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Home My WebLink AboutCO2024-001477Calcium hypochlorite 162 1001b Trichloisocyanuric acid, dry 272 501b uriatic acid 144 1 gal Sodium bicarbonate 49 251b Salt 63 501b Diatomaceous earth 75 251b E0 p Minerals@ SAFETY DATA SHEET ------- Page I of 4 SECTION 1: PRODUCT AND COMPANY IDENTIFICATION PRODUCT IDENTIFIER Celatom@ FW-6,FW-12, FW-14, FW-18, FW-20, FW-40, FW-50, FW-60, FW-70, FW-80, SP CHEMICAL NAME Diatomaceous Earth, Flux -Calcined CHEMICAL FAMILY Silica MATERIAL USE Filter Aid RESTRICTION ON USE None Known MANUFACTURER EP Minerals, LLC., 9785 Gateway Dr., Reno, NV 89521 TELEPHONE NO. (775) 824 7600 (Monday — Friday 8:00 am PST — 5:00 pm PST) EMERGENCY TELEPHONE NO. (775) 824 7600 (Monday — Friday 8:00 am PST — 5:00 pm PST) SDS DATE OF PREPARATION j May 21, 2018 SECTION 2: HAZARDS IDENTIFICATION OSHA GHS HAZARD Carcinogen Category 1A CLASSIFICATION Specific Target Organ Toxicity, Repeated Exposure Category 1 HAZARDS NOT OTHERWISE None CLASSIFIED DANGER Nil May cause cancer by inhalation. Causes damage to lungs through prolonged or repeated exposure. Obtain special instructions before use. LABEL ELEMENTS Do not handle until all safety precautions have been read and understood. Do not breathe dust. Wear eye protection. If exposed or concerned: Get medical advice. Dispose of contents in accordance with local, state and federal regulations. SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS INGREDIENT IDENTIFICATION APPROXIMATE CONCENTRATION C.A.S. NUMBERS Diatomaceous Earth, Flux -Calcined (kieseiguhr) 100% 68855-54-9 (contains 35-50% Crystalline Silica - Cristobalite) L 14464-46-1 SECTION 4: FIRST AID MEASURES EYE Flush eyes with generous quantities of water or eye rinse solution. Consult physician if irritation persists. SKIN Use moisture renewing lotions if dryness occurs. INGESTION Drink generous amounts of water to reduce bulk and drying effects. INHALATION Remove to fresh air. Blow nose to evacuate dust. Most important Dust may cause abrasive irritation to eyes. Prolonged skin contact may cause dryness. Dust may cause nose, symptomsieffects, acute and throat and upper respiratory tract irritation. Prolonged inhalation of respirable dust containing silica may cause a delayed progressive lung disease, silicosis and lung cancer. See Section 11 for additional information. Indication of immediate medical attention and special treatment, if Immediate medical attention is not normally required. If dust irritates the eyes, seek medical attention. necessary MATERIAL NAME Celatom@ FW-6,FW-12, FW-14, FW-18, FW-20, FW-40, FW-50, FW-60, FW-70, FW-80, SP, Page 2 of 4 SECTION 5: FIRE FIGHTING MEASURES EXTINGUISHING MEDIA Not applicable, the material is not combustible. SPECIFIC HARDS ARISING Not applicable, the material is not combustible. AZ FROM THE CHEMICAL SPECIAL PROTECTIVE EQUIPMENT AND PRECAUTIONS Not applicable, the material is not combustible. FOR FIRE-FIGHTERS SECTION 6: ACCIDENTAL RELEASE MEASURES If dust is present, use respirator fitted with particulate filter as specified in Section 8. Protect eyes with goggles. PERSONAL PRECAUTIONS Do not breathe dust. ENVIRONMENTAL This material is not a significant environmental concern. PRECAUTIONS METHODS AND MATERIALS FOR CONTAINMENT AND CLEANING Vacuum clean spillage or wet sweep. Avoid creating airborne dust. Place in a container for use or disposal. UP SECTION 7: HANDLING AND STORAGE PRECAUTIONS FOR SAFE Minimize dust generation. Avoid contact with eyes. Do not breathe dust. Repair or dispose of broken bags. Observe all label precautions and warnings. In the U.S. refer to the OSHA Respirable Crystalline Silica HANDLING Standards; 29CFR1910.1053, 1915.1053 and 1926.1053 for specific handling and use requirements. .. . ...... . .. CONDITIONS FOR SAFE Store in a dry place to maintain packaging integrity and product quality. Do not store near hydrofluoric acid or STORAGE concentrated caustic solutions. SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION EXPOSURE GUIDELINES: Component OSHA PEL ACGIH TLV i MSHA PEL NIOSH REL 5 mg/m3 respirable Diatomaceous Earth, Flux -calcined (kieselguhr) dust None 5 Mg/M3 respirable dust None Established 15 MgJM3 total dust Established 15 Mg/M3 total dust Crystalline Silica (Cristobalite) (effective until I x 30 MgJM3 0.025 Mg/ M3 1 x 