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Fire Block 113
SAFETY DATA SHEET / MATERIAL SAFETY DATA SHEET Date of Preparation: September 12, 2016
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Section 1: IDENTIFICATION
Product Name: Fire Block 113
Synonyms: Not available.
Product Use: Foam Sealant.
Restrictions on Use: Not available.
Manufacturer/Supplier: Selena USA, Inc.
486 Century Lane
Holland, MI 49423
Emergency Phone: ChemTrec: 1-800-424-9300
Date of Preparation of SDS: September 12, 2016
Section 2: HAZARD(S) IDENTIFICATION
GHS INFORMATION
Classification: Flammable Aerosols, Category 2
Gases Under Pressure - Compressed Gas
Skin Irritation, Category 2
Eye Irritation, Category 2B
Sensitization - Respiratory, Category 1
Sensitization - Skin, Category 1
Specific Target Organ Toxicity (Single Exposure), Category 3 - Respiratory
Irritation
Specific Target Organ Toxicity (Repeated Exposure), Category 2
LABEL ELEMENTS
Hazard
Pictogram(s):
Signal Word: Danger
Hazard
Statements:
Flammable aerosol.
Contains gas under pressure; may explode if heated.
Causes skin irritation.
Causes eye irritation.
May cause allergy or asthma symptoms or breathing difficulties if inhaled.
May cause an allergic skin reaction.
May cause respiratory irritation.
May cause damage to organs through prolonged or repeated exposure.
Precautionary Statements
Prevention: Obtain special instructions before use.
Keep away from heat, sparks, open flames, and hot surfaces. – No smoking.
Do not spray on an open flame or other ignition source.
Pressurized container: Do not pierce or burn, even after use.
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Do not breathe mist, vapors, or spray.
Avoid contact during pregnancy and while nursing.
Wash thoroughly after handling.
Do not eat, drink or smoke when using this product.
Use only outdoors or in a well-ventilated area.
Contaminated work clothing should not be allowed out of the workplace.
Wear protective gloves, protective clothing and eye protection.
Wear respiratory protection.
Response: If on skin: Wash with plenty of soap and water.
If inhaled: Remove person to fresh air and keep comfortable for breathing.
If in eyes: Rinse cautiously with water for several minutes. Remove contact
lenses, if present and easy to do. Continue rinsing.
If skin irritation or rash occurs: Get medical advice/attention.
If eye irritation persists: Get medical advice/attention.
If experiencing respiratory symptoms: Call a poison center or doctor.
Take off contaminated clothing and wash it before reuse.
Storage: Store in a well-ventilated place. Keep container tightly closed.
Store locked up.
Protect from sunlight.
Do not expose to temperatures exceeding 50°C/ 122°F.
Disposal: Dispose of contents/container in accordance with applicable regional, national
and local laws and regulations.
Hazards Not Otherwise Classified: Not applicable.
Ingredients with Unknown Toxicity: 8% of this product mixture consists of ingredient(s) of
unknown acute toxicity.
This material is considered hazardous by the OSHA Hazard Communication Standard, (29 CFR
1910.1200).
Section 3: COMPOSITION / INFORMATION ON INGREDIENTS
Hazardous Ingredient(s) Common name / Synonyms CAS No. % wt./wt.
Isocyanic acid,
polymethylenepolyphenylene ester
Polymeric Methylene Diphenyl
Diisocyanate (PMDI)
9016-87-9 30 - 60
2-Propanol, 1-chloro-, 2,2',2''-
phosphate
Tri-(2-chloroisopropyl)phosphate
(TCPP)
13674-84-5 6 - 12
Propane, 2-methyl- Isobutane 75-28-5 6 - 12
Methane, 1,1'-oxybis- Dimethyl ether 115-10-6 6 - 12
Morpholine, 4,4'-(oxydi-2,1-
ethanediyl)bis-
Dimorpholinodiethyl ether 6425-39-4 0.1 - 1
Exact percentage (concentration) of composition has been withheld as a trade secret.
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Section 4: FIRST-AID MEASURES
Inhalation: If inhaled: Remove person to fresh air and keep comfortable for breathing.
If experiencing respiratory symptoms: Call a poison center or doctor.
