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HomeMy WebLinkAboutCO2023-1062LIAR 3 0 7621 C//o Io Y, At CLL List of Hazardous Materials Stored Onsite and Amounts: - Isopropyl Alcohol (Amount — two totes or 600 gals) - IPA-33 (Amount — one tote or 300 gals) Enviroklean Product Development, Inc. 3215 East County Road 120 Midland, TX 79706 ��EPDI (3) 683-0800 SAFETY DATA SHEET Revision date: June 1, 2015 SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT NAME: Isopropyl Alcohol (IPA) SUPPLIER: 3215 East County Road 120 ADDRESS: Midland, TX 79706 (432)683-0800 EMERGENCY PHONE Chemtrec (800) 424-9300 PHONE: (432) 683-0800 FAX: (432) 683-0800 CHEMICAL NAME: Propan-2-ol RECOMMENED USE: Industrial Solvent RESTRICTIONS ON USE: Advice in this document relates only to product as originally supplied. Other derivative chemicals will have different properties and hazards. Advice should be sought on their safe handling and use. SECTION 2: HAZARD IDENTIFICATION 2.1 GHS Classification: Flammable Liquid, Cat. 2 Eye Irritation, Cat. 2A Specific Target Organ Toxicity - single exposure (Inhalation, oral) Cat. 3 (Narcotic effects) 2.2 GHS Label Element: Pictogram: Signal Word: Danger 2.3 Hazard Statements: Physical: H225 Highly flammable liquid and vapor Health: H319 Causes serious eye irritation H336 May cause drowsiness or dizziness. Environmental: Not classified as an environmental hazard under GHS criteria 2.4 Precautionary Statements: Prevention: P210 Keep away from heat/sparks/open flames/hot surfaces — No smoking P233 Keep container tightly closed P240 Ground/bond container and receiving equipment P241 Use explosion -proof electrical/ventilating/lighting/equipment P242 Use only non -sparking tools P243 Take precautionary measures against static discharge P261 Avoid breathing mist of vapors P264 Wash hands thoroughly after handling P271 Use only outdoors or in a well -ventilated area P280 Wear protective Gloves/protective clothing/eye protection/face protection Response: P303+P361+P353 IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower P370+P378 IN CASE OF FIRE: Use appropriate media for extinction P305+P351+P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P337+P313: If eye irritation persists: Get medical advice/attention P304+P340: IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing P312: Call a POISON CENTER or doctor/physician if you feel unwell Isopropyl Alcohol (IPA) Page 1 of 8 Revision Date: June 1, 2015 SAFETY DATA SHEET SECTION 2: HAZARD IDENTIFICATION (CONTINUED) 2.4 Precautionary Statements: (continued) Storage: P403+P233: Store in a well -ventilated place. Keep container tightly closed P235: Keep cool P405: Store locked up Disposal: P501: Dispose of contents and container to appropriate waste site or reclaimer in accordance with local and national regulations. 2.5 Other Hazards Which Do Not Result In Classification: Slightly irritating to respiratory system. Vapors are heavier than air, Vapors may travel across the ground and reach remote ignition sources causing a flashback fire danger. This material is a static accumulator. Even with proper grounding and bonding, this material can still accumulate and electrostatic charge. If sufficient charge is allowed to accumulate, electrostatic discharge and ignition of flammable air -vapor mixtures can occur. The classification of this material is based on OSHA HCS 2012 criteria. SECTION 3: COMPOSITIONIIN FORMATION ON INGREDIENTS 3.1 Substance/Mixture: Substance 3.2 Synonyms: IPA, Isporopanol, Propan-2-ol, Propanol, sec, Propyl alcohol, Sec-, Dimethyl carbinol 3.3 Hazardous Components: Chemical Name Synonyms CAS Number j Concentration (%) Isopropyl alcohol propan-2-ol 67-63-0 I >= 10 - <= 33 SECTION 4: FIRST AID MEASURES 4.1 First Aid Measures: General Advice: In general no treatment is necessary, however, obtain medical advice Inhalation: Remove to fresh air. If rapid recovery does not occur, transport to nearest medical facility for additional treatment. Skin Contact: Remove contaminated clothing. Flush exposed area with water and follow by washing with soap if available. If persistent irritation occurs, obtain medical attention. Eye Contact: Immediately flush eyes with large amounts of water for at least 15 minutes while holding eyelids open. Transport to the nearest medical facility for additional treatment. Ingestion: If swallowed do not induce vomiting. Transport to the nearest medical facility for additional treatment. If vomiting occurs spontaneously, keep the head below the hips to prevent aspiration. If any of the following delayed signs and symptoms appear within the next 6 hours, transport to the nearest medical facility: fever grater that 101 °F (38.3°C), shortness of breath, chest congestion or continued coughing or wheezing. Most Important Symptoms and Effects, Both Acute and Delayed: If material enters lungs, signs and symptoms may include coughing, choking, wheezing, difficulty in breathing, chest congestion, shortness of breath, and/or fever. Eye irritation signs and symptoms may include a burning sensation, redness, swelling, and/or blurred vision. Protection of First-Aiders: When administering first aid, ensure that you are wearing the appropriate personal protective equipment according to the incident, injury and surroundings. Immediate Medical Attention, Special Treatment: Potential for chemical pneumonitis. Call a doctor or poison control center for guidance. SECTION 5: FIRE -FIGHTING MEASURES 5.1 Suitable Extinguishing Media: Alcohol -resistant foam, water spray of fog. Dry chemical powder, carbon dioxide, sand or earth may be used for small fires only. 5.2 Unsuitable Extinguishing Media: None. 5.3 Specific Hazards During Fire -Fighting: The vapor is heavier than air, spreads along the ground and distant ignition is possible. Carbon monoxide may be evolved if incomplete combustion occurs. 5.4 Specific Extinguishing Methods: Standard procedure for chemical fires. Isopropyl Alcohol (IPA) Page 2 of 8 Revision Date: June1, 2015 SAFETY DATA SHEET SECTION 5: FIRE -FIGHTING MEASURES (CONTINUED) 5.5 Further Information: Clear fire area of all non -emergency personnel. Keep adjacent containers cool by spraying with water. 