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HomeMy WebLinkAboutCO2015-3815BASF We create chemistry Safety Data Sheet MasterSeal SL 180LIQ also GOLD LABEL LOOP SEALANT LIQUID Revision date: 2015/01/27 Page: 1 /11 Version: 3.0 (30605571/SDS GENUS/EN) 1. Identification Product identifier used on the label MasterSeal SL 18OLIQ also GOLD LABEL LOOP SEALANT LIQUID Recommended use of the chemical and restriction on use Recommended use': for industrial and professional users * The "Recommended use' identified for this product is provided solely to comply with a US Federal requirement and is not part of the seller's published specification. The terms of this Safety Data Sheet (SDS) do not create or infer any warranty, express or implied, including by incorporation into or reference in the seller's sales agreement. Details of the supplier of the safety data sheet Company: BASF CORPORATION 100 Park Avenue Florham Park, NJ 07932, USA Telephone: +1 973 245 -6000 Emergency telephone number C H E M T R E C: 1 -800- 424 -9300 BASF HOTLINE: 1 -800- 832 -HELP (4357) Other means of identification Chemical family: No data available. 2. Hazards Identification According to Regulation 2012 OSHA Hazard Communication Standard, 29 CFR Part 1910 1200 Classification of the product Asp. Tox. 1 Flam. Liq. 3 Skin Carr. /Irrit. 2 Eye Dam. /Irrit. 2A STOT SE 3 (irritating to respiratory system) Aspiration hazard Flammable liquids Skin corrosion /irritation Serious eye damage /eye irritation Specific target organ toxicity — single exposure Safety Data Sheet MasterSeal SL 180LIQ also GOLD LABEL LOOP SEALANT STOT RE 1 Specific target organ toxicity — repeated exposure Aquatic Acute 2 Hazardous to the aquatic environment - acute Aquatic Chronic 3 Hazardous to the aquatic environment - chronic Label elements Pictogram: O' Signal Word: Danger Hazard Statement H226 Flammable liquid and vapour. H319 Causes serious eye irritation. H315 Causes skin irritation. H304 May be fatal if swallowed and enters airways. H335 May cause respiratory irritation. H372 Causes damage to organs (Auditory organ) through prolonged or P243 repeated exposure. H412 Harmful to aquatic life with long lasting effects. H401 Toxic to aquatic life. Precautionary Statements (Prevention) P280 Wear protective gloves and eye /face protection. P271 Use only outdoors or in a well - ventilated area. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P273 Avoid release to the environment. P260 Do not breathe dust/gas /mist/vapours. P243 Take precautionary measures against static discharge. P241 Use explosion -proof electrical/ ventilating /lighting /equipment. P270 Do not eat, drink or smoke when using this product. P264 Wash with plenty of water and soap thoroughly after handling. P240 Ground /bond container and receiving equipment. P242 Use only non - sparking tools. Precautionary Statements (Response): Safety Data Sheet MasterSeal SL 180LIQ also GOLD LABEL LOOP SEALANT P312 Call a POISON CENTER or doctor /physician if you feel unwell. P305+ P351+ P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P314 Get medical advice /attention if you feel unwell. P301+ P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor /physician. P303+ P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water /shower. P304 +P340 IF INHALED: Remove person to fresh air and keep comfortable for breathing. P332+ P313 If skin irritation occurs: Get medical advice /attention. P331 Do NOT induce vomiting. P337+ P311 If eye irritation persists: Call a POISON CENTER or doctor /physician. P362+ P364 Take off contaminated clothing and wash before reuse. P370+ P378 In case of fire: Use... to extinguish. Precautionary Statements (Storage): P233 Keep container tightly closed. P403+ P235 Store in a well - ventilated place. Keep cool. P405 Store locked up. Precautionary Statements (Disposal): P501 Dispose of contents /container to hazardous or special waste collection point. Hazards not otherwise classified If.applicable information is provided in this section on other hazards which do not result in classification but which may contribute to the overall hazards of the substance or mixture. According to Regulation 1994 OSHA Hazard Communication Standard, 29 CFR Part 19101200 Emergency overview WARNING: FLAMMABLE LIQUID AND VAPOR. MAY CAUSE EYE, SKIN AND RESPIRATORY TRACT IRRITATION. MAY BE HARMFUL IF SWALLOWED. REPORTS HAVE ASSOCIATED REPEATED AND PROLONGED OCCUPATIONAL OVEREXPOSURE TO SOLVENTS WITH PERMANENT BRAIN AND NERVOUS SYSTEM DAMAGE. Overexposure may cause CNS depression including headache, dizziness, nausea and loss of consciousness. CONTAINS MATERIAL WHICH CAN CAUSE CANCER. Keep container tightly closed. Avoid all sources of ignition: heat, sparks, open flame. 3. Composition / Information on Ingredients According to Regulation 2012 OSHA Hazard Communication Standard: 29 CFR Part 1910 1200 CAS Number Content (WNW) Chemical name 100 -42 -5 >= 25.0 - < 50.0 % Styrene According to Regulation 1994 OSHA Hazard Communication Standard; 29 CFR Part 1910 1200 Safety Data Sheet MasterSeal SL 180LIQ also GOLD LABEL LOOP SEALANT CAS Number Content (WIW) Chemical name 100 -42 -5 >= 15.0 - <= 40.0 % Styrene 4. First -Aid Measures Description of first aid measures General advice: First aid personnel should pay attention to their own safety. Immediately remove contaminated clothing. If inhaled: If difficulties occur after vapour /aerosol has been inhaled, remove to fresh air and seek medical attention. If on skin: After contact with skin, wash immediately with plenty of water and soap. Under no circumstances should organic solvent be used. If irritation develops, seek medical attention. If in eyes: Wash affected eyes for at least 15 minutes under running water with eyelids held open, consult an eye specialist. If swallowed: Rinse mouth immediately and then drink plenty of water, seek medical attention. Do not induce vomiting unless told to by a poison control center or doctor. Most important symptoms and effects, both acute and delayed Symptoms: The most important known symptoms and effects are described in the labelling (see section 2) and /or in section 11. Hazards: No applicable information available. Indication of any immediate medical attention and special treatment needed Note to physician Treatment: Treat according to symptoms (decontamination, vital functions), no known specific antidote. 