Acute and delayed symptoms and effects: May cause allergy or asthma
symptoms or breathing difficulties if inhaled. May cause respiratory
irritation. Signs/symptoms may include cough, sneezing, nasal discharge,
headache, hoarseness, and nose and throat pain. At room temperature,
MDI vapors are minimal due to low volatility. However, certain operations
may generate vapor or mist concentrations sufficient to cause respiratory
irritation and other adverse effects. Such operations include those in which
the material is heated, sprayed or otherwise mechanically dispersed.
Allergy-prone people who have been sensitized to isocyanates or even
have not been previously exposed to isocyanates may experience
symptoms at concentrations as low as 0.0014 ppm. Asthma sufferers or
people who easily get contact dermatitis should therefore not be exposed
to isocyanates.
Eye Contact: If in eyes: Rinse cautiously with water for at least 15 minutes. Remove
contact lenses, if present and easy to do. Continue rinsing. If eye irritation
persists: Get medical advice/attention.
Acute and delayed symptoms and effects: Causes eye irritation.
Signs/symptoms may include redness, swelling, pain, tearing, and blurred
or hazy vision. PMDI may cause severe watering, formation of solid
particles in the eye fluid, glaucoma, photophobia (sensitivity to light),
blepharospasm (uncontrollable winking), conjunctivitis (inflammation of the
mucous membranes of the eye lids with possible discharge), keratitis
(inflammation of the cornea) and damage the cornea (opacity or clouding).
Skin Contact: Remove the foam from skin using a cloth. Take off immediately all
contaminated clothing. Remove uncured foam from skin using delicate
solvent like acetone or mineral spirit (avoid contact with eyes). Hardened
foam may be removed by persistent washing with soap and large
quantities of water. If skin irritation or rash occurs: Get medical
advice/attention. W ash contaminated clothing before reuse.
Acute and delayed symptoms and effects: May cause an allergic skin
reaction. Causes skin irritation. Signs/symptoms may include localized
redness, swelling, and itching. Prolonged skin contact may cause redness,
swelling, blistering and possible skin sensitization (dermatitis). MDI
compounds have a mild tanning action on the skin.
Ingestion: If swallowed: Call a poison center or doctor if you feel unwell. If vomiting
occurs naturally, have victim lean forward to reduce the risk of aspiration.
Do NOT induce vomiting unless directed to do so by medical personnel.
Never give anything by mouth to an unconscious person.
Acute and delayed symptoms and effects: May cause gastrointestinal
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irritation. Signs/symptoms may include abdominal pain, stomach upset,
nausea, vomiting and diarrhea.
General Advice: In case of accident or if you feel unwell, seek medical advice immediately
(show the label or SDS where possible).
Note to Physicians: Symptoms may not appear immediately.
Section 5: FIRE-FIGHTING MEASURES
FLAMMABILITY AND EXPLOSION INFORMATION
Flammable aerosol. Contains gas under pressure; may explode if heated. Containers may
explode when heated. Ruptured cylinders may rocket.
Sensitivity to Mechanical Impact: This material is not sensitive to mechanical impact.
Sensitivity to Static Discharge: This material is sensitive to static discharge.
MEANS OF EXTINCTION
Suitable Extinguishing Media: Dry chemical, CO2 or water spray. Move containers from fire
area if you can do it without risk.
Unsuitable Extinguishing Media: Not available.
Products of Combustion: Oxides of carbon. Oxides of nitrogen. Oxides of phosphorus.
Hydrogen chloride. Chlorine. Isocyanate vapours.
Protection of Firefighters: Wear positive pressure self-contained breathing apparatus
(SCBA). Wear chemical protective clothing that is specifically
recommended by the manufacturer. It may provide little or no
thermal protection. Structural firefighters' protective clothing
will only provide limited protection.
Section 6: ACCIDENTAL RELEASE MEASURES
Emergency Procedures:
As an immediate precautionary measure, isolate spill or leak area.
Keep unauthorized personnel away. Stay upwind. Keep out of low
areas. Ventilate closed spaces before entering. Do not touch or
walk through spilled material.
Personal Precautions: Use personal protection recommended in Section 8.
Environmental Precautions: Prevent entry into waterways, sewers, basements or confined
areas.
Methods for Containment: Stop leak if you can do it without risk. Do not direct water at spill
or source of leak. Use water spray to reduce vapors or divert
vapor cloud drift.
Methods for Clean-Up: Remove from surfaces by scraping up excess material and
removing residual residue with cloth and solvent such as acetone
or mineral spirit, paint thinner, etc. Hardened foam can only be
removed physically or mechanically by scraping or buffing.