5.6 Special Protective Equipment for Fire -Fighters: Proper protective equipment including chemical resistant gloves are to be worn; chemical resistant suit is indicated if large contact with spilled product is expected. Self -Contained Breathing Apparatus must be worn when approaching a fire in a confined space. Select fire fighter's clothing approved to relevant Standards (e.g., Europe: EN469). SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1 Personal Precautions, Protective Equipment and Emergency Procedures: Observe the relevant local and international regulation. Notify authorities if any exposure to the general public or the environment occurs or is likely to occur. Local authorities should be advised if significant spillages cannot be contained. The vapor is heavier than air, spreads along the ground and distant ignition is possible. Vapor may form an explosive mixture with air. Avoid contact with skin, eyes and clothing. Isolate hazard area and deny entry to unnecessary or unprotected personnel. Stay upwind and keep out of low areas. 6.2 Environmental Precautions: Shut off leaks, if possible without personal risks. Remove all possible sources of ignition in the surrounding area. Use appropriate containment to avoid environmental contamination. Prevent from spreading or entering drains, ditches or rivers by using sand, earth, or other appropriate barriers. Attempt to disperse the vapor or to direct its flow to a safe location for example by using fog sprays. Take precautionary measures against static discharge. Ensure electrical continuity by bonding and grounding (earthing) all equipment. Ventilate contaminated area thoroughly. Monitor area with combustible gas indicator. 6.3 Methods and Materials for Containment and Cleaning Up: For large liquid spills (> 1 drum): Transfer by mechanical means such as vacuum truck to a salvage tank for recovery or safe disposal. Do not flush away residues with water. Retain as contaminated waste. Allow residues to evaporate or soak up with an appropriate absorbent material and dispose of safely. Remove contaminated soil and dispose of safely. For small liquid spills (< 1 drum): Transfer by mechanical means to a labeled, sealable container for product recovery or safe disposal. Allow residues to evaporate or soak up with an appropriate absorbent material and dispose of safely. Remove contaminated soil and dispose of safely. Additional Advice: For guidance on selection of personal protective equipment, see Section 8 of the Safety Data Sheet. For guidance on disposal of spilled material, see Section 13 of the Safety Data Sheet. US Regulations may require reporting releases of this material to the environment which exceed the reportable quantity (see Section 15) to the National Response Center at (800) 424-8802. SECTION 7: HANDLING AND STORAGE 7.1 Technical Measures: Avoid breathing vapors or contact with material. Only use in well ventilated areas. Wash thoroughly after handling. For guidance on selection of personal protective equipment, see Section 8 of the Safety Data Sheet. Use the information in the data sheet as input to a risk assessment of local circumstances to help determine appropriate controls for safe handling, storage and disposal of this material. Ensure that all local regulations regarding handling and storage facilities are followed. 7.2 Precautions for Safe Handling: Avoid contact with skin, eyes and clothing. Use local exhaust ventilation if there is risk of inhalation of vapors, mists or aerosols. 7.3 Avoidance of Contact: Strong oxidizing agents. 7.4 Advice on Protection Against Fire and Explosion: Bulk storage tanks should be diked (bunded). Extinguish any naked flames. Do not smoke. Remove ignition sources. Avoid sparks. Electrostatic discharge may cause fire. Ensure electrical continuity by bonding and grounding (earthing) all equipment to reduce the risk. The vapors in the head space of the storage vessel may lie in the flammable/explosive range and hence may be flammable. Properly dispose of any contaminated rags or cleaning materials in order to prevent fires. Do NOT use compressed air for filling, discharging, or handling operations. 7.5 Product Transfer: Refer to guidance under Handling Section. 7.6 Conditions for Safe Storage, Including any Incompatibilities: The vapor is heavier than air. Beware of accumulation in pits and confirmed spaces. For guidance on packaging and storage, follow and specific legislation and see Section 15. 7.7 Packaging Materials: For containers, or container linings, use mild steel, stainless steel. 7.8 Unsuitable Materials: Natural, butyl, neoprene, or nitrile rubbers. 7.9 Container Advice: Containers, even those that have been emptied, can contain explosive vapors. Do not cut, drill, grind, weld or perform similar operations on or near containers. Additional Information: Ensure that all local regulations regarding handling and storage facilities are followed. See additional references that provide safe handling practices: American Petroleum institute 2003 (Protection Against Ignitions Arising out of Static, Lightning and Stray Currents) or National Fire Protection Agency 77 (Recommended Practices on Static Electricity). CENELEC CLCITR 50404 (Electrostatics — Code of Practice for the avoidance of hazards due to static electricity). Isopropyl Alcohol (IPA) Page 3 of 8 Revision Date: June1, 2015 SAFETY DATA SHEET SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION 8.1 Components with Workplace Control Parameters: Component CAS Number Type Value Type Source (Form of Exposure) Isopropyl Alcohol 67-63-0 TWA 200 : m ACGIH STEL 400 uum ACGIH 400 ppm OSHA Z-1 TWA 980 m• {/m3 8.2 Biological Occupational Exposure Limits: CAS Control Biological Permissible Component Number Parameters Specimen Sampling Time Concentration Basis Isopropyl Alcohol 67-63-0 Acetone Urine End of shift at 40 mg/I ACGIH BEI end of work- week 8.3 Monitoring Methods: Monitoring of the concentration of substances in the breathing zone of workers or in the general workplace may be required to confirm compliance with an OEL and adequacy of exposure controls. For some substances biological monitoring may also be appropriate. Validated exposure measurement methods should be applied by a competent person and samples analyzed by an accredited laboratory. Examples of sources of recommended exposure measurement methods are given below or contact the supplier. Further national methods may be available. National Institute of Occupational Safety and Health (NIOSH), USA: Manual of Analytical Methods .htto://www.cdc.00v/niosh/ Occupational Safety and Health Administration (OSHA), USA: Sampling and Analytical Methods httn://www.osha.aov/ Health and Safety Executive (HSE), UK: Methods for the Determination of Hazardous Substances httr)://www.hse-oov.uk/ Instiut fi)r Arbeitsschutz