HomeMy WebLinkAboutCO2021-2779Shenzhen Anbotek Compliance Laboratory Limited
Page 1 of 8 Report No. SZABB181214025-03
This Test Report is issued by the Company subject to its General Conditions of Service printed overleaf. Attention is drawn to the limitations of
liability, indemnification and jurisdictional issues defined therein. The results shown in this report refer only to the sample(s) tested unless
otherwise stated. This Test Report cannot be reproduced, except in full, without prior written permission of the company.
Shenzhen Anbotek Compliance Laboratory Limited
Address: East of 4/F., Building A, Hourui No.3 Industrial Zone, Xixiang Street, Bao'an District, Shenzhen, Guangdong, China
Tel: (86) 755-26066440 Fax: (86)755-26066021 Http: //www.anbotek.com.cn
Shenzhen Anbotek Compliance Laboratory Limited
MSDS REPORT
Report No…………..: SZABB181214025-03
Client………………..: BST POWER (SHENZHEN) LIMITED
Address…………….: No.37 Xinlong Road, Dakang, Henggang Street ,Longgang
District, Shenzhen, P. R. China
Manufacturer………: Hengyang LC Energy Storage Limited
Address…………….: No. 2, Huagong Road., Songmu Industrial Park,
ShiguDistrict, Hengyang, Hunan, P. R. China
Date of Received Sample : 2019-01-02
Date(s) of Report : 2019-01-02 to 2019-01-03
Written by :
Approved by :
Position : Authorized signatory
Shenzhen Anbotek Compliance Laboratory Limited
Page 2 of 8 Report No. SZABB181214025-03
This Test Report is issued by the Company subject to its General Conditions of Service printed overleaf. Attention is drawn to the limitations of
liability, indemnification and jurisdictional issues defined therein. The results shown in this report refer only to the sample(s) tested unless
otherwise stated. This Test Report cannot be reproduced, except in full, without prior written permission of the company.
Shenzhen Anbotek Compliance Laboratory Limited
Address: East of 4/F., Building A, Hourui No.3 Industrial Zone, Xixiang Street, Bao'an District, Shenzhen, Guangdong, China
Tel: (86) 755-26066440 Fax: (86)755-26066021 Http: //www.anbotek.com.cn
MATERIAL SAFETY DATA SHEET
Section 1. Chemical Product and Company Identification
Products Name: Lithium-ion Cell
Model Number: IFR26650 G2
Rating: Nominal Voltage: 3.2V
Rated Capacity: 3300mAh, 10.56Wh
Weight: 81.502g
Manufacture Name: Hengyang LC Energy Storage Limited
Address: No. 2, Huagong Road., Songmu Industrial Park, Shigu District, Hengyang,
Hunan, P. R. China
Telephone No.:0734-3336600
Fax: 0734-3336601
Section 2. Composition/Information on Ingredients
Chemical Name CAS No. Percent of Content
Lithium Iron Phosphate (LiFePO4) 15365-14-7 25-35%
Carbon, as Graphite 7440-44-0 10-20%
Aluminum 7429-90-5 4-9%
Copper 7440-50-8 8-12%
Electrolyte /
12-22%
Ethylene carbonate 96-49-1
Dimethyl carbonate 616-38-6
Ethyl methyl carbonate 623-53-0
Shenzhen Anbotek Compliance Laboratory Limited
Page 3 of 8 Report No. SZABB181214025-03
This Test Report is issued by the Company subject to its General Conditions of Service printed overleaf. Attention is drawn to the limitations of
liability, indemnification and jurisdictional issues defined therein. The results shown in this report refer only to the sample(s) tested unless
otherwise stated. This Test Report cannot be reproduced, except in full, without prior written permission of the company.
Shenzhen Anbotek Compliance Laboratory Limited
Address: East of 4/F., Building A, Hourui No.3 Industrial Zone, Xixiang Street, Bao'an District, Shenzhen, Guangdong, China
Tel: (86) 755-26066440 Fax: (86)755-26066021 Http: //www.anbotek.com.cn
Section 3. Hazards Summarizing
Danger sort: N/A
Routes of entry:
1. Eyes and Skin – When leaking, the electrolyte solution contained in the battery irritates to
ocular tissues and the skin.
2. Inhalation Respiratory (and eye) irritation may occur if fumes are released due heat or
an abundance of leaking batteries.
3. Ingestion – The ingestion of the battery can be harmful. Content of open battery can cause
serious chemical burns of mouth, esophagus and gastrointestinal tract.
Health harm:
Exposure to leaking electrolyte from ruptured or leaking battery can cause:
1. Inhalation Burns and irritation of the respiratory system, coughing, wheezing, and
shortness of breath.
2. Eyes Redness, tearing, burns. The electrolyte is corrosive to all ocular tissues.
3. Skin The electrolyte is corrosive and causes skin irritation and burns.
4. Ingestion The electrolyte solution causes tissue damage to throat and gastrointestinal track.
Environment harm: Not necessary under conditions of normal use.
Explosion danger: The battery may be explosive at high temperature (above 150) or
exposing to the fire.
Section 4. First Aid Measures
Skin contact: Not anticipated. If the battery is leaking and the contained material contacts the
skin, flush with copious amounts of clear water for at least 15 minutes.
Eye contact: Not anticipated. If the battery is leaking and the contained material contacts eyes,
flush with copious amounts of clear water for at least 15 minutes. Get medical attention at once.
Inhalation: Not anticipated. If the battery is leaking, remove to fresh air. If irritation persists,
consult a physician.
Ingestion: Not anticipated. If the battery is leaking and the contained material is ingested, rinse
mouth and surrounding area with clear water at once. Consult a physician immediately for
treatment.
Section 5. Fire Fighting Measures
Unusual Fire and Explosion Hazards: Battery may explode or leak potentially hazardous
vapors subject to: exposed to excessive heat (above the maximum rated temperature as specified
by the manufacturer) or fire, over-charged, short circuit, punctured and crushed.
Hazardous Combustion Products: Fire, excessive heat, or over voltage conditions may produce
Shenzhen Anbotek Compliance Laboratory Limited
Page 4 of 8 Report No. SZABB181214025-03
This Test Report is issued by the Company subject to its General Conditions of Service printed overleaf. Attention is drawn to the limitations of
liability, indemnification and jurisdictional issues defined therein. The results shown in this report refer only to the sample(s) tested unless
otherwise stated. This Test Report cannot be reproduced, except in full, without prior written permission of the company.
Shenzhen Anbotek Compliance Laboratory Limited
Address: East of 4/F., Building A, Hourui No.3 Industrial Zone, Xixiang Street, Bao'an District, Shenzhen, Guangdong, China
Tel: (86) 755-26066440 Fax: (86)755-26066021 //www.anbotek.com.cn
hazardous decomposition products. Damaged batteries can result in rapid heating and the release
of flammable vapors.
Extinguishing Media: Dry chemical type extinguishers are the most effective means to
extinguish a battery fire. A CO2 extinguisher will also work effectively.
Fire Fighting Procedures: Use a positive pressure self-contained breathing apparatus if batteries
are involved in a fire. Full protective clothing is necessary. During water application, caution
is advised as burning pieces of flammable particles may be ejected from the fire.
Section 6. Accidental Release Measures
The material contained within the battery would only be released under abusive conditions. In the
event of battery rupture and leakage, collect all the released materials that are not hot or
burning in an appropriate waste disposal container while wearing proper
protective clothing and ventilate the area. Placed in approved container and disposed according
to the local regulations.
Section 7. Handling and Storage
Handling:
1. Batteries are designed to be recharged. However, improperly charging a battery may cause the
battery to flame. When charging the battery, use dedicated chargers and follow the specified
conditions.
2. Never disassemble or modify a battery.
3. Do not immerse, throw, and wet a battery in water.
4. Should a battery unintentionally be crushed, thus releasing its contents, rubber gloves must be
used to handle all battery components. Avoid the inhalation of any vapors that may be
emitted.
5. Short circuit causes heating. In addition, short circuit reduces the life of the battery and can
lead to ignition of surrounding materials. Physical contact with to short-circuited battery can
cause skin burn.
6. Avoid reversing the battery polarity, which can cause the battery to be damaged or flame.
7. In the event of skin or eye exposure to the electrolyte, refer to Section 4, First Aid Measures.
Storage:
1. Batteries should be separated from other materials and stored in a noncombustible, well
ventilated, sprinkler-protected structure with sufficient clearance between walls and battery
stacks. Do not place batteries near heating equipment, nor expose to direct sunlight for long
periods.
2. Do not store batteries above 35 or below –20. Store batteries in a cool (about 20±5)
in a long time, dry and ventilated area that is subject to little temperature change. Elevated
Shenzhen Anbotek Compliance Laboratory Limited
Page 5 of 8 Report No. SZABB181214025-03
This Test Report is issued by the Company subject to its General Conditions of Service printed overleaf. Attention is drawn to the limitations of
liability, indemnification and jurisdictional issues defined therein. The results shown in this report refer only to the sample(s) tested unless
otherwise stated. This Test Report cannot be reproduced, except in full, without prior written permission of the company.
Shenzhen Anbotek Compliance Laboratory Limited
Address: East of 4/F., Building A, Hourui No.3 Industrial Zone, Xixiang Street, Bao'an District, Shenzhen, Guangdong, China
Tel: (86) 755-26066440 Fax: (86)755-26066021 //www.anbotek.com.cn
temperatures can result in reduced battery cycle life. Battery exposure to temperatures in
excess of 60 will result in the battery venting flammable liquid and gases.
3. Keep batteries in original package until use and do not jumble them.
Section 8. Exposure Controls/Personal Protection
Engineering Controls: Keep away from heat and open flame.
Ventilation: Not necessary under conditions of normal use. In case of abuse, use adequate
mechanical ventilation (local exhaust) for the battery that vent gas or fumes.
Respiratory Protection: Not necessary under conditions of normal use. If battery is burning,
leave the area immediately. During fire fighting fireman should use self-contained breathing,
full-face respiratory equipment. Fires may be fought but only from safe fire fighting distance,
evacuate all persons from the area of fire immediately.
Eye Protection: Not necessary under conditions of normal use. Use safety glasses with side
shields if handling a leaking or ruptured battery.
Body Protection: Not necessary under conditions of normal use. Use rubber apron and
protective working in case of handling a leaking of ruptured battery.
Protective Gloves: Not necessary under conditions of normal use. Use chemical resistant rubber
gloves if handling a leaking or ruptured battery.
Others: Use good chemical hygiene practice. Wash hands thoroughly after cleaning-up a battery
spill caused by leaking battery. No eating, drinking, or smoking in battery storage area.
Section 9. Physical and Chemical Properties
State: Solid
Odor: N/A
pH: N/A
Vapor pressure: N/A
Vapor density: N/A
Boiling point: N/A
Solubility in water: Insoluble
Specific gravity: N/A
Density: N/A
Shenzhen Anbotek Compliance Laboratory Limited
Page 6 of 8 Report No. SZABB181214025-03
This Test Report is issued by the Company subject to its General Conditions of Service printed overleaf. Attention is drawn to the limitations of
liability, indemnification and jurisdictional issues defined therein. The results shown in this report refer only to the sample(s) tested unless
otherwise stated. This Test Report cannot be reproduced, except in full, without prior written permission of the company.
