver, kidneys and cause anemia.
SECTION 12. ECOLOGICAL INFORMATION
ECOLOGICALTOXICITY
The ecological toxicity of this product is not known. However, the following data exists for ethanol:
Toxicity threshold (cell multiplication inhibition test)
Bacteria (psuedomonas putida) 6500 mg /L
Algae (Microcystis aeruginosa) 1450mg/L
Green Algae (Scenedesmusquadricauda) 500 mg /L
Protozoa (Entosiphonsulcatum) 65 mg/L
Ptotozoa (Uronema parduczi Chatton- Lwoff) 6120 mg/L
Fingerling Trout: 24 hr LC5011,200 mg/L
Guppies (Poecilia reticulata) L050: (7 days): 11,050 ppm
Creek chub (Semotilusatromaculatus); 24 hr. LC50 >7000 mg /L
OTHER ECOLOGICAL INFORMATION
NID
CHEMICAL FATE INFORMATION
This product hydrolyzes slowly in wet alkaline or acidic conditionsto silicon dioxide and ethanol
OTHER REGULATORY INFORMATION
No other regulatory information is availableon this product.
SECTION 13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL
The characteristic of Ignitability per RCRA could apply to the unused product if it becomes a waste
material. The EPA hazardouswaste number D001 could apply. It is the responsibility of the waste
generatorto evaluate whether his wastes are hazardous by characteristics or listing.
CONTAINER DISPOSAL
Containers should be cleaned of residual product before disposal. Empty containers should be disposed
of in accordancewith all applicable laws and regulations.
I SECTION 14. TRANSPORT INFORMATION
SHIPPING DESCRIPTION
Flammable liquid, n.o,s. (contains ethyl silicate and ethyl alcohol)
Class 3, UN 1993, PG III
US DOT EMERGENCY 1993GUIDE NO. 27
NAERG GUIDE NO. 128
Material Safety Data Sheet
DATE PRINTED: 3/912007 PAGE S
SILBOND40 MSDS NO. CM
SECTION 14. TRANSPORT INFORMATION (continued)
REQUIRED LABEL(S)
Flammable liquid
ENVIRONMENTAL HAZARDOUS SUBSTANCE
This product does not contain an environmentally hazardous substance nor marine pollutant per 49 C F R
172.101 Appendix.
SECTIONIS, REGULATORY INFORMATION
Clean Air A d Sac1-.111
CAA 112
EXPOSURE
LIMITS/REGULATORY INFORMATION
CERCLA Hazardous Substances
DSL
Domestic Substance List - Canada
(IN MG /M3)
[ARC Carcinogens -Gres, 1,2A,2B
MA LIST
Massachusetts Substance List
NDSL
SUBSTANCE DESCRIPTION REG. AGCY
PEL
TLV
TWA
STEL
CEIL
Ethyl Silicate
OSHA
850
N/D
n
N/D
NID
MITI
ACGIH
Nn
85
w
N/D
Nm
NIOSH
N/D
N/D
85
Nn
N!D
SUPPLIER
NID
N/D
Nn
Nn
N/D
LISTED ON THE FOLLOWING
DSL MA LIST NJ R -T -K
PA UST
TSCA
MITI 2.2448
Ethanol
OSHA
1900
Nm
NID
NID
N/D
ACGIH
NID
1880
Nn
Nn
N/D
NIOSH
Nn
NID
1900
NID
N/D
SUPPLIER
Nn
N/D
N/D
NID
N/D
LISTED ON I'llE FOLLOWING
DSL MA. LIST NJ R -T-K
PA LIST
TSCA
CAA 111 MITI 2 -202
Ethyl Polysilicates
OSHA
Nn
Nn
NID
N/D
N/D
ACGIH
NID
Nrn
NID
N/D
Nn
NIOSH
Nn
Nn
N/D
N/D
N/D
SUPPLIER
N/D
NID
Nn
NID
N/D
LISTED CNTHE FOLLOWING.
DSL PA LIST TSCA MITI 7-48a
LEGEND
EXPOSURE LIMIT DESCRIPTIONS
CEIL
Ceiling Exposure Limit
PEL
Permissible Exposure Limit
STEL
Shor,, Term Exposure Limit
TLV
Threshold Limit Value
TWA
Time Weighted Average
REGULATORY LIST DESCRIPTIONS
CAA 111
Clean Air A d Sac1-.111
CAA 112
CleanAirA d Sed. 112
CERCLA
CERCLA Hazardous Substances
DSL
Domestic Substance List - Canada
IARC
[ARC Carcinogens -Gres, 1,2A,2B
MA LIST
Massachusetts Substance List
NDSL
Non - Domestic Subst. List - Canada
NJ R -T -K
New Jersey R -T -K Hazard. Sub.
PA. LIST
Penn. Hazardous Substance List
PROP65
California PropositionM
SARA 302
SARA Title fl] , Section 302
SARA313
SARA Title H1 , Section 313
TSCA
Toxic Subst. Cont. Act - listed
MITI
Japanese MITI list
N!D
Not Determined
Material Safety Data Sheet
DATE PRINTED: 31912007 PAGE 9
SILBOND 40 MSDS NO. 004
SECTION 16. OTHER INFORMATION
GENERAL
CREATED BY REVISION NO.
Product She odship Group
OTHER INFORMATION
No other information is available
WHMIS HAZARD CLASS B -2, D2B
HAZARD RATINGSOURCE HMIS
HEALTH 0 FLAMMABILITY
REACTMTY 0 OTHER
REVISION CHANGE(S):
1. Review
11Am
Silbond
Material Safety Data Sheet
PAGE 1
MSDS NO. 002
SECTION 1. PRODUCT INFORMATION
PRODUCT NAME
SILBOND '' PURE
SYNONYM
Silicic acid, tetraethyl ester, Tetraethyl orthosilicate
CAS # 78 -10-4
PRODUCT USE
High Purity TEOS
MANUFACTURERS NAME
Silbond Corporation
EMERGENCYCONTACT
Carl McLaughlin.
EMERGENCY TELEPHONE #1
1- 517 - 436 -3171
ISSUE DATE
01/0112007
CHEMICAL NAME
Tetraethyl Orthosilicate
CHEMICAL FORMULA
Si (OC2H5)4
CHEMICAL FAMILY
Alkyl Silicate
ADDRESS
9901 Sand Creek Highway
Weston, MI 49289
COUNTRY
U.S.A.
EMERGENCY TELEPHONE #2
CHEMTREC USA 1- 800 - 424 -9300
OUTSIDE USA 703 -527 -3887
>; i`ION 2. COMF " - ONIIN FORMATION ON
SUBSTANCE DESCRIPTION PERCENT C =. , 11
Tetraethyl Orthosilicate - 100.UU0 18 -10-4
SECTION 3. HAZARDS IDENTIFICATION
APPEARANCE 8 ODOR
Clear liquid with a sweet odor.
STATEMENT OF HAZARDS
CAUTION!
COMBUSTIBLE LIQUID AND VAPOR
KEEPAWAY FROM HEATAND FLAME
KEEP CONTAINER CLOSED
USE ADEQUATE VENTILATION
FIRE AND EXPLOSION HAZARDS
This product is a combustible liquid. Vapors are heavierthan air and may travelto a source of ignition and
flash back. Vapor mixtures are explosive above the flash point. Drums have nylon closures and should vent
during fires..