Deutschen Gesetzlichem Unfallversicherung (IFA), Germany httD://www.douv.de/inhalt/index.iso L'Institut National de Recherche et de Securite, (INRS), France htto://www.inrs.fr/accueil 8.4 Engineering Measures: The level of protection and types of controls necessary will vary depending upon potential exposure conditions. Select controls based on a risk assessment of local circumstances. Appropriate measures include: Use sealed systems as far as possible. Adequate explosion -proof ventilation to control airborne concentrations below the exposure guidelines/limits. Local exhaust ventilation is recommended. Firewater monitors and deluge systems are recommended. Eye washes and showers for emergency use. Where material is heated, sprayed or mist formed, there is greater potential for airborne concentrations to be generated. General Information: Always observe good personal hygiene measures, such as washing hands after handling the material and before eating, drinking, and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. Discard contaminated clothing and footwear that cannot be cleaned. Practice good housekeeping. Define procedures for safe handling and maintenance of controls. Educate and train workers in the hazards and control measures relevant to normal activities associated with this product. Ensure appropriate selection, testing and maintenance of equipment used to control exposure, e.g. personal protective equipment, local exhaust ventilation. Drain down system prior to equipment break-in or maintenance. Retain drain downs in sealed storage pending disposal or subsequent recycle. 8.5 Personal Protective Equipment: Respiratory Protection: If engineering controls do not maintain airborne concentrations to a level which is adequate to protect worker health, select respiratory protection equipment suitable for the specific conditions of use and meeting relevant legislation. Check with respiratory protective equipment suppliers. Where air -filtering respirators are suitable, (e.g. airborne concentrations are high, risk of oxygen deficiency, confined space) use appropriate positive pressure breathing apparatus. Where air -filtering respirators are suitable, select an appropriate combination of mask and filter. If air -filtering respirators are suitable for conditions of use: Select a filter suitable for organic gases and vapors [boiling point >65°C (149°F)]. Respirator selection, use and maintenance should be in accordance with the requirements of the OSHA Respiratory Protection Standard, 29 CFR 1910.134. Hand Protection: Where hand contact with the product may occur the use of gloves approved to relevant standard (e.g. Europe: EN374, US: F739) made from the following materials may provide suitable chemical protection. Longer term protection: Butyl rubber, Nitrile rubber. Incidental contact/splash protection: PVC or neoprene rubber gloves for continuous contact we recommend gloves with breakthrough time of more than 240 minutes with preference for > 480 minutes where suitable gloves can be identified. For short-term/splash protection we recommend the same, but recognize that suitable gloved offering this level of protection may not be available and in this case a lower breakthrough time maybe acceptable so long as appropriate maintenance and replacement regimes are followed. Glove thickness is not a good predictor of glove resistance to a chemical as it is dependent on the exact composition of the glove material Glove thickness should be typically greater than 0.35 mm depending on the glove make and model. Suitability and durability of a glove is dependent on usage, e.g. frequency and duration of contact, chemical resistance of glove material, dexterity. Always seek advice from glove suppliers. Contaminated glove should be replaced. Personal hygiene is a key element of effective hand care. Gloves must only be worn on clean hands. After using gloves, and should be washed and dried thoroughly. Application of a non - perfumed moisturizer is recommended. Isopropyl Alcohol (IPA) Page 4 of 8 Revision Date: June1, 2015 SAFETY DATA SHEET SECTION 8: EXPOSURE CONTROLS/PERSONAL PROTECTION (CONTINUED) 8.5 Personal Protective Equipment: (continued) Eye Protection: Wear goggles for use against liquids and gas. Wear full face shield if splashes are likely to occur. Skin and Body Protection: Wear antistatic and flame retardant clothing if a local risk assessment deems it so. Skin protections not required under normal conditions of use. For prolonged or repeated exposures use impervious clothing over parts of the body subject to exposure. If repeated and/or prolonged skin exposure to the substance is likely, then wear suitable gloves tested to relevant Standard, and provide employee skin care programs. Protective Measures: Personal protective equipment (PPE) should meet recommended national standard. Check with PPE Suppliers. Hygiene Measures: Wash hands before eating, drinking, smoking and using the toilet. Launder contaminated clothing before re -use. SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES The physical and chemical property data are typical values and do not constitute a specification. 9.1 Information on basic physical and chemical properties: Form: Color: Odor: Odor threshold: pH: Melting point/freezing point: Boiling point/boilinq range: Flash point: Evaporation rate: Flammability (solid, gas): Upper explosion limit: Lower explosion limit: Vapor pressure: Relative vapor density: Relative density: Density: Water solubility: Solubility in other solvents: n-octanol/water partition coefficient (log Po,,,): Auto -ignition temperature: Decomposition temperature Viscosity, dynamic: Viscosity, kinematic: Explosive properties: Oxidizing properties: Surface tension: Conductivity: Molecular weight: f Li.-;uid Clear j Characteristic Data not available Not applicable -88°C (-126°F) 82 - 83-C (180 - 181°F) 12°C (54°F) Method: Abel 1.5 (ASTM D 3539, nBuAc=1) Not applicable Upper flammability limit 12%(V) Lower flammability limit 2%(V) 6.020 Pa 20°C (68°F) 2 ;20°C (68aF)) 0.78 — 0.79 (20°C (68°F)) 785 — 786 kg/m' (20°C (68°F)) Method: ASTM D4052 Comi:letel: miscible. Readil • soluble in various organic solvents. 0.05 425°C .797°F , ASTM D-2155 Not a ,rlicable 2.43 mPa.s Data not available 1 Classification Code: Not classified Not applicable 22.7 mN/m, 20°C (68°F) Electrical conductivity: > 10 000 pS/m, A number of factors, for example liquid temperature, presence of contaminants, and anti -static additives can greatly influence the conductivity of a li(:uid. This material is not expected to be a static accumulator. 