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Home My WebLink AboutCO2024-001047 Hazardous materialI ODOM regaraing I WCK.031324 Isopropyl alcohol (70%) ("IPA") is purchased (typically from Walgreen's) in 32 oz bottle size a will be stored in a flammable I storage cabinet. This, in turn, is diluted at 15%/85% ratio with water in a 32 oz spray bottle so there would be about 5 oz of IPA in each spray bottle. This is used as a "tack" solution to activate the adhesive on the films products. At our maximum capacity, we may go through —15 bottles (32 oz) of IPA each month. SAFETY DATA SHEET EASTMAM Version Revision Date: 1.0 04/08/2020 PRD Product name iffero1..grOTIT8 SDS Number: Date of last issue: - 150000116328 Date of first issue: 04/08/2020 SISUS / Z81 0001 Isopropyl Alcohol Equipment Cleaner (70%) 06-00, E41206011 E4120602, E4120603 Manufacturer or supplier's details Company name of supplier Eastman Chemical Company Address 200 South Wilcox Drive Kingsport TN 37660-5280 Telephone (423) 229-2000 Emergency telephone CHEMTREC: +1-800-424-9300, +1-703-527-3887 CCN7321 Recommended use of the chemical and restrictions on use 7kecommended use Cleaning agent Restrictions on use None known. SECTION 2. HAZARDS IDENTIFICATION GHS classification in accordance with 29 CFR 1910.1200 Flammable liquids Category 2 Eye irritation Category 2A Specific target organ toxicity : Category 3 (Respiratory system, Central nervous system) - single exposure Hazard pictograms x"� %N7 Signal Word Danger Hazard Statements H225 Highly flammable liquid and vapor. H319 Causes serious eye irritation. H335 May cause respiratory irritation. H336 May cause drowsiness or dizziness. 1EASTMAN lsopropyl Alcohol Equipment Cleaner (70%) Version Revision Date: SDS Number: Date of last issue: - 1.0 04/08/2020 150000116328 Date of first issue: 04/08/2020 PRD SDSUS / Z8 / 0001 Precautionary Statements : Prevention: P210 Keep away from heat/ sparks/ open flames/ hot surfaces. No smoking. P233 Keep container tightly closed. P240 Ground/bond container and recei\hng equipment. P241 Use explosion -proof electrical/ \entilating/ lighting/ equip- ment. P242 Use only non -sparking tools. P243 Take precautionary measures against static discharge. P261 Avoid breathing dust/ fume/ gas/ mist/ \rapors/ spray. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-\entilated area. P280 Wear protecti\e gloves/ eye protection/ face protection. Response: P303 + P361 + P353 IF ON SKIN (or hair): Take off immediate all contaminated clothing. Rinse skin with water/ shower. P304 + P340 + P312 IF INHALED: Remow person to fresh air and keep comfortable for breathing. Call a POISON CENTER/ doctor if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for se\eral minutes. Remow contact lenses, if present and ea,; to do. Continue rinsing. P337 + P313 If eye irritation persists: Get medical ad\,ice/ attei tion. P370 + P378 In case of fire: Use dry sand, dry chemical or alci hol-resistant foam to extinguish. Storage: P403 + P233 Store in a well -ventilated place. Keep container tightly closed. P403 + P235 Store in a well -ventilated place. Keep cool. P405 Store locked up. Disposal: P501 Dispose of contents/ container to an appro\ed waste dis- posal plant. 'Ither hazards None known. Components jChemical name jCAS-No. lisooroloyl alcohol 67-63-0 lWater j7732-18-5 SECTION 4. FIRST AID MEASURES If inhaled Move to fresh air. Treat symptomatically. Concentration 60-70 30-40 PAFA SAFETY DATA SHEET Falsimilm lsopropyl Alcohol Equipment Cleaner (70%) Version Re�sion Date: SDS Number: Date of last issue: - 1.0 04/08/2020 150000116328 Date of first issue: 04/08/2020 PRID SDSUS I Z8 / 0001 If symptoms persist, call a physician. In case of skin contact Wash off with soap and water. If symptoms persist, call a physician. In case of eye contact Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/ attention. If swallowed