Shenzhen Anbotek Compliance Laboratory Limited
Address: East of 4/F., Building A, Hourui No.3 Industrial Zone, Xixiang Street, Bao'an District, Shenzhen, Guangdong, China
Tel: (86) 755-26066440 Fax: (86)755-26066021 //www.anbotek.com.cn
Section 10. Stability and Reactivity
Stability: Stable
Conditions to Avoid: Do not heat, throw into fire, disassemble, short circuit, immerse in water
or overcharge, etc.
Incompatibility: None during normal operation. Avoid exposure heat, open flame and corrosives.
Hazardous Polymerization: Will not occur.
Hazardous Decomposition Products: The battery may release irritative gas once the
electrolyte leakage.
Section 11. Toxicological Information
The battery does not elicit toxicological properties during routine handling and use. If the
battery is opened through misuse or damage, discard immediately. Internal components of
cell are irritant and sensitization.
Irritancy: The electrolytes contained in this battery can irritate eyes with any contact. Prolonged
contact with the skin or mucous membranes may cause irritation.
Sensitization: No information is available.
Teratogenicity: No information is available.
Carcinogenicity: No information is available.
Mutagenicity: No information is available.
Reproductive toxicity: No information is available.
Section 12. Ecological Information
1. When properly used and disposed, the battery does not present environmental hazard.
2. The battery does not contain mercury, cadmium, or lead.
3. Do not let internal components enter marine environment. Avoid releasing to water ways,
wastewater or ground water.
Section 13. Disposal Considerations
1. Disposal of the battery should be performed by permitted, professional disposal firms
knowledgeable in Federal, State or Local requirements of hazardous waste treatment and
hazardous waste transportation.
2. The battery should be completely discharged prior to disposal and/or the terminals taped or
capped to prevent short circuit. When completely discharged it is not considered hazardous.
3. The battery contains recyclable materials. Recycling options available in your local area
Shenzhen Anbotek Compliance Laboratory Limited
Page 7 of 8 Report No. SZABB181214025-03
This Test Report is issued by the Company subject to its General Conditions of Service printed overleaf. Attention is drawn to the limitations of
liability, indemnification and jurisdictional issues defined therein. The results shown in this report refer only to the sample(s) tested unless
otherwise stated. This Test Report cannot be reproduced, except in full, without prior written permission of the company.
Shenzhen Anbotek Compliance Laboratory Limited
Address: East of 4/F., Building A, Hourui No.3 Industrial Zone, Xixiang Street, Bao'an District, Shenzhen, Guangdong, China
Tel: (86) 755-26066440 Fax: (86)755-26066021 //www.anbotek.com.cn
should be considered when disposing of this product, through licensed waste carrier.
Section 14. Transport Information
According to PACKING INSTRUCTION 965 ~ 967 of IATA DGR 60th Edition for
transportation, the special provision 188 of IMDG (inc Amdt 38-16). The batteries should be
securely packed and protected against short-circuits. Examine whether the package of the
containers are integrate and tighten closed before transport. Take in a cargo of them without
falling, dropping, and breakage. Prevent collapse of cargo piles. Don’t put the goods together
with oxidizer and chief food chemicals. The transport vehicle and ship should be cleaned and
sterilized before transport. During transport, the vehicle should prevent exposure, rain and high
temperature. For stopovers, the vehicle should be away from fire and heat sources. When
transported by sea, the assemble place should keep away from bedroom and kitchen, and
isolated from the engine room, power and fire source. Under the condition of Road
Transportation, the driver should drive in accordance with regulated route, don’t stop over in
the residential area and congested area.
a) UN number
3480&3481
b) UN Proper shipping name
LITHIUM ION BATTERIES (including lithium ion polymer batteries) or; LITHIUM ION
BATTERIES CONTAINED IN EQUIPMENT or LITHIUM ION BATTERIES PACKED
WITH EQUIPMENT (including lithium ion polymer batteries)
c) Transport hazard class(es)
9
d) Packing Instruction (if applicable)
965 II/ IB, 966 II, 967 II
e) Marine pollutant (Yes/No)
No
f) Transport in bulk (according to Annex II of MARPOL 73/78 and the IBC Code)
No information available.
g) Special precautions
No information available.
Shenzhen Anbotek Compliance Laboratory Limited
Page 8 of 8 Report No. SZABB181214025-03
This Test Report is issued by the Company subject to its General Conditions of Service printed overleaf. Attention is drawn to the limitations of
liability, indemnification and jurisdictional issues defined therein. The results shown in this report refer only to the sample(s) tested unless
otherwise stated. This Test Report cannot be reproduced, except in full, without prior written permission of the company.
Shenzhen Anbotek Compliance Laboratory Limited
Address: East of 4/F., Building A, Hourui No.3 Industrial Zone, Xixiang Street, Bao'an District, Shenzhen, Guangdong, China
Tel: (86) 755-26066440 Fax: (86)755-26066021 Http: //www.anbotek.com.cn
Section 15. Regulatory Information
The transport of rechargeable lithium-ion batteries regulated by the united nations as detailed in
the “model Regulations on the transport of dangerous Goods Ref. ST/SG/AC.10/1 Revision 19
2015”.
Defined by UN in the “Recommendations on the transport of Dangerous Goods Chapter 38.3
Manual of Tests and Criteria Ref. ST/SG/AC/ 10/11 sixth revised edition 2015”. The
Lithium-ion Cells and the battery Packs may or may not be assigned to the UN No. 3480
Class-9 that is restricted for transport.
Section 16. Other Information
Prepared Department: BST POWER (SHENZHEN) LIMITED
DS Report No.: CANEC1725054802 Date: 27 Dec 2017 Page 1 of 1
SHENZHEN BETTER POWER BATTERY CO.,LTD
NO.11 AND 26 BLDG,DALANG TONGFU VILLAGE INDUSTRY ZONE,LONGHUA TOWN,BAOAN
DNDISTRLET,SHENZHEN GUANGDONG.P.RCHINA
SGS Job No. : CP17-067262-SZ
Sample Name : Ni-MH Battery
Manufacturer : BETTERPOWER BATTERY CO., LTD.
Country of Origin : CHINA
End Uses : Household&Industrial power
Composition/Ingredient of sample
as per client submission) : See section 3 Composition/information on ingredients on the SDS report
Job Receiving Date : 12 Dec 2017
SDS Preparation Period : 12 Dec 2017 - 18 Dec 2017
Service Requested : Safety Data Sheet (SDS) for the sample with submitted composition.
Summary : As per request, the contents and formats of the SDS are prepared in
accordance with European Commission Regulation (EC) No 1907/2006,
Regulation (EC) No 1272/2008 and Regulation (EU) No 2015/830, and is
provided per attached.
Remark:
The SDS is prepared based on the information provided by client.
This sample is likely to be classified as article with substances not intende d
to be released and is out of scope of a SDS as set out in Regulation (EC) No
1907/2006. This SDS is generated for client’s reference only.
Signed for and on behalf of
SGS-CSTC Standards Technical Services Co., Ltd. Guangzhou Branch
Zm guan
Approved Signatory
Page 1/11
Safety Data Sheet
Regulation (EC) No. 1907/2006 and 1272/2008
Printing date 18.12.2017 Revision: 18.12.2017Versionnumber1
46.0.9
SECTION 1: Identification of the substance/mixture and of the company/undertaking
1.1 Product identifier
Trade name: Ni-MH Battery
1.2 Relevant identified uses of the substance or mixture and uses advised against
Application of the substance / the mixture:Household & Industrial power
1.3 Details of the supplier of the safety data sheet
Manufacturer / Supplier:BETTERPOWER BATTERY CO.,LTD.
Full address:
NO.11 BIDGS,TONGFUCUN INDUSTRIAL ZONE,SHIAO,DALANG,LONGHUA NEW
DISTRICT,SHENZHEN,CHINA
Phone number:+86 0755 2807 8972
Email:qa03@betterpower.com.cn
Only Representative / other EU contact point:Not available
Further information obtainable from:BETTERPOWER BATTERY CO.,LTD.
1.4 Emergency telephone number:
UNITED KINGDOM
National Poisons Information Service
Tel: +44 (0) 344 892 0111 (for healthcare professional)
44 (0) 845 46 47 (in England or Wales)
44 (0) 8454 24 24 24 (in Scotland)
86-18898350210 Zhao Xiaojun
1.5 Reference Number:CP17-067262-SZ; CANEC1725054802
1.6 Remark:
This sample is likely to be classified as article with substances not intended to be released and is out of
scope of a SDS as set out in Regulation (EC) No 1907/2006. This SDS is generated for client’s reference only.
SECTION 2: Hazards identification
2.1 Classification of the substance or mixture
Classification according to Regulation (EC) No 1272/2008
GHS02 flame
Flam. Sol. 1 H228 Flammable solid.
GHS08 health hazard
Resp. Sens. 1 H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
Muta. 2 H341 Suspected of causing genetic defects.
Carc. 1A H350i May cause cancer by inhalation.
Repr. 1B H360D May damage the unborn child.
STOT RE 1 H372 Causes damage to organs through prolonged or repeated exposure.
GHS09 environment
Aquatic Acute 1 H400 Very toxic to aquatic life.
Aquatic Chronic 1 H410 Very toxic to aquatic life with long lasting effects.
GHS07
Contd. on page 2)
EU
Page 2/11
Safety Data Sheet
Regulation (EC) No. 1907/2006 and 1272/2008
Printing date 18.12.2017 Revision: 18.12.2017Versionnumber1
Trade name: Ni-MH Battery
Contd. of page 1)
46.0.9
Acute Tox. 4 H302 Harmful if swallowed.
Skin Irrit. 2 H315 Causes skin irritation.
Eye Irrit. 2 H319 Causes serious eye irritation.
Skin Sens. 1 H317 May cause an allergic skin reaction.
Information concerning particular hazards for human and environment:
The product has to be labelled due to the calculation procedure of Regulation (EC) No. 1272/2008.
Classification system:
The classification is according to the latest edition of EU Regulation (EC) No. 1272/2008, and extended by
company and literature data.
2.2 Label elements
Labelling according to Regulation (EC) No 1272/2008
The product is classified and labelled according to the CLP regulation.
Hazard pictograms
GHS02 GHS07 GHS08 GHS09
Signal word Danger
Hazard-determining components of labelling:
nickel dihydroxide
nickel powder (particle diameter < 1 mm)
cobalt
potassium hydroxide
Hazard statements
H228 Flammable solid.
H302 Harmful if swallowed.
H315 Causes skin irritation.
H319 Causes serious eye irritation.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H317 May cause an allergic skin reaction.
H341 Suspected of causing genetic defects.
H350i May cause cancer by inhalation.
H360D May damage the unborn child.
H372 Causes damage to organs through prolonged or repeated exposure.
H410 Very toxic to aquatic life with long lasting effects.
Precautionary statements
P101 If medical advice is needed, have product container or label at hand.
P102 Keep out of reach of children.
P103 Read label before use.
P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No
smoking.
P241 Use explosion-proof [electrical/ventilating/lighting] equipment.
P260 Do not breathe dust/fume/gas/mist/vapours/spray.
P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if
present and easy to do. Continue rinsing.
P405 Store locked up.
P501 Dispose of contents/container in accordance with local/regional/national/international
regulations.