Other Information: See Section 13 for disposal considerations.
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Section 7: HANDLING AND STORAGE
Handling:
Do not swallow. Do not breathe mist, vapors, or spray. Avoid contact during pregnancy and
while nursing. Pressurized container: Do not pierce or burn, even after use. Obtain special
instructions before use. Do not handle until all safety precautions have been read and
understood. Keep away from heat, sparks, open flames, and hot surfaces. – No smoking. Do
not spray on an open flame or other ignition source. Wash thoroughly after handling. Do not eat,
drink or smoke when using this product. Use only outdoors or in a well-ventilated area.
Contaminated work clothing should not be allowed out of the workplace. See Section 8 for
information on Personal Protective Equipment.
Storage:
Store in a well-ventilated place. Keep container tightly closed. Store locked up. Protect from
sunlight. Protect from sunlight. Do not expose to temperatures exceeding 50°C / 122°F. Store
away from incompatible materials. See Section 10 for information on Incompatible Materials.
Keep out of the reach of children.
Section 8: EXPOSURE CONTROLS / PERSONAL PROTECTION
Exposure Guidelines
Component
Polymeric Methylene Diphenyl Diisocyanate (PMDI) [CAS No. 9016-87-9]
ACGIH: 0.005 ppm (TWA); (1985), For Methylene bisphenyl isocyanate (MDI)
OSHA: 0.02 ppm (C), 0.2 mg/m³ (C); For Methylene bisphenyl isocyanate (MDI)
Tri-(2-chloroisopropyl)phosphate (TCPP) [CAS No. 13674-84-5]
ACGIH: No TLV established.
OSHA: No PEL established.
Isobutane [CAS No. 75-28-5]
ACGIH: 1000 ppm (TWA); (2001)
OSHA: No PEL established.
Dimethyl ether [CAS No. 115-10-6]
ACGIH: No TLV established.
OSHA: No PEL established.
Dimorpholinodiethyl ether [CAS No. 6425-39-4]
ACGIH: No TLV established.
OSHA: No PEL established.
PEL: Permissible Exposure Limit
TLV: Threshold Limit Value
TWA: Time-Weighted Average
C: Ceiling
Engineering Controls: Use ventilation adequate to keep exposures (airborne levels
of dust, fume, vapour, gas, etc.) below recommended
exposure limits.
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PERSONAL PROTECTIVE EQUIPMENT (PPE)
Eye/Face Protection: Wear safety glasses. Ensure that eyewash stations are
close to the workstation location. Use equipment for eye
protection that meets the standards referenced by CSA
Standard CAN/CSA-Z94.3-92 and OSHA regulations in 29
CFR 1910.133 for Personal Protective Equipment.
Hand Protection: Wear protective gloves. Consult manufacturer specifications
for further information.
Skin and Body Protection : Wear protective clothing.
Respiratory Protection: Wear respiratory protection. If engineering controls and
ventilation are not sufficient to control exposure to below the
allowable limits then an appropriate NIOSH/MSHA approved
air-purifying respirator that meets the requirements of CSA
Standard CAN/CSA-Z94.4-11, or self-contained breathing
apparatus must be used. Supplied air breathing apparatus
must be used when oxygen concentrations are low or if
airborne concentrations exceed the limits of the air-purifying
respirators.
General Hygiene Considerations: Handle according to established industrial hygiene and
safety practices.
Section 9: PHYSICAL AND CHEMICAL PROPERTIES
Appearance: Rapidly curing foam dispensed by gaseous propellant
from an aerosol container.
Colour: Orange.
Odour: Characteristic.
Odour Threshold: Not available.
Physical State: Liquid (Aerosol foam.)
pH: Not available.
Melting Point / Freezing Point: Not available.
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Initial Boiling Point: Not available.
Boiling Range: Not available.
Flash Point: < 0 °C (32 °F)
Evaporation Rate: Not available.
Flammability (solid, gas): See Section 5.
Lower Flammability Limit: 1.8 % (Isobutane)
Upper Flammability Limit: 8.4 % (Isobutane)
Vapor Pressure: Not available.
Vapor Density: Not available.
Relative Density: 1.00 (Water = 1)
Solubilities: Insoluble in water; reacts with water.
Partition Coefficient: n-
Octanol/Water:
Not available.
Auto-ignition Temperature: Product is not self-igniting.
Decomposition Temperature: Not available.
Viscosity: Not available.