Call a physician or poison control center immediately. Do NOT induce vomiting. If victim is fully conscious, give a cupful of water. Never give anything by mouth to an unconscious person. Hold person's head low, to prevent aspiration. Most important symptoms Causes serious eye irritation. and effects, both acute and May cause respiratory irritation. delayed May cause drowsiness or dizziness. Notes to physician Treat symptomatically. SECTION 5. FIRE -FIGHTING MEASURES Specific hazards during fire fighting Hazardous combustion prod- ucts RrAmm- for fire-fighters Carbon dioxide (CO2) Dry chemical Water spray MEEK= ear an approved positive pressure self-contained breathing apparatus in addition to standard fire fighting gear. Imo ,ersonal precautions, protective equipment and emergency procedures Wear appropriate personal protective equipment. Local authorities should be ad%Ased if significant spillages cannot be contained. En\Aronmental precautions : Avoid release tothe emironment 3/14 lsopropyl Alcohol Equipment Cleaner (70%) Version Revision Date: SDS Number'. Date of last issue: - 1.0 04/08/2020 150000116328 Date of first issue'. 04/08/2020 PRD SMUS / Z81 0001 Methods and materials for Contain spillage, soak up with non-combustible absorbent containment and cleaning up material, (e.g. sand, earth, diatomaceous earth, vermiculite) and transfer to a container for disposal according to local national regulations (see section 13). After cleaning, flush away traces with water. Eliminate all ignition sources if safe to do so. RIAMOR 0 j 1 0. 1., i � i I � I I � i 14 912 1 Advice on protection against : None known. fire and explosion Advice on safe handling Do not get in eyes. Do not taste or swallow. Wash thoroughly after handling. Keep away from fire (No Smoking). Keep away from fire, sparks and heated surfaces. Do not use sparking tools. Conditions for safe storage Keep container closed when not in use. Store locked up. Ingredients with workplace control parameters -,- Components CAS- -'-- Va lue alue type (Form of exposure; isopropyl alcohol 67-63-0 TWA STEL TWA M 11MIT, TWA STEL Biological occupational exposure limits Components CAS -No. Control : parameters isopropyl alcohol 67-63-0 Acetone Control parame- ters / Permissible concentration 200 ppm 400 ppm 400 ppm 980 mg/m3 500 ppm 1,225 mg/m3 400 ppm 980 mg/m3 400 ppm 980 mg/m3 500 ppm _1,225 m9/m3 IMM ACGIH ACGIH NIOSH REL OSHA Z-1 OSHA PO OSHA PO Biological I Sam- Permissible Basis specimen pling concentra- time tion Urine End of 40 mg/l ;k_CG1H shift at BEI end of work- /14 SAFETY DATA SHEET UJILSIMAN .1 lsopropyl Alcohol Equipment Cleaner(70%) Version Revision Date: SD S Number: Date of last issue: - 1.0 04/08/2020 150000116328 Date of first issue: 04/08/2020 PRD SDSUS I Z8 / 0001 Components CAS -No. Control Biological Sam- Permissible Basis parameters specimen pling I concentra- time j tion Week Engineering measures Good general ventilation (typically 10 air changes per hour) should be sufficient to control airborne le Is. Ensure adequate \entilation. Personal protective equipment Respiratory protection Use respiratory protection unless adequate local exhaust \entilation is prmAded or exposure assessment demonstrates that exposures are within recommended exposure guidelines. 71m, T1,17=07M M4 Eye protection Wear safety glasses with side shields (or goggles). Face -shield Always wear eye protection when the potential for inad\ertent eye contact with the product cannot be excluded. Protective measures Remove respiratory and skin/eye protection only after vapors ha \e been cleared from the area. Ensure that eye flushing systems and safety showers are located close to the working place. Use personal protecti\oe equipment as required. Hygiene measures Handle in accordance with good industrial hygiene and safety practice. SECTION 9. PHYSICAL AND CHEMICAL PROPERTA EM Color clear Odor solvent