Additional information:
Restricted to professional users.
2.3 Other hazards:
Results of PBT and vPvB assessment
PBT:Not applicable.
Contd. on page 3)
EU
Page 3/11
Safety Data Sheet
Regulation (EC) No. 1907/2006 and 1272/2008
Printing date 18.12.2017 Revision: 18.12.2017Versionnumber1
Trade name: Ni-MH Battery
Contd. of page 2)
46.0.9
vPvB:Not applicable.
SECTION 3: Composition/information on ingredients
3.2 Mixtures
Description:
Mixture of the substances listed below with nonhazardous additions.
For the wording of the listed hazard statements refer to section 16.
Composition:
CAS: 7440-02-0
EINECS: 231-111-4
Index number: 028-002-01-4
nickel powder (particle diameter < 1 mm)
Carc. 2, H351; STOT RE 1, H372; Skin Sens. 1, H317; Aquatic
Chronic 3, H412
35.5%
CAS: 12054-48-7
EINECS: 235-008-5
Index number: 028-008-00-X
nickel dihydroxide
Resp. Sens. 1, H334; Muta. 2, H341; Carc. 1A, H350i; Repr. 1B,
H360D; STOT RE 1, H372; Aquatic Acute 1, H400; Aquatic
Chronic 1, H410; Acute Tox. 4, H302; Acute Tox. 4, H332; Skin
Irrit. 2, H315; Skin Sens. 1, H317
28.5%
CAS: 7439-91-0
EINECS: 231-099-0
lanthanum
Water-react. 1, H260
12.5%
CAS: 7440-45-1
EINECS: 231-154-9
cerium
Flam. Sol. 1, H228
11.0%
CAS: 7440-48-4
EINECS: 231-158-0
Index number: 027-001-00-9
cobalt
Resp. Sens. 1, H334; Skin Sens. 1, H317; Aquatic Chronic 4,
H413
7.6%
CAS: 7439-96-5
EINECS: 231-105-1
manganese
Flam. Sol. 2, H228
3.0%
CAS: 1310-58-3
EINECS: 215-181-3
Index number: 019-002-00-8
potassium hydroxide
Skin Corr. 1A, H314; Acute Tox. 4, H302
1.0%
CAS: 1310-73-2
EINECS: 215-185-5
Index number: 011-002-00-6
sodium hydroxide
Skin Corr. 1A, H314
0.5%
CAS: 1310-65-2
EINECS: 215-183-4
lithium hydroxide
Acute Tox. 3, H301; Skin Corr. 1A, H314
0.3%
CAS: 7440-00-8
EINECS: 231-109-3
neodymium
Flam. Sol. 2, H228; Water-react. 1, H260
0.1%
SECTION 4: First aid measures
4.1 Description of first aid measures
General description:
Symptoms of poisoning may even occur after several hours; therefore medical observation for at least 48
hours after the accident.
After inhalation:
Supply fresh air and to be sure call for a doctor.
In case of unconsciousness place patient stably in side position for transportation.
After skin contact:Immediately wash with water and soap and rinse thoroughly.
After eye contact:
Rinse opened eye for several minutes under running water. If symptoms persist, consult a doctor.
After swallowing:Call for a doctor immediately.
4.2 Most important symptoms and effects, both acute and delayed:
No further relevant information available.
Contd. on page 4)
EU
Page 4/11
Safety Data Sheet
Regulation (EC) No. 1907/2006 and 1272/2008
Printing date 18.12.2017 Revision: 18.12.2017Versionnumber1
Trade name: Ni-MH Battery
Contd. of page 3)
46.0.9
4.3 Indication of any immediate medical attention and special treatment needed:
No further relevant information available.
SECTION 5: Firefighting measures
5.1 Extinguishing media
Suitable extinguishing agents:
CO, powder or water spray. Fight larger fires with water spray or alcohol resistant foam.
For safety reasons unsuitable extinguishing agents:Water
5.2 Special hazards arising from the substance or mixture:No further relevant information available.
5.3 Advice for firefighters
Protective equipment:No special measures required.
SECTION 6: Accidental release measures
6.1 Personal precautions, protective equipment and emergency procedures:
Wear protective equipment. Keep unprotected persons away.
6.2 Environmental precautions:
Inform respective authorities in case of seepage into water course or sewage system.
Do not allow to enter sewers/ surface or ground water.
6.3 Methods and material for containment and cleaning up:
Dispose contaminated material as waste according to Section 13.
Ensure adequate ventilation.
Do not flush with water or aqueous cleansing agents
6.4 Reference to other sections:
See Section 7 for information on safe handling.
See Section 8 for information on personal protection equipment.
See Section 13 for disposal information.
SECTION 7: Handling and storage
7.1 Precautions for safe handling:
Ensure good ventilation/exhaustion at the workplace.
For the general occupational hygienic measures refer to Section 8.
Information about fire - and explosion protection:Keep ignition sources away - Do not smoke.
7.2 Conditions for safe storage, including any incompatibilities
Requirements to be met by storerooms and receptacles:No special requirements.
Information about storage in one common storage facility:Not required.
Further information about storage conditions:
Keep container tightly sealed.
Store in cool, dry conditions in well sealed receptacles.
7.3 Specific end use(s):No further relevant information available.
EU
Contd. on page 5)
Page 5/11
Safety Data Sheet
Regulation (EC) No. 1907/2006 and 1272/2008
Printing date 18.12.2017 Revision: 18.12.2017Versionnumber1
Trade name: Ni-MH Battery
Contd. of page 4)
46.0.9
SECTION 8: Exposure controls/personal protection
8.1 Control parameters
Ingredients with limit values that require monitoring at the workplace:
7440-02-0 nickel powder (particle diameter < 1 mm) (35.5%)
WEL (Great Britain) Long-term value: 0.5 mg/m³
as Ni; Sk; Carc
AGW (Germany) Long-term value: 0.006 A mg/m³
8(II);AGS, 10, Sh, Y
VME (France) Long-term value: 1 mg/m³
C2
12054-48-7 nickel dihydroxide (28.5%)
WEL (Great Britain) Long-term value: 0.5 mg/m³
as Ni; Sk; Carc
MAK (Germany) einatembare Fraktion; vgl.Abschn.XII
VME (France) Long-term value: 1 mg/m³
C1A, M2, R1B
7440-48-4 cobalt (7.6%)
WEL (Great Britain) Long-term value: 0.1 mg/m³
as Co; Carc, Sen
MAK (Germany) einatembare Fraktion; vgl.Abschn.XIII
7439-96-5 manganese (3.0%)
WEL (Great Britain) Long-term value: 0.5 mg/m³
as Mn
AGW (Germany) Long-term value: 0.02A; 0.2E mg/m³
8(II);DFG,Y,10, 20
1310-58-3 potassium hydroxide (1.0%)
WEL (Great Britain) Short-term value: 2 mg/m³
VME (France) Short-term value: 2 mg/m³
1310-73-2 sodium hydroxide (0.5%)
WEL (Great Britain) Short-term value: 2 mg/m³
MAK (Germany) vgl.Abschn.IIb
VME (France) Long-term value: 2 mg/m³
1310-65-2 lithium hydroxide (0.3%)
WEL (Great Britain) Short-term value: 1 mg/m³
MAK (Germany) vgl. Abschn. IIb
Regulatory information
WEL (Great Britain): EH40/2011
AGW (Germany): TRGS 900
VME (France): ED 984, 07.2012
MAK (Germany): MAK- und BAT-Liste
DNELs:Not available
PNECs:Not available
Ingredients with biological limit values:
7439-96-5 manganese
BGW (Germany) 20 µg/l
Untersuchungsmaterial: Vollblut
Probennahmezeitpunkt: bei Langzeitexposition: Nach mehreren vorangegangenen
Schichten, Expositionsende bzw. Schichtende
Parameter: Mangan
Contd. on page 6)
EU
Page 6/11
Safety Data Sheet
Regulation (EC) No. 1907/2006 and 1272/2008
Printing date 18.12.2017 Revision: 18.12.2017Versionnumber1
Trade name: Ni-MH Battery
Contd. of page 5)
46.0.9
Additional information:The lists valid during the making were used as basis.
8.2 Exposure controls
Based on the composition shown in Section 3, the following measures are suggested for occupational safety
measure.
Appropriate engineering controls:
Keep away from foodstuffs, beverages and feed.
Immediately remove all soiled and contaminated clothing
Wash hands before breaks and at the end of work.
Store protective clothing separately.
Avoid contact with the eyes and skin.
See Section 7 for information about design of technical facilities.
Personal protective equipment
Respiratory protection:
In case of brief exposure or low pollution use respiratory filter device. In case of intensive or longer exposure
use self-contained respiratory protective device.
Protection of hands:
Protective gloves
The glove material has to be impermeable and resistant to the product/ the substance/ the preparation.
Due to missing tests no recommendation to the glove material can be given for the product/ the preparation/
the chemical mixture.
Selection of the glove material on consideration of the penetration times, rates of diffusion and the
degradation
Material of gloves
The selection of the suitable gloves does not only depend on the material, but also on further marks of quality
and varies from manufacturer to manufacturer. As the product is a preparation of several substances, the
resistance of the glove material can not be calculated in advance and has therefore to be checked prior to the
application.
Penetration time of glove material:
The exact break through time has to be found out by the manufacturer of the protective gloves and has to be
observed.
Eye protection:
Tightly sealed goggles
Environmental exposure controls:
Control measures must be made in accordance with Community environmental protection legislation.
SECTION 9: Physical and chemical properties
9.1 Information on basic physical and chemical properties
Appearance
Form:Solid, cylindrical (sealed unit)
Colour:Silver-grey
Odour:Odourless
Odour threshold:Not available
pH-value:Not available
Change in condition
Melting point/Freezing point:Not available
Initial boiling point and boiling range:Not available
Contd. on page 7)
EU
Page 7/11
Safety Data Sheet
Regulation (EC) No. 1907/2006 and 1272/2008
Printing date 18.12.2017 Revision: 18.12.2017Versionnumber1
Trade name: Ni-MH Battery
Contd. of page 6)
46.0.9
Flash point:Not available
Flammability (solid, gas):Not available
Auto-Ignition temperature:Not available
Decomposition temperature:Not available
Self-igniting:Product is not selfigniting.
Explosive properties:Product does not present an explosion hazard.
Explosion limits
Lower:Not available
Upper:Not available
Oxidising properties:Not available
Vapour pressure:Not available
Density:Not available
Relative density:Not available
Vapour density:Not available
Evaporation rate:Not available
Solubility in / Miscibility with
water:Not available
Partition coefficient: n-octanol/water:Not available
Viscosity
Dynamic:Not available
Kinematic:Not available
9.2 Other information No further relevant information available.
SECTION 10: Stability and reactivity
10.1 Reactivity:Data not available
10.2 Chemical stability:Data not available
10.3 Possibility of hazardous reactions:Contact with water releases flammable gases.
10.4 Conditions to avoid:No further relevant information available.
10.5 Incompatible materials:No further relevant information available.
10.6 Hazardous decomposition products:No dangerous decomposition products known.
SECTION 11: Toxicological information
11.1 Information on toxicological effects
Acute toxicity
Harmful if swallowed.