Percent Volatile, wt. %: Not available.
VOC content, wt. %: Not available.
Density: Not available.
Coefficient of Water/Oil Distribution: Not available.
Section 10: STABILITY AND REACTIVITY
Reactivity: Contact with incompatible materials. Sources of ignition. Exposure to
heat.
Chemical Stability: Stable under normal storage conditions.
Possibility of Hazardous
Reactions:
None known.
Conditions to Avoid: Contact with incompatible materials. Sources of ignition. Exposure to
heat.
Incompatible Materials: Acids. Bases. Oxidizers. Alkali metals. Metals. Amines. Alcohols.
Hazardous Decomposition Products: Isocyanate vapours. Carbon dioxide.
Section 11: TOXICOLOGICAL INFORMATION
EFFECTS OF ACUTE EXPOSURE
Product Toxicity
Oral: Not available.
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Dermal: Not available.
Inhalation: Not available.
Component Toxicity
Component CAS No. LD50 oral LD50 dermal LC50
Polymeric Methylene
Diphenyl Diisocyanate
9016-87-9 49000 mg/kg
(rat)
> 9400 mg/kg
(rabbit)
490 mg/m³ (rat);
4H
Tri-(2-chloroisopropyl)
phosphate (TCPP)
13674-84-5 1500 mg/kg
(rat)
Not available. Not available.
Isobutane 75-28-5 Not available. Not available. 570000 ppm
(rat); 15M
Dimethyl ether 115-10-6 Not available. Not available. 308000 mg/m³
(rat);
Dimorpholinodiethyl ether 6425-39-4 Not available. Not available. Not available.
Likely Routes of Exposure: Eye contact. Skin contact. Inhalation. Ingestion.
Target Organs: Skin. Eyes. Gastrointestinal tract. Respiratory system. Lungs.
Cardiovascular system. Nervous system.
Symptoms (including delayed and immediate effects)
Inhalation: May cause allergy or asthma symptoms or breathing difficulties if inhaled. May
cause respiratory irritation. Signs/symptoms may include cough, sneezing, nasal
discharge, headache, hoarseness, and nose and throat pain. At room temperature,
MDI vapors are minimal due to low volatility. However, certain operations may
generate vapor or mist concentrations sufficient to cause respiratory irritation and
other adverse effects. Such operations include those in which the material is
heated, sprayed or otherwise mechanically dispersed. Allergy-prone people who
have been sensitized to isocyanates or even have not been previously exposed to
isocyanates may experience symptoms at concentrations as low as 0.0014 ppm.
Asthma sufferers or people who easily get contact dermatitis should therefore not
be exposed to isocyanates.
Eye: Causes eye irritation. Signs/symptoms may include redness, swelling, pain, tearing,
and blurred or hazy vision. PMDI may cause severe watering, formation of solid
particles in the eye fluid, glaucoma, photophobia (sensitivity to light),
blepharospasm (uncontrollable winking), conjunctivitis (inflammation of the mucous
membranes of the eye lids with possible discharge), keratitis (inflammation of the
cornea) and damage the cornea (opacity or clouding).
Skin: May cause an allergic skin reaction. Causes skin irritation. Signs/symptoms may
include localized redness, swelling, and itching. Prolonged skin contact may cause
redness, swelling, blistering and possible skin sensitization (dermatitis). MDI
compounds have a mild tanning action on the skin.
Ingestion: May cause gastrointestinal irritation. Signs/symptoms may include abdominal pain,
stomach upset, nausea, vomiting and diarrhea.
Skin Sensitization: Hazardous by OSHA/WHMIS criteria. May cause sensitisation
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through skin contact.
Respiratory Sensitization: Hazardous by OSHA/WHMIS criteria. May cause sensitisation
through inhalation. Allergy-prone people who have been sensitized
to isocyanates or even have not been previously exposed to
isocyanates may experience symptoms at concentrations as low as
0.0014 ppm. Asthma sufferers or people who easily get contact
dermatitis should therefore not be exposed to isocyanates.
Medical Conditions
Aggravated By Exposure:
Not available.
EFFECTS OF CHRONIC EXPOSURE (from short and long-term exposure)
Target Organs: Skin. Eyes. Gastrointestinal tract. Respiratory system. Lungs.
Cardiovascular system. Nervous system.
Chronic Effects: Prolonged or repeated contact may dry skin and cause irritation.