30 mg/m3 0.05 Mg/ M3 6/23/2017 for Construction and 6123/2018 for 2 % Si02+2 Respirable dust 2 % Si02+2 Respirable dust General Industry and Oil and Gas) total dust total dust 1 x 10 mg/m3 1 x 10 mg/m, 2 % 1-_'1U2_t_2 2 % Si02+2 Respirable dust Respirable dust Crystalline Silica (Cristobalite) (effective 0.05 mulm3 0.025 Mg/ M 3 1 x 30 malm3 0.05 mg/ m3 6/23/2017 for Construction and 6/2312018 for Respirable dust Respirable dust 2 % Si02+2 Respirable dust General Industry and Oil and Gas) total dust 1 x 10 mq/m3 2 % Si02+2 Respirable dust ENGINEERING CONTROLS Use general or local exhaust ventilation to control dust within recommended exposure limits. Refer to ACGIH publication "Industrial Ventilation" or similar publications for design of ventilation systems. PERSONAL PROTECTIVE EQUIPMENT: EYE I FACE PROTECTION Goggles to protect from dust SKIN PROTECTION No special equipment is needed. Respirators fitted with filters certified to standard 42CFR84 under series N95 should be wom when dust is present. If the dust concentration is less than ten (10) times the Permissible Exposure Limit (PEL) use a quarter or half -mask respirator with a N95 dust filter or a single use dust mask rated N95. If dust concentration is greater RESPIRATORY PROTECTION than ten (10) times and less than fifty (50) times the PEL, a full -face piece respirator fitted with replaceable N95 filters is recommended. If dust concentration is greater than fifty (50) and less than two hundred (200) times the PEL use a power air -purifying (positive pressure) respirator with a replaceable N95 filter. If dust concentration is greater than two hundred (200) times the PEL use a type C, supplied air respirator (continuous flow, positive pressure), with full face piece, hood or helmet. GENERAL HYGIENE Avoid breathing dust. Avoid contact with eyes. Wash hands after handling and before eating or drinking. MATERIAL NAME ... . . . ......... ...... ....... _ . . . ........... Celatom@ FW-6, FW-12, FW-14, FW-18, FW-20, FW-40, FW-50, FW-60, FW-70, FW-80, SP Page 3 of 4 SECTION 9: PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE, COLOR Light pink to white powder ODOR Odorless PHYSICAL STATE Solid ODOR THRESHOLD Not applicable VAPOR PRESSURE Not applicable VAPOR DENSITY Not applicable . .......... . . BOILING POINT Not applicable MELTING POINT > 1300' C FLASH POINT Not applicable pH (10% SUSPENSION) 10 FLAMMABILITY LIMITS Not applicable EVAPORATION RATE Not applicable DECOMPOSITION > 1300'C SPEC. GRAVITY / RELATIVE 2.3 TEMPERATURE DENSITY AUTOIGNITION TEMPERATURE Not applicable PARTITION COEFFICIENT — n- OCTANOATER LIW Not applicable FLAMMABILITY (solid/gas) Not applicable SOLUBILITY — WATER < 1 % VISCOSITY Not applicable NE9931x� rA REACTIVITY Material is not reactive. CHEMICAL STABILITY Material is stable. POSSIBILITY OF HAZARDOUS Material is not reactive under normal conditions of handling unless mixed with incompatible substances below. REACTIONS CONDITIONS TO AVOID Not applicable INCOMPATIBLE MATERIALS Hydrofluoric acid and concentrated caustic solutions may react violently with the product. HAZARDOUS DECOMPOSITION Not applicable PRODUCTS . .......... . . SECTION 11: TOXICOLOGICAL INFORMATION POTENTIAL HEALTH EFFECTS Likely Routes of Exposure See below EYE May cause irritation (tear formation and redness) if dust gets in eyes. .............. SKIN Not absorbed by the skin, but may cause dryness if prolonged exposure. Ingestion of small quantities is not considered harmful, but may cause irritation of the mouth, throat and INGESTION stomach. Acute inhalation can cause dryness of the nasal passage and lung congestion, coughing and general throat INHALATION irritation. Acute inhalation of high concentrations of respirable crystalline silica may cause acute silicosis. This product contains crystalline silica. Respirable crystalline silica may cause lung cancer and lung disease CHRONIC EFFECTS (silicosis) if inhaled for prolonged periods. Symptoms of silicosis include wheezing, cough and shortness of breath. Flux -calcined diatomaceous earth (Kieseiguhr) is composed of amorphous and crystalline silica. Respirable crystalline silica (cristobalite) is classified by 1ARC and NTP as a known human carcinogen. Crystalline silica is CARCINOGENICITY only known to cause cancer when inhaled in a respirable form. It is not known to cause