LD/LC50 values relevant for classification:
7440-48-4 cobalt
Oral LD50 6170 mg/kg (rat)
7439-96-5 manganese
Oral LD50 9000 mg/kg (rat)
Skin corrosion/irritation:
Causes skin irritation.
Contd. on page 8)
EU
Page 8/11
Safety Data Sheet
Regulation (EC) No. 1907/2006 and 1272/2008
Printing date 18.12.2017 Revision: 18.12.2017Versionnumber1
Trade name: Ni-MH Battery
Contd. of page 7)
46.0.9
Serious eye damage/irritation:
Causes serious eye irritation.
Respiratory or skin sensitization:
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
Germ cell mutagenicity
Suspected of causing genetic defects.
Carcinogenicity
May cause cancer by inhalation.
Reproductive toxicity
May damage the unborn child.
STOT-single exposure Based on available data, the classification criteria are not met.
STOT-repeated exposure
Causes damage to organs through prolonged or repeated exposure.
Aspiration hazard Based on available data, the classification criteria are not met.
SECTION 12: Ecological information
12.1 Toxicity
Aquatic toxicity:No further relevant information available.
12.2 Persistence and degradability:No further relevant information available.
12.3 Bioaccumulative potential:No further relevant information available.
12.4 Mobility in soil:No further relevant information available.
12.5 Results of PBT and vPvB assessment
PBT:Not applicable.
vPvB:Not applicable.
12.6 Other adverse effects No further relevant information available.
12.7 Additional ecological information:
General notes:
Water hazard class 3 (German Regulation) (Self-assessment): extremely hazardous for water
Do not allow product to reach ground water, water course or sewage system, even in small quantities.
Danger to drinking water if even extremely small quantities leak into the ground.
Also poisonous for fish and plankton in water bodies.
Very toxic for aquatic organisms
SECTION 13: Disposal considerations
13.1 Waste treatment methods
Recommendation:
Must not be disposed together with household garbage. Do not allow product to reach sewage system.
Uncleaned packaging
Recommendation:Disposal must be made according to official regulations.
SECTION 14: Transport information
14.1 UN-Number
ADR/RID/ADN, IATA Not applicable
IMDG UN3496
14.2 UN proper shipping name
ADR/RID/ADN, IATA Not applicable
Contd. on page 9)
EU
Page 9/11
Safety Data Sheet
Regulation (EC) No. 1907/2006 and 1272/2008
Printing date 18.12.2017 Revision: 18.12.2017Versionnumber1
Trade name: Ni-MH Battery
Contd. of page 8)
46.0.9
IMDG Batteries, nickel-metal hydride (nickel dihydroxide ),
MARINE POLLUTANT
14.3 Transport hazard class(es)
ADR/RID/ADN, IATA
Class Not applicable
Label -
IMDG
Class 9 Miscellaneous dangerous substances and articles.
Label 9
14.4 Packing group
ADR/RID/ADN, IMDG, IATA Not applicable
14.5 Environmental hazards Product contains environmentally hazardous substances:
nickel dihydroxide
Marine pollutant:Symbol (fish and tree)
14.6 Special precautions for user:Not applicable.
Danger code (Kemler):-
EMS Number:F-A,S-I
14.7 Transport in bulk according to Annex II of
Marpol and the IBC Code Not applicable.
14.8 Transport/Additional information:
IMDG
Limited quantities (LQ)0
Excepted quantities (EQ)Code: E0
Not permitted as Excepted Quantity
SECTION 15: Regulatory information
15.1 Safety, health and environmental regulations/legislation specific for the substance or mixture
MAK(German Maximum Workplace Concentration)
12054-48-7 nickel dihydroxide 1
7440-48-4 cobalt 2
Directive 2012/18/EU
Named dangerous substances - ANNEX I None of the ingredients is listed.
Seveso category
E1 Hazardous to the Aquatic Environment
O1 Substances or mixtures with hazard statement EUH014
Qualifying quantity (tonnes) for the application of lower-tier requirements 100 t
Qualifying quantity (tonnes) for the application of upper-tier requirements 200 t
National regulations:
Additional classification according to Decree on Hazardous Materials, Annex II:
Carcinogenic hazardous material group III (dangerous).
Information about limitation of use:
Workers are not allowed to be exposed to the hazard ous carcinogenic materials contained in this
preparation. Exceptions can be made by the authorities in certain cases.
Waterhazard class:Water hazard class 3 (Self-assessment): extremely hazardous for water.
Contd. on page 10)
EU
Page 10/11
Safety Data Sheet
Regulation (EC) No. 1907/2006 and 1272/2008
Printing date 18.12.2017 Revision: 18.12.2017Versionnumber1
Trade name: Ni-MH Battery
Contd. of page 9)
46.0.9
Other regulations, limitations and prohibitive regulations
SVHC Candidate List of REACH Regulation Annex XIV Authorisation (7/7/2017)
None of the ingredients is listed
REACH Regulation Annex XVII Restriction (13/6/2017)
See Section 16 for information about restriction of use.
None of the ingredients is listed
REACH Regulation Annex XIV Authorisation List (13/6/2017)
None of the ingredients is listed
15.2 Chemical safety assessment:A Chemical Safety Assessment has not been carried out.
SECTION 16: Other information
Relevant hazard statements
H228 Flammable solid.
H260 In contact with water releases flammable gases which may ignite spontaneously.
H301 Toxic if swallowed.
H302 Harmful if swallowed.
H314 Causes severe skin burns and eye damage.
H315 Causes skin irritation.
H317 May cause an allergic skin reaction.
H332 Harmful if inhaled.
H334 May cause allergy or asthma symptoms or breathing difficulties if inhaled.
H341 Suspected of causing genetic defects.
H350i May cause cancer by inhalation.
H351 Suspected of causing cancer.
H360D May damage the unborn child.
H372 Causes damage to organs through prolonged or repeated exposure.
H400 Very toxic to aquatic life.
H410 Very toxic to aquatic life with long lasting effects.
H412 Harmful to aquatic life with long lasting effects.
H413 May cause long lasting harmful effects to aquatic life.
The contents and format of this SDS are in accordance with Regulation (EC) No 1907/2006, 1272/2008 and
Regulation (EU) No 2015/830.
DISCLAIMER OF LIABILITY
The information in this SDS was obtained from sourc es which we believe are reliable. However, the
information is provided without any warranty, express or implied, regarding its correctness. The conditions
or methods of handling, storage, use or disposal of the product are beyond our control and may be beyond
our knowledge. For this and other reason, we do not assume responsibility and expressly disclaim liability for
loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of
the product. This SDS was prepared and is to be used only for this product. If the product is used as a
component in another product, this SDS information may not be applicable.
Remark:
This sample is likely to be classified as article with substances not intended to be released and is out of
scope of a SDS as set out in Regulation (EC) No 1907/2006. This SDS is generated for client’s reference only.
Contd. on page 11)
EU
Page 11/11
Safety Data Sheet
Regulation (EC) No. 1907/2006 and 1272/2008
Printing date 18.12.2017 Revision: 18.12.2017Versionnumber1
Trade name: Ni-MH Battery
Contd. of page 10)
46.0.9
Classification according to Regulation (EC) No. 1272/2008
Flammable solids On basis of test data
Acute toxicity - oral
Skin corrosion/irritation
Serious eye damage/eye irritation
Respiratory sensitisation
Skin sensitisation
Germ cell mutagenicity
Carcinogenicity
Reproductive toxicity
Specific target organ toxicity (repeated exposure)
Hazardous to the aquatic environment - short-term
acute) aquatic hazard
Hazardous to the aquatic environment - long-term
chronic) aquatic hazard
The classification of the mixture is generally based on
the calculation method using substance data
according to Regulation (EC) No 1272/2008.
Abbreviations and acronyms:
ADR: Accord européen sur le transport des marchandises dangereuses par Route (European Agreement concerning the International
Carriage of Dangerous Goods by Road)
IMDG: International Maritime Code for Dangerous Goods
IATA: International Air Transport Association
GHS: Globally Harmonised System of Classification and Labelling of Chemicals
EINECS: European Inventory of Existing Commercial Chemical Substances
ELINCS: European List of Notified Chemical Substances
CAS: Chemical Abstracts Service (division of the American Chemical Society)
DNEL: Derived No-Effect Level (REACH)
PNEC: Predicted No-Effect Concentration (REACH)
LC50: Lethal concentration, 50 percent
LD50: Lethal dose, 50 percent
PBT: Persistent, Bioaccumulative and Toxic
vPvB: very Persistent and very Bioaccumulative
Flam. Sol. 1: Flammable solids – Category 1
Flam. Sol. 2: Flammable solids – Category 2
Water-react. 1: Substances and mixtures which in contact with water emit flammable gases – Category 1
Acute Tox. 3: Acute toxicity – Category 3
Acute Tox. 4: Acute toxicity – Category 4
Skin Corr. 1A: Skin corrosion/irritation – Category 1A
Skin Irrit. 2: Skin corrosion/irritation – Category 2
Eye Irrit. 2: Serious eye damage/eye irritation – Category 2
Resp. Sens. 1: Respiratory sensitisation – Category 1
Skin Sens. 1: Skin sensitisation – Category 1
Muta. 2: Germ cell mutagenicity – Category 2
Carc. 1A: Carcinogenicity – Category 1Ai
Carc. 2: Carcinogenicity – Category 2
Repr. 1B: Reproductive toxicity – Category 1B
STOT RE 1: Specific target organ toxicity (repeated exposure) – Category 1
Aquatic Acute 1: Hazardous to the aquatic environment - acute aquatic hazard – Category 1
Aquatic Chronic 1: Hazardous to the aquatic environment - long-term aquatic hazard – Category 1
Aquatic Chronic 3: Hazardous to the aquatic environment - long-term aquatic hazard – Category 3
Aquatic Chronic 4: Hazardous to the aquatic environment - long-term aquatic hazard – Category 4
End of document
EU
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Material Safety Data Sheet
Page 1 of 8
Material Safety Data Sheet
Lithium-ion Battery Pack
Model/type reference: LBP-348A
Tradem ark:
Nominal Voltage: 14.4VDC
Typical Capacity: 28.8W h
W eight: 618g
Shape and Physical Dim ension (mm): L: 348mm; W : 86mm; H: 38mm
Preparation Date: Sep. 12, 2017
Version num ber: V1.0
Manufacture: Shenzhen Longood Intelligent Electric Co., Ltd
Address: 8-4 Bldg, Tongfuyu Industrial Zone, Aiqun Rd,
Shangpai Community, Shiyan Town, Bao'an
District, Shenzhen, Guangdong, 518108, China
TEL: +86-0755-33236887
Compiled by: JIE YE
Approved by: YONGQING WEN
Material Safety Data Sheet
Page 2 of 8
Section 1- Chemical Product and Compan y Identification
1. Chemical Product Identification
Product name: Lithium-ion Battery Pack
Model: LBP-348A
2. Company Identification
Manufacturer /Supplier Nam e: Shenzhen Longood Intelligent Electric Co., Ltd
Address: 8-4 Bldg, Tongfuyu Industrial Zone, Aiqun Rd, Shangpai Community, Shiyan Town,
Bao'an District, Shenzhen, Guangdong, 518108, China
Telephone num ber of the manufacturer: +86-0755-33236887
E-m ail address:
Referenced docum ents: ISO 11014:2009 Safety data sheet for chemical products;
Section 2 – Hazards Identification
Preparation
hazards and
classification
W hen the battery is In extrem e pressure deform ation, high-tem perature
environm ent, ov erload, short-circuit condition, or disassem ble the battery, an
explosion of fire and chemical burn hazards m ay occur.