5. Fire - Fighting Measures Extinguishing media Suitable extinguishing media: foam, water spray, dry powder, carbon dioxide Unsuitable extinguishing media for safety reasons: water jet Special hazards arising from the substance or mixture Safety Data Sheet MasterSeal SL 180LIQ also GOLD LABEL LOOP SEALANT LIQUID Revision date: 2015/01/27 Page: 5/11 Version: 3.0 (30605571/SDS GEN US /EN) Hazards during fire- fighting: carbon dioxide, carbon monoxide, harmful vapours, nitrogen oxides, fumes /smoke, carbon black Advice for fire - fighters Protective equipment for fire- fighting: Wear a self- contained breathing apparatus. Further information: The degree of risk is governed by the burning substance and the fire conditions. If exposed to fire, keep containers cool by spraying with water. Collect contaminated extinguishing water separately, do not allow to reach sewage or effluent systems. Contaminated extinguishing water must be disposed of in accordance with official regulations. 6. Accidental release measures Personal precautions, protective equipment and emergency procedures Do not breathe vapour /aerosol /spray mists. Wear eye /face protection. If exposed to high vapour concentration, leave area immediately. Use personal protective clothing. Handle in accordance with good building materials hygiene and safety practice. Environmental precautions Contain contaminated water /firefighting water. Do not discharge into drains /surface waters /groundwater. Methods and material for containment and cleaning up For small amounts: Pick up with inert absorbent material (e.g. sand, earth etc.). Dispose of contaminated material as prescribed. For large amounts: Pump off product. 7. Handling and Storage Precautions for safe handling Avoid aerosol formation. Avoid inhalation of mists /vapours. Avoid skin contact. No special measures necessary provided product is used correctly. Conditions for safe storage, including any incompatibilities No applicable information available. Suitable materials for containers: tinned carbon steel (Tinplate) Further information on storage conditions: Keep only in the original container in a cool, dry, well - ventilated place away from ignition sources, heat or flame. Protect from direct sunlight. Protect from temperatures below: 0 °C The packed product must be protected from temperatures below the indicated one. 8. Exposure Controls /Personal Protection Components with occupational exposure limits Safety Data Sheet MasterSeal SL 180LIQ also GOLD LABEL LOOP SEALANT LIQUID Revision date : 2015/01/27 Page: 6/11 Version: 3.0 (30605571/SDS GENUS/EN) Styrene OSHA PEL TWA value 100 ppm ; CLV 200 ppm ;max. conc. 600 ppm ; STEL value 100 ppm 425 mg /m3 ; TWA value 50 ppm 215 mg /m3 ; ACGIH TLV TWA value 20 ppm ; STEL value 40 ppm ; Advice on system design: No applicable information available. Personal protective equipment Respiratory protection: Wear a NIOSH- certified (or equivalent) respirator as necessary. Hand protection: Wear chemical resistant protective gloves., Manufacturer's directions for use should be observed because of great diversity of types. Eye protection: Safety glasses with side - shields. Body protection: Impermeable protective clothing General safety and hygiene measures: Do not inhale gases /vapours /aerosols. Avoid contact with the skin, eyes and clothing. Avoid exposure - obtain special instructions before use. Handle in accordance with good building materials hygiene and safety practice. Wearing of closed work clothing is recommended. When using, do not eat, drink or smoke. Hands and /or face should be washed before breaks and at the end of the shift. At the end of the shift the skin should be cleaned and skin -care agents applied. Gloves must be inspected regularly and prior to each use. Replace if necessary (e.g. pinhole leaks). 9. Physical and Chemical Properties Form: liquid Odour: pungent odour Odour threshold: No data available. Colour: Purple pH value: not applicable Melting point: No applicable information available. Boiling point: No applicable information available. Information on: Styrene Boiling point: ---------------------------------- 145'C ( 1,013 hPa) Literature data. Sublimation point: No applicable information available. Flash point: 32 °C (ASTM D3278) Flammability: No applicable information available. Lower explosion limit: No applicable information available. Upper explosion limit: No applicable information available. Autoignition: 490'C Information on: Styrene Autoignition: 490'C Literature data. Vapour pressure: No applicable information available Safety Data Sheet MasterSeal SL 180LIQ also GOLD LABEL LOOP SEALANT LIQUID Version: 3.0 (30605571/SDS GEN US /EN) Information on: Styrene Vapour pressure: ---------------------------------- 6.67 hPa ( 20 °C) (measured) Literature data. Density: approx. 1.13 ( 25 °C) g /cm3 Relative density: No applicable information available. Bulk density: not applicable Vapour density: No applicable information available. Partitioning coefficient n- No data available. octanol /water (log Pow): Thermal decomposition: No decomposition if stored and handled as prescribed /indicated. Viscosity, dynamic: No applicable information available. Viscosity, kinematic: No applicable information available. Solubility (quantitative): No applicable information available. Solubility (qualitative): No applicable information available. Evaporation rate: No applicable information available. Other Information: If necessary, information on other physical and chemical parameters is indicated in this section. 