60.1 g/mol SECTION 10: STABILITY AND REACTIVITY 10.1 Reactivity: The product does not pose any further reactivity hazards in addition to those listed in the following sub -paragraph. 10.2 Chemical Stability: No hazardous reaction is expected when handled and stored according to provisions. 10.3 Possibility of Hazardous Reactions: Reacts with strong oxidizing agents. 10.4 Conditions to Avoid: Avoid heat, sparks, open flames and other ignition sources. Prevent vapor accumulation. In certain circumstances product can ignite due to static electricity. 10.5 Incompatible Materials: Strong oxidizing agents. 10.6 Hazardous Decomposition Products: Thermal decomposition is highly dependent on conditions. A complex mixture of airborne solids, liquids and gases, including carbon monoxide, carbon dioxide, Sulphur oxides and unidentified organic compounds will be evolved when this material undergoes combustion or thermal or oxidative degradation. Isopropyl Alcohol (IPA) Page 5 of 8 Revision Date: June1, 2015 SAFETY DATA SHEET ' SECTION 11: TOXICOLOGICAL INFORMATION 11.1 Information on Toxicological Effects: Basis for Assessment: Information given is based on product testing. Routes of Exposure: Exposure may occur via inhalation, ingestion, skin absorption, skin or eye contact, and accidental ingestion. Acute Toxicity: Routes of Exposure Acute Oral Toxicity Acute Dermal Toxicity Acute Inhalation Toxicity Skin Corrosion/irritation: Not irritating to skin. Serious Eye Damage/Irritation: Causes serious eye irritation. Respiratory or Skin Sensitization: Not expected to be a skin sensitizer. Germ Cell Mutagenicity: Not mutagenic. Carcinogenicity: Not a carcinogen. Material Values Isopropyl Alcohol LD50: = > 5,000 mg/kg, Rat Remarks: Low toxicity Isopropyl Alcohol LD50: = > 5,000 mg/kg, Rabbit Remarks: Low toxicity Isopropyl Alcohol Remarks: Low toxicity by inhalation IARC: No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by IARC. ACGIH: No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. OSHA: No component of this product present at levels greater than or equal to 0.1 % is identified as a carcinogen or potential carcinogen by OSHA. NTP: No component of this product present at levels greater than or equal to 0.1 % is identified as known or anticipated carcinogen by NTP. Reproductive Toxicity: Does not impair fertility. Not a developmental toxicant. STOT— Single Exposure: May cause drowsiness and dizziness. STOT — Repeated Exposure: Kidney: caused kidney effects in male rats which are not considered relevant to humans. Aspiration Toxicity: Aspiration into the lings when swallowed or vomited may cause chemical pneumonitis which can be fatal. Further Information: Exposure may enhance the toxicity of other materials. Classifications by other authorities under varying regulatory frameworks may exist. SECTION 12: ECOLOGICAL INFORMATION Basis for Assessment: Information given is based on product testing. 12.1 Ecotoxicity: Toxicity to Fish (Acute Toxicity): Practically nontoxic: LL/EUIL50 > 100 mg/I. Toxicity to Daphnia and Other Aquatic Invertebrates (Acute Toxicity): Practically non toxic: LL/EUIL50 > 100 mgll. Toxicity to Algae (Acute Toxicity): Practically non toxic: LUEL/I1-50 > 100 mg/I. Isopropyl Alcohol (IPA) Page 6 of 8 Revision Date: June1, 2015 SAFETY DATA SHEET SECTION 12: ECOLOGICAL INFORMATION (CONTINUED) Basis for Assessment: Information given is based on product testing. 12.1 Ecotoxicity: (continued) Toxicity to Fish (Chronic Toxicity): Data not available. Toxicity to Daphnia and Other Aquatic Invertebrates (Chronic Toxicity): Data not available. Toxicity to Bacteria (Chronic Toxicity): Practically non toxic: LUEUIL50 > 100 mg/I. 12.2 Persistence and Degradability: Biodegradability: Readily biodegradable. Oxidizes rapidly by photo -chemical reactions in air. 12.3 Bioaccumulative Potential: Not expected to bioaccumulate significantly. 12.4 Mobility in Soil: Dissolves in water. If product enters soil, one or more constituents will be mobile and may contaminate groundwater. Other Adverse Effects: No data available. 12.5 Additional Ecological Information: Not expected to have ozone depletion potential. SECTION 13: DISPOSAL CONSIDERATIONS 13.1 Disposal Methods: Waste from Residues: Recover or recycle if possible. It is the responsibility of the waste generator to determine the toxicity and physical properties of the material generated to determine the proper waste classification and disposal methods in compliance with applicable regulations. Do not dispose into the environment, in drains or in water courses. Waste product should not be allowed to contaminate soil or water. Contaminated Packaging: Drain container thoroughly. After draining, vent in a safe place away from sparks and fires. Residues may cause an explosion hazard. Do not puncture, cut or weld un-cleaned drums. Send to drum re -coverer or metal re -claimer. Local Legislation: Local regulations may be more stringent than regional or national requirements and must be complied with. Disposal should be in accordance with applicable regional, national, and local laws and regulations. Comply with any local recovery or waste disposal regulations. SECTION 14: TRANSPORT INFORMATION 14.1 National Regulations: US Department of Transportation Classification (49 CFR Parts 171-180): UN/ID/NA Number: UN 1219 Proper shipping name: Isopropanol Class: 3 Packing group: II Labels: 3 ERG Code.: 129 Marine pollutant: No 14.2 International Regulation: IATA-DGR UN/ID No.: UN 1219 Proper shipping name: Isopropanol Class: 3 Packing group: II Labels: 3 IMDG-Code UN Number: UN 1219 Proper shipping name: Isopropanol Class: 3 Packing group: II Labels: 3 Marine pollutant: No Isopropyl Alcohol (IPA) Page 7 of 8 Revision Date: June1, 2015 SAFETY DATA SHEET SECTION 14: TRANSPORT INFORMATION (CONTINUED) 14.3 Transport in Bulk According to Annex II of MARPOL 73178 and the IBC Code: Pollution category: Z Ship type: 2 Product name: Isopropyl alcohol Special precautions: Refer to Section 7, Handling & Storage, for special precautions which a user needs to be aware of or needs to comply with in connection with transport. 14.4 Special Precautions for User: Refer to Section 7, Handling & Storage, for special precautions which a user needs to be aware of or needs to comply with in connection with transport. 