Apperance,
Color, and
Odor
Solid object with no odor, no color.
Primary
Route(s) of
Exposure
These chemicals are contained in a sealed stainless steel enclosure. Risk of
exposure occurs only if the cell is mechanically, thermally or electrically abused to
the point of com promising the enclosure. If this occurs, exposure to the electrolyte
solution contained within can occur by Inhalation, Ingestion, Eye contact and Skin
contact
Potential
Health
Effects:
ACUTE (short term): see Section 8 for exposure controls In the ev ent that this
battery has been ruptured, the electrolyte solution contained within the battery
would be corrosiv e and can cause burns.
Inhalation: A battery volatilizes no gas unless it was dam aged. Dam aged battery
will volatilize little gas that m ay stim ulate the respiratory tract or cause an
anaphylaxis in serious condition.
Ingestion: Swallowing battery will be dam aged to the respiratory tract and cause
chemical burns to the stom ach; in serious conditions it will cause perm anent
dam age.
Skin: In norm al condition, contact between the battery and skin will not cause any
harm s. Contact with a damaged battery m ay cause skin allergies or chemical
burns.
Eye: in norm al condition, contact between the battery and eyes will not cause any
harm s. Howev er, the gas volatilize from a dam aged battery m ay be harmful to
eyes.
CHRONIC (long term): see Section 11 for additional toxicological data.
Medical
Conditions
Aggrav ated by
Exposure
Not applicable
Reported as
carcinogen
Not applicable
Material Safety Data Sheet
Page 3 of 8
Section 3 – Composition/Information on Ingredients
Li-ion Battery is a mixture.
Hazardous Ingredients
Chemical Name)
w/w CAS Number LD50(mg/kg)
oral-rat)
LC50(mg/L)
Aluminum Foil (Al) 2-8 7429-90-5 N/A N/A
Copper Foil (Cu) 5-10 7440-50-8 3.5(ipr-mouse) N/A
Linear and Cyclic Carbonic
Solvents(See other information)
5-15 N/APP 11000 (weighted
avg)
N/A
Graphite Powder 15-20 7440-44-0 440(ivn-mouse) N/A
Cobalt lithium manganese nickel
oxide
30-33 182442-95-1 N/A N/A
Polyvinylidene Fluoride
PVDF)(-[-CH2-CF2-]-n)
0.1-4 24937-79-9 N/A N/A
Steel, nickel and inert polymer 0.5-4 N/A N/A N/A
Lithium Hexafluorophosphate
LiPF6)
1-3 21324-40-3 1702 Rat:>20
Carbon black and others 0-3 1333-86-4 N/APP N/APP
Note: CAS num ber is Chemical Abstract Service Registry Num ber.
N/A=Not apply.
Section 4 – First-aid Measures
Inhalation Remove to fresh air and ventilate the contaminated area. Give oxygen or artificial
respiration if needed.
Skin contact If skin contact with contents of an open battery occurs, as quickly as possible
rem ove contaminated clothing, shoes and leather goods. Immediately flush with
lukewarm , gently flowing water for at least 15 minutes and sop for at least 15
minutes. If irritation or pain persists, seek m edical attention. Com pletely
decontaminate clothing, shoes and leather goods before reuse or discard.
Eye contact If eye contact with contents of an open battery occurs, imm ediately flush the
contaminated eye(s) with lukewarm , gently flowing water for at least 15 minutes
while holding the eyelids open. Neutral saline solution m ay be used as soon as it is
av ailable. If necessary, continue flushing during transport to em ergency care
facility. Take care not to rinse contaminated water into the unaffected eye or onto
face. Quickly transport victim to an em ergency care facility.
Ingestion If ingestion of contents of an open battery occurs, never give anything by m outh if
victim is rapidly losing consciousness, or is unconscious or conv ulsing. Hav e victim
rinse m outh thoroughly with water. DO NOT INDUCE VOMITING. Have victim
drink 60 to 240 Ml (2-8 oz.) of water. If vomiting occurs naturally, hav e victim lean
forward to reduce risk of aspiration. Have victim rinse m outh with water again.
Quickly transport victim to an em ergency care facility.
Material Safety Data Sheet
Page 4 of 8
Section 5 – Fire-fighting Measures
Fire and
explosion
hazard
The batteries can leak and/or spout vaporized or decomposed and combustible
electrolyte fumes in case of exposure above 90 resulting from inappropriate use
or from the environment. Possible formation of hydrogen fluoride (HF) and
phosphorous oxides during fire. LiPF6 salt contained in the electrolyte releases
hydrogen fluoride (HF) in contact with water.
Suitable
extinguishing
Media
Suitable: CO2
Dry chemical or Foam extinguishers
Not to be used: Type D extinguishers
Special
exposure
hazards
Following cell overheating due to external source or due to improper use,
electrolyte leakage or battery container rupture may occur and release inner
component/material in the environment.
Eye contact: The electrolyte solution contained in the battery is irritant to ocular
tissues.
Skin contact: The electrolyte solution contained in the battery cause skin
irritantion.
Ingestion: The ingestion of the electrolyte solution causes tissue damage to throat
and gastro/respiratory tract.
Inhalation: Contents of a leaking or ruptured battery can cause respiratory tract,
mucus, membrane irritation and edema.
Special
protective
equipment
Use self-contained breathing apparatus to avoid breathing irritant fumes. Wear
protective clothing and equipment to prevent baby contact with electrolyte solution
Section 6 – Accidental Release Measures
Personal Precautions, protective equipm ent, and
em ergency procedures
Restrict access to area until com pletion of clean-
up. Do not touch the spilled m aterial. W ear
adequate personal protective equipm ent as
indicated in Section 8.
Environm ental Precautions Prev ent material from contaminating soil and
from entering sewers or waterways.
Methods and m aterials for Containm ent Stop the leak if safe to do so. Contain the spilled
liquid with dry sand or earth. Clean up spills
imm ediately.
Methods and m aterials for cleaning up Absorb spilled m aterial with an inert absorbent
dry sand or earth). Scoop contaminated
absorbent into an acceptable waste container.
Collect all contaminated absorbent and dispose
of according to directions in Section 13. Scrub
the area with detergent and water; collect all
contaminated wash water for proper disposal.
Material Safety Data Sheet
Page 5 of 8
Section 7 – Handling and Storage
The batteries should not be opened destroyed nor incinerated since they may leak or rupture and
release in the environment the ingredients they contain.
Handling Do not dism antle, open or shred secondary Li-
ion Battery Pack;
Don’t handling Li-ion Battery with m etalwork.
Do not open, dissem ble, crush or burn battery.
Ensure good v entilation/ exhaustion at the
workplace. Prevent form ation of dust.
Information about protection against explosions
and fires: Keep ignition sources away- Do not
smoke.
Storage Store in a cool (preferably below 30 ) and
ventilated area away from moisture, sources of
heat, open flames, food and drink. Keep
adequate clearance between walls and
batteries. Temperature above 90 may result
in battery leakage and rupture. Since short
circuit can cause burn, leakage and rupture
hazard, keep batteries in original packaging until
use and do not jumble them.
Other Manufacturer recommendations regarding
maximum recommended currents and operating
temperature range.
Applying pressure on deforming the battery may
lead to disassembly followed by eye, skin and
throat irritation.
Section 8 – Exposure Controls and Personal Protection
Personal Protective Equipm ent Respiratory Protection: Not necessary under
norm al conditions.
Skin and body Protection: Not necessary
under norm al conditions, W ear neoprene or
nitrile rubber glov es if handling an open or
leaking battery.
Hand protection: W ear neoprene or natural
rubber m aterial gloves if handling an open or
leaking battery.
Eye Protection: Not necessary under norm al
conditions, W ear safety glasses if handling an
open or leaking battery.
Other Protective Equipm ent Hav e a safety shower and eye wash fountain
readily av ailable in the immediate work area.
Hygiene Measures Do not eat, drink, or sm oke in work area.
Maintain good housekeeping.
Material Safety Data Sheet
Page 6 of 8
Section 9 - Physical and Chemical Properties
Physical
State
Form : Solid
Color: Grey
Odour: Monotony
Change in condition:
pH, with indication of the concentration Not applicable
Melting point/freezing point Not av ailable.
Boiling Point, initial boiling point and Boiling
range:
Not av ailable.
Flash Point Not av ailable.
Upper/lower flamm ability or explosive limits Not av ailable.
Vapor Pressure: Not applicable
Vapor Density: (Air = 1) Not applicable
Density/relative density Not av ailable.
Solubility in W ater: Insoluble
n-octanol/water partition coefficient Not av ailable.
Auto-ignition tem perature 130°C
Decom position tem perature Not av ailable.
Odout threshold Not av ailable.
Ev aporation rate Not av ailable.
Flamm ability (soil, gas) Not av ailable.
Viscosity Not applicable
Section 10 - Stability and Reactivity
Stability The product is stable under norm al conditions.
Conditions to Av oid (e.g. static discharge, shock
or vibration)
Do not subject Li-ion Battery to m echanical
shock.
Vibration encoutered during transportation does
not cause leakage, fire or explosion.
Do not disassem ble, crush, short or install with
incorrect polarity. Av oid mechanical or electrical
abuse.
Incom patible Materials Not Av ailable
Hazardous Decom position Products This m aterial m ay release toxic fum es if burned
or exposed to fire
Material Safety Data Sheet
Page 7 of 8
Possibility of Hazardous Reaction Not Av ailable
Section 11 - Toxicological Information
Irritation Risk of irritation occurs only if the cell is
m echanically, therm ally or electrically abused to
the point of com promising the enclosure. If this
occurs, irritation to the skin, eyes and respiratory
tract m ay occur.
Sensitization Not Av ailable
Neurological Effects Not Av ailable
Teratoaenicitv Not Av ailable
Reproductiv e Toxicity Not Av ailable
Mutagenicity (Genetic Effects) Not Av ailable
Toxicologically Synergistic Materials Not Av ailable
Section 12 - Ecological Information
General note: W ater hazard class 1(Self -assessm ent): slightly
hazardous for water.
Do not allow undiluted product or large quantities
of it to reach ground water, water course or
sewage system .
Anticipated behavior of a chemical product in
environm ent/possible environm ental
im pace/ecotoxicity
Not Av ailable
Mobility in soil Not Av ailable
Persistence and Degradability Not Av ailable
Bioaccum ulation potential Not Av ailable
Other Adv erse Effects Not Av ailable
Section 13 – Disposal Considerations
Product disposal recomm endation: Observ e local, state and federal laws and regulations.
Packaging disposal recomm endation: Be aware discarded batteries m ay cause fire, tape the
battery terminals to insulate them . Don’t disassem bly the battery. Com pletely discharge containers
no tear drops, no powder rest, scraped carefully). Containers m ay be recycled or re-used. Observ e
local, state and federal laws and regulations.