10. Stability and Reactivity Reactivity No hazardous reactions if stored and handled as prescribed /indicated. Oxidizing properties: Based on its structural properties the product is not classified as oxidizing. Chemical stability The product is stable if stored and handled as prescribed /indicated. Possibility of hazardous reactions The product is stable if stored and handled as prescribed /indicated. Risk of polymerization. Conditions to avoid See MSDS section 7 - Handling and storage. Incompatible materials strong acids, strong bases, strong oxidizing agents, strong reducing agents Hazardous decomposition products Decomposition products: No hazardous decomposition products if stored and handled as prescribed /indicated. Thermal decomposition: No decomposition if stored and handled as prescribed /indicated. 11. Toxicological information Primary routes of exposure Safety Data Sheet MasterSeal SL 180LIQ also GOLD LABEL LOOP SEALANT mevision uate : wi oioi iz r Page: 8/11 Version: 3.0 (30605571/SDS GEN US /EN) Routes of entry for solids and liquids are ingestion and inhalation, but may include eye or skin contact. Routes of entry for gases include inhalation and eye contact. Skin contact may be a route of entry for liquefied gases. Acute Toxicity /Effects Acute toxicity Assessment of acute toxicity: No applicable information available. Oral No applicable information available Inhalation No applicable information available Dermal No applicable information available Assessment other acute effects Assessment of STOT single: Causes temporary irritation of the respiratory tract. Irritation / corrosion Assessment of irritating effects: Eye contact causes irritation. Skin contact causes irritation. Aspiration Hazard May also damage the lung at swallowing (aspiration hazard). Chronic Toxicity /Effects Repeated dose toxicitv Assessment of repeated dose toxicity: Repeated exposure to small quantities may affect certain organs. Carcinogenicity Information on: Styrene Assessment of carcinogenicity: IARC (International Agency for Research on Cancer) has classified this substance as group 28 (The agent is possibly carcinogenic to humans). NTP listed as reasonably anticipated to be a human carcinogen. Other Information The product has not been tested. The statement has been derived from the properties of the individual components. Symptoms of Exposure The most important known symptoms and effects are described in the labelling (see section 2) and /or in section 11. Safety Data Sheet MasterSeal SL 18OLIQ also GOLD LABEL LOOP SEALANT Version: 3.0 (30605571/SDS GEN US /EN) 12. Ecological Information Toxicity Aquatic toxicity Assessment of aquatic toxicity: Acutely harmful for aquatic organisms. May cause long -term adverse effects in the aquatic environment. Aquatic toxicity Information on: Styrene Assessment of aquatic toxicity: Acutely toxic for aquatic organisms. Harmful to aquatic organisms based on long -term (chronic) toxicity study data. Toxicity to fish Information on: Styrene LC50 (96 h) 4.02 mo, Pimephales promelas (other, Flow through.) Literature data. Aquatic invertebrates Information on: Styrene EC50 (48 h) 4.7 mo, Daphnia magna (OECD Guideline 202, part 1, Flow through.) Literature data. Aquatic plants Information on: Styrene EC50 (72 h) 4.9 mo (growth rate), Selenastrum capricornutum (other) Literature data. EC10 (96 h) 0.28 mg1l (growth rate), Desmodesmus subspicatus (other) Microorganisms /Effect on activated sludge Toxicity to microorganisms Information on: Styrene OECD Guideline 209 aquatic activated sludge /EC20 (30 min): 140 mg11 Additional information Other ecotoxicological advice: Do not discharge product into the environment without control. The product has not been tested. The statements on ecotoxicology have been derived from the properties of the individual components. Safety Data Sheet MasterSeal SL 180LIQ also GOLD LABEL LOOP SEALANT LIQUID Revision date: 2015/01/27 Page: 10/11 Version: 3.0 (30605571/SDS GEN US /EN) 13. Disposal considerations Waste disposal of substance: Dispose of in accordance with national, state and local regulations. Residues should be disposed of in the same manner as the substance /product. Do not discharge into drains /surface waters /groundwater. Container disposal: Contaminated packaging should be emptied as far as possible; then it can be passed on for recycling after being thoroughly cleaned. 14. Transport Information Land transport USDOT Hazard class: Packing group: ID number: Hazard label: Proper shipping name: Sea transport IMDG Hazard class: Packing group: ID number: Hazard label: Marine pollutant: Proper shipping name: Air transport IATA/ICAO Hazard class: Packing group: ID number: Hazard label: Proper shipping name: 15. Regulatory Information Federal Regulations 3 III UN 1866 3 RESIN SOLUTION 3 UN 1866 3 NO RESIN SOLUTION 3 III UN 1866 3 RESIN SOLUTION Registration status: Chemical TSCA, US released / listed EPCRA 311/312 (Hazard categories): Reactivity; Acute; Chronic; Fire Safety Data Sheet MasterSeal SL 180LIQ also GOLD LABEL LOOP SEALANT EPCRA 313: CAS Number Chemical name 100 -42 -5 Styrene CERCLA RQ CAS Number Chemical name 1000 LBS 100 -42 -5 Styrene State regulations State RTK CAS Number Chemical name MA, NJ, PA 100 -42 -5 Styrene NFPA Hazard codes: Health: 2 Fire: 3 Reactivity: 1 Special: HMIS III rating Health: 2 Flammability: 3 Physical hazard:1 16. Other Information SDS Prepared by: BASF NA Product Regulations SIDS Prepared on: 2015/01/27 We support worldwide Responsible Care(D initiatives. We value the health and safety of our employees, customers, suppliers and neighbors, and the protection of the environment. Our commitment to Responsible Care is integral to conducting our business and operating our facilities in a safe and environmentally responsible fashion, supporting our customers and suppliers in ensuring the safe and environmentally sound handling of our products, and minimizing the impact of our operations on society and the environment during production, storage, transport, use and disposal of our products. IMPORTANT: WHILE THE DESCRIPTIONS, DESIGNS, DATA AND INFORMATION CONTAINED HEREIN ARE PRESENTED IN GOOD FAITH AND BELIEVED TO BE ACCURATE, IT IS PROVIDED FOR YOUR GUIDANCE ONLY. BECAUSE MANY FACTORS MAY AFFECT PROCESSING OR APPLICATION /USE, WE RECOMMEND THAT YOU MAKE TESTS TO DETERMINE THE SUITABILITY OF A PRODUCT FOR YOUR PARTICULAR PURPOSE PRIOR TO