,..o,r -3; - - •r,� -. a.! v ae,t c t ...;ana.•o.a ar-1 se
_ a ^. 4_ trea,.c -acya - -7: Gfs,cr #c,ma; ca i
Silbond Corporation • 9901 Sand Creek Highway • P.O. Box 200 • Weston. M1 49289 • (51 7) 436-3171 • silbond @silbond.com
Material Safety
DATE PRINTED 511012007
SILBONDe PURE NISDS NO.
SECTION_ 3. HAZARDS IDENTIFICATION (CONTINUEL
PRIMARY ROUTE OF EXPOSURE
Skin contact and inhalationare the principal routes of exposure to this product.
INHALATION ACUTE EXPOSURE EFFECTS
Inhalation of vapor may irritate the respiratory tract and may cause central nervous system depression with
dizziness, headache. or confusion.
SKIN CONTACT ACUTE EXPOSURE EFFECTS
Prolonged or repeated contact may cause moderate irritation.
EYECONTACTACUTEEXPOSUREEFFECTS
Prolonged or repeated exposure may cause irritation. By testing was a non irritant to rabbit eyes.
INGESTION ACUTE EXPOSURE EFFECTS
Irritationto the mouth. throat, esophagus and stomach may be caused by ingestion of this material.
NFPA HEALTH RATING
2
NFPA FLAMMABILITY RATING
2
NFPA REACTIVITY RATING
0
NFPA OTHER
NA
SECTION 4. FIRST AID MEASURES I
INHALATION
Removeto fresh air If breathing becomes difficult. oxygen may be given. preferably with a physicians advice
if not breathing. give artificial respiration. Get medical attention.
SKIN CONTACT
Remove contaminated clothing and equipment Wash all affected areas with plenty of soap and water for at
least 15 minutes. Do not attempt to neutralize with chemical agents. Wash any contaminated clothing and
shoes before reuse. Obtain medical advice if irritation occurs.
EYE CONTACT
rlush eyes with large quantities of running water for a minimum of 15 minutes. If the victim is wearing contact
lenses. remove them. Hold the eyelids apart during flushing to ensure rinsing of the entire surface of the eye
and lidsMh water. DO NOT let victim rub eye(s) Do not attempt to neutralizewith chemical agents. Oils or
ointments should not be used at this time. Get medical attention if eye irritation occurs.
INGESTION
If swallowed. do not induce vomiting. Give several glasses of water Never give anything by mouth to a person
who is unconscious or convulsing. If victim is unconscious. monitor pulse, breathing, and airway. If breathing
stops.. begin artificial respiration immediately. If the heart has stopped, give cardiopulmonary resuscitation
(CPR). Get medical attention immediately.
MEDICAL CONDITIONS AGGRAVATED
Medical conditions that are generally recognized and being aggravated by exposure to this product include
asthma and inflammatory or fibrotic pulmonary diseases. Persons with preexisting skin. liver, kidney. blood
and/or chronic respiratory disease are at increased risk if exposed to this material.
Material Safety Data Sheet
DATE PRINTED &10/2007 Material
3
SILSONM PURE NISIIS NO. 002
NOTETO PHYSICIAN
No gsak antidote is known. Based on the individual reactions of the patient, the physician'sjudgment
should be used to control symptoms and clinical conditions.
SECTION 5. FIRE FIGHTING MEASURES
FLASH POINT
105.0 °F 40.6 °C
FLASH METHOD
Tag Closed Cup
AUTO IGNITION TEMPERATURE
NID F N/D C
UPPER EXPLOSION LIMIT
NID
LOWER EXPLOSION LIMIT
NID
EXTINGUISHING METHOD
Use water fog, dry powder, foam or carbon dioxide extinguishing agents
FIRE FIGHTING PROCEDURES
As in any fire, prevent human exposure to fire. smoke, fumes or products of combustion. Evacuate non-
essential personnel from the fire area. Firefighters should wear full -face. self- contained breathing apparatus
and impervious protective clothing. II possible. move containers from the fire area. High - pressure water may
spread product from broken containers increasing contamination of fire hazard. Dike fire water for later
disposal. Do not allow contaminated water to enter waterways.
FIRE AND EXPLOSION HAZARDS
This product is a combustible liquid. Vapors are heavier than air and may travel to a source of ignition and
flashback. Vapor -air mixtures are explosive above the flash point. Containers have nylon closures and should
vent during fires.
OTHER FIRE AND EXPLOSION HAZARDS
Decomposesunder fire conditionsto give off oxides of silicon and carbon.
HAZARDOUS PRODUCTS /COMBUSTION
Oxides of silicon and carbon may be produced by the combustion of this product.
SECTION 6. ACCIDENTAL RELEASE MEASURES
CLEAN -UP
If material is spilled, all ignition sources in the area should be extinguished and the leak stopped at the source.
For large spills dike ahead of spill to contain. For small spills. absorb with sand. clay or other inert absorbent
Place in containersfor disposal. Personnel involved in spill control and cleanup should lbllo%� the
recommended exposure controls in SECTION 8 of this MSDS. All non - essential personnel should be
evacuated from the immediate spill area.
a ' c
-ria Safe-,y Lja.ta Shoc�
I !ON 8, �-�Xt--OS��,�RE�'-"(i.NTROLSs'PE-.RSONAiL I
(")TFIER PROTElICTION
I-
sninc ng s d
E I-, (Jo --I k,nq or Sn 'k ng ids
F-XP'.'SURF L-NOITS
I ; 4? ma j 1
, . J
lcf -,
-nm H(o
@68 °F
cF
@ 68 LF
`F
cF
Material Safety Data Sheet
DATE PRINTED: &!10!2007 PAGE 7
SILSOND6 PURE MSDSNO. 002
SECTION 11. TOXICOLOGICAL INFORMATION (Continued)
OTHER EFFECTS
No other toxic effects for this product are known.
TARGET ORGANS
Overexposure to this product may affect the skin and respiratory system. Overexposure to ethyl silicate may
cause damage to the her, kidneys and cause anemia.
SECTION 12. ECOLOGICAL INFORMATION
ECOLOGICAL TOXICITY
The ecological toxicity of this product is not known.
OTHER ECOLOGICAL INFORMATION
Other ecological information on this product is not known
CHEMICAL FATE INFORMATION
This product hydrolyzes slowly in wet alkaline or acidic conditions to silicon oxides and ethanol.
OTHER REGULATORY INFORMATION
No other regulatory information is available on this product.
SECTION 13. DISPOSAL CONSIDERATIONS
WASTE DISPOSAL
The characteristic of Ignitability per RCRA could apply to the unused product if it becomes a waste material.
The EPA hazardous waste number D001 could apply. It is the responsibility of the waste generator to evaluate
whether his wastes are hazardous by characteristics or listing.
CONTAINER DISPOSAL
Containers should be cleaned of residual product before disposal. Empty containers should be disposed of in
accordancewith all applicable laws and regulations. No burning or welding should be done on empty
containers.