The potential effects on the environm ent and hum an health of the substances used in batteries and
accum ulators; the desirability of not disposing of waste batteries and accum ulators as unsorted
m unicipal waste and of participating in their separate collection so as to facilitate treatm ent and
recycling;
Material Safety Data Sheet
Page 8 of 8
Section 14 – Transport Information
14.1 Lithium ion battery containing Watt-hour rating is not more than 100Wh.
14.2 The lithium ion battery have been tested under provisions of the UN Manual of Test and
Criteria, the battery is passed the UN 38.3 test, Part III, sub-section 38.3 (withstanding a
1.2m drop test) and are classified as non-dangerous goods.
14.3 Lithium ion batteries can be treated as “Non-dangerous goods” under the United Nations
Recommendations on the Transport of Dangerous Goods, Special Provision 188, Provided
that packaging is strong and prevent products from short -circuit.
14.4 The Li-ion battery is complied with Section IA of PI965 (58th Edition-2017).
14.5 The consignment can be shipped as “Not Restricted” in accordance with the current edition-
58th of IATA- DGR-2017.
14.6 With regard to air transport, the following regulations are cited and considered:
The International Civil Aviation Organization (ICAO) Technical Instructions.
The International Air transport Association (IATA) Dangerous Goods Regulations.
The International Maritime Dangerous Goods (IMDG) Code.
The US Hazardous Materials Regulation (HMR) pursuant to a final rule issued by RSPA.
The Office of Hazardous Materials Safety within the US Department of Transportation (DOT)
Research and Special Programs Administration (RSPA)
Section 15 - Regulator y Information
The transport of rechargeable Lithium-ion batteries is regulated by various bodies (IATA, IMO, ADR,
US-DOT) that following the United Nations “Recommendations on the Transport of Dangerous
Goods, Model Regulations, 15th Revised edition - Ref. ST/SG/AG.10/1 Rev .15”
Depending on their lithium metal equivalent weight content, design, and ability to pass safety tests
defined by the UN in the “Recommendations on the Transport of Dangerous Goods-Manual of Tests
and Criteria- 4th Revised edition- Ref. ST/SG/AG.10/11 Rev .4 Amendment 1 <<Lithium Batteries>>”,
the Lithium-ion cells and the battery packs are not be assigned to the UN 3480 Class-9, that is
restricted for transport.
Individual Lithium-ion cells and battery packs with respectively less than 20 and 100 Wh per gram
that pass the UN – defined safety tests, are not restricted for transport.
Section 16 - Other Information
This inform ation has been compiled from sources considered to dependable and is, to the
best of our knowledge and belief, accurate and reliable as of the date compiled.
However, no representation, warranty (either expressed or implied) or guarantee is
made to the accuracy, reliability or completeness of the information contained hearin.
This information relates to t he specific materials designated and may not be valid for
such material used in combination with any other materials or in any process. It is the
user ’s responsibility to satisfy himself as to the suitability and com pleteness of this
information for his pa rticular use.
We do not accept liability for any loss or damage that may occur, whether direct, indirect,
incidental or consequential, from the use of this information. We do not offer warranty
against patent infringement.
Additional information is avail able by calling the telephone number above designated
purpose.
The End******************
Material Safety Data Sheet
Page 1 of 8
Material Safety Data Sheet
Lithium-ion Battery Pack
Model/type reference: LBP-350A
Tradem ark:
Nominal Voltage: 10.8VDC
Typical Capacity: 43.2W h
W eight: 755g
Shape and Physical Dim ension (mm): L: 387mm; W : 86mm; H: 38mm
Preparation Date: Sep. 12, 2017
Version num ber: V1.0
Manufacture: Shenzhen Longood Intelligent Electric Co., Ltd
Address: 8-4 Bldg, Tongfuyu Industrial Zone, Aiqun Rd,
Shangpai Community, Shiyan Town, Bao'an
District, Shenzhen, Guangdong, 518108, China
TEL: +86-0755-33236887
Compiled by: JIE YE
Approved by: YONGQING WEN
Material Safety Data Sheet
Page 2 of 8
Section 1- Chemical Product and Compan y Identification
1. Chemical Product Identification
Product name: Lithium-ion Battery Pack
Model: LBP-350A
2. Company Identification
Manufacturer /Supplier Nam e: Shenzhen Longood Intelligent Electric Co., Ltd
Address: 8-4 Bldg, Tongfuyu Industrial Zone, Aiqun Rd, Shangpai Community, Shiyan Town,
Bao'an District, Shenzhen, Guangdong, 518108, China
Telephone num ber of the manufacturer: +86-0755-33236887
E-m ail address:
Referenced docum ents: ISO 11014:2009 Safety data sheet for chemical products;
Section 2 – Hazards Identification
Preparation
hazards and
classification
W hen the battery is In extrem e pressure deform ation, high-tem perature
environm ent, ov erload, short-circuit condition, or disassem ble the battery, an
explosion of fire and chemical burn hazards m ay occur.
Apperance,
Color, and
Odor
Solid object with no odor, no color.
Primary
Route(s) of
Exposure
These chemicals are contained in a sealed stainless steel enclosure. Risk of
exposure occurs only if the cell is mechanically, thermally or electrically abused to
the point of com promising the enclosure. If this occurs, exposure to the electrolyte
solution contained within can occur by Inhalation, Ingestion, Eye contact and Skin
contact.
Potential
Health
Effects:
ACUTE (short term): see Section 8 for exposure controls In the ev ent that this
battery has been ruptured, the electrolyte solution contained within the battery
would be corrosiv e and can cause burns.
Inhalation: A battery volatilizes no gas unless it was dam aged. Dam aged battery
will volatilize little gas that m ay stim ulate the respiratory tract or cause an
anaphylaxis in serious condition.
Ingestion: Swallowing battery will be dam aged to the respiratory tract and cause
chemical burns to the stom ach; in serious conditions it will cause perm anent
dam age.
Skin: In norm al condition, contact between the battery and skin will not cause any
harm s. Contact with a damaged battery m ay cause skin allergies or chemical
burns.
Eye: in norm al condition, contact between the battery and eyes will not cause any
harm s. Howev er, the gas volatilize from a dam aged battery m ay be harmful to
eyes.
CHRONIC (long term): see Section 11 for additional toxicological data.
Medical
Conditions
Aggrav ated by
Exposure
Not applicable
Reported as
carcinogen
Not applicable
Material Safety Data Sheet
Page 3 of 8
Section 3 – Composition/Information on Ingredients
Li-ion Battery is a mixture.
Hazardous Ingredients
Chemical Name)
w/w CAS Number LD50(mg/kg)
oral-rat)
LC50(mg/L)
Aluminum Foil (Al) 2-8 7429-90-5 N/A N/A
Copper Foil (Cu) 5-10 7440-50-8 3.5(ipr-mouse) N/A
Linear and Cyclic Carbonic
Solvents(See other information)
5-15 N/APP 11000 (weighted
avg)
N/A
Graphite Powder 15-20 7440-44-0 440(ivn-mouse) N/A
Cobalt lithium manganese nickel
oxide
30-33 182442-95-1 N/A N/A
Polyvinylidene Fluoride
PVDF)(-[-CH2-CF2-]-n)
0.1-4 24937-79-9 N/A N/A
Steel, nickel and inert polymer 0.5-4 N/A N/A N/A
Lithium Hexafluorophosphate
LiPF6)
1-3 21324-40-3 1702 Rat:>20
Carbon black and others 0-3 1333-86-4 N/APP N/APP
Note: CAS num ber is Chemical Abstract Service Registry Num ber.
N/A=Not apply.
Section 4 – First-aid Measures
Inhalation Remove to fresh air and ventilate the contaminated area. Give oxygen or artificial
respiration if needed.
Skin contact If skin contact with contents of an open battery occurs, as quickly as possible
rem ove contaminated clothing, shoes and leather goods. Immediately flush with
lukewarm , gently flowing water for at least 15 minutes and sop for at least 15
minutes. If irritation or pain persists, seek m edical attention. Com pletely
decontaminate clothing, shoes and leather goods before reuse or discard.
Eye contact If eye contact with contents of an open battery occurs, imm ediately flush the
contaminated eye(s) with lukewarm , gently flowing water for at least 15 minutes
while holding the eyelids open. Neutral saline solution m ay be used as soon as it is
av ailable. If necessary, continue flushing during transport to em ergency care
facility. Take care not to rinse contaminated water into the unaffected eye or onto
face. Quickly transport victim to an em ergency care facility.
Ingestion If ingestion of contents of an open battery occurs, never give anything by m outh if
victim is rapidly losing consciousness, or is unconscious or conv ulsing. Hav e victim
rinse m outh thoroughly with water. DO NOT INDUCE VOMITING. Have victim
drink 60 to 240 Ml (2-8 oz.) of water. If vomiting occurs naturally, hav e victim lean
forward to reduce risk of aspiration. Have victim rinse m outh with water again.
Quickly transport victim to an em ergency care facility.
Material Safety Data Sheet
Page 4 of 8
Section 5 – Fire-fighting Measures
Fire and
explosion
hazard
The batteries can leak and/or spout vaporized or decomposed and combustible
electrolyte fumes in case of exposure above 90 resulting from inappropriate use
or from the environment. Possible formation of hydrogen fluoride (HF) and
phosphorous oxides during fire. LiPF6 salt contained in the electrolyte releases
hydrogen fluoride (HF) in contact with water.
Suitable
extinguishing
Media
Suitable: CO2
Dry chemical or Foam extinguishers
Not to be used: Type D extinguishers
Special
exposure
hazards
Following cell overheating due to external source or due to improper use,
electrolyte leakage or battery container rupture may occur and release inner
component/material in the environment.
Eye contact: The electrolyte solution contained in the battery is irritant to ocular
tissues.
Skin contact: The electrolyte solution contained in the battery cause skin
irritantion.
Ingestion: The ingestion of the electrolyte solution causes tissue damage to throat
and gastro/respiratory tract.
Inhalation: Contents of a leaking or ruptured battery can cause respiratory tract,
mucus, membrane irritation and edema.
Special
protective
equipment
Use self-contained breathing apparatus to avoid breathing irritant fumes. Wear
protective clothing and equipment to prevent baby contact with electrolyte solution
Section 6 – Accidental Release Measures
Personal Precautions, protective equipm ent, and
em ergency procedures
Restrict access to area until com pletion of clean-
up. Do not touch the spilled m aterial. W ear
adequate personal protective equipm ent as
indicated in Section 8.
Environm ental Precautions Prev ent material from contaminating soil and
from entering sewers or waterways.
Methods and m aterials for Containm ent Stop the leak if safe to do so. Contain the spilled
liquid with dry sand or earth. Clean up spills
imm ediately.
Methods and m aterials for cleaning up Absorb spilled m aterial with an inert absorbent
dry sand or earth). Scoop contaminated
absorbent into an acceptable waste container.
Collect all contaminated absorbent and dispose
of according to directions in Section 13. Scrub
the area with detergent and water; collect all
contaminated wash water for proper disposal.
Material Safety Data Sheet
Page 5 of 8
Section 7 – Handling and Storage
The batteries should not be opened destroyed nor incinerated since they may leak or rupture and
release in the environment the ingredients they contain.
Handling Do not dism antle, open or shred secondary Li-
ion Battery Pack;
Don’t handling Li-ion Battery with m etalwork.
Do not open, dissem ble, crush or burn battery.