USE. NO WARRANTIES OF ANY KIND, EITHER EXPRESSED OR IMPLIED, INCLUDING WARRANTIES OF MERCHANTABILITY OR FITNESS FOR A PARTICULAR PURPOSE, ARE MADE REGARDING PRODUCTS DESCRIBED OR DESIGNS, DATA OR INFORMATION SET FORTH, OR THAT THE PRODUCTS, DESIGNS, DATA OR INFORMATION MAY BE USED WITHOUT INFRINGING THE INTELLECTUAL PROPERTY RIGHTS OF OTHERS. IN NO CASE SHALL THE DESCRIPTIONS, INFORMATION, DATA OR DESIGNS PROVIDED BE CONSIDERED A PART OF OUR TERMS AND CONDITIONS OF SALE. FURTHER, YOU EXPRESSLY UNDERSTAND AND AGREE THAT THE DESCRIPTIONS, DESIGNS, DATA, AND INFORMATION FURNISHED BY OUR COMPANY HEREUNDER ARE GIVEN GRATIS AND WE ASSUME NO OBLIGATION OR LIABILITY FOR THE DESCRIPTION, DESIGNS, DATA AND INFORMATION GIVEN OR RESULTS OBTAINED, ALL SUCH BEING GIVEN AND ACCEPTED AT YOUR RISK. END OF DATA SHEET Material Safety Data Sheet BASF The Chemical Company GOLD LABEL ALL SEASON LOOP SEALANT POWDER Version 1.4 06128/2006 1. PRODUCT AND COMPANY INFORMATION Company BASF Building Systems 546 -93 -0 889 Valley Park Drive 1317 -61 -9 Shakopee, MN 55379 Telephone 952- 496 -6000 Emergency telephone number (800) 424 -9300 (703) 527 -3887 (Outside Continental US) Product name GOLD LABEL ALL SEASON LOOP SEALANT POWDER MSDS ID No. 10183 TSCA Inventory All components of this product are included, or are exempt from inclusion, in the EPA Toxic Substances Control Act (TSCA) Chemical Substance Inventory. Canadian DSL All components of this product are included, or are exempt from inclusion, in the Canadian Domestic Substance List (DSL). Product Use Description Sealant 2. HAZARDOUS INGREDIENTS Chemical CAS No. LIMESTONE 1317 -65 -3 MAGNESIUM CARBONATE 546 -93 -0 IRON OXIDE 1317 -61 -9 SILICA, CRYSTALLINE QUARTZ 14808 -60 -7 3. HAZARDS IDENTIFICATION HMIS® Rating WHMIS Class Primary Routes of Entry Effects of Overexposure Inhalation Skin HEALTH 2- D2B E TLV STEL 5 mg /m3 N.E. 10 mg /m3 N.E. 3 mg /m3 N.E. 0.05 mg /m3 N.E. Ingestion Inhalation Eye contact Skin contact FLAMMABILITY 0 PEL CEIL 5 mg /m3 N.E. 5 mg /m3 N.E. N.E. N.E. 0.1 mg /m3 N.E PHYSICAL HAZARD 1 Wei ht % 60.00 - 100.00 % 1.00-5.00% 1.00-5.00% 0.10-1.00% Inhalation of dust can cause coughing and labored breathing and possible temporary but reversible irritation on mucous membranes and respiratory tract. Can cause slight to moderate irritation due to abrasive action. In combination with Page 1 of 7 Material Safety Data Sheet BASF The Chemical Company GOLD LABEL ALL SEASON LOOP SEALANT POWDER Version 1.4 06/28/2006 Flush eyes with water, lifting upper and lower lids occasionally for 15 minutes. Seek water, repeated or prolonged dermal exposure can cause moderate to severe alkali medical attention. burns. Eyes Can cause severe irritation, redness, tearing and blurred vision. Prolonged or repeated water. Seek medical advice. contact can cause burns and possibly corneal injury. Ingestion Irritating to mouth, throat and stomach. Chronic exposure This product contains Crystalline (quartz) Silica which has been listed as a human person vomits, place him /her in the recovery position. carcinogen by NTP (Group 1) and IARC (Human Carcinogen) and a Suspected Human Remove victim from exposure. If difficulty with breathing, administer oxygen. If breathing Carcinogen by ACGIH (category A2). Repeated or prolonged over exposure to free has stopped administer artificial respiration, preferably mouth -to- mouth. Seek immediate respirable Crystalline (quartz) silica can cause silicosis or other delayed and serious lung medical attention. injury. Repeated or prolonged overexposure to free respirable silica can cause silicosis or other delayed and serious lung injury. Carcinogenicity ACGIH IARC NTP OSHA - -- _ _ ; LIMESTONE _ _ - -_... — - - -- '. N.E. TN.E �, N E. ' N.E. _ _ ___ _ MAGNESIUM CARBONATE _ _ � N.E. ! N.E N.E. N.E. i - IRON OXIDE_ __ -- - - - - - -- - - - -- - - --- - -- - _.._..---- r- - - - - -- -,. N. E. N.E. SILICA, CRYSTALLINE QUARTZ _ Suspected human Human carcinogen N.E. carcinogen. 4. FIRST AID MEASURES Eye contact Flush eyes with water, lifting upper and lower lids occasionally for 15 minutes. Seek medical attention. Skin contact Take off contaminated clothing and shoes immediately. Wash off with soap and plenty of water. Seek medical advice. Ingestion Do not induce vomiting without medical advice. If conscious, drink plenty of water. Call a physician immediately. Never give anything by mouth to an unconscious person. If a person vomits, place him /her in the recovery position. Inhalation Remove victim from exposure. If difficulty with breathing, administer oxygen. If breathing has stopped administer artificial respiration, preferably mouth -to- mouth. Seek immediate medical attention. 5. FIRE - FIGHTING MEASURES Flash point Autoignition temperature Lower explosion limit Upper explosion limit Suitable extinguishing media Not combustible. Not combustible. not applicable not applicable water fog carbon dioxide (CO2) dry chemical alcohol- resistant foam Page 2 of 7 Material Safety Data Sheet GOLD LABEL ALL SEASON LOOP SEALANT POWDER Version 1.4 Fire and Explosion Hazards Special Fire - fighting Procedures BASF The Chemical Company 06/28/2006 This product is alkaline and releases considerable heat on contact with small amounts of water. Avoid contact between resulting hot alkaline paste and metallic aluminum. Such contact could generate hydrogen gas. As in any fire, wear pressure demand self- contained breathing apparatus ( NIOSH approved or equivalent) and full protective gear. 6. ACCIDENTAL RELEASE MEASURES Methods for cleaning up Clean up promptly by sweeping or vacuum. Clean thoroughly. After cleaning, flush away traces with water. Keep in suitable, closed containers for disposal. Wear personal protective equipment (refer to section 8). 7. HANDLING AND STORAGE Handling Use only in area provided with appropriate ventilation. Keep out of reach of children. Avoid exceeding of the given occupational exposure limits (see section 2). Avoid formation of respirable particles. Storage Keep container tightly closed. 