cancer by any other route of exposure. . . . ...... . . . .. . . ..... ..... NTP Respirable crystalline silica (cristobalite) is classified as a known human carcinogen. IARC Respirable crystalline silica (cristobalite) is classified as a known human carcinogen. NUMERICAL MEASURES OF No data available TOXICITY CORROSIVENESS, Not applicable SENSITIZATION, IRRITANCY ; Page 4 of 4 MATERIAL NAME Celatom@ FW-6, FW-1 2, FW-1 4, FWA 8, FW-20, FW-40, FW-50, FW-60, FW-70, FW-80, SP REPRODUCTIVE TOXICITY Not available TERATOGENICITY, Not available MUTAGENICITY SECTION 12: ECOLOGICAL INFORMATION ECOTOXICITY: Diatomaceous earth products have shown some efficacy as a natural insecticide, but otherwise have no demonstrated toxicity in regards to aquatic or terrestrial life. PERSISTENCE AND DEGDABILITY Non -biodegradable, inert. RA BIOACCUMULATIVE POTENTIAL Little potential for bioaccumulation MOBILITY IN SOIL No mobility OTHER ADVERSE EFFECTS None known SECTION 13: DISPOSAL CONSIDERATIONS WASTE DISPOSAL If this material as supplied becomes a waste, use solid waste disposal common to landfill type operations or in slurry to sumps. Not considered a hazardous waste under RCRA (40CFR Part 261). PACKAGING DISPOSAL Dispose of in accordance with applicable laws and regulations, typically solid waste disposal common to landfill type operations. SECTION 14: TRANSPORT INFORMATION BASIC SHIPPING INFORMATION DOT shipping classification 55 (no restrictions). Technical name is "Diatomaceous Earth". ADDITIONAL INFORMATION No special requirements or placarding necessary. SECTION 15: REGULATORY INFORMATION U.S. FEDERAL: i TSCA Diatomaceous Earth and Cristobalite appear on the EPA TSCA inventory list. CERCLA Diatomaceous Earth is not classified as a hazardous substance under regulations of the Comprehensive Environmental Response Compensation and Liability Act (CERCLA), 40 CFR 302. SARA TITLE III Not listed. California Proposition 65: &WARNING: This product can expose you to crystalline silica, which is known to the State of California to cause cancer. For more information go to www.P65Warnings.ca.gov. . . . ........ . SECTION 16: OTHER INFORMATION 0* Health 0 >,, 4-Extreme 0 X 0 '> 3-High U) 0 Flammability Z V 2-Moderate 1-Slight 0 Reactivity 0-Insignificant E Protective Equipment ORIGINAL ISSUE DATE November 18, 1985 REVISION DATE i May 21, 2018 1 REVISION NO. 15 1N9LYdTrTr*TWA'SW*'r=e I ' ff6_(WVr_1Vffl1�" lood faith to comply with applicai e federal and state laws. No warranty, representation or guaranty of any kind, express or implied, is hereby provided or intended with respect to the completeness of the information contained herein. We accept no responsibility and iisclaim all liability for any harmful effects which may be caused by the purchase, resale, use or exposure to our product. Customer users of silica must comply with all applicable health and safety laws, regulations and orders, including OSHA Hazardous Communication Standard. Nil NATURALSODA SODIUM BICARBONATE Safety Data Sheet Section 1: Identification Product Name: SODIUM BICARBONATE Emergency Phone Number: CHEMTREC: 800-424-9300 Other Identification: Baking Soda, Bicarbonate of Soda, CAS: 144-55-8 Sodium HvdroQen Carbonate Ma I nufacturer: Natural Soda LLC Intended Use: food and baking ingredient, specialty products, 3200 County Road 31 fire retardant, animal nutrition, pharmaceutical, household and Rifle, Colorado 81650 USA personal care, mild cleaners, general industrial. Phone Number: 1-970-878-3674 Section 2: Hazard(s Identification Classification of Substance Other Hazards Classification (GHS-US): Not Classified Inhalation: Breathing dusts may cause coughing or difficulty Label Elements breathing. GHS-US Labeling: No applicable labeling Eye Contact; Direct eye contact may cause irritation, reddening Unknown Acute Toxicity (GHS-US) or tearing. Not available Skin Contact: Direct contact may cause irritation. Section 3: Composition Information on Ingredients Substance CAS#: 144-55-8 Common Name: Sodium Bicarbonate Formula: NaHCOs Chemical Names: Sodium Bicarbonate, Bicarbonate of Soda Purity: 99+% m/wr Sodium Hydrogen Carbonate Impurities: No impurities relevant for classification and labelipj Section 4: First -aid Measures Most Important Symptoms and Effects, Acute and Delayed Description of First -Aid Measures enerai: 'None expected under normal conditions of use. General: No known delayed effects. Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice. Eye Contact: Contact may cause irritation due to mechanical Eye Contact: Immediately rinse eyes with water. Remove any abrasion. contact lenses, and continue flushing eyes with running water for at least 15 minutes. Get immediate medical attention.- .............. ...... .. Skin: Contact with large amounts of dust may cause mechanical Skin: Wash affected areas with plenty of water, and soap if irritation. available, for several minutes. Seek medical attention if irritation develors or p-ersists. Inhalation: Prolonged inhalation of dust may cause respiratory Inhalation: Remove from area to fresh air. Seek medical irritation. attention if respiratory irritation develops or if breathing becomes difficult. i Ingestion: Large doses may product systemic alkalosis and Ingestion: May cause nausea, vomiting and abdominal pain. exransion in extracellular fluid volume with edema. Large doses can cause alkalosis. Indication of Any Immediate Medical Attention and Special Treatment Needed If exposed or concerned, pet medical advice and attention. Section 5: Fire -fighting Measures General: This ,,product will not burn, and can be used a di-� F,,,owder extin,, uishino medium. Extinquishina Media Advice for Firefthters I Suitable Extinguishing Media: Use material suitable for No special precautions required. surrounding fire conditions. General Measures: Wear self-contained breathing apparatus Unsuitable Extinguishing Media: none. --- when entering area unless atmosphere is proved to be safe. Special Hazards Arisina from the Substance Protection During Firefighting: Do not enter fire area without Fire Hazard: Not Flammable proper protective equipment, including respiratory protection. Explosion Hazards: Not Explosive Hazardous Combustion Products: CO2 (displacement of Reactivity: Hazardous reactions will not occur under normal breathable atmosphere). conditions. Section 6: Accidental Release Measures General Personal Precautions, Protective Equipment and Emergency Procedures: For dry spills, sweep or shovel and place in containers for disposal in accordance with applicable regulations (see Disposal Considerations section). Handle in accordance with good industrial hygiene and safety practice. Avoid formation of dust. Avoid excess skin and eye contact. Avoid contamination of bodies of water durin,.,.t cleanu),.,. . ..... For Non -Emergency Personnel Environmental Precautions Keep dust levels to a minimum Avoid any mixture with an acid into sewer or drain (CO2 gas Wear suitable personal protective e�;uipment formation For E- m I ergency Personnel Methods for Containment: vacuum or shovel into bags Equip cleanup crew with proper protection. Methods for Cleanup: Avoid generation of dust during cleanup Ventilate area. of spills. KeeP in suitable closed labeled container for disposal— : Section 7. Handling and Storage ns for Safe Handling':— Avoid contact with eyes, skin and Precautions Conditions for Safe Storage: Store in a cool, dry and well - clothing. Wash hands thoroughly with soap and water after ventilated location. Good housekeeping should be maintained to handling and before eating, drinking or smoking. minimize dust accumulation and generation. Incompatibilities: KeeL, away from acids, water. ............ Page 1 of 3 NATURAL SODA SODIUM BICARBONATE Safety Data Sheet . Control Parameters [Particles not otherwise classified) Eye Protection: Use vented goggles or safety glasses in US ACGIH (TWA): 3 mg/m3 Respirable Dust excessively dusty conditions 10 Mg/M3 Total Dust Skin Protection: Not required under normal conditions. Use gloves and protective clothing if excessively dusty, or if skin is US OSHA PEL (TWA): 6 mg/m3 Respirable Dust damaged 15 Mg/M3 Total Dust Respiratory Protection: None required where adequate ventilation is provided. If airborne concentrations are high, use a Engineering Controls: Use local exhaust ventilation to keep NIOSH/MSHA approved respirator that has been selected by a airborne levels below exposure limits. technically qualified person for the specific work conditions. L-MM 0711PRI111:1 ff'[= granular Appearance: White 9 Explosive Limits: Not applicable p Odor: No odor Vapor Pressure: Not ap plicable Odor threshold: Not applicable Vapor Density: Not ass.,,Iicable pH Value: 1% Solution = 8.0-8.5 Bulk Density: 60Ibs/ft31 Melting Point: Decomposes above 500C without melting Specific Gravity: H ;0=1 4'Cr,: 2.16 Boiling Point: Not applicable Solubility In Water: 8.8% at 20°C Flash Point: Not Applicable Partition coefficient: Not applicable ;.inor2a r�lcs�ubstancei Evaporation Rate: Not aoplicable Auto -ignition temperature: Not a{ olicable Flammability: Not applicable Ycan be used to �,ut out fires i Decomposition temperature: >50°C Molecular Weight: 84.01 ii/cc Viscosity: Not avplicable Boiling Point: Decomposes an heating Section 10., Stability and Reactivity Reactivity: Hazardous reactions will not occur under normal Conditions to Avoid: Exposure to moisture or moist air. circumstances. Temperatures above 150OF t65°C} Chemical Stability: Stable in dry air, in moist air forms sodium Incompatible Materials: Acids. Aluminum (tarnishes). carbonate, an irritant. Po - ssibility of Hazardous Reactions: Hazardous polymerization Hazardous Decomposition Products: When heated to will not occur. decomposition, sodium bicarbonate i:-,roduces carbon dioxide. Section I I: Toxicological Information Symptoms after Inhalation: Prolonged inhalation of dust may EYES: Mid (rabbit) 100 mg/ 30 sec cause respiratory irritation. SKIN: Mid (human) 30 mg/ 3 days -intermittent Symptoms after Skin Contact: Large amounts of dust may INGESTION: Oral LD60 (rat) 4220 mg/kg cause mechanical irritation. Oral LD60 (mouse) 3360 mg/kg Symptoms after Eye Contact: Contact may cause irritation due Oral LDL5 (man) 20 mg/kg/ 5 days -intermittent to mechanical abrasion. Oral LDL5 (infant) 1260 mg/kg Symptoms after Ingestion: Large doses may produce symptomatic alkalosis and expansion in extracellular fluid volume with edema. Chronic Symptoms: None expected under normal conditions of use Skin corrosion/irritation: Not classified Serious Eye Damage/Irritation: Not classified Respiratory or skin sensitization: Not classified Germ cell mutagenicity: Not classified Teratogenicity: Not classified Carcinogenicity: Not classified Specific Target Organ Toxicity: Not classified Reproductive Toxicity: Not classified Aspiration Hazard: Not classified Section 12: Ecological Information Toxicity LC 50 Fish 1: 7100mg/I Zueqilh Persistence and Degradability: Not established LC 50 Fish 1: 8250-9000 mg/I Ex;:,osure time 96h, Bio-accumulative Potential: Not established EC 50 Daphnia 1: 4100 mg/I Mobility in Soil:-. Not available EC 50 Daphnia 1: 2350 mo/I ,Exposure time 48h,, Other Adverse Effects: No other adverse effects are identified LC 50 Fish 2: 7700 m91I ,Rainbow trout, Section 13: Dispo,sal-Considerations Disposal Guidance: If permitted by local and state regulations, place in a hazardous or industrial waste landfill. Tonnage quantities are not, however, recommended for the landfill, and if possible, should be re -used for an appropriate application. Small quantities may be flushed to sewers if permitted by NPDES or POTW permit. Refer to federal, state, provincial and local regulations for applicable site- st."ecific requirements. Keep out of drinking water sources. See Reaulatwy Information for more details. CARCINOGENICITY: Sodium Bicarbonate is not listed as a carcinogen by the Environmental Protection Agency (EPA), the State of California, the National Toxicology Program, or the International Agency for Research on Cancer. See Regulatory Information Section for additional information. Page 2 of 3 NATURAL SODA SODIUM BICARBONATE Safety Data Sheet Chemicals, A \. Inc. ar AAW am Arch arcH FOR ANY EMERGENCY, 24 HOURS / 7 DAYS, CALL: FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTRECO: 1-800-654-6911 I(OUTSIDE USA: 1-423-780-2970) 1-800-424-9300 (OUTSIDE USA: 1-703-527-3887) USA: 1-423-780-2347) PRODUCT NAME: ABI Power Blast 70 SECTION 1. PRODUCT AND COMPANY IDENTIFICATIO1 Arch Chemicals, Inc. Alpharefta, GA 30004 SECTIQAL2—W..4 Najd�� Serious eye damage Acute toxicity (Inhalation) !q1QQft-t?-r-vP-t flps'2v,� single exposure NAWWQ�� EM= Hazard statements 'AB-1 Power Bla—st M - REVISION DATE: 06/12/2017 MSDS Number: SYNONYMS: CHEMICAL FAMILY.