14.5 Additional Information: This product may be transported under nitrogen blanketing. Nitrogen is an odorless and invisible gas. Exposure to nitrogen may cause asphyxiation or death. Personnel must observe strict safety precautions when involved with a confined space entry. SECTION 15: REGULATORY INFORMATION OSHA Hazards: This material is considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910. 1200). EPCRA— Emergency Planning and Community Right -to -Know Act: CERCLA Reportable Quantity: This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity: This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Hazards: Fire Hazard. Immediate (Acute) Health Hazard. SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313: This material does not contain any chemical components with known CAS numbers that exceed the threshold (De Minimis) reporting levels established by SARA Title III, Section 313. Clean Water Act: This product does not contain any Hazardous Chemicals listed under the US Clean Water Act, Section 311. Table 117.3. Pennsylvania Right -to -Know: Isopropyl alcohol CAS # 67-63-0 New Jersey Right -to -Know: Isopropyl alcohol CAS # 67-63-0 California Prop 65: This product does not contain any chemicals known to the State of California to cause cancer, birth defects, or any other reproductive harm. The components of this product are reported in the following inventories: Inventory Status: AICS: Listed DSL: Listed CH INV: Listed IECSC: Listed ENCS: Listed KECI: Listed NZIoC: Listed PICCS: Listed EINECS: Listed TSCA: Listed Other regulations: The regulatory information is not intended to be comprehensive. Other regulations may apply to this material. SECTION 16: OTHER INFORMATION Revision Date June 1, 2015 The information contained herein is based on our current knowledge of the underlying data and is intended to describe the product for the purpose of health, safety and environmental requirements only. No warranty or guarantee is expressed or implied regarding the accuracy of this data or the results to be obtained from the use of the product. Isopropyl Alcohol (IPA) Page 8 of 8 Revision Date: June1, 2015 C01 C international Sales Co., Inc IN CASE OF TRANSPORTATION EMERGENCY CONTACT: CHEMTREC:(800) 424-9300 ' ----------------------- _ ALL OTHER INQUIRIES: < > < > (770) 904-7042 H www.ciscochem.com 266 Rue Cezzan Lavonia, GA 30553 1. IDENTIFICATION ISOPROPYL ALCOHOL SAFETY DATA SHEET: ISOPROPYL ALCOHOL SYNONYMS: 1SOPROPANOL, IPA CAS - NO: 67-63-0 Is1Nl:CS NO: 200-661-7 CHEMICAL FORAlULA: 0-HS-O 2. HAZARDS IDENTIFICATION OSHA rf[CS status I'his material iS considered hazardous by the OSHA Hazard Communication Standard (29 C"FR 1910,1200). Classification of the substance or mixture FLANIMA13LE LIQUIDS - Category SERIOUS EYE DAMAGE EYE IRRITATION - Category ? SPECiFiC TARCM UROAN TOXICITY (SINGI.F. EXPOSURE) (Narcotic effects) - Cacegury 3 CiIIS label elements Signal Nord: DANGER! Hazard Stalements: I lighly flammable liquid and vapor. May displace oxygen and cause rapid sui'livation. Causes Scriour eye irritation, May cause drowsiness and dizziness Precautionary statements General: React label before use. Keep out of reach of children. If medical advice is needed, have product container air label at hand. Prevention: Wear protcetive doves. Wcar eye or laee protection. Keep aA ay from heat, sparks. open tlamcs and hot surtaces. - No smoking. Use explosion-proor electrical. ventilating, lighting and all material -handling equipment. Use only non -sparking, tools. Take precautionary measures against statie discharge. Keep container tightly closed. Use only outdoors or in a well -ventilated area. Avoid breathing vapor. Wash hands thoroughly afro handling. Use and .store only outdoors or in a ev,:Il ventilated place. Response: IF !NI IALED: Remove victim to fresh air and keep at rest in a position comfortable For breathing. Call a POISON C'F\TER or physician if you feel umvell. IV ON SKIN (car hair): 'fake off immediately all contaminated clothing. Rinse skin with water or shower. IF IN EYES: Rinse cautiously with Haler ror sc%c;ral minutes. Remove contact lenses. if Present and easy to du, Continue SDS: ISOPROPYL ALCOHOL Page: i co rinsing. if eve irritation persists: Get medical attention. Storage: Store locked up. Store in it well -ventilated place. Keep Cool Disposal Dispose of content., and container in accordance with all local, regional, national and international regulations. Hazards not othervo ise classitled None Know n Potential Acute TTealth Effects: Hazardous in ease of eye contact (irritant), of ingestion. of inhalation. Slightly haLard,)Us in case ofshtn contact (irritant, sensitizer. permeator). Potential Chronic Health Effects: Slightly hazardous in case of skin contact (sensitizer). CARCINOGENIC FFFFC'TS. A.4 (Not classifiable for human or animal,) by AC'GTH, 3 (Not classifiable 11or human.) by IARC. MGTAGENIC EFFECTS: Not available. TERATOGEN1C EFFECTS: Not available. DFVFIOPMENTAL'roxlCiTY: Classified RePruduetivetiyacnt'toxiu,female, Development toxin IPOSSiBI-F1. The substance may be toxic to kidneys, liver, skin, central nervous system WNS). Repeated or prolonged exposure to the substance can produce target organs damage. 3. COMPOSITION C ONIPOS11ION NAIVIL. CAS fr % BY WEIGHT Isopropyl Alcohol 67-63-0 100 4. FIRST AID MEASURES 000000M000011❑Description oftiecessary first aid measures EYECONTACT Immediately flush eves with plenty of water,occasionally lifting the upper and lower eyelids. Check for and reprove any contact lenses. Continue to rin+e for at least 10 minutes, Get medical attention, TNIIALATION Remove victim to fresh air and keep at rest in a position comfortable Ibr breathing. If it is suspceted that finues are still present, the rescuer should wear an appropriate mask or scU=contained breathing apparatus. if not breathing, if breathing is irregular or if respiratory arrest occurs. provide artificial respiration or ox5 gen by trained personnel. It may be dangerous to the person providing aid to give mouth-to-mpttth resuscitation. Get medical attention. If uecessary� call a poison center ur physician. l f unconsciou4, place in recovery; position and got medical attention immediately. Maintain an open airway. Loosen tight clothing such as a collar, tie, belt or waistband. 