8. EXPOSURE CONTROLS / PERSONAL PROTECTION Eye protection Wear as appropriate: safety glasses with side - shields face - shield goggles Hand protection Wear as appropriate: impervious gloves Body Protection Wear as appropriate: preventive skin protection impervious clothing Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment. When workers are facing concentrations above the exposure limit they must use NIOSH approved respirators. Hygienic Practices Avoid contact with skin, eyes and clothing. Ensure adequate ventilation, especially in confined areas. Handle in accordance with good industrial hygiene and safety practice. Wash hands before breaks and at the end of workday. When using, do not eat, drink or smoke. Engineering Controls Local exhaust ventilation can be necessary to control any air contaminants to within their TLVs during the use of this product. 9. PHYSICAL AND CHEMICAL PROPERTIES Color . gray Page 3 of 7 Material Safety Data Sheet GOLD LABEL ALL SEASON LOOP SEALANT POWDER Version 1.4 Physical State powder Odor No information available. pH (at 100 %) not applicable Odor Threshold no data available Vapor Pressure not applicable Vapor Density not applicable Boiling point/range no data available Freeze Point no data available Water solubility slightly soluble Specific Gravity 2.6 Viscosity no data available Evaporation rate i no data available Partition coefficient (n- no data available octanol /water) VOC Concentration as applied 0 g/1 (less water and exempt solvents) 10. STABILITY AND REACTIVITY Stability Conditions to avoid Materials to avoid Hazardous decomposition products Hazardous polymerization Stable under recommended storage conditions. no data available strong acids and strong bases strong oxidizing agents . no data available Will not occur under normal conditions. BASF The Chemical Company 06/28/2006 11. TOXICOLOGICAL INFORMATION Acute inhalation toxicity Tvpe Value Species Exposure time Product LC50 no data available Component Page 4 of 7 Material Safety Data Sheet BASF The Chemical Company GOLD LABEL ALL SEASON LOOP SEALANT POWDER Version 1.4 LIMESTONE MAGNESIUM CARBONATE IRON OXIDE SILICA, CRYSTALLINE QUARTZ Acute oral toxicity Product Comoonent LIMESTONE MAGNESIUM CARBONATE IRON OXIDE SILICA, CRYSTALLINE QUARTZ Acute dermal toxicity Product Component LIMESTONE MAGNESIUM CARBONATE IRON OXIDE SILICA, CRYSTALLINE QUARTZ 12. ECOLOGICAL INFORMATION LC50 no data available LC50 no data available LC50 no data available LC50 no data available TVDe Value Species LD50 (Oral) no data available LD50 (Oral) 6,450 mg /kg rat LD50 (Oral) no data available LD50 (Oral) no data available LD50 (Oral) 1,300 mg /kg Type Value Species LD50 (Dermal) no data available LD50 (Dermal) no data available LD50 (Dermal) no data available LD50 (Dermal) no data available LD50 (Dermal) no data available Ecotoxicological Information : There is no data available for this product. 13. DISPOSAL CONSIDERATIONS Recommendations: Use excess product in an alternate beneficial application. Handle disposal of waste material in manner which complies with local, state, province and federal regulation. 14. TRANSPORT INFORMATION DOT Proper shipping name Not regulated IATA Proper shipping name Not regulated Page 5 of 7 06/28/2006 Material Safety Data Sheet The Chemical Company GOLD LABEL ALL SEASON LOOP SEALANT POWDER Version 1.4 06/28/2006 15. REGULATORY INFORMATION SARA 311/312 (RTK) This product has been reviewed according to the EPA'Hazard Categories' promulgated under Sections 311 and 312 of the Superfund Amendments and Reauthorization Act of 1986 (SARA Title III) and is considered, under applicable definitions, to meet the following categories: IMMEDIATE (ACUTE) HEALTH HAZARD DELAYED (CHRONIC) HEALTH HAZARD SARA 313 This product contains the following substances subject to the reporting requirements of Section 313 of Title III of the Superfund Amendments and Reauthorization Act of 1986 and 40 CFR Part 372: Weight % CAS No. Chemical Name This product contains no chemicals subject to the SARA 313 supplier notification requirements. CERCLA CERCLA section 103(a) specifically requires the person in charge of a vessel orfacility to report immediately to the National Response Center (NRC) a release of a hazardous substance whose amount equals or exceeds the assigned RQ. The following hazardous substances are contained in this product. RQ CAS No. Chemical Name No CERCLA chemicals exist in this product above reportable concentrations. TSCA Section 12(b) Export Notification This product contains the following chemical substances subject to the reporting requirements of TSCA 12(b) if exported from the United States: CAS No. Chemical Name There are no TSCA 12(b) Chemicals in this product. California Proposition 65 The chemical(s) noted below and contained in this product, are known to the state of California to cause cancer, birth defects or other reproductive harm. Unless otherwise specified in Section 2 of this MSDS, these chemicals are present at < 0.1 %: CAS No. Chemical Name 14808 -60 -7 SILICA, CRYSTALLINE QUARTZ 7439 -97 -6 MERCURY 7439 -92 -1 INORGANIC LEAD 7440 -38 -2 ARSENIC 7440 -43 -9 CADMIUM 7440 -02 -0 NICKEL 16. OTHER INFORMATION Legend N.E. -Not Established TLV - Threshold Limit Value STEL - Short Term Exposure Limit Page 6 of 7 Material Safety Data Sheet GOLD LABEL ALL SEASON LOOP SEALANT POWDER Version 1.4 PEL - Permissible Exposure Limit CEIL - Ceiling Prepared By . Environment, Health and Safety Department 7-1, 1 BASF The Chemical Company This information is furnished without warranty, representation, or license of any kind, except that this information is accurate to the best of the manufacturer's knowledge, or is obtained from sources believed by the manufacturer to be accurate and is not intended to be all inclusive. No warranty is expressed or implied regarding the accuracy of this information or the results to be obtained from its use thereof. The manufacturer assumes no responsibility for injuries proximately caused by use of the Material if reasonable safety procedures are not followed as stipulated in this Data Sheet. Additionally, the manufacturer assumes no responsibility for injuries proximately caused by abnormal use of the Material even if reasonable safety procedures are followed. Buyer assumes the risk in its use of the Material. End of MSDS. Page 7 of 7 MATERIAL SAFETY DATA SHEET FOR ODORIZED PROPANE 1. Chemical Product and Company Identification Product Name: Odorized Commercial Propane Name & Address: Chemical Name: Propane AmeriGas Propane, L.P. Chemical Family: Paraffinic Hydrocarbon P. O. Box 965 Formula: C3He Valley Forge, PA. 19482 Synonyms: Dimethylm ethane, LP -Gas, Liquefied Petroleum Gas (LPG), Propane, Propyl Hydride Transportation Emergency Number: For General Information, Call: CHEMTREC 1- 800 - 424 -9300 I- a1n- as7 -1nnn c.Fe+., no... 2. Composition / Information on Ingredients i INGREDIENT NAME /CAS NUMBER Propane / 74 -98 -6 ........ ............................... Ethane / 74 -84 -0 .......... ............................... Propylene / 115 -07 -1 .... ............................... Butanes / 106 -97 -8 ....... ............................... Ethyl Mercaptan / 75- 08- 1 .............................. PERCENTAGE .87.5 -100 13-7.0 0-5.0 0 -2.5- 0 - 50 ppm OSHA PEL ACGIH TLV Simple asphyxiant 1,000 ppm Simple asphyxiant Simple asphyxiant Simple asphyxiant 0.5 ppm 0.5 ppm WARNING: The intensity of the chemical odorant (e.g., ethyl mercaptan) may "fade" or diminish due to chemical oxidation, adsorption or absorption. Individuals with nasal perception problems may not be able to smell the odorant. Leaking propane from underground gas lines may lose its odor as it passes through certain soils. No odorant is effective 100% of the time. Therefore, circumstances can exist when individuals are in the presence of leaking propane and not be alerted by the smell. Contact AmeriGas for more information about odor, propane gas detectors and other safety considerations associated with the handling, storage and use of propane. 3. Hazards Identification DANGER! Flammable liquefied gas under pressure. Keep away from heat, sparks, flame, and all other ignition sources. Vapor replaces oxygen available for breathing and may cause suffocation in confined spaces. Use only with adequate ventilation. Reliance upon detection of odor may not provide adequate warning of potentially hazardous concentrations. Vapor is heavier than air; may collect at low levels. Liquid can cause freeze burn similar to frostbite. Do not get liquid in eyes, on skin, or on clothing. Avoid breathing vapor. Keep service valve closed when not in use. FIRE HAZARD (Red) HEALTH HAZARD <8> REACTIVITY (Blue) (Yellow) SPECIAL HAZARDS* Minimal 0 Moderate 2 Severe 4 Slight 1 Serious 3 *(Ref. NFPA 704) POTENTIAL HEALTH EFFECTS INFORMATION ROUTES OF EXPOSURE: Inhalation: Asphyxiation. Before suffocation could occur, the tower flammability limit of propane in air would be exceeded, possibly causing both an oxygen- deficient and explosive atmosphere. Exposure to concentrations >10% may cause dizziness. Exposure to atmospheres containing 19% or less oxygen will bring about unconsciousness without warning. Lack of sufficient oxygen may cause serious injury or death. Eye Contact: Contact with liquid can cause freezing of tissue. Skin Contact: Contact with liquid can cause frostbite. Skin Absorption: None. Ingestion: Ingestion is not expected to occur in normal use. However, liquid can cause freeze burn similar to frostbite. CHRONIC EFFECTS: None. CARCINOGENICITY: Propane is not listed by NTP, OSHA or ARC. 4. First Aid Measures INHALATION: Individuals suffering from lack of oxygen should be removed to fresh air. If victim is not breathing, administer artificial respiration. If breathing is difficult, administer oxygen. Obtain immediate medical assistance. EYE CONTACT: Gently flush eyes with lukewarm water. Obtain immediate medical assistance. SKIN CONTACT: Remove saturated clothes, shoes and jewelry. Immerse affected area in lukewarm water not exceeding 105° F. Keep immersed. Obtain immediate medical assistance. INGESTION: If swallowed, obtain immediate medical assistance. 5. Fire - Fighting Measures FLASH POINT: -156 °F (- 104 °C) AUTOIGNITION: 842 -F (432 °C) IGNITION TEMPERATURE IN AIR: 920 °F to 1120 °F (493 °C to 549 °C) FLAMMABLE LIMITS IN AIR (% by volume): Lower: 2.15% Upper: 9.6% EXTINGUISHING MEDIA: Dry chemical, CO2, water spray or fog for surrounding area. Do not attempt to extinguish fire until propane source is isolated. SPECIAL FIRE - FIGHTING INSTRUCTIONS: Evacuate all unnecessary personnel from the area. Allow only properly trained and protected emergency response personnel in area. A NIOSH approved self- contained breathing apparatus may be required. If gas flow cannot be shut off, do not attempt to extinguish fire. Allow fire to burn itself out. Use high volume water supply to cool exposed pressure containers and nearby equipment. Approach a flame - enveloped container from the sides, never from the ends. Use extreme caution when applying water to a container that has been exposed to heat or flame for more than a short time. For uncontrollable fires and /or when flame is impinging on container, withdraw all personnel and evacuate vicinity immediately. UNUSUAL FIRE AND EXPLOSION HAZARDS: Propane is heavier than air and can collect in low areas. Flash back along a vapor trail is possible. Pressure in a container can build up due to heat; and, container may rupture suddenly and violently without warning if pressure relief devices fail to function properly. If flames are against the container, withdraw immediately on hearing a rising sound, if venting increases in volume or intensity or if there is discoloration of the container due to fire. Propane released from a properly functioning relief valve on an overheated container can also become ignited. HAZARDOUS COMBUSTION PRODUCTS: None. 6. Accidental Release Measures IF MATERIAL IS RELEASED OR SPILLED: Evacuate the immediate area. Eliminate any possible sources of ignition and provide maximum ventilation. Shut off source of propane, if possible. If leaking from container or valve, contact your supplier or AmeriGas immediately. 