SECTION 14. TRANSPORT INFORMATION
SHIPPING DESCRIPTION
FOR US(BULK):
Combustible Liquid. n.o.s. (Tetra ethyl silicate)
Combustible Liquid, NA 1993, PG III
DOT EMERGENCY GUIDE NO. 27
NAERG GUIDE NO 128
(unregulated in non -bulk containers)
FOR INTERNATIONAL:
Tetra ethyl silicate
class 3, packing group III
UN 1292
REQUIRED LABEL(S)
Combustible liquid ( Bulk U.S.;
Flammable Liquid (International)
ENVIRONMENTALLY HAZARDOUS SUBSTANCE OR MARINE POLLUTANT
This product does not contain an environmentally hazardous substance or marine pollutant per 49 CFR
172.101 Appendix A & B.
Material Safety Data Sheet
DATE PRINTED 510!2007 PAGE 8
SILBOND,S PURE MSDSNO 002
I SECTION 15. REGULATORY INFORMATION
EXPOSURE LIMITS/REGULATORY INFORMATION
(IN MG11l
SUBSTANCE DESCRIPTION REG. AGCY
PEL
TLV
TWA
STEL
CEIL
Tetraethyl Orthosilicate OSHA
850
N/D
N/D
N/D
N/D
ACGIH
Nin
85
N/D
N/D
N/D
NIOSH
N/D
NM
85
N/D
N/D
SUPPLIER
Nrt
N/D
WD
N m
LISTEDON THE FOLLOWING MA LIST NJ R -TK
PA LIST TSCA
M T 2.2= -412
LEGEND
EXPOSURE LIMIT DESCRIPTIONS
wEIL
Ceiling Exposure Limit
PEL
Pe-m,ss u!e Eywsure Limit
S7-EL
Short Term Exposure Limit
V
Threshold Lim ; Value
MA LIST
Tirne Weighted Average
REGULATORY LIST DESCRIPTIONS
CAA 112
Clean Air Ad Sect 112
C 6= -41
CERCLA Hazardous S.,: s:an czs
DSL
Domestic Substance "t-Cana-.a
LARC
ARC Carcinogens -Gres. 1,2A,2B
MA LIST
Massaa-use ",s Substance List
NDSL
Non- DomesticSuGS: L.st- Canaca
NJ R -TK
New Jersey R -T -K Hazard Sub
PA LIST
Pe-- Hazardous SubstanceL ;st
PROP65
',^Iornia Proposition 65
SARA 302
" 7t+e 1I1 , Section 302
SARA 3
SARA Tit':e Ill, Section 3, 2
TSCA
at Cont. A-- - listed
MITI
L'S'
(.,LA I Lu B'Y
Product StewardshipGrot.Il_
OTHER INFORMATION
No other informationis avaiiaL
WHMIS HAZARDCLASS
HAZARD RATING SOURCE:
HEALTH
REACTMTY C,
REVISIONCHANGE(S):
1. Review
mcvi l N Nu. 004
R -3
= €t
FLAMMABILITY
OTHER
TNBT
C17 MA, Titanates
MATERIAL SAFETY DATA SHEET
MSDS
1. Identification
Product : Tytan TNBT Chemical Family: Titanium Alkoxide
Address : Borica Co., Ltd. Structure:
6F, No. 158, Xin Sheng S. Rd.,
Sec. 1, Taipei 10061, Taiwan
Emergency : +886 -2- 2358 -2958 (ASIA/USA)
Phone No. +32 89 46 42 94 (ELTROPE)
Synonyms : Titanium tetrabutanolate
Formula : Ti (OC4H9) 4
EC No : 227 -006 -8
2. Hazard Identification
Hazard Symbol
Xi
Descriptive
Flammable
Irritating to skin.
Risk of serious damage to eyes.
CH3(CH2)3O
Ti.. "''�n
CH3(CH2)30/ O(CH2)3CH3
O(CH2)3CH3
This data sheet is based on a consideration of the properties of
the constituents.
3. Composition / Ineredients
Chemical Name
CAS No
Percent
Symbol; R Phrases
composition
Tetra n -butyl titanate
5593 -70 -4
>98
Xi; R10, 38, 41
I- Butanol
71 -36 -3
<2
Xn; R10, 22, 37/38, 41,
67
REACH Pre-registration No.: 17- 2119420728 -37 -0000
4. First Aid
Eye contact Immediately irrigate with eyewash solution or clean water, holding
the eyelids apart, for at least 10 minutes.
A qualified medical person must only attempt removal of any
precipitated solids from the eye.
Medical Treat symptomatically and supportively
Version 2.2 Product: Tytan TNBT
Revision Date 2011 -03 -15 Page 1 of 5
TN BT
MSDS
5. Fire Fighting
Flammable.
Keep fire exposed containers cool by spraying with water.
Extinguishing Media : Alcohol- resistant foam. Do not use water jet.
Fire Fighting Protective : A self - contained breathing apparatus and full protective
Equipment clothing must be worn in fire conditions.
6. Accidental Release
Eliminate sources of ignition. Evacuate the area. Provided it is safe to do so, isolate the
source of the leak. Ensure suitable personal protection (including respiratory protection)
during removal of spillages. Do not allow product to enter drains, sewers or watercourses.
Contain spillages with sand, earth or any suitable adsorbent material. Transfer to a lidded
container for disposal. Wash the spillage area with water.
7. Handling and Storage
Handling Do not breathe vapour.
Avoid contact with skin and eyes.
Provide adequate ventilation.
All electrical equipment must be adequately flame proofed.
When using does not eat, drink or smoke.
Weigh out/use in dry atmosphere.
Wash hands and exposed skin after use.
Storage Keep away- from sources of ignition — No Smoking.
Avoid ingress of moisture by keeping containers properly sealed
when not in use.
Storage tem erp ature — Keep only in original container at
temperatures not exceeding 40 deg C.
Storage life — 2 years (in the original uno ened sales container).
Version 2.2 Product: Tytan TNBT
Revision Date 2011 -03 -15 Page 2 of 5
Skin Contact Immediately wash the affected area with soap and water using a
brush to remove any precipitated solids. Seek medical attention if
irritation occurs.
Medical Treat symptomatically and supportively
Ingestion Providing person is conscious wash out mouth with plenty of water
and give plenty of water to drink, do not induce vomiting. Seek
medical attention.
Medical Treat symptomatically and supportively
Inhalation Remove from exposure.
If breathing is difficult give oxygen, if breathing stops or shows
signs of failing give artificial respiration. Do not use mouth -to-
mouth method. Seek medical attention.
Medical Treat symptomatically and supportively
5. Fire Fighting
Flammable.
Keep fire exposed containers cool by spraying with water.
Extinguishing Media : Alcohol- resistant foam. Do not use water jet.
Fire Fighting Protective : A self - contained breathing apparatus and full protective
Equipment clothing must be worn in fire conditions.
6. Accidental Release
Eliminate sources of ignition. Evacuate the area. Provided it is safe to do so, isolate the
source of the leak. Ensure suitable personal protection (including respiratory protection)
during removal of spillages. Do not allow product to enter drains, sewers or watercourses.
Contain spillages with sand, earth or any suitable adsorbent material. Transfer to a lidded
container for disposal. Wash the spillage area with water.
7. Handling and Storage
Handling Do not breathe vapour.