Ensure good v entilation/ exhaustion at the
workplace. Prevent form ation of dust.
Information about protection against explosions
and fires: Keep ignition sources away- Do not
smoke.
Storage Store in a cool (preferably below 30 ) and
ventilated area away from moisture, sources of
heat, open flames, food and drink. Keep
adequate clearance between walls and
batteries. Temperature above 90 may result
in battery leakage and rupture. Since short
circuit can cause burn, leakage and rupture
hazard, keep batteries in original packaging until
use and do not jumble them.
Other Manufacturer recommendations regarding
maximum recommended currents and operating
temperature range.
Applying pressure on deforming the battery may
lead to disassembly followed by eye, skin and
throat irritation.
Section 8 – Exposure Controls and Personal Protection
Personal Protective Equipm ent Respiratory Protection: Not necessary under
norm al conditions.
Skin and body Protection: Not necessary
under norm al conditions, W ear neoprene or
nitrile rubber glov es if handling an open or
leaking battery.
Hand protection: W ear neoprene or natural
rubber m aterial gloves if handling an open or
leaking battery.
Eye Protection: Not necessary under norm al
conditions, W ear safety glasses if handling an
open or leaking battery.
Other Protective Equipm ent Hav e a safety shower and eye wash fountain
readily av ailable in the immediate work area.
Hygiene Measures Do not eat, drink, or sm oke in work area.
Maintain good housekeeping.
Material Safety Data Sheet
Page 6 of 8
Section 9 - Physical and Chemical Properties
Physical
State
Form : Solid
Color: Grey
Odour: Monotony
Change in condition:
pH, with indication of the concentration Not applicable
Melting point/freezing point Not av ailable.
Boiling Point, initial boiling point and Boiling
range:
Not av ailable.
Flash Point Not av ailable.
Upper/lower flamm ability or explosive limits Not av ailable.
Vapor Pressure: Not applicable
Vapor Density: (Air = 1) Not applicable
Density/relative density Not av ailable.
Solubility in W ater: Insoluble
n-octanol/water partition coefficient Not av ailable.
Auto-ignition tem perature 130°C
Decom position tem perature Not av ailable.
Odout threshold Not av ailable.
Ev aporation rate Not av ailable.
Flamm ability (soil, gas) Not av ailable.
Viscosity Not applicable
Section 10 - Stability and Reactivity
Stability The product is stable under norm al conditions.
Conditions to Av oid (e.g. static discharge, shock
or vibration)
Do not subject Li-ion Battery to m echanical
shock.
Vibration encoutered during transportation does
not cause leakage, fire or explosion.
Do not disassem ble, crush, short or install with
incorrect polarity. Av oid m echanical or electrical
abuse.
Incom patible Materials Not Av ailable
Hazardous Decom position Products This m aterial m ay release toxic fum es if burned
or exposed to fire
Possibility of Hazardous Reaction Not Av ailable
Material Safety Data Sheet
Page 7 of 8
Section 11 - Toxicological Information
Irritation Risk of irritation occurs only if the cell is
m echanically, therm ally or electrically abused to
the point of com promising the enclosure. If this
occurs, irritation to the skin, eyes and respiratory
tract m ay occur.
Sensitization Not Av ailable
Neurological Effects Not Av ailable
Teratoaenicitv Not Av ailable
Reproductiv e Toxicity Not Av ailable
Mutagenicity (Genetic Effects) Not Av ailable
Toxicologically Synergistic Materials Not Av ailable
Section 12 - Ecological Information
General note: W ater hazard class 1(Self -assessm ent): slightly
hazardous for water.
Do not allow undiluted product or large quantities
of it to reach ground water, water course or
sewage system .
Anticipated behavior of a chemical product in
environm ent/possible environm ental
im pace/ecotoxicity
Not Av ailable
Mobility in soil Not Av ailable
Persistence and Degradability Not Av ailable
Bioaccum ulation potential Not Av ailable
Other Adv erse Effects Not Av ailable
Section 13 – Disposal Considerations
Product disposal recomm endation: Observ e local, state and federal laws and regulations.
Packaging disposal recomm endation: Be aware discarded batteries m ay cause fire, tape the
battery terminals to insulate them . Don’t disassem bly the battery. Com pletely discharge containers
no tear drops, no powder rest, scraped carefully). Containers m ay be recycled or re-used. Observ e
local, state and federal laws and regulations.
The potential effects on the environm ent and hum an health of the substances used in batteries and
accum ulators; the desirability of not disposing of waste batteries and accum ulators as unsorted
m unicipal waste and of participating in their separate collection so as to facilitate treatm ent and
recycling;
Material Safety Data Sheet
Page 8 of 8
Section 14 – Transport Information
14.1 Lithium ion battery containing Watt-hour rating is not more than 100Wh.
14.2 The lithium ion battery have been tested under provisions of the UN Manual of Test and
Criteria, the battery is passed the UN 38.3 test, Part III, sub-section 38.3 (withstanding a
1.2m drop test) and are classified as non-dangerous goods.
14.3 Lithium ion batteries can be treated as “Non-dangerous goods” under the United Nations
Recommendations on the Transport of Dangerous Goods, Special Provision 188, Provided
that packaging is strong and prevent products from short -circuit.
14.4 The Li-ion battery is complied with Section IA of PI965 (58th Edition-2017).
14.5 The consignment can be shipped as “Not Restricted” in accordance with the current edition-
58th of IATA- DGR-2017.
14.6 With regard to air transport, the following regulations are cited and considered:
The International Civil Aviation Organization (ICAO) Technical Instructions.
The International Air transport Association (IATA) Dangerous Goods Regulations.
The International Maritime Dangerous Goods (IMDG) Code.
The US Hazardous Materials Regulation (HMR) pursuant to a final rule issued by RSPA.
The Office of Hazardous Materials Safety within the US Department of Transportation (DOT)
Research and Special Programs Administration (RSPA)
Section 15 - Regulator y Information
The transport of rechargeable Lithium-ion batteries is regulated by various bodies (IATA, IMO, ADR,
US-DOT) that following the United Nations “Recommendations on the Transport of Dangerous
Goods, Model Regulations, 15th Revised edition - Ref. ST/SG/AG.10/1 Rev .15”
Depending on their lithium metal equivalent weight content, design, and ability to pass safety tests
defined by the UN in the “Recommendations on the Transport of Dangerous Goods-Manual of Tests
and Criteria- 4th Revised edition- Ref. ST/SG/AG.10/11 Rev .4 Amendment 1 <<Lithium Batteries>>”,
the Lithium-ion cells and the battery packs are not be assigned to the UN 3480 Class-9, that is
restricted for transport.
Individual Lithium-ion cells and battery packs with respectively less than 20 and 100 Wh per gram
that pass the UN – defined safety tests, are not restricted for transport.
Section 16 - Other Information
This inform ation has been compiled from sources considered to dependable and is, to the
best of our knowledge and belief, accurate and reliable as of the date compiled.
However, no representation, warranty (either expressed or implied) or guarantee is
made to the accuracy, reliability or completeness of the information contained hearin.
This information relates to t he specific materials designated and may not be valid for
such material used in combination with any other materials or in any process. It is the
user ’s responsibility to satisfy himself as to the suitability and com pleteness of this
information for his pa rticular use.
We do not accept liability for any loss or damage that may occur, whether direct, indirect,
incidental or consequential, from the use of this information. We do not offer warranty
against patent infringement.
Additional information is avail able by calling the telephone number above designated
purpose.
The End******************
Any reproduction of this document must be done in full. No single part of this document may be reproduced without
permission from STS, All Test Data Presented in this report is only applicable to presented Test sample.
Shenzhen STS Test Services Co., Ltd.
1/F, Building B, Zhuoke Science Park, No.190,Chongqing Road,
Fuyong Street, Bao’an District, Shenzhen, Guangdong,China
TEL: +86-755 3688 6288 FAX: +86-755 3688 6277
MATERIAL SAFETY DATA SHEET
Report No:STS1803146B02
Issued for
SHENZHEN SHENLANAIFA ENERGY CO.,LTD
4 Floor, Qingxiang industrial pak, Dongfang Avenue,
SongGang, Baoan, ShenZhen
Product Name: Li-ion Polymer Battery
Model Name: SL603452
Nominal Voltage: DC 3.7V
Typical Capacity: 1200m Ah
Brand: N/A
Version number: V1.0
S
T
L
A
B
S
age 2 of 10 Report No.: STS1803146B02
Revision History
Rev. Issue Date Report No. Effect Page Contents
00 24 Mar.2018 STS1803146B02 ALL Initial Issue
age 3 of 10 Report No.: STS1803146B02
Section 1- Chemical Product and Company Identification
Product Identification: Li-ion Polymer Battery
Brand Name: N/A
Model Name: SL603452
Rated Power: 4.44Wh
Manufacture’s/Supplier Name: SHENZHEN SHENLANAIFA ENERGY CO.,LTD
Address: 4 Floor, Qingxiang industrial pak, Dongfang Avenue, SongGang,
Baoan, ShenZhen
Connect Person: Xiaoxin Su
Telephone: 15013469010
Email: -
Preparation Date: 24 Mar.2018
This MSDS was prepared by Shenzhen STS Test Services Co., Ltd.
Item Number: STS1803146B02
Referenced documents: ISO 11014:2009 Safety data sheet for chemical products
Compiled by :
Brad Liang Yuan )
Technical Manager :
Vita Li)
Authorized Signatory :
Bovey Yang)
age 4 of 10 Report No.: STS1803146B02
Section 2 – Hazards Identification
Preparation hazards and
classification
Not dangerous with normal use. Do not dismantle, open or shred
lithium-ion battery the ingredients contained within or their
ingredients products could be harmful.
Apperance, Color, and Odor Solid object with no odor,Silver color.
Primary Route(s) of Exposure
These chemicals are contained in a sealed stainless steel enclosure.
Risk of exposure occurs only if the cell is mechanically, thermally or
electrically abused to the point of comprom ising the enclosure. If this
occurs, exposure to the electrolyte solution contained within can
occur by Inhalation, Ingestion, Eye contact and Skin contact
Potential Health Effects
ACUTE (short term): see Section 8 for exposure controls In the
event that this battery has been ruptured, the electrolyte solution
contained within the battery would be corrosive and can cause burns.
Inhalation: Inhalation of materials from a sealed battery is not an
expected route of exposure. Vapors or mists from a ruptured b attery
may cause respiratory irritation.
Ingestion: Swallowing of materials from a sealed battery is not an
expected route of exposure. Swallowing the contents of an open
battery can cause serious chemical burns of mouth, esophagus, and
gastrointestinal tract.
Skin: Contact between the battery and skin will not cause any harm.
Skin contact with contents of an open battery can cause severe
irritation or burns to the skin. Eye: Contact between the battery and
the eye will not cause any harm. Eye contact wit h contents of an
open battery can cause severe irritation or burns to the eye.
CHRONIC (long term): see Section 11 for additional toxicological
data
Medical Conditions Aggravated
by Exposure Not applicable
Reported as carcinogen Not applicable
age 5 of 10 Report No.: STS1803146B02
Section 3 – Composition/Information on Ingredients
Hazardous Ingredients (Chemical
Name)
Concentration /
Concentration range
CAS Number
Lithium cobalt oxide 40-45% 12190-79-3
Graphite 15-24% 7782-42-5
Electrolyte 14-22% --
Aluminum 12-16% 7429-90-5
Copper 9-12% 7440-50-8
PVDF 0.5-1.0% 24937-79-9
Carbon Black 0.5-1.5% 1333-86-4
Li-ion Polymer Battery is a mixture.