7. Handling and Storage HANDLING PRECAUTIONS: Propane vapor is heavier than air and can collect in low areas that are without sufficient ventilation. Conduct system checks for leaks with a leak detector or solution, never with flame. Make certain the container service valve is shut off prior to connecting or disconnecting. If container valve does not operate properly, discontinue use and contact AmeriGas. Never insert an object (e.g., wrench, screwdriver, pry bar, etc.) into pressure relief valve or cylinder valve cap openings. Do not drop or abuse cylinders. Never strike an arc on a gas container or make a container part of an electrical circuit. See Section 16, "OTHER INFORMATION ", for additional precautions. STORAGE PRECAUTIONS: Store in a safe, authorized location (outside, detached storage is preferred) with adequate ventilation. Specific requirements are listed in NFPA 58, LP -GAS CODE. Isolate from heat and ignition sources. Containers should never be allowed to reach temperature exceeding 125 °F (52 °C). Isolate from combustible materials. Provide separate storage locations for other compressed and flammable gases. Propane containers should be separated from oxygen cylinders or other oxidizers by a minimum distance of 20 feet, or by a barrier of non - combustible material at least 5 feet high having a fire rating of at least 1/2 hour. Full and empty cylinders should be segregated. Keep cylinders in an upright position at all times so that each pressure relief valve communicates with the vapor space. Keep container valve closed and plugged or capped when not in use. Install protective caps when cylinders are not connected for use. Empty containers retain some residue and should be treated as if they were full. 8. Exposure Control / Personal Protection ENGINEERING CONTROLS Ventilation: Provide ventilation adequate to ensure propane does not reach a flammable mixture. RESPIRATORY PROTECTION General Use: None. Emergency Use: If concentrations are high enough to warrant supplied -air or NIOSH self- contained breathing apparatus, then the atmosphere may be flammable (See Section 5). Appropriate precautions must be taken regarding flammability. PROTECTIVE CLOTHING: Avoid skin contact with liquid propane because of possibility of freeze burn. Wear gloves and protective clothing that are impervious to the product for the duration of the anticipated exposure. EYE PROTECTION: Safety glasses, goggles or face shields are recommended when handling cylinders. OTHER PROTECTIVE EQUIPMENT: Safety shoes are recommended when handling cylinders. 2 9. Physical and Chemical Properties BOILING POINT: @ 14.7 psia = -44° F ( @1.00 atm.pressure = -42 °C) SPECIFIC GRAVITY OF VAPOR (Air = 1) at 60° F (15.56 °C): 1.50 SPECIFIC GRAVITY OF LIQUID (Water = 1) at 60° F: 0.504 VAPOR PRESSURE: @ 70° F (20 °C) = 127 psig; @ 105° F (45 °C) = 210 psig; @ 130 °F (55 °C) = 287 psig EXPANSION RATIO (From liquid to gas @ 14.7 psia): 1 to 270 SOLUBILITY IN WATER: Slight, 0.1 to 1.0% APPEARANCE AND ODOR: A colorless and tasteless gas at normal temperature and pressure. An odorant (ethyl mercaptan) is added to provide a strong unpleasant odor. Should a propane -air mixture reach the lower limits of flammability, the ethyl mercaptan concentration will be approximately 0.5 ppm in air. ODORANT WARNING: Odorant is added to aid in the detection of leaks. One common odorant is ethyl mercaptan, CAS No. 75 -08 -1. Odorant has a foul smell. The ability of people to detect odors varies widely. Also, the odor level can be reduced by certain chemical reactions with material in the propane system or when fugitive propane gas from underground leaks passes through certain soils. No odorant will be 100% effective in all circumstances. If the presence of the odorant is not obvious, notify AmeriGas immediately. 10. Stability and Reactivity STABILITY: Stable. Conditions to Avoid: Keep away from high heat, strong oxidizing agents and sources of ignition. REACTIVITY: Hazardous Decomposition Products: Under fire conditions, fumes, smoke, carbon monoxide, aldehydes and other decomposition products. In most applications where there is inadequate venting to the outside air, incomplete combustion will produce carbon monoxide (a toxic gas) and potentially develop concentrations that can create a serious health hazard. Hazardous Polymerization: Will not occur. 11. Toxicological Information Propane is non -toxic and is a simple asphyxiant. It has slight anesthetic properties. Higher concentrations may cause dizziness. IRRITANCY OF MATERIAL: None. SENSITIZATION TO MATERIAL: None REPRODUCTIVE EFFECTS: None MUTAGENICITY: None TERATOGENICITY: None SYNERGISTIC MATERIALS: None 12. Ecological Information No adverse ecological effects are expected. Propane does not contain any Class I or Class II ozone - depleting chemicals (40 CFR Part 82). Propane is not listed as a marine pollutant by DOT (49 CFR Part 171). 13. Disposal Considerations WASTE DISPOSAL METHOD: Do not attempt to dispose of residual or unused product in the container; return it to your supplier or contact AmeriGas for safe disposal. Residual product within a process system may be burned at a controlled rate if a suitable burning unit is available on site, and is done in accordance with federal, state and local regulations. 14. Transport Information DOT SHIPPING NAME: Liquefied Petroleum Gas IDENTIFICATION NUMBER: UN 1075 IMO SHIPPING NAME: Propane IMO IDENTIFICATION NUMBER: UN 1978 HAZARD CLASS: 2.1 (Flammable Gas) PRODUCT RQ: None SHIPPING LABEL (S): Flammable Gas PLACARD (WHEN REQUIRED): Flammable Gas SPECIAL SHIPPING INFORMATION: Container must be transported in a well - ventilated vehicle, secured, and in a position such that the pressure relief device is in communication with the vapor space. 