Avoid contact with skin and eyes.
Provide adequate ventilation.
All electrical equipment must be adequately flame proofed.
When using does not eat, drink or smoke.
Weigh out/use in dry atmosphere.
Wash hands and exposed skin after use.
Storage Keep away- from sources of ignition — No Smoking.
Avoid ingress of moisture by keeping containers properly sealed
when not in use.
Storage tem erp ature — Keep only in original container at
temperatures not exceeding 40 deg C.
Storage life — 2 years (in the original uno ened sales container).
Version 2.2 Product: Tytan TNBT
Revision Date 2011 -03 -15 Page 2 of 5
TN BT
MSDS
8. Exposure / Personal Protection
Suitable respiratory equipment with positive air supply should be used in cases of insufficient
ventilation or where operational procedures demand it.
Wear suitable protective clothing, gloves and eye /face protection. PVC gloves and goggles
are recommended.
Occupational Exposure
Hazardous Ingredient
LTEL 8hr TWA
STEL
Comments
m
m /m 3
m
m /In3
Butan -1 -ol
-
-
50
154
OES
9. Physical and Chemical Properties
Appearance
Odour
Boiling Point
Flash Point
Flammability Limits,
v /v, n- butanol
Soluble Water
Other
pH
Specific Gravity
Autoflammability
Explosive Properties
Oxidising Properties
Pour Point
Vapour Pressure
Partition Coefficient
Viscosity (mPa.$)
Titanium Content
: Almost colourless to pale yellow liquid. Yellows with age. This
colour change does not affect the products reactivity.
: Alcohol -like
: 312 °C at 760 mmllg
: 40 °C (closed cup)
The flash point is lowered by exposure to atmospheric moisture,
which causes hydrolysis of this product. Reaction liberates n-
butanol.
: l,ower: 1.4 %
Upper: 11.2 %
: Hydrolysed by water
: Miscible with most organic solvents
: Not applicable. flvdrolysed by water.
: 0.995 at 25 °C
: No data
: Non - explosive.
The flash point is lowered by exposure to atmospheric moisture,
which causes hydrolysis of this product. Reaction liberates n-
butanol. The vapour of this product can form potentially explosive
mixtures with air.
: Not applicable
: -50 °C
: 2 at 21 °C (Pascals)
: Not applicable
: 60 at 25 °C
: 14.1%
10. Stability and Reactivity
Conditions to avoid : No specific conditions to avoid.
Hazardous Polymerisation : Will not occur
Hazardous Decomposition : Reaction with water (moisture) produces n- butanol. When
Products heated to decomposition hydrocarbons, carbon monoxide,
carbon dioxide may be produced.
Version 2.2 Product: Tytan TNBT
Revision Date 2011 -03 -15 Page 3 of 5
TN BT
MSDS
11. Toxicological Data
This health hazard assessment
is based on the properties of the hydrolysis products and the
solvent.
Oral Toxicity
Hydrolyses on contact with moisture and therefore solid
polymeric titanium compounds may be deposited on the
gastrointestinal tract and may have an obstructive action.
Ingestion may cause irritation of the gastrointestinal tract.
Oral Median Lethal Dose (n- butanol) 790 mg/kg (rat).
May cause headache, nausea and vomiting. Adverse effects
similar to inhalation will occur. Consumption of alcohol
increases toxic effect.
Dermal Toxicity
Hydrolyses on contact with moisture and therefore solid
polymeric titanium compounds may be deposited on the skin.
n- butanol may be absorbed through the skin. May cause skin
irritation. Repeated or prolonged contact may cause defatting
of the skin resulting in dryness, cracking and dermatitis.
Inhalation
The vapour has anaesthetic properties and when inhaled at
concentrations above the occupational exposure limit it may
cause headache, fatigue, dizziness, incardination and loss of
consciousness.
Eye contact
Risk of serious damage to eyes. Hydrolyses on contact with
moisture and therefore solid polymeric titanium compounds
may be deposited on the eye.
Long Term Effects
This material has been in use for many years with no
evidence of adverse effects.
12. Ecoloeical Data
Toxicity : Accidental discharge into water systems is likely to be
hazardous to aquatic life.
Environmental Distribution : The product hydrolyses in water to give n- butanol and
polymeric titanium compounds and eventually titanium
dioxide. Butanol is soluble in water and has a low
potential for bioaccumulation.
Persistence and Degradation : There is evidence of rapid hydrolysis in water.
Effect on Effluent : No information available.
Treatment
13. Disposal
The only suitable method for disposal of waste products is by controlled incineration in a
furnace, which should be carried out by authorised waste disposal contractors. Emptied drums
will contain vapour and /or product residues. All hazard precautions on this data sheet must be
observed when handling the emptied container. Waste drums should not be reused cut or
welded and should on]); be disposed of via authorised waste disposal contractors.
14. Transport Data
KEY DATA
UN Number
UN Packing Group
1993
III
Version 2.2 Product: Tytan TNBT
Revision Date 2011 -03 -15 Page 4 of 5
TN BT
UN Class - Primary
AIR
ICAO/IATA Class
- Primary
SEA
IMDG Class -
Primary
Marine Pollutant
Proper Shipping
Name
ROAD / RAIL
ADR/RID Class
3
3
3
: Not classified as a Marine Pollutant
: Flammable Liquid N.O.S. (Contains 1- Butanol)
3
15. Regulatory Information
MSDS
All components of this product are in compliance with the following inventories
U.S. TSCA
EC EINECS
Canadian DSL
Australian AILS
Korean ECL
Japanese ENCS
Chinese IECSC
Classification
: Flammable, Irritant
Indications of danger
: IRRITANT
Symbol
: Xi
Risk Phrases
: R10: Flammable.
R38: Irritating to skin.
R41: Risk of serious damage to eyes.
Safety Phrases
: S26: In case of contact with eyes, rinse immediately with plenty
- of water and seek medical advice.
537/39: Wear suitable gloves and eye /face protection_
16. Other Information
This data sheet was prepared in accordance with Directive 2001/58/EC, OSHA - HSC 29 CFR
1910.1200 and in line with OSHA form 174.
R Phrases of Sections 2 & 3
R22: Harmful if swallowed.
R37/38: Irritating to respiratory system and skin.
R67: Vapours may cause drowsiness and dizziness.
The information and recommendations in this publication are, to the best of our knowledge,
information and belief, accurate at the date of publication. Nothing herein is to be construed
as a warranty, express or otherwise. In all cases, it is the responsibility of the user to
determine the applicability of such information or the suitability of any products for their own
particular purpose.
+:s+ t + a+ + c i f ,
I� i� she pGilCy of BGrlca �G update +t his 1niG i� a�IGii regularly. You are therefore advised to
check that this sheet is the most recent issue.
Version 2.2 Product: Tytan TNBT
Revision Date 2011 -03 -15 Page 5 of 5
COMPANY IDENTITY: SolvChem, Inc. DATE: 10/16/10
PRODUCT IDENTITY: VM & P RULE 66 PAGE: 1 OF 7
SDS NUMBER: VMPRUL66
SAFETY DATA SHEET
This Safety Data Sheet conforms to ANSI Z400.5, and to the format requirements
and the International Chemical Safety Cards of the Global Harmonizing System.