Labeling according to EC directives.
No symbol and risk phrase are required.
Note:CAS number is Chemical Abstract Service Registry Number
N/A=Not apply.
Section 4 – First-aid Measures
Inhalation If contents of an opened battery are inhaled, remove source of contamination or move
victim to fresh air. Obtain medical advice.
Skin contact If skin contact with contents of an open battery occurs, as quickly as possible remove
contaminated clothing, shoes and leather goods. Immediately flush with lukewarm,
gently flowing water for at least 30 minutes. If irritation or pain persists, seek medical
attention. Completely decontaminate clothing, shoes and leather goods before reuse
or discard.
Eye contact If eye contact with contents of an open battery occurs, immediately flush the
contaminated eye(s) with lukewarm, gently flowing water for at least 30 minutes while
holding the eyelids open. Neutral saline solution may be used as soon as it is
available. If necessary, continue flushing during transport to emergency care facility.
Take care not to rinse contaminated water into the unaffected eye or onto face.
Quickly transport victim to an emergency care facility.
Ingestion If ingestion of contents of an open battery occurs, never give anything by mouth if
victim is rapidly losing consciousness, or is unconscious or convulsing. Have victim
rinse mouth thoroughly with water. DO NOT INDUCE VOMITING. Have victim drink 60
to 240 mL (2-8 oz.) of water. If vomiting occurs naturally, have victim lean forward to
reduce risk of aspiration. Have victim rinse mouth with water again. Quickly transport
victim to an emergency care facility.
Section 5 – Fire-fighting Measures
age 6 of 10 Report No.: STS1803146B02
Flammable
Properties
In the event that this battery has been ruptured, the electrolyte solution contain within
the battery would be flammable. Like any sealed container, battery cells may rupture
when exposed to excessive heat; this could result in the release of flammable or
corrosive materials.
Suitable
extinguishing
Media
Use extinguishing media suitable for the materials that are burning.
Unsuitable
extinguishing
Media
Not available
Explosion Data Sensitivity to Mechanical Impact: This may result in rupture in extreme
cases Sensitivity to Static Discharge: Not Applicable
Specific
Hazards arising
from the
chemical
Fires involving lithium-ion battery an be controlled with water. When water is used,
however, hydrogen gas may evolve. In a confined space, hydrogen gas can form an
explosive mixture. In this situation, smothering agents are recommended to extinguish
the fire
Protective
Equipment and
precautions for
firefighters
As for any fire, evacuate the area and fight the fire from a safe distance. Wear a
pressure-demand, self-contained breathing apparatus and full protective gear. Fight
fire from a protected location or a safe distance. Use NIOSH/MSHA approved full -face
self-contained breathing apparatus(SCBA) with full protective gear.
NFPA Health: 0 Flammability: 0 Instability: 0
Section 6 – Accidental Release Measures
Personal Precautions, protective equipment,
and emergency procedures
Restrict access to area until completion of clean-up. Do
not touch the spilled material. Wear adequate personal
protective equipment as indicated in Section 8.
Environmental Precautions Prevent material from contaminating soil and from
entering sewers or waterways.
Methods and materials for Containment Stop the leak if safe to do so. Contain the spilled liquid
with dry sand or earth. Clean up spills immediately.
Methods and materials for cleaning up Absorb spilled material with an inert absorbent (dry
sand or earth). Scoop contaminated absorbent into an
acceptable waste container. Collect all contaminated
absorbent and dispose of according to directions in
Section 13. Scrub the area with detergent and water;
collect all contaminated wash water for proper disposal.
Section 7 – Handling and Storage
age 7 of 10 Report No.: STS1803146B02
Handling Don’t handling lithium-ion battery ith metal work. Do not
open, dissemble, crush or burn battery. Ensure good
ventilation/ exhaustion at the workplace.
Prevent formation of dust.
Information about protection against explosions and
fires: Keep ignition sources away- Do not smoke.
Storage If the lithium-ion battery are subject to storage for such
a long term as more than 3 months, it is recommended
to recharge the lithium-ion battery periodically.
3 months: -10~+40, 45 to 85%RH
And recommended at 0~+35 for long period
storage.
The capacity recovery rate in the delivery state (50%
capacity of fully charged) after storage is assumed to be
80% or more.
The voltage for a long time storage shall be 3.7V-4.2V
range.
Do not storage lithium-ion battery haphazardly in a box
or drawer where they may short-circuit each other or be
short-circuited by other metal objects.
Keep out of reach of children.
Do not expose lithium-ion battery to heat or fire. Avoid
storage in direct sunlight.
Do not store together with oxidizing and acidic
materials.
Section 8 – Exposure Controls and Personal Protection
Engineering Controls Use local exhaust ventilation or other engineering
controls to control sources of dust, mist, fumes and
vapor.
Keep away from heat and open flame. Store in a cool,
dry place.
Personal Protective Equipment Respiratory Protection: Not necessary under normal
conditions.
Skin and body Protection: Not necessary under
normal conditions, Wear neoprene or nitrile rubber
gloves if handling an open or leaking battery.
Hand protection: Wear neoprene or natural rubber
material gloves if handling an open or leaking battery.
Eye Protection: Not necessary under normal
conditions, Wear safety glasses if handling an open or
leaking battery.
Other Protective Equipment Have a safety shower and eye wash fountain readily
available in the immediate work area.
Hygiene Measures Do not eat, drink, or smoke in work area. Maintain good
housekeeping.
age 8 of 10 Report No.: STS1803146B02
Section 9 - Physical and Chemical Properties
Physical State
Form: Solid
Color:Silver
Odour: Monotony
Change in condition:
pH, with indication of the conecentration Not applicable
Melting point/freezing point Not available.
Boiling Point, initial boiling point and Boiling
range: Not available.
Flash Point Not available.
Upper/lower flammability or explosive limits Not available.
Vapor Pressure: Not applicable
Vapor Density: (Air = 1) Not applicable
Density/relative desity Not available.
Solubility in Water: Insoluble
n-octanol/water partition coefficient Not available.
Auto-ignition temperature 130°C
Decomposition temperature Not available.
Odout threshold Not available.
Evaporation rate Not available.
Flammability (soil, gas) Not available.
Viscosity Not applicable
Section 10 - Stability and Reactivity
Stability The product is stable under normal conditions.
Conditions to Avoid (e.g. static discharge,
shock or vibration)
Do not subject lithium-ion batteryto mechanical shock.
Vibration encoutered during transportation does not
cause leakage, fire or explosion.
Do not disassemble, crush, short or install with incorrect
polarity. Avoid mechanical or electrical abuse.
Incompatible Materials Not Available
Hazardous Decomposition Products
This material may release toxic fumes if burned
or exposed to fire
Possibility of Hazardous Reaction Not Available
age 9 of 10 Report No.: STS1803146B02
Section 11 - Toxicological Information
Irritation
Risk of irritation occurs only if the cell is mechanically,
thermally or electrically abused to the point of
compromising the enclosure. If this occurs, irritation to
the skin, eyes and respiratory tract may occur.
Sensitization Not Available
Neurological Effects Not Available
Teratoaenicitv Not Available
Reproductive Toxicity Not Available
Mutagenicity (Genetic Effects) Not Available
Toxicologically Synergistic Materials Not Available
Section 12 - Ecological Information
General note:
Water hazard class 1(Self-assessment): slightly
hazardous for water.
Do not allow undiluted product or large quantities of it to
reach ground water, water course or sewage system.
Anticipated behavior of a chemical product
in environment/possible environmental
impace/ecotoxicity
Not Available
Mobility in soil Not Available
Persistence and Degradability Not Available
Bioaccumulation potential Not Available
Other Adverse Effects Not Available
Section 13 – Disposal Considerations
Product disposal recommendation: Observe local, state and federal laws and regulations.
Packaging disposal recommendation: Be aware discarded batteries may cause fire, tape the batt ery terminals
to insulate them. Don’t disassembly the battery. Completely discharge containers(no tear drops, no powder
rest, scraped carefully). Containers may be recycled or re-used. Observe local, state and federal laws and
regulations.
Section 14 – Transport Information
The lithium-ion battery tested according to the requirements of the UN manual of tests and Critera,Part
III,subsection 38.3.
Lithium-ion battery according to Section II/Section IB of Packing Instruction 965, or Section II of Packin g
Instrution 966~967 of the 2018 IATA Dangerous Goods regulations 59th Edition may be transported.and
Applicable U.S.DOT regulations for the safe transport of lithium-ion battery.
More information concerning shipping, testing, m arking and packaging can be obtained from label master at
http://www.labelmaster.com/.
age 10 of 10 Report No.: STS1803146B02
The packaging shall be adequate to avoid mechanical damage during transport,handling and stacking.The
materials and pack design shall be chosen so as to prevent the development of unintentional electrical
conduction,corrosion of the terminals and ingress of moisture.
The package must be handled with care and that a flammability hazard exists if the package is damaged.
Each package must be labeled with a lithium-ion battery handling label or in addition to be Class 9 hazard
label.
Polymer lithium-ion batteries can be treated as”Non-dangerous goods” under the United Nations
Recommendations on the Transport of Dangerous Goods, Special Provision 188, provide d that packaging is
strong and prevent the products from short-circuit.
With regard to transport, the following regulations are cited and considered:
The International Civil Aviation Organization(ICAO) Technical Instructions.
The International Air transport Association (IATA) Dangerous Goods Regulations.
UN number of lithium battery: Un3480 or Un3481;
UN Proper shipping name/Description(technical name):Lithium ion batteries of Lithium ion batteries
Contained in equipment of Lithium ion batteries packed with equipment.
The International Maritime Dangerous Goods (IMDG) Code.
For Polymer lithium-ion batteries by sea,provided that packaging is strong and prevent the products from
short-circuit.
UN number of lithium battery: Un3480 or Un3481;
UN Proper shipping name/Description(technical name):Lithium ion batteries of Lithium ion batteries
Contained in equipment of Lithium ion batteries packed with equipment.
The US Hazardous Materials Regulation (HMR) pursuant to a final rule issued by RSPA
The Office of Hazardous Materials Safety within the US Department of Transportations’ (DOT) Research and
Special Programs Administration (RSPA)
Section 15 - Regulatory Information
OSHA hazard communication standard (29 CFR 1910.1200)
Hazardous Non-hazardous
Section 16 - Other Information
The information above is believed to be accurate and represents the best information currently available to
us. However, concord makes no warranty of merchantability or any other warranty, express or impl ied, with
respect to such information, and we assume no liability resulting from its use. Users should make their own
investigations to determine the suitability of the information for their particular purposes. Although reasonable
precautions have been taken in the preparation of the data contained herein, it is offered solely for your
information, consideration and investigation. this material safety data s heet provides guidelines for the safe
handling and use of this product; it does not and cannot advise on all possible situations, therefore, your
specific use of this product should be evaluated to determine if additional precautions are required.
The data/information contained herein has been reviewed and approved for general release on the basis that
this document contains no export controlled information.
END OF THE REPORT