013]0MI0000[X7❑W0000000000 ODODDD=00013Q❑[IOI DOEIOO [ ODDO❑❑DMMOOOODDEMODOOOODOODO SKE CONTACT Flush contaminated skin with plenty of water. Remove contaminated clothing tmd shoes. Get medical attention if s) mptonts occur. Wash elothinu before reuse. Clean shoes, thoroughly before reuse. lN(j1_S"f1ON Wash out mouth with water. Remove dentures ifan3•. Remove victim to fresh air and keep at rest in a position comCortable for breathing. Ifmarcrial has been swallowed and the exposed person is conscious, give small quantities of water to drink. Step if the exposed person feels sick as vomiting may be dangerous. Do not induce vomiting unless directed to do so by modieal personnel, If vomiting occur,, the head should be kept low so that vomit does not enter the lungs. Get medical attenticnt. If neces,ary, call a poison center or physician. Never give anything by mouth to an unconscious person. if unconscious, place io recovery position and get medical attention immediately. Maintain an open airway. Loosen tight clothing such a, it collar, tie, ball or waistband. SDS: ISOPROPYL ALCOHOL Page; 2 �Q !�m..m►ws�ah .. Most important ,ymptonts'cl'li ets, acute and delayed Potential acute health effects ElYI, CON] AC T: C"Ruses serious eye: irritation iNHAL41`ION: Call causc central nervous sv:steni (C'NS) depression, NT,ty cause drowsiness di zinc; SiCIIti CONTACT: Not known significant effects or critical hazards PROS I'l3I I'll.: Try it) Joann up the fr0701 tissues anal seek medical ,dtantion 11GFS'l iON: Can cause central nervous system (("NS) depression. irritating to month, throat and stomach 0%er-explore argnsrsymploms FYF CONTACT Adverse symptoms may include the following: pain OR irritation redness %% a teri n , INI IALATION: Adverse symptoms tnay include the Tolloaing: naumca or votuiting headache dro%"inc,s'latigue di77iness� t ertigo unconsciausnes4 SKIN CONTACT: No specific data INCIFSTION: No specific data Indication of immediate medical attenriun and special treatment ncLded, if necessary Notes to physician: 'Treat syntptomatically. . Contact poison treatment spcciali�t immediately if large quantities have been ingested or inhaled. Sp? !chic Treatments: No specific treatment Protection of first-aiders: No action shall be taken involving any personal ri,,k or without stthable training. If it is suspected that flutes are .till present, the rescuer should wear an appropriate mask or self-contained breathing, apparatus. it may be dangerous to the parson Providing aid to give mouth-to-mouth resuscitation. 5. FIRE FIGHTING MEASURES Flammability of the. Product: Flammable;, Auto -ignition Temperature: 399T (750.2''F) Flash Points: CLOSED CUP: 1 l.fift7°C (53'F) - 12.778 deg. C (55 deg. 1') (TACT) Flammable Limits: LOWER:2'.'r+, UPPER: 12.7°,) ProdUC15 of Combustion: These products are carbon oxides (CO, CO21. Fire Placard. in Presence of Various Substances: Highly flammable in presence of open flames and sparks, of heat. Flammable in presence of oCidizing materials. Nun- flammable in presence oaf shocks SDS: ISOPROPYL ALCOHOL Page. 3 CO h Explosion Hazards in Presence Or Various Substances: Risks of explosion of the product in presence of mechanical impact: Not available. Explosive in presence of open flames and sparks, of heat, Fire Fighting, Media and Instructions: Flammable liquid, soluble or dispersed in stater. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Ilse alcohol tbam, water spray or fog. Special Remarks on Fire Ha7urds Vapor may travel considerable distance to source of ignition and flash back. CAUTION: MAY BURN WIT] I NEAR INViSIBLE FLAME. Hydrogen peroxide sharply reduces the autoi-nition temperature of Isopropyl alcohol. After a delay, Isopropyl alcohol ignites on contact with dioxgenyl tctralluorborate, chromium trioxide, ant] potassium tert-butoxide. When heated to decomposition it emit, acrid smoke and Nines. Special Remarks on Explosion Hazards: Secondary- alcohols are readily autooxidized in contact w ith oxygen or air, forming ketones and hydrogen peroxide. It can become potentially explosive. It reacts 'Aith oxygen to form dangerously unstable peroxides which can concentrate and explode during distillation or evaporation. The presence of 2-hutanone increases the reaction rate for peroxide formation. Explosive in the form of vapor when exposed to heat or flame. May form explosive mixtures with air. lsopropyl alcohol , phosgene forms isopropyl chlorofunnate and hydrogen chloride. In the presence of iron salts, thermal decuinpositon can occur, whien in some cases can become explosive. A homogeneous mixture of concentrated peroxides - isopropyl alcohol are capable of detonation by shuck or heat. Barium perchlorate + isopropyl alcohol gi\ es the highly explosive alkyl perchloratcs.l'onns explosive mixtures with trinitomnethane and hydrogen peroxide. it product's a violent explosive reaction when heated with aluminum isopropo'cide — cro(onaldehyde. Mixtures of isopropyl alcohol t nitrororm are explosive. 6. ACCIDENTAL RELEASE MEASURES Personal precautions. protective equipment anti emergency procedures For non-cuiere ency personnel No action shall be taken im olvinb any personal risk or without suitable (ruining. Evacuate surrounding areas. Keep unnecessary and unprotected personnel from entering. Do not touch or . alk through spilled material. Shut offal I ignition sources. No tlares, smokinng or flanuzs in hazard area. Avoid breathing vapor or mist. Provide adequate ventilation_ Wear appropriate respirator when tentilation is inadequate. Put on appropriate personal prttretive equipment. For emergency responders It speciarlited clothing is required to deal with the spillage, take note of any- infonnation in Section 8 on suitable and unsuitable materials. See also the information in 1-or non- cmer wricy personnel". I?nvironincnCtl precaution Avoid dispersal orspilled material and runoffand contact with sail, waterways. drains and seNvers, inform the relevant authorities if the product has caused environmental pollution (sewers, waturw•ay's, soil or air). Methods and materials for containment and elcunim_ up Small spill Stop leak irwithout risk. Move containers t'ronn spill area. Use apart.-proorlools and e.\plosion-pruofequipment. Dihite with water and mop tip if water-soluble, Alternatively, or if water -insoluble, absorh with an inert dry material and place in an appropriates waste disposal container. Dispose of via a licensed waste disposal contractor. Largc spill Stop leak it'without risk. Move containers from spill area. Use ,park -proof tools and explosion -proof equipment. Approach release from upwind. Prevent entry into sewers. water courses. basements ur curifrned areas. Wash spillages into an effluent ircatment plant or proceed as h711oAs. Contain and collect spillage with noon-cumbustibl4, ubsuncenl material e.g. ,and, o arth, vermiculite or diatumaccuus earth ant] place in container for disposal according to local regulations (see Section I Dispose of via a licensed waste disposal contractor Contaminated ahsorbent nwterial may pose the same hazard as the spilled product. Nate: see Section I for emergency contact information and Section 13 for waste disposal. 