THIS SDS COMPLIES WITH 29 CFR 1910.1200 (HAZARD COMMUNICATION STANDARD)
IMPORTANT: Read this SDS before handling & disposing of this product.
Pass this information on to employees, customers, & users of this product.
SECTION 1. IDENTIFICATION OF THE SUBSTANCE OR MIXTURE AND OF THE SUPPLIER
PRODUCT IDENTITY:
NEW MSDS DATE:
COMPANY IDENTITY:
COMPANY ADDRESS:
COMPANY CITY:
COMPANY PHONE:
EMERGENCY PHONES:
RISK STATEMENTS:
VM & P RULE 66
10/16/2010
SolvChem, Inc.
1904 Mykawa Road
Pearland, TX 77581 -0490
1 -281- 485 -5377
CHEMTREC: 1- 800 - 424 -9300 (USA)
CANUTEC: 1- 613 -996 -6666 (CANADA)
SECTION 2. HAZARDS IDENTIFICATION
DANGER!!
R11/13 Highly Flammable! Serious electrostatic hazard!
R36/37/38 Irritating to eyes, respiratory system and skin.
R18 In use, may form flammable /explosive vapor -air mixture.
R65 Harmful: may cause lung damage if swallowed.
SAFETY STATEMENTS:
S2 Keep out of the reach of children.
S23 Do not breathe has, fumes, vapor, or spray.
S24 Avoid contact with skin.
S62 If swallowed, do not induce vomiting; seek medical advice
immediately and show this container or label.
SEE SECTION 11 FOR OTHER TOXICOLOGICAL INFORMATION (ACUTE & CHRONIC HAZARDS)
SECTION 3. COMPOSITION /INFORMATION ON INGREDIENTS
MATERIAL CAS# EINECS# WT% TWA (OSHA) TLV (ACGIH)
Petroleum Hydrocarbon
Solvent (C8 -C9) 64742 -49 -0 - 100 500 ppm 300 ppm
COMPANY IDENTITY: SolvChem, Inc. DATE: 10/16/10
PRODUCT IDENTITY: VM & P RULE 66 PAGE: 2 OF 7
SDS NUMBER: VMPRUL66
SECTION 4. FIRST AID MEASURES
EYE CONTACT:
For eyes, flush with plenty of water for 15 minutes & get medical attention.
SKIN CONTACT:
In case of contact with skin immediately remove contaminated clothing.
Wash thoroughly with soap & water. Wash contaminated clothing before reuse.
INHALATION:
After high vapor exposure, remove to fresh air. If breathing is difficult, give
oxygen. If breathing has stopped, trained personnel should immediately begin
artificial respiration. If the heart has stopped, trained personnel
should immediately begin cardiopulmonary resuscitation (CPR).
SWALLOWING:
Rinse mouth. Do NOT induce vomiting. GET MEDICAL ATTENTION IMMEDIATELY.
Do NOT give liquids to an unconscious or convulsing person.
SECTION 5. FIRE FIGHTING MEASURES
FIRE & EXPLOSION PREVENTIVE MEASURES
NO open flames, NO sparks, & NO smoking. Use a closed system, ventilation,
explosion -proof electrical equipment, lighting.
Do NOT use compressed air for filling, discharging, or handling.
EXTINGUISHING MEDIA
Use dry powder, AFFF, carbon dioxide.
SPECIAL FIRE FIGHTING PROCEDURES
Water spray may be ineffective on fire but can protect fire - fighters
& cool closed containers. Use fog nozzles if water is used.
Do not enter confined fire -space without full bunker gear.
(Helmet with face shield, bunker coats, gloves & rubber boots).
Use NIOSH approved positive - pressure self- contained breathing apparatus.
UNUSUAL EXPLOSION AND FIRE PROCEDURES
HIGHLY FLAMMABLE!! VAPORS CAN CAUSE FLASH FIRE
Isolate from oxidizers, heat, sparks, electric equipment & open flame.
Closed containers may explode if exposed to extreme heat.
Applying to hot surfaces requires special precautions.
Empty container very hazardous! Continue all label precautions!
COMPANY IDENTITY: SolvChem, Inc. DATE: 10/16/10
PRODUCT IDENTITY: VM & P RULE 66 PAGE: 3 OF 7
SOS NUMBER: VMPRUL66
SECTION 6. ACCIDENTAL RELEASE MEASURES
PERSONAL PROTECTIVE MEASURES:
Vapors may ignite explosively & spread long distances. Prevent vapor buildup.
Keep unprotected personnel away.
Ventilate spill area. Remove all ignition sources.
Filter respirator for organic vapors.
ENVIRONMENTAL PRECAUTIONS:
Keep from entering storm sewers and ditches which lead to waterways.
CONTAINMENT AND CLEAN -UP MEASURES:
Stop spill at source. Dike and contain.
Absorb remaining liquid in sand or inert absorbent.
SECTION 7. HANDLING AND STORAGE
HANDLING
Isolate from oxidizers, heat, sparks, electric equipment & open flame.
Use only with adequate ventilation. Avoid breathing of vapor or spray mist.
Avoid contact with skin & eyes.
Wear OSHA Standard goggles or face shield. Consult Safety Equipment Supplier. Wear
gloves, apron & footwear impervious to this material. Wash clothing before reuse.
Avoid free fall of liquid. Ground containers when transferring. Do not flame cut, saw,
drill, braze, or weld. Empty container very hazardous! Continue all label precautions!
To minimize static discharge when transferring, ensure electrical continuity
by bonding and grounding all equipment. Use an inlet line diameter of at
least 3.5 inches (8.9 centimeters) with a maximum flow rate of 1 meter /second.
STORAGE
Isolate from strong oxidants. Do not store above 49 C/120 F.
Keep container tightly closed & upright when not in use to prevent leakage.
SECTION 8. EXPOSURE CONTROLS /PERSONAL PROTECTION
RESPIRATORY EXPOSURE CONTROLS
A respiratory protection program that meets OSHA 29 CFR 1910.134 and
ANSI 286.2 requirements or European Standard EN 149 must be followed
whenever workplace conditions warrant a respirator's use.
VENTILATION
LOCAL EXHAUST: Necessary MECHANICAL (GENERAL): Acceptable
SPECIAL: None OTHER: None
Please refer to ACGIH document, "Industrial Ventilation, A Manual of
Recommended Practices ", most recent edition, for details.
PERSONAL PROTECTIONS:
Wear OSHA Standard goggles or face shield. Consult Safety Equipment Supplier. Wear
gloves, apron & footwear impervious to this material. Wash clothing before reuse.
COMPANY IDENTITY: SolvChem, Inc. DATE: 10/16/10
PRODUCT IDENTITY: VM & P RULE 66 PAGE: 4 OF 7
SDS NUMBER: VMPRUL66
SECTION 8. EXPOSURE CONTROLS /PERSONAL PROTECTION (CONTINUED)
WORK & HYGIENIC PRACTICES:
Provide readily accessible eye wash stations & safety showers.
Wash at end of each workshift & before eating, smoking or using the toilet.
Promptly remove clothing that becomes contaminated. Destroy contaminated
leather articles. Launder or discard contaminated clothing.