Odor -FiresWold not determinei pH not determined 5/14 SAFETY DATA SHEET MUM Version Revision Date: SIDS Number Date of last issue: - 1.0 04/08/2020 150000116328 Date offirst issue: O4/O8/2O2O PRO 8DSUS/ZM/DOO1 Flash point 68 ^F/2O °C Method: Setmflesh closed cup Evaporation rate not determined Upper explosion |imit/Upper not determined flammability limit Lower explosion |imit/Lower not determined flammability limit Vapor pressure not determined Relative vapor density not determined Re|atiwe density 0.0817 (68 ^F /2D ^C) Sn|uW|ity(ies) Water solubility Moderate Partition coefficient: n- No data available octamn|/weter Decomposition temperature 325 "F/ 183 ^C Method: 0SC Visuomity, kinematic not determined Explosive properties No data available Oxidizing properties No data available Reactivity Stable Chemical stability Stable under normal conditions. Possibility cfhazardous nmac- : Stable tions Hazardous decomposition products formed under fire conditions. Conditions to avoid Heat. flames and sparks. Incompatible materials Oxidizing agents Hazardous decomposition Carbon dioxide(C%}2) SAFETY DATA SHEET lsopropyl Alcohol Equipment Cleaner (70%) am 0= [Ir-MINWAIVID� 3= SDS Rumber: 150000116328 SDSUS / Z8 / 0001 Carbon monoxide SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Not classified based on available information. Product: Acute oral toxicity Acute inhalation toxicity Acute dermal toxicity Components: isopropyl alcohol: Acute oral toxicity EASTMAMM Date of last issue: - Date of first issue: 04/08/2020 Remarks: Ro data available Remarks: No data available Remarks: No data available LD50 Oral (Rat): 5,800 mg/kg LC50 (Rat): 59 mg/l Exposure time: 4 h Test atmosphere: vapor Acute dermal toxicity LD50 Dermal (Rabbit): 12,900 mg/kg Skin corrosion/irritation Not classified based on available information. Product: Remarks No data available Components: isopropyl alcohol: Species Rabbit Exposure time 24 h Result slight irritation Serious eye damage/eye irritation Causes serious eye irritation. Product: Remarks Causes eye irritation. Qom orients: isopropyl alcohol: Species Rabbit Result Moderate eye irritation 7/14 EASTMAM Isopropyl Alcohol Equipment Cleaner ®1 Version Revision Date: SDS Number: Date of last issue: - 1.0 04/08/2020 150000116328 Date of first issue: 04/08/2020 PRD SDSUS / Z8 / 0001 Respiratory or skin sensitization Skin sensitization Not classified based on available information. Respiratory sensitization Not classified based on available information. Components: .sopropyl alcohol: Test Type Species V,estilt Skin sensitization Guinea pig 1U9,10 -1 ZAA ncmg�L_� �_ �_4 Germ cell mutagenicity Not classified based on a\railable information. Carcinogenicity Not classified based on available information. Product: Remarks This information is not available. IARC No ingredient of this product present at levels greater than or equal to 0. 1 % is identified as probable, possible or confirmed human carcinogen by IARC. OSHA No component of this product present at le\els greater than or equal to 0. 1 % is on OSHA's list of regulated carcinogens. NTP No ingredient of this product present at le\els greater than or equal to 0. 1 % is identified as a known or anticipated carcinogen by NTP Reproductive toxicity �Iot classiled based or Product: Effects on fertility STOT-single exposure May cause respiratory irritation. May cause drowsiness or dizziness. 