7. HANDLING AND STORAGE Precautions liar sale handling SDS: ISOPROPYL ALCOHOL Page: 4 Ca Protective Measures Put on appropriate personal protective equipment (sec Scetiun n). Do nut ingest. Amid contact with eves, skin artd clothing. Avoid breathing vapor or mist. Use only with adequate ventilation. Wear appropriate respirator when ventilation is inadequate. [fin not eater storage areas and confined spaces unless adequately ventilated. Keep in the urigntal container or an approved alternative made front a compatible material. kept tightly closed v&,hen not in use. Store kind use away from heat, sparks. open flame or any other ignition sourec. Use explosion -proof electrical (ventilating, lighting and niatcrial handling) equiprttcnt. Use only non -sparking tools. Take Precautionary measures against electrostatic discharges. F.inpty containers retain product residue and can be ha/arduuc. Do not reuse container. Advice (in general : occupational hygiene Eating,drinking and.smoking should be prohibited in arras where this material is handled. stored and proeess.d. Workers should wash hands and race before eating, drinking and smoking. Remove contaminated clothing, and protectivc equipment before entering cating areas,. See also Section R for additional information on hygiene measures. Conditions ftir safe storage.: including any incompatibilities Stura in accordance with local rc41ulations. Store in a scnregated and approved area. Store in original container protected from direct sunlight ill a dry, Cool turd Wo:11-ventilated area; away rrom incompatible materials (sec Section 10) and fluid and drink. Sttue hocked up. Fliminate all ignition sources. Separate from oxidving materials, Keep container lightly closed and scaled until ready 11or use. Containers that have been opened must be carclully resealed and kept uprizht to prevent Icakage. Do not store in unlabeled containers. Use appropriute containment to avoid onvirunmental contamination. 8. EXPOSURE CONTROLS AND PERSONAL PROECTION Eneineering Controls: Provide exhaust ventilatiun or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyev ash stations and safety showers are proximal to the work -station location. Personal Protection: Splash goggles. Lab coat. Vapor respirator. Be sure to use in approveohcertitied respirator or equivalent. Gloves. Persunal Protection in Case of a Large Spill: Splash goggles. Full suit. Vapor respirator. Trouts, Gloves. A self contained breathing apparatus should be used to avoid inhalation sit' the product. Suggested protective clothing inight not be sufficient: consult a Specialist BEFORE handling this product. Exposure Limits: TWA: 983 S"1'l:l_: 1230 (mr,.. m3) (Australia] TWA: 200 STI L: 400 (ppm) from ACGIH (`11A) [United States] [ 19991 TWA: 980 STFL: 1225 (mg!m3') from NIOSH TYN'A: 400 STF.L: 500 (ppm) front NiOSII TWA: 400 STEL: 500 (ppnt) tUllited Kingdom (UK)] TWA: 999 S7'EL: 1259 ('mg/m3)(United Kingdom (UM] TWA: 400 SILL: 500 (ppm) from OSHA (PEL) (United States] TWA: 980 STF.L: 1225 (mgim3) from OSIIA (PEL) [United States]Consult local authorities for acceptable exposure limits. 9. PHYSICAL AND CHEMICAL PROPERTIES Physical state and appearance: Liquid. Odor: Pleasant Odor resembling that of a mixture of ethanol and acetone. Taste: Bitter. (Slight.) Molecular Weight: 60.1 g'mu)e Color: Colorless. plI (1 :u solniwater): Not available. SDS. ISOPROPYL ALCOHOL Page: 5 GQ Boiling Point: (180.5'F) Melting Point:-88.5'C (-127.31F) Critical Temperature: 235"C (455''F) Specific Gravity: 0.78505 (Water= 1) Vapor Pressure: 4.4 kPa ((ci, 20'C) Vapor Density: 2.07 (Air — I ) Votatilin : Not available. Odor Threshold: 22 ppm (Sittig, 1991) 700 ppm for unadapted panelists (Verschuren, 1983). Watery"Oil Dist. Coen.: The product is equally soluble in oil and water: log(oil Hater) — ().1 tonicity (in Water): Not available. Dispersion Properties: SOC solubility in water, methanol, diethyl ether, n-octanol. acetone. Solubility: hasily soluble in cold water, hot water, methanol, diethyl ether. n-octinol, acetone. Insoluble in salt solutiun. Soluble in benzene. Miscible with most organic solvents including alcohol, ethyl alcohol, chloroform. 10. STABILITY AND REACTIVITY Stability: The product is stable. Instability Tent(xrature: Not available. Condition~ of Instability: Heat, Ignition sources. incompatible materials Incompatibility with various substances: Reactive with oxidizing agents, acids, alkalis. C.'orrusivity: Non -corrosive in presence ol•glass. Special Remarks on Reactivity: Reacts violently with hydrogen -4- palladium combination, nitroform, olcuni. COCK'. aluminum triisupropoxide, oxidants Incompatible with acetaldehyde, chlorine, ethylene oxide, isocyanates, acids, alkaline earth, alkali metals, caustics. amines. crotonaldchyde. phosgene, ammonia. Isopropyl alcohol reacts with metallic aluminum at high temperatures. Isopropyl alcohol attacks Some plastics, rubber, and coatings. Vigorous reaction with sodium dichromate I sulfuric acid. Special Remarks on CWTusivity. May attack some rorma of plastic, rubber and coating Polymerization: Will not occur. 11. TOXICOLOGICAL INFORMATION Routes or Entry: Absorbed through skin. Dermal contact. Eye contact. Inhalation. Toxicity to Animals: WARNING: T11E L.C'50 VALUES IIEREUNDER ARE ESTI:19ATED ON TILE BASIS OF A 4-11OUR EXPOSURE. Acute oral toxicity (I.D50): 3600 mg'kg [house]. Acute dermal toxicity (LD50): 12800 mgkg rRahhitj. Acute toxicity of the vapor 16000 8 hours [Raij. Chronic FITects on I lumans: CARCINOGENIC EFFECTS: AEI (Not clas,it5able 1brhuman or animal.) bN. ACGIH, 3 (Not classifiable tbrhuman.) by IARC. DEVELOPMENTAL TOXICITY: Classified Reprodui:ti%c systeinftoximfemale. Development toxin I POSSIBI_ F.l. May cause SDS: ISOPROPYL ALCOHOL Page: 6� C.v.�intr—shy 3a.