SECTION 9. PHYSICAL & CHEMICAL PROPERTIES
APPEARANCE:
ODOR:
ODOR THRESHOLD:
pH (Neutrality):
MELTING POINT /FREEZING POINT:
BOILING RANGE (IBP,50 %,Dry Point):
FLASH POINT (TEST METHOD):
EVAPORATION RATE (n -BUTYL ACETATE =1):
FLAMMABILITY CLASSIFICATION:
LOWER FLAMMABLE LIMIT IN AIR (% by vol):
Not Available
VAPOR PRESSURE (mm of Hg) @20 C
VAPOR DENSITY (air =1):
GRAVITY @ 68/68 F / 20/20 C:
SPECIFIC GRAVITY (Water =l):
POUNDS /GALLON:
WATER SOLUBILITY:
PARTITION COEFFICIENT (n- Octane /Water):
AUTO IGNITION TEMPERATURE:
DECOMPOSITION TEMPERATURE:
REFRACTIVE INDEX:
VOC'S (>0.44 Lbs /Sq In)
TOTAL VOC'S (TVOC) *:
NONEXEMPT VOC'S (CVOC) *:
HAZARDOUS AIR POLLUTANTS (HAPS):
NONEXEMPT VOC PARTIAL PRESSURE (mm of Hg @ 20 C)
Liquid, Water -White
Mild
Not Available
Not Applicable
Not Available
127 135 143 C / 260 275 291 F
18 C / 65 F (TCC)
1.1
Class I B
1.2
7.0 kPa / 5 mm Hg
4.1
0.760
6.331
Negligible
2.1 - 5
287 C / 550 F
Not Available
1.420
100.0 Vol% / 759.0 g/L / 6.2 Lbs /Gal
100.0 Vol% / 759.0 g/L / 6.2 Lbs /Gal
100.0 Vol% / 759.0 g/L / 6.2 Lbs /Gal
0.0 Wt% /0.0 g/L / 0.000 Lbs /Gal
11.0
* Using California South Coast Air Quality Management District (SCAQMD) Rule 443.1.
SECTION 10. STABILITY & REACTIVITY
STABILITY
Stable under normal conditions.
CONDITIONS TO AVOID
Isolate from oxidizers, heat, sparks, electric equipment & open flame.
MATERIALS TO AVOID
Reacts with strong oxidants, causing fire & explosion hazard.
HAZARDOUS DECOMPOSITION PRODUCTS
Carbon Monoxide, Carbon Dioxide from burning.
HAZARDOUS POLYMERIZATION
Will not occur.
COMPANY IDENTITY: SolvChem, Inc.
PRODUCT IDENTITY: VM & P RULE 66
SOS NUMBER: VMPRUL66
SECTION 11. TOXICOLOGICAL INFORMATION
ACUTE HAZARDS
EYE & SKIN CONTACT:
Primary irritation to skin, defatting, dermatitis.
Primary irritation to eyes, redness, tearing, blurred vision.
Liquid can cause eye irritation. Wash thoroughly after handling.
INHALATION:
Anesthetic. Irritates respiratory tract. Acute overexposure
can cause serious nervous system depression. Vapor harmful.
SWALLOWING:
Harmful or fatal if swallowed.
Swallowing can cause abdominal irritation, nausea, vomiting & diarrhea.
The symptoms of chemical pneumonitis may not show up for a few days.
SUBCHRONIC HAZARDS /CONDITIONS AGGRAVATED
CONDITIONS AGGRAVATED
Persons with severe skin, liver or kidney problems should avoid use.
CHRONIC HAZARDS
CANCER, REPRODUCTIVE & OTHER CHRONIC HAZARDS:
Leukemia been reported in humans from Benzene.
This product contains less than 98 ppm of Benzene.
Not considered hazardous in such low concentrations.
Absorption thru skin may be harmful.
MATERIAL
MAMMALIAN TOXICITY INFORMATION
CAS# EINECS#
Light Aliphatic Naphtha 64741 -66 -8 -
DATE: 10/16/10
PAGE: 5 OF 7
LOWEST KNOWN LETHAL DOSE DATA
LOWEST KNOWN LC5O (VAPORS)
3400 ppm (Rats)
COMPANY IDENTITY: SolvChem, Inc. DATE: 10/16/10
PRODUCT IDENTITY: VM & P RULE 66 PAGE: 6 OF 7
SDS NUMBER: VMPRUL66
SECTION 12. ECOLOGICAL INFORMATION
AQUATIC ANIMAL INFORMATION:
No aquatic environmental information is available on this product.
MOBILITY IN SOIL
This material is a mobile liquid.
DEGRADABILITY
This product is nonbiodegradable.
ACCUMULATION
This product does not accumulate or biomagnify in the environment.
SECTION 13. DISPOSAL CONSIDERATIONS
Processing, use or contamination may change the waste management options.
Recycle / dispose of observing national, regional, state, provincial and local
health, safety & pollution laws. If in doubt, contact appropriate agencies.
SECTION 14. TRANSPORT INFORMATION
DOT SHIPPING NAME: UN1268, Petroleum Distillates, n.o.s. (Naphtha Solvent), 3, PG -II
DRUM LABEL: (FLAMMABLE LIQUID)
IATA / ICAO: UN1268, Petroleum Distillates, n.o.s. (Naphtha Solvent), 3, PG -II
IMO / IMDG: UN1268, Petroleum Distillates, n.o.s. (Naphtha Solvent), 3, PG -II
EMERGENCY RESPONSE GUIDEBOOK NUMBER: 128
SECTION 15. REGULATORY INFORMATION
EPA REGULATION:
SARA SECTION 311/312 HAZARDS: Acute Health, Fire
All components
of this product are on the TSCA list.
SARA Title III Section 313
Supplier Notification
This product contains the
indicated < *> toxic chemicals subject to the
reporting requirements of
Section 313 of the Emergency Planning & Community
Right -To -Know Act of 1986
& of 40 CFR 372. This
information must be
included in all MSDSs that
are copied and distributed for this material.
SARA TITLE III INGREDIENTS
CAS# EINECS#
WT% (REG.SECTION)
RQ(LBS)
2,2,4 - Trimethylpentane
540 -84 -1 -
1- 5 (311,312)
1000
Xylenes
1330 -20 -7 -
0- 1 (311,312)
100
Ethylbenzene
100 -41 -4 -
0- 0.1 (311,312)
1000
Benzene
71 -43 -2 -
0 -0.005 (311,312)
10
COMPANY IDENTITY: SolvChem, Inc.
PRODUCT IDENTITY: VM & P RULE 66
SDS NUMBER: VMPRUL66
SECTION 15. REGULATORY INFORMATION (CONTINUED)
INTERNATIONAL REGULATIONS
The components of this product are listed on the chemical
inventories of the following countries:
Australia, Canada, China, Europe (EINECS), Japan, Korea, United Kingdom.
CANADA: WORKPLACE HAZARDOUS MATERIALS INFORMATION SYSTEM (WHMIS)
B2: Flammable Liquid.
D2B: Irritating to skin / eyes.
SECTION 16. OTHER INFORMATION
HAZARD RATINGS:
DATE: 10/16/10
PAGE: 7 OF 7
HEALTH (NFPA): 1, HEALTH (HMIS): 1, FLAMMABILITY: 3, REACTIVITY: 0
(Personal Protection Rating to be supplied by user based on use conditions.)