10 WONIFT."A F.101 OT-repeated exposure UA&Ah- IFT&TA M. my, SAFETY DATA SHEET WISIMIM .1sopropyl Alcohol Equipment Cleaner (70%) Version Revision Date: SDS Number: Date of last issue: - 1.0 04/08/2020 150000116328 Date of first issue: 04/08/2020 PRD SDSUS / Z8 / 0001 Product: Remarks I,Lr4T*T_T_W "r, M. #I Aspiration toxicity Not classified based on available information. Product: No aspiration toxicity classification Components; isopropyl alcohol: May be harmful if swallowed and enters airways. Further information Product: Remarks None known. Ecotoxicity Components: isopropyl alcohol: Toxicity to fish LC50 (Pimephales promelas (fathead minnow)): > 790 mg/I Exposure time: 96 h LC50 (Leuciscus idus (Golden orfe)): 8,970 - 9,280 mg1l Exposure time: 48 h Toxicity to daphnia and other : LC50 (daphnid): > 790 mg/l aquatic invertebrates Exposure time: 96 h Persistence and degradability Components: isopropyl alcohol: Biodegradability Result: Readily biodegradable. Biodegradation: 53 % Exposure time: 5 d Biochemical Oxygen De- Biochemical oxygen demand within 5 days mand (OD) 1,190 - 1,720 mg/g 9/14 SAFETY DATA SHEET EASIMJXN lsopropyl Alcohol Eq u ipment Cleaner (70%) Version Revision Date: SDS Number: Date of last issue: - 1.0 04/08/2020 150000116328 Date of first issue: 04/08/2020 PRID SDSUS / Z8 / 0001 BOD-20- 1,680 mg/g Chemical Oxygen Demand 2,230 mg/g (COD) ThOD 2,400 mg/g Bioaccumulative potential comPQRqRtq. isopropyl alcohol: Partition coefficient: n- Pow: 1.4 octanol/water log Pow: 0.14 Mobility in it No data available Other adverse effects No data available SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues Dispose of in accordance with local regulations. SECTION 14. TRANSPORT INFORMATION International Regulations IATA-DGR UN/ID No. LIN 1219 Proper shipping name Isopropanol Solution Class 3 Packing group 11 Labels Flammable Liquids Packing instruction (cargo 364 aircraft) Packing instruction (passen- 353 ger aircraft) IMDG-Code LIN number LIN 1219 Proper shipping name ISOPROPANOL SOLUTION Class 3 Packing group 11 Labels 3 ES Code F-E, S-D Marine pollutant no 10/14 EASTMAN , lsopropyl Alcohol Equipment Cleaner /® Version ReIiision Date: SDS Number: Date of last issue: - 1.0 04/08/2020 150000116328 Date of first issue: 04/08/2020 PRD SDSUS I Z8 / 0001 Transport in bulk according to Annex 11 of MARPOL 73/78 and the IBC Code Not applicable for product as supplied. 49 CFIR UN/ID/NA number Proper shipping name Class Packing grou Labels ERG Code Marine pollutal 2A 1219 �sopropanol solution 3 11 FLAMMABLE LIQUID 129 no Special precautions for user The transport classification (s) provided herein are for informational purposes only, and solely based upon the properties of the unpackaged material as it is described within this Safety Data Sheet. Transportation classifications may vary by mode of transportation, package sizes, and variations in regional or country regulations. SECTION 15. REGULATORY INFORMATION EPCRA - Emergency Planning and Community Rit-to-Know CERCLA Reportable Quantity This material does not contain any components with a CERCLA RQ. SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 302 Extremely Hazardous Substances Threshold Planning Quantity This material does not contain any components with a section 302 EHS TPQ. SARA 3111312 Hazards Flammable (gases, aerosols, liquids, or solids) Serious eye damage or eye irritation Specific target organ toxicity (single or repeated exposure) SARA 313 The following components are subject to reporting levi established by SARA Title III, Section 313: MZWMAEI=111111• • I W-1111 r-rim-T21n. I This product does not contain any chemicals known to the State of California to cause cancer, birth, or any other reproducthe defects. lim TSCA All substances listed as acti\e on the TSCA inventory 11 /14 SAFETY DATA SHEET UJISIMIM lsopropyl Alcohol Eq u ipment Cleaner (70%) Version Revision Date: SS Number'. Date of last issue: - 1.0 04/08/2020 150000116328 Date of first issue: 04/08/2020 PRD SDSUS I Z8 / 0001 AICS On the inventory, or in compliance with the inventory DSL All components of this product are on the Canadian DSL ENCS On the inventory, or in compliance with the inventory ISHL On the inventory, or in compliance with the inventory KECI On the inventory, or in compliance with the inventory PICCS On the imentory, or in compliance with the inventory IECSC On the inventory, or