- # 000000024566 none Hypochlorite V USYNTML9 R1 A IM MN Category 2 Category 4 Category 2 Category 1 Category 3 Category 3 (Respiratory system) AIN 11 AM A4, Danger H272 May intensify fire; oxidizer ANW Arch Chemicals. A7S C H., Inc. arm u 1 irritation. H318 Causes serious eye damage. H331 Toxic if inhaled. H335 May cause respiratory irritation. Precautionary statements Prevention: P21 0 Keep away from heat. P220 Keep/Store away from clothing/ combustible materials. P221 Take any precaution to avoid mixing with combustibles. P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well -ventilated area. P280 Wear protective gloves/ eye protection/ face protection. Response: P301 + P312 + P330 IF SWALLOWED: Call a POISON CENTER/doctor if you feel unwell. Rinse mouth. P302 + P352 IF ON SKIN: Wash with plenty of soap and water. P304 + P340 + P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER/doctor if you feel unwell. P305 + P351 + P338 + P31 0 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a POISON CENTER/doctor. P332 + P313 If skin irritation occurs: Get medical advice/ attention. P362 Take off contaminated clothing and wash before reuse. P370 + P378 In case of fire: Use water spray to extinguish. Storage: P403 + P233 Store in a well -ventilated place. Keep container tightly closed. P405 Store locked up. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. CAS OR CHEMICAL NAME CAS # % RANGE Calcium hypochlorite 7778-54-3 60- 80 SODIUM CHLORIDE 7647-14-5 10- 20 ABI Power Blast 70 REVISION DATE: 06/12/2017 Page 2 of 12 WE 10137-74-8 O - 5 10043-52-4 O - 5 1305-62-0 U - 4 471-34-1 O G 7732-18-5 5510 General Advice: Call a poison control center or doctor for treatment advice. For 24-hour emergency medical assistance, call Arch Chemical Emergency Action Network at 1-800-654-6911. Have the product container or label with you when calling a poison control center or doctor, or going for treatment. Inhalation. IF INHALED: Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. Call a poison control center or doctor for further treatment advice. Skin Contact: IF ON SKIN OR CLOTHING: Take off contaminated clothing. Rinse skin immediately with plenty of water for 15-20 minutes. Call a poison control center or doctor for treatment advice. Eye Contact: IF IN EYES: Hold eye open and rinse slowly and gently with water for 15-20 minutes. Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. Call a poison control center or doctor for treatment advice. Ingestion: IF SWALLOWED: Call a poison control center or doctor immediately for treatmen) advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless told to do so by a poison control center or doctor. Do not give anything by mouth to an unconscious person. Notes to Physician: Probable mucosal damage may contraindicate the use of gastric lavage. ABI Power Blast 70 Flammable Properties Flash Point: FIVATITAW 22151=1=� % in air: LiA�Le--c-EO--kLx,2-W,-LP-LE)�nAas[v �Limit, % in air: Not applicable Not applicable Water only. Do not use dry extinguishers containing ammonium compounds. Use water to cool containers exposed to fire. See Section 6 for protective equipment for fire fighting. Not applicable Not applicable SECTION 6. ACCIDENTAL RELEASE MEASURES Personal Protection for Emergency Response to a large quantity spill (100 pounds or greater) or when Situations: dusting or decomposition gas exposure could occur requires the use of a positive pressure full face supplied air repirator or self contained breathing apparatus (SCBA), chemical resistant gloves, coveralls and boots. In case of fire, this personal protective equipment should be used in addition to normal fire fighter equipment. gmlm�= � Air Release: Vapors may be suppressed by the use of water fog. All water utilize"11 to assist in fume suppression, decontamination or fire suppression may be contaminated and must be contained before disposal and/or treatment. Water Release: This product is heavier than water. This material is soluble in water. Monitor all exit water for available chlorine and pH. Advise local authorities of any contaminated water release. Land Release: Contact 1-800-654-6911 immediately. DANGER: All spills of this product should be treated as contaminated. Contaminated product may initiate a chemical reaction that may spontaneously ignite any combustible material present, resulting in a fire of great intensity. In case of a spill, separate all spilled product from packaging, debris and other material. Using a clean broom or shovel, place all spilled product into plastic bags, and place those