This information is intended solely for the use of individuals
trained in the NFPA & HMIS hazard rating systems.
EMPLOYEE TRAINING
See Section 2 for Risk & Safety Statements. Employees should be made aware
of all hazards of this material (as stated in this SDS) before handling it.
NOTICE
The supplier disclaims all expressed or implied warranties of merchantability or fitness
for a specific use, with respect to the product or the information provided herein,
except for conformation to contracted specifications. All information appearing herein
is based upon data obtained from manufacturers and /or recognized technical sources.
While the information is believed to be accurate, we make no representations as to its
accuracy or sufficiency.
Conditions of use are beyond our control, and therefore users are responsible for
verifying the data under their own operating conditions to determine whether the product
is suitable for their particular purposes and they assume all risks of their handling,
and disposal of the product. Users also assume all risks in regards to the publication
or use of, or reliance upon information contained herein.
This information relates only to the product designated herein, and does not relate to
its use in combination with any other material or process.
Unless updated, the Safety Data Sheet is valid until 10/16/2013.
GT Products, Inc.
MATERIAL SAFETY DATA SHEET
PRODUCT GT Products® X -5835
1. PRODUCT AND COMPANY IDENTIFICATION
Manufactured by:
GT Products, Inc.
501 Industrial Blvd.
Grapevine, TX 76051
Date Prepared/ Revised:
Chemical Type/ Description:
2. HAZARDOUS INGREDIENTS
Telephone: (800) 221 -0866
(817) 481 -7113
Fax: (817) 421 -1211
gtproducts.com
EMERGENCY (Chemtrec): (800) 424 -9300
03/21/12 by: Daniel Shaw
Silicone Water Repellent
Component
% (Approx.)
Ex osure Limits
CAS No.
methoxy substituted
40 -45%
not established
68037 -85 -4
silicone resin
for methanol OSHA std is:
200 ppm, 8 hr. TWA
alkyltri methoxysi lane
10 -20%
not established
18395 -30 -7
for methanol OSHA std is:
200 ppm, 8 hr. TWA
titanium compound
1 -3%
not established supplier recommends
5593 -70 -4
20 m 8 hr. TWA
This product contains Methylpolysiloxanes, which can generate Formaldehyde at approximately 300 °F (150 °C)
and above, in atmospheres which contain oxygen. Formaldehyde is a skin, eye, and throat irritant, is toxic and a
potential cancer hazard.
HMIS RATING: FLAMMABILITY: 3
3. EFFECTS OF EXPOSURE
Potential Health Effects:
Ingestion:
Skin Contact:
Inhalation:
Eye Contact:
REACTIVITY :1 HEALTH:2
Ingestion will result in hydrolysis releasing methanol and ethanol. Do
not ingest.
May cause contact dermatitis on long exposure.
May irritate.
Will irritate.
X -5835 printed: 05/20/13 page 1 of 4
GT Products
4. FIRST AID MEASURES
Ingestion: Ingestion will result in hydrolysis producing methanol and ethanol.
Seek medical attention. Treat for methanol poisoning.
Skin: Remove with dry towel, then wash with soap and water.
Eyes: Rinse 15 minutes with running water. Seek medical attention if
irritation persists.
Inhalation: Seek fresh air if needed.
Other: Not applicable.
5. FIRE FIGHTING INFORMATION
Flash Point (Method):
78 °F (Setaflash) Note: Flash point varies somewhat due to the
variable methanol content. Material burns poorly producing significant
Si02 ash. Flame self - extinguishes when ignition source is removed.
However, the low flash of the alcohols (mainly methanol) typically
present make it a red -label flammable.
Flammability Class:
Flammable Liquid Class I -A.
Flammability Limits in Air:
Not available.
Extinguishing Media:
All standard media for chemical fires.
Hazardous Combustion Products
CO, COZ, Si02, HzCO
Special Fire Fighting Notes:
Like all silicones or products containing them, GT Products® X -5835
can produce formaldehyde when strongly heated in air. Additionally,
GT Productsc' X -5835 will generate methanol upon contact with water
or during improper storage.
6. ACCIDENTAL RELEASE MEASURES
Pick up spilled material with absorbent clay, then wash area thoroughly with water and detergent Scrubbing will
be required if the spilled material has been allowed to cure. Spilled material is very slippery.
7. HANDLING AND STORAGE
Handling: Avoid contact with eyes and prolonged skin contact.
Storage: Store in cool (< 100 0F), closed and dry containers.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering Controls: Good general ventilation.
Personal Protective Equipment
Eyes: Safety glasses.
Skin: Rubber or plastic gloves as desired.
Inhalation: Respirator fitted with organic vapor cartridges if exposure causes
discomfort. This is not normally required.
X -5835 printed: 05/20/13 page 2 of 4
GT Products
a
10
PHYSICAL AND CHEMICAL PROPERTIES
Physical State:
Color:
Odor:
Boiling Point:
Vapor Density (air = 1):
Density:
Solubility in Water:
Clear low viscosity liquid.
Colorless.
Slight odor of methanol.
Will not boil, but rather begins decomposing at temperatures >60C.d.
All components are heavier than air. Any methanol present (or
formed) is also heavier than air though not by much (1.1x).
1.00 ±0.02
Negligible. Reacts with water.
STABILITY AND REACTIVITY
Chemical Stability:
Hazardous Polymerization:
Decomposition Products:
Materials to Avoid:
Conditions to Avoid:
Stable in the absence of contamination and moisture.
Will not occur.
Only in fire conditions or when contaminated - see section 5.
Water, acids, bases, oxidizing agents.
Keep tightly sealed to avoid contamination and exposure to
atmospheric moisture. Storage in the original container, in a cool dry
place will avoid problems.
11. TOXICOLOGICAL INFORMATION
No additional information is available. See Section 2 and Section 3.
12. ECOLOGICAL INFORMATION
None available
13. DISPOSAL CONSIDERATIONS
Disposal should be made in accordance with state and local regulations.
14. TRANSPORT INFORMATION
DOT SHIPPING NAME: "FLAMMABLE LIQUID N.O.S. — Silicone Mixture Contains Methanol"
DOT HAZARD CLASS: Flammable Liquid.
UN /NA Number: UN1993.
IMDG — P.S.N.: FLAMMABLE LIQUID N.O.S. (Methanol)
IMDG — CLASS: Class 3.
IMDG — PACKING GROUP: PGIII
IMDG — Marine Pollutant: Not a known Marine Pollutant
IATA - P.S.N.: FLAMMABLE LIQUID N.O.S. (Ethanol, Methanol)
X -5835 printed: 05/20/13 page 3 of 4
GT Products
IATA - CLASS: Class 3
IATA — PACKING GROUP: PGIII
15. REGULATORY INFORMATION
TSCA INVENTORY STATUS:
SARA TITLE III / CERCLA
SECTION 302 EXTREMELY TOXIC:
SECTION 304 CERCLA HAZARD:
SECTION 311 / 312 HAZARD
CLASS:
SECTION 313 TOXIC CHEMICALS:
CANADIAN REGULATIONS
Canadian DSL /NDSL Inventory:
Canadian WHMIS Classification:
Canadian Ingredient Disclosure
List:
AUSTRALIAN REGULATIONS
Australian Inventory of Chemical
Substances(AICS) Status:
Hazardous Substances
Information System:
These materials or all of their
contents are listed on the Toxic
Substances Control Act (TSCA).