Carcinogenicity: Product is not classified as a carcinogen. See Component
Carcinogenicity table below for information on individual components.
Component Carcinogenicity
Component ACGIH IARC NTP OSHA Prop 65
Polymeric Methylene Diphenyl
Diisocyanate (PMDI)
Not listed. Group 3 Not listed. Not listed. Not listed.
Mutagenicity: Not available.
Reproductive Effects: May cause harm to breast-fed children. Avoid contact during
pregnancy/while nursing.
Developmental Effects
Teratogenicity: Not available.
Embryotoxicity: Not available.
Toxicologically Synergistic Materials: Not available.
Section 12: ECOLOGICAL INFORMATION
Ecotoxicity: Not available.
Persistence / Degradability: Not available.
Bioaccumulation / Accumulation: Not available.
Mobility in Environment: Not available.
Other Adverse Effects: Not available.
Section 13: DISPOSAL CONSIDERATIONS
Disposal Instructions: Disposal should be in accordance with applicable regional, national
and local laws and regulations. Local regulations may be more
stringent than regional or national requirements.
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Section 14: TRANSPORT INFORMATION
U.S. Department of Transportation (DOT)
Proper Shipping Name: UN1950, AEROSOLS, 2.1
Class: 2.1
UN Number: UN1950
Packing Group: Not applicable.
Label Code:
Canada Transportation of Dangerous Goods (TDG)
Proper Shipping Name: UN1950, AEROSOLS, 2.1
Class: 2.1
UN Number: UN1950
Packing Group: Not applicable.
Label Code:
Section 15: REGULATORY INFORMATION
Chemical Inventories
US (TSCA)
The components of this product are in compliance with the chemical notification requirements of
TSCA.
Canada (DSL)
The components of this product are in compliance with the chemical notification requirements of
the NSN Regulations under CEPA, 1999.
Federal Regulations
Canada
This product has been classified in accordance with the hazard criteria of the Controlled
Products Regulations and the MSDS contains all the information required by the Controlled
Products Regulations.
WHMIS Classification: Class A - Compressed Gas.
Class B5 - Flammable Aerosols.
Class D2A - Respiratory sensitization.
Class D2B - Skin sensitization.
Class D2B - Skin irritant.
Class D2B - Eye irritant.
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Hazard Symbols:
United States
This SDS has been prepared to meet the U.S. OSHA Hazard Communication Standard, 29
CFR 1910.1200.
SARA Title III
Component Section 302
(EHS) TPQ
(lbs.)
Section
304 EHS
RQ (lbs.)
CERCLA
RQ (lbs.)
Section
313
RCRA
CODE
CAA
112( r ) TQ
(lbs.)
Polymeric
Methylene
Diphenyl
Diisocyanate
Not listed. Not listed. Not listed. 313# Not listed. Not listed.
Isobutane Not listed. Not listed. Not listed. Not listed. Not listed. 10000
Dimethyl ether Not listed. Not listed. Not listed. Not listed. Not listed. 10000
State Regulations
Massachusetts
US Massachusetts Commonwealth's Right-to-Know Law (Appendix A to 105 Code of
Massachusetts Regulations Section 670.000)
Component CAS No. RTK List
Polymeric Methylene Diphenyl Diisocyanate (PMDI) 9016-87-9 Listed.
Isobutane 75-28-5 Listed.
Dimethyl ether 115-10-6 Listed.
New Jersey
US New Jersey Worker and Community Right-to-Know Act (New Jersey Statute Annotated
Section 34:5A-5)
Component CAS No. RTK List
Polymeric Methylene Diphenyl Diisocyanate (PMDI) 9016-87-9 Listed.
Isobutane 75-28-5 SHHS
Dimethyl ether 115-10-6 SHHS
Note: SHHS = Special Health Hazard Substance
Pennsylvania
US Pennsylvania Worker and Community Right-to-Know Law (34 Pa. Code Chap. 301-323)
Component CAS No. RTK List
Isobutane 75-28-5 Listed.
Dimethyl ether 115-10-6 Listed.
Section 16: OTHER INFORMATION
Disclaimer:
The information contained in this document applies to this specific material as supplied. It may
not be valid for this material if it is used in combination with any other materials. It is the user’s
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responsibility to satisfy oneself as to the suitability and completeness of this information for his
own particular use.
Date of Preparation of SDS: September 12, 2016
SDS Expiry Date (Canada): September 11, 2019
Version: 1.1