3 15. Regulatory Information The following information concerns U.S. Federal regulatory requirements potentially applicable to this product. Not all such requirements are identified. Users of this product are responsible for their own regulatory compliance on a federal, state [provincial] and local level. U.S. FEDERAL REGULATIONS Environmental Protection Agency (EPA) Comprehensive Environmental Response, Compensation and Liability Act of 1980 (CERCLA) - 40 CFR Parts 117 and 302 Reportable Quantity (RQ): None Superfund Amendment and Reauthorization Act (SARA) • Sections 302/304: Relates to emergency planning on threshold planning quantities (TPQ) and release reporting based on reportable quantities (RQ) of EPA's extremely hazardous substances (40 CFR Part 355). Extremely Hazardous Substances: None Threshold Planning Quantity (TPQ): None Sections 311/312: Relates to submission of material safety data sheets (MSDSs) and chemical inventory reporting with identification of EPA - defined hazard classes (40 CFR Part 370). The hazard classes for this product are: IMMEDIATE: No PRESSURE: Yes DELAYED: No REACTIVITY: No FLAMMABLE: Yes • Section 313: Relates to submission of annual reports of release of toxic chemicals that appear in 40 CFR Part 372. Propane does not require reporting under Section 313. Toxic Substance Control Act (TSCA) Propane is listed on the TSCA inventory. Occupational Safety and Health Administration (OSHA) The following 29 CFR Parts may apply to propane: 29 CFR 1910.110: Storage and Handling of Liquefied Petroleum Gases 29 CFR 1910.119: Process Safety Management of Highly Hazardous Chemicals 29 CFR 1910.1200: Hazardous Communications Food and Drug Administration (FDA) 21 CFR 184.1655: Generally recognized as safe (GRAS) as a direct human food ingredient when used as a propellant, aerating agent and gas. 16. Other Information SPECIAL PRECAUTIONS: Use piping and equipment adequately designed to withstand pressure to be encountered. NFPA 58, LP -GAS CODE and OSHA 29 CFR 1910.10 require that all persons employed in handling LP -gases be trained in proper handling and operating procedures, which the employer shall document. Contact your propane supplier or AmeriGas to arrange for the required training. Allow only trained and qualified persons to install and service propane containers and systems. ISSUE INFORMATION Issue Date: December 2002 Issued By: Director of Safety Supersedes Date: April 2002 Phone Number: 1- 610 - 337 -7000 This material safety data sheet and the information it contains is offered to you in good faith as accurate. This Supplier does not manufacture this product, but is a supplier of the product that is independently produced by others. Much of the information contained in this data sheet was received from sources outside our Company. To the best of our knowledge this information is accurate, but this Supplier does not guarantee its accuracy or completeness. Health and safety precautions in this data sheet may not be adequate for all individuals and /or situations. It is the user's obligation to evaluate and use this product safely, comply with all applicable laws and regulations and to assume the risks involved in the use of this product. NO WARRANTY OR MERCHANTABILITY, FITNESS FOR ANY PARTICULAR PURPOSES, OR ANY OTHER WARRANTY IS EXPRESSED OR IS TO BE IMPLIED REGARDING THE ACCURACY OF COMPLETENESS OF THIS INFORMATION, THE RESULTS TO BE OBTAINED FROM THE USE OF THIS INFORMATION OR THE PRODUCT, THE SAFETY OF THIS PRODUCT, OR THE HAZARDS RELATED TO ITS USE. • Material Safety Data Sheet The information presenh5d intheseforms is believed to be correct and sufficient to meet the requirements of OSHA Hazard Communication standard (29 CFR 1910.1200) concerning workers right to know. This MSDS covers the following Aervoe aerosol product. PRODUCT NAME: 200 Clear Marking Coat SECTION I - MANUFACTURER IDENTIFICATION S' ,MANUFACTURER'S NAME: Aervoe Industries Inc. ADDRESS: 1198 Mark Circle, Gardnerville, NV 894J,Q INFORMATION PHONE: 775- 782 -0100 EMERGENCYPHONE:1- 800 -424 -9300 = DATE REVISED: January 22, 2007 REASON REVISED: Updated SECTION II - HAZARDOUS INGREDIENTS I SARA III INFORMATION OCCUPATIONAL EXPOSURE LIMITS HAZARDOUS WEIGHT OSHA ACG,IH LD50 SPECIES LC50 SPECIES COMPONENTS PERCENT PEL TLV & ROUTE & ROUTE\ (CAS 67 -64 -1) Hydrocarbon Propellant 1000 ppm 1000 ppm N I AV N / AV. (CAS68476 -86 -8) 10 -30 Aliphatic Petroleum Distillates NIAV 300ppm N /AV 9 N /AV (CAS 64742 -89 -8) 5-10 } , Propylene Glycol Methyl Ether Acetate . N 1 AV N ! AV N I AV N I AV (CAS108 -65 -6) 1-5 EthylAcetate 400ppm 400ppm N I AV N I AV (CAS 141 -78 -6) 1 - 5 Methyl Ethyl Ketone 200 ppm 200 ppm N / AV N /AV (CAS 78 -93 -3) 1 -5 n- ButylAcetate 150ppm 150 ppm -, N I AV N I AV (CAS 123 -86 -4) 1-5 'Indicates toxic chemical(s) subjectto the reporting requirements of section 313 of Title I I I and of 40 CFR 372 NOTE: N I AP = Not Applicable N 1 AV = Not Available j N l� 0 t -333 TEXAS SALES AND USE TAX RESALE CERTIFICATE I, the purchaser named above, claim the right to make a non - taxable purchase (for resale of the taxable items described below or on the attached order or invoice) from: Seller: Street address: City, State, ZIP Description of items to be purchased on the attached order or invoice: Description of the type of business activity generally engaged in or type of items normally sold by the purchaser: The taxable items described above, or on the attached order or invoice, will be resold, rented or leased by me within the geographical limits of the United States of America, its territories and possessions or within the geographical limits of the United I'Vlexican States, in their present form or attached to other taxable items to be sold. I understand that if I make any use of the items other than retention, demonstration ordisplaywhile holding them forsale, lease or rental, I must pay sales tax on the items at the time of use based upon either the purchase price or the fair market rental value for the period of time used. I understand that it is a criminal offense to give a resale certificate to the seller for taxable items that 1 know, at the time of purchase, are purchased for use rather than for the purpose of resale, lease or rental, and depending on the amount of tax evaded, the offense may range from a Class C misdemeanor to a felony of the second degree. Purchas r____ Title Date sign e �� /f President /6 - /9 -zo ft — This certificate should be furnished to the supplier. Do not send the completed certificate to the �f P,,hii, a........