in compliance with the inventory TSCA list No substances are subject to a Significant New Use Rule. SECTION 16. OTHER INFORMATION Further information NFPA 704: 122�� a=. HMISO ratings are based on a 0-4 rating scale, with 0 representing minimal haz- ards or risks, and 4 representing sig cant hazards or risks. The represents Special hazard a chronic hazard, while the "I" represents the absence of a chronic hazard. Inirc-T-MIN -1-T-17717TW. =I- ACGIH USA. ACGIH Threshold Limit Values (TLV) ACGIH BEI ACGIH - Biological Exposure Indices (BEI) NIOSH REL USA. NIOSH Recommended Exposure Limits OSHA PO USA. OSHA - TABLE Z-1 Limits for Air Contaminants - 1910.1000 OSHA Z-1 USA. Occupational Exposure Limits (OSHA) - Table Z-1 Lim- its for Air Contaminants 12/14 F �l M EASTMAN a�0 Version Revision Date: 1.0 04/08/2020 PRID US / Z8 Date of last issue: - rp, . RAI-2,0XIt-3,I) MEAW, lsopropyl Alcohol Equipment Cleaner (70%) Version Revision Date: SDS Number: Date of last issue: - 1.0 04/08/2020 150000116328 Date of first issue: 04/08/2020 PRD SDSUS / Z8 / 0001 ACGIH / TWA 8-hour, time -weighted average ACGIH / STEL Short-term exposure limit NIOSH REL /TWA Time -weighted merage concentration for up to a 10-hour workday during a 40-hour workweek NIOSH REL / ST STEL - 15-minute TWA exposure that should not be exceeded at any time during a workday OSHA PO / TWA 8-hour time weighted merage OSHA PO / STEL Short-term exposure limit OSHA Z-1 / TWA 8-hour time weighted merage AICS -Australian Inventory of Chemical Substances; ASTM -American Society for the Testing of and Liability Act-, CMR - Carcinogen, Mutagen or Reproductive Toxicant,- DIN - Standard of the German Institute for Stand ardisation; DOT - Department of Transportation; DSL - Domestic Sub- stances List (Canada); ECx - Concentration associated with x% response; EHS - Extremely Haz- ardous Substance; ELx - Loading rate associated with x% response; EmS - Emergency Schedule; ENCS - Existing and New Chemical Substances (Japan); ErCx - Concentration associated with x% growth rate response; ERG - Emergency Response Guide; GHS - Globally Harmonized Sys- tem; GLP - Good Laboratory Practice; HMIS - Hazardous Materials Identification System; [ARC - International Agency for Research on Cancer; IATA - International Air Transport Association; IBC - International Code for the Construction and Equipment of Ships carrying Dangerous Chemicals in Bulk, IC50 - Half maximal inhibito concentration- ICAO - Internat, I F,-Y'VWT?i) Ez G - i11,1111 Mrsbut'l Effect Concentration; NO(A)EL - No Observed (Adverse) Effect Level; NOELR - No Observable Effect Loading Rate; NTP - National Toxicology Program- NZIoC - New Zealand Inventory of Chemicals; OECD - Organization for Economic Co-operati�n and Development; OPPTS - Office of Chemical Safety and Pollution Prevention; PBT - Persistent, Bioaccumulative and Toxic sub- stance-, PICCS - Philippines Inventory of Chemicals and Chemical Substances; (Q)SAR - (Quanti- tative) Structure Activity Relationship- RCRA - Resource Conservation and Recovery Act; REACH - Regulation (EC) No 1907/2066 of the European Parliament and of the Council concern- ing the Registration, Ewaluation, Authorisation and Restriction of Chemicals; RQ - Reportable Quantity; SADT - Self -Accelerating Decomposition Temperature; SARA - Superfund Amend- ments and Reauthorization Act; SDS - Safety Data Sheet-, TCSI - Taiwan Chemical Substance Inventory; TSCA - Toxic Substances Control Act (United States); UN - United Nations; UNRTDG - United Nations Recommendations on the Transport of Dangerous Goods; vPvB - Very Persistent and Very Bioaccumulative Revision Date : 04/08/20A The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor- mation and belief at the date of its publication. The information given is designed only as a guid- ance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless speced in the text. MUM