�L. inz damage to the 11ollowing organs: kidneys, liver, skin, central nervous system (CNS) Other Toxic E11'ects on Humans: lazarduus in case of ingestion, of inhalation. Slightly hazardous in case of skin contact (irritant, sensitizer, permeator). Special Remarks on Toxicity to Animals: Not available. Special Remarks on Chronic Effects on Humans: May cause adverse rcproductivefteratoacnic effects (fertility, retoxicity, developmental abnomtalitics (development toxin) based on animal studies. Detected in maternal milk in human. Special Remarks on other Toxic Effects on Humans: Acute Potential l Icalth L:ffccts: Skin: May cause mild skin irritation, and sensitization. l:ycs: Can cause eye irritation. Inhalation: Breathing in small amounts of this material during normal handling is not likely to cause harmful effects. however, breathing larva amounts may be harmful and may affectthe respiratory system and mucous membranes (irritation), behavior and brain (Central nervous system depression - headache, dizziness, drowsiness_ stupor, incoordination. unconsciousness. coma and possible death), peripheral nerve and sensation, blood.. urinary system, and liver. Ingestion: Swallowing small amounts during normal handling is not likcIv to cause harmful effects, Sw'alluvvino large amounts may be harmful. Swallowing large amounts may cause gastrointestinal tract irritation w" nausea. vomiting and diarrhea, abdominal pain. It also may of fi;ct the urinary system, cardiovascular system, sense organs. behavior or central nervous system (somnolence, generally depressed activity, irritability, headache, dizziness. drowsiness), liver, and respiratory system (breathing dilficulty). Chronic Potential Health Effizs: -tad cause delhtting of the skin and dermatitis and allergic reaction, May cause adverse reproductive effects based on animal data (studies). l?. ECOLOGICAL INFORMATION Ecotoxicity: Ecotoxicky in water (LC 50): 100000 mgll 96 hours [Fathead Minnow], t)4000 mg`I 90 hours [Fathead Minnow]. B0115 and COD: Not available. Products of 13iodcgradation: Possibly hazardous short teen degradation products are not likely. However, lung terns degradation products may arise. Toxicit} of the Products of Biodegradation: The product itself and its product,, of degradation arc not toxic. Special Remarks on the Products oCBiodegradation: Not available. 13. DISPOSAL CONSIDERATIONS Disposal tncthod4 The generation of waste should be avoided or minimized wherever possible. Disposal of this product, solutions and any by-product~ should at all times comply with the requirements ofenvirunmenttl protection and waste disposal legislation and any regional local authority requirements. Dispose of surplus and non -recyclable products via; a lieensad waste disposal contractor. waste should not be disposed of untreated to the sewer unless fully compliant with the requirements of all authorities with jurisdiction. Waste packaging, should he recycled. Incineration or landfill should only be considered when recycling is not feasible. This material and its container must be disposed of in a safe way. Care should be taken when handling emptied containers That have not been cleaned or rinsed out. Empty containers or liners may retain some product residues. Vapor from product residues may create a highly pannnablo or explosive atmosphere inside the container. Flu not cut, weld or grind used containers unless they have been cleaned thoroughly internally. Avoid dispersal or -spilled material and runoff and contact m ith soil. nvaterways, drains and sewers. 14. TRANSPORT fNFORMATfON DOT Classification: CLASS 3: Flammable liquid. Identification:: Lopropyl Alcohol UNNA: 1219 PG: II Special Provisions For'I ransport: Not available. PROPI-R SHIPPiNG DOCl NIF.NTA`CION: L'N 1219, ISOPROPYL ALCOHOL.3, PG 11 FLA:11NIABLL- LIQUID SDS: ISOPROPYL ALCOHOL Page: 7 Co Special precautions for user Transport within user's premises: always transport in closed containers that art: upright and secure.. Ensure that persons transponing the product know what to do in the event of an accident or ,pillage. Transport in hull: according to Annex 11 of h7ARPOL 7 f7N and the [Be ('ode Not available. 15. REGULATORY INFORMATION Federal and State Regulations: Connecticut hazardous material swi'ey.: Isopropyl alcohol Illinois toxic substances disclosure to employee act: isopropyl alcohol Rhcrdc Island RTK hazardous suhstaices: lNopropyl alcohol Pennsylvania RTK: fsopropyl ale:uhgl Hlorida; Isopropyl alcohol Minnesota: isuprupy) alcuhol Massachusett; RTK: Isopropyl alcohol New Jersey: Isopropyl alcohol New Jersey spill list: Isoprupyl alcohol Director's list of Hazardous Substances: Isopropy I alcohol Tenne.,ee: Isopropyl alcohol TSCA R(h) inventory: Isopropyl alcohol `l'SCA 4(a) final testing order: Isopropyl alcohol I'SC'A 8(a) Ililt: Isopropyl alcohol TSCA 8(d) [land S data reporting: Isopropy I alcohol: Effective date: 12't 5/h6 Sunset bate: 12I 51%TSCA 1 2(b) rule time export: isopropyl alcohol SARA 313 u+eic chemical noritication and release reporting,: Isopropyl alcohol Other Regulation~: OSHA: llazarduus by definition of I larard Communication Standard (29 C FR 191 U,12t)p), EINECS: This product is an Ilse European Inventory of Existing Commercial Chemical Substances. Other C'lassilications: WIIMIS (Canada): CLASS B-`_': Flammable liquid with a flash point tower than 37.8" C (I00,F). CLASS D-213: Material causing other toxic effects (TOXIC), DSCL WEC;): R 11- Ilighly f7anunable. Rah- irritating to eyes. S7- Keep container tightly closed. S 16- Kcep assay from sources of ignition - No smoking. S24125- Avoid contact with skin and cye;. S26- In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. I MIS (U,S,A.): health lIazard: i Fire Hazard: 3 Reactivity: 0 Personal Protection: h National Fire Protection Association (U.S,A.). Health: 1 Flammability: 3 Reactivity: a Spec iIte hazard: Protective Equipment: Gloves. Lab coat. Vapor respirator. Ile sure to use an approved certified respirator or equivalent. Wear appropriate respirattor'when ventilation is inadequate. Splash goggles. 16.OTHER INFORMATION The information above is believed to be accurate and represents the best inrorntation current]\ available to us. However, we make no warranty of merchantability ur any other warranty. express or implied, with respect to such information, and we assume no liability resulting from its use:. Lasers should make their own ins estigations to determine the suitability of the information for their particular purposes. In no event shall C'iSC O he liable ror any claims, losses, or drantt_es of arty third party or for lost profits or any special, indirect, incidental, consequential or exemplary dama—ge . howsoever arising, even if CiSCO has been advised of the possibility of such damages. Dale Created: 5/11 /201.5 Date Updated: 2/4/2016 SDS: ISOPROPYL ALCOHOL Page: 8 CC)