bags into a clean, dry disposal container, properly marked and labeled. Disposal containers made of plastic or metal are recommended. Do not seal disposal containers tightly. Immediately remove all product in disposal containers to an isolated area outdoors. Place all damaged packaging material in a disposal container of water to assure decontamination (i.e. removal of all product) before disposal. Place all undamaged packaging in a clean, dry container properly marked and labeled. Call for disposal procedures. ABI Power Blast 70 REVISION DATE: 06/12/2017 Page 4 of 12 Chemicals, Arch A RCH!, Inc. Additional Spill Information Hazardous concentrations in air may be found in local spill area arrl� immediately downwind. Remove all sources of ignition. Stop source of spill as soon as possible and notify appropriate personnel. Dispose of spill residues per guidelines under Section 13, Disposal Consideration. This material may be neutralized for disposal; you are requested to contact Arch Chemicals at 1-800-654-6911 before beginning any such procedure. FOR ALL TRANSPORTATION ACCIDENTS, CALL CHEMTREC: 1-800-424-9300 REPORTABLE QUANTITY: 10 lbs. (as calcium hypochlorite) per 40 CFR 302.4. Handling: Avoid inhalation of dust and fumes. Do not take internally. Avoid contact with skin, eyes and clothing. Upon contact with skin or eyes, wash off with water. Remove contaminated clothing and wash before reuse. Storage: Keep product tightly sealed in original containers. Store product in a cool, dry, well -ventilated area. Store away from combustible or flammable products. Keep product packaging clean and free of all contamination, including, e.g. other pool treatment products, acids, organic materials, nitrogen -containing compounds, dry powder fire extinguishers (containing mono -ammonium phosphate), oxidizers, all corrosive liquids, flammable or combustible materials, etc. Shelf Life Limitations: Do not store product where the average daily temperature exceeds 950 F. Storage above this temperature may result in rapid decomposition, evolution of chlorine gas and heat sufficient to ignite combustible products. Shelf life (that is, the period of time before the product goes below stated label strength) is determined by storage time and temperatures. Store in a cool, dry and well ventilated area. Prolonged storage at elevated temperatures will significantly shorten the shelf life. Storage in a climate controlled storage area or building is recommended in those areas where extremes of high temperature occur. Incompatible Materials for Storage: Do not allow product to come in contact with other materials, including e.g. other pool treatment products, acids, organic materials, nitrogen -containing compounds, dry powder fire extinguishers (containing mono -ammonium phosphate), oxidizers, all corrosive liquids, flammable or combustible materials, etc. A chemical reaction with such substances can cause a fire of great intensity. Do Not Store At temperatures Average daily temperature of 35* C / 950 F. Storage above this Above: temperature may result in rapid decomposition, evolution of chlorine gas and heat sufficient to ignite combustible products. ABI Power Blast 70 REVISION DATE: 06/12/2017 Page 5 of 12 IN M Ventilation: Local exhaust ventilation or other engineering controls are normally requireiV when handling or using this product to keep airborne exposures below the TLV, PEL or other recommended exposure limit. Protective Equipment for Routine Use of Product Respiratory Protection Wear a NIOSH approved respirator if levels above the exposure limits are Respirator Type A NIOSH approved full -face air purifying respirator equipped with combination chlorine/P1 00 cartridges. Air purifying respirators should not be used in oxygen deficient or IDLH atmospheres or if exposure concentrations exceed ten (10) times the published limit. Skin Protection Wear impervious gloves to avoid skin contact. A full impervious suit is recommended if exposure is possible to a large portion of the body. A safety shower should be provided in the immediate work area. Eye Protection: Use chemical goggles. Emergency eyewash should be provided in the immediate work area. Protective Clothing Type: Neoprene, Nitrile, Natural rubber (This includes: gloves, boots, apron, protective suit) Calcium hydroxide (1305-82-0) _ Vapor