None
None
Acute: Yes; Chronic: Yes; Fire: Yes;
Pressure: No
None present or none present in
regulated quantities
The components of this product are
on the DSL or NDSL Inventories.
Class B Division 2
No components listed
The components of this product are
listed on the AICS
No components of this product are
listed by the Hazardous Substances
Information System as a Hazardous
Substance
OTHER FOREIGN INVENTORIES
EU /EINECS All ingredients listed or exempt
CHINA /IECSC: All ingredients listed or exempt
16. OTHER INFORMATION
We believe the above information is correct as of the date of this MSDS. However, as this information and the
conditions under which the product are used are beyond the control of GT PRODUCTS, INC., it is the user's
obligation to determine the conditions for the safe use of the product. No warranty, expressed or implied, is
hereby made.
X -5835 printed: 05/20/13 page 4 of 4
GT Products, Inc.
MATERIAL SAFETY DATA SHEET
PRODUCT
GT Products° X5921
Exposure Limits
CAS No.
1. PRODUCT AND COMPANY IDENTIFICATION
8 -10%
Manufactured by:
Trade Secret
GT Products, Inc.
Telephone: (800) 221 -0866
501 Industrial Blvd.
(817) 481 -7113
Grapevine, TX 76051
Fax: (817) 421 -1211
for methanol OSHA std is:
gtproducts.com
EMERGENCY (Chemtrec): (800) 424 -9300
Date Prepared/ Revised: 06/15/11
by: Daniel Shaw
Chemical Type/ Description:
Silicone Water Repellent
2. HAZARDOUS INGREDIENTS
not established supplier recommends
Trade Secret
Component
% (Approx.)
Exposure Limits
CAS No.
petroleum distillate
8 -10%
OSHA PEL TWA 500 pprn
Trade Secret
alkyltrimethoxysilane
8 -10%
not established
Trade Secret
for methanol OSHA std is:
200 ppm, 8 hr. TWA
titanium compound
1 -3%
not established supplier recommends
Trade Secret
20 ppm, 8 hr. TWA
This product contains Methylpolysiloxanes, which can generate Formaldehyde at approximately 300 °F (150 °C)
and above, in atmospheres which contain oxygen. Formaldehyde is a skin, eye, and throat irritant, is toxic and a
potential cancer hazard.
HMIS RATING: FLAMMABILITY: 3 REACTIVITY: 1 HEALTH: 1
3. EFFECTS OF EXPOSURE
Potential Health Effects:
Ingestion: Ingestion will result in hydrolysis releasing methanol. Do not ingest.
Skin Contact: May cause contact dermatitis on long exposure.
Inhalation: May irritate.
Eye Contact: Will irritate.
4. FIRST AID MEASURES
Ingestion: Ingestion will result in hydrolysis producing methanol. Seek medical
attention. Treat for methanol poisoning.
Skin: Remove with dry towel, then wash with soap and water.
Eyes: Rinse 15 minutes with running water. Seek medical attention if
X5921 printed: 05/20/13 page 1 of 3
GT Products
irritation persists.
Inhalation: Seek fresh air if needed.
Other: Not applicable.
5. FIRE FIGHTING INFORMATION
Flash Point (Method):
Note: Flashpoint as determined by Setaflash can vary widely due to
Handling:
the variable, but exceedingly small, methanol content. Usually a flash
Storage:
will be obtained once or twice somewhat near the flash point of
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
methanol (52 0F). Then no additional flash will be observed until the
Good general ventilation.
temp is well over 200 °F. However, due to that initial flash and in
compliance with DOT regulations we report a flash point <100 °F. Comment [KAWI]: changed on 3114/7 to
Flammability Class:
Flammable Liquid Class I -B. bring MSS into compliance with placarding
Flammability Limits in Air:
Not available. (red label).
Extinguishing Media:
All standard media for chemical fires.
Hazardous Combustion Products
CO, CO2, Si02, H2CO
Special Fire Fighting Notes:
Like all silicones or products containing them, GT Products' XS921 can
Clear low viscosity liquid.
produce formaldehyde when strongly heated in air. Additionally,
Colorless.
GT Products® X5921 will generate methanol upon contact with water
Slight odor of methanol & petroleum distillate.
or during improper storage.
6. ACCIDENTAL RELEASE MEASURES
Pick up spilled material with absorbent clay, then wash area thoroughly with water and detergent Scrubbing will
be required if the spilled material has been allowed to cure. Spilled material is very slippery.
7. HANDLING AND STORAGE
Handling:
Avoid contact with eyes and prolonged skin contact.
Storage:
Store in cool (< 100 1F), closed and dry containers.
8. EXPOSURE CONTROLS / PERSONAL PROTECTION
Engineering Controls:
Good general ventilation.
Personal Protective Enuioment
Eyes:
Safety glasses.
Skin:
Rubber or plastic gloves as desired.
Inhalation:
Respirator fitted with organic vapor cartridges if exposure causes
discomfort. This is not normally required.
9. PHYSICAL AND CHEMICAL
PROPERTIES
Physical State:
Clear low viscosity liquid.
Color:
Colorless.
Odor:
Slight odor of methanol & petroleum distillate.
Boiling Point:
Will not boil, but rather begins decomposing at temperatures >60C.
Vapor Density (air = 1):
All components are heavier than air. Any methanol present (or
X5921
printed: 05/20/13 page 2 of 3
GT Products
formed) is also heavier than air though not by much (1.1x).
Specific Gravity: 0.96±0.02
Solubility in Water: Negligible. Reacts with water.
10. STABILITY AND REACTIVITY
Chemical Stability: Stable in the absence of contamination and moisture.
Hazardous Polymerization: Will not occur.
Decomposition Products: Only in fire conditions or when contaminated - see section 5.
Materials to Avoid: Water, acids, bases, oxidizing agents.
Conditions to Avoid: Keep tightly sealed to avoid contamination and exposure to
atmospheric moisture. Storage in the original container, in a cool dry
place will avoid problems.
11. TOXICOLOGICAL INFORMATION
No additional information is available. See Section 2 and Section 3.
12. ECOLOGICAL INFORMATION
None available
13. DISPOSAL CONSIDERATIONS
Disposal should be made in accordance with state and local regulations.
14. TRANSPORT INFORMATION
DOT SHIPPING NAME: Flammable Liquid Contains Silicone and Alcohols.
DOT HAZARD CLASS: Flammable Liquid Class I -B.
UN /NA Number: UN 1993.
15. REGULATORY INFORMATION
TSCA INVENTORY STATUS: These materials or all of their contents are listed on the Toxic
Substances Control Act (TSCA).
16. OTHER INFORMATION
We believe the above information is correct as of the date of this MSDS. However, as this information and the
conditions under which the product are used are beyond the control of GT PRODUCTS, INC., it is the user's
obligation to determine the conditions for the safe use of the product. No warranty, expressed or implied, is
hereby made.
X5921 printed: 05/20/13 page 3 of 3