Density: Fat Solubility: Value Control | parameters � TWA 5mo/m/3 i solid free flowing, granular white No data. (Active inQredient)143.00o/nno| Not applicable 10.4-10.8 Not applicable Not applicable Not applicable MMEMMMME REVISION DATE: 06/12/2017 Not applicable Not applicablel Not applicable Stability and Reactivity Summary: Product is not sensitive to mechanical shock or impact. Product is not sensitive to electrical static discharge. Product will not undergo hazardous polymerization. Product is an NFPA Class 3 oxidizer which can cause a severe increase in fire intensity. Not pyrophoric. Not an organic peroxide. If subjected to excessive temperatures, the product may undergo rapid decomposition, evolution of chlorine gas, and heat sufficient to ignite combustible substances. If product is exposed to small amounts of water, it car react violently to produce heat and toxic gases and spatter. Use copious amounts of water for fires involving this product. Conditions to Avoid: Do not store next to heat source, in direct sunlight, or elevated storage temperature. Do not store where the daily average temperature exceeds 95 OF. Prevent ingress of humidity and moisture into container or package. Always close the lid. Chemical Incompatibility: This product is chemically reactive with many substances, including, e.g., other pool treatment products, acids, organics, nitrogen -containing compounds, dry powder fire extinguishers (containing mono -ammonium phosphate), oxidizers, corrosive ,flammable or combustible materials. Do not allow product to contact any foreign matter, including other water treatment products. Contamination or improper use may cause a fire of great intensity, explosion or the release of toxic gases. If product is exposed to small amounts of water, it can react violently to produce heat and toxic gases and spatter. Hazardous Decomposition Products: Chlorine Calcium hypochlorite LD50 850mg/kg Rat G[)D|UK8 CHLORIDE LD50 3.000 mg/kg Rat LD50 3.550 mg/kg Rot Calcium chloride LD50 2.301 mg/kg Rat AB|Power Blast 7D Arch A FRI C H0, Inc. LD50 1.000nng/kg Rai Calcium hydroxide LD50 7.340mg/kg Rot Component Animal Toxiuo!uciy Dermal LD5Ovalue: Calcium chloride LD50 > 5,000 mg/kg Rabbit LD50 2,630 mg/kg Rat Oral LD50 value: LD50 approximately 800 mg/kg Rat Dermal LD50 value: LD50 > 2,000 mg/kg Rabbit Inhalation LC50 Inhalation LC50 1.00 h (Nose Only) > 2.04 mg/I Rat Inhalation LC50 4 h Skin Irritation: DRY MATERIAL CAUSES MODERATE SKIN IRRITATION., WET MATERIAL CAUSES SKIN BURNS. Eye Irritation: Corrosive to eyes. Skin Sensitization: This material is not known or reported to be a skin or respiratory sensitizer. Acute Toxicity: This product is corrosive to all tissues contacted and upon inhalation, may cause irritation to mucous membranes and respiratory tract.The dry material is irritating to the skin. However when wet, it will produce burns to the skin. Subchronic / Chronic There are no known or reported effects from repeated exposure except those Toxicity: secondary to burns. Reproductive and Calcium hypochlorite has been tested for teratogenicity in laboratory Developmental Toxicity: animals. Results of this study have shown that calcium hypochlorite is not a Mutagenicity- Calcium hypochlorite has been tested in the Dominant lethal assay in male mice, and it did not induce a dominant lethal response. Calcium hypochlorite has been reported to produce mutagenic activity in two in vitro assays. It has, however, been shown to lack the capability to produce mutations in animals based on results from the micronucleus assay. In vitro assays frequently are inappropriate to judge the mutagenic potential of bactericidal chemicals due to a high degree of cellular toxicity. The concentration which produces mutations in these in vitro assays is significantly greater than the concentrations used for disinfection. Based on high cellular toxicity in in vitro assays and the lack of mutagenicity in animals, the risk of genetic damage to humans is judged not significant. Carcinogenicity: This product is not known or reported to be carcinogenic by any reference source including [ARC, OSHA, NTP or EPA. One hundred mice were exposed dermally 3 times a week for 18 months to a solution of calcium hypochlorite. Histopathological examination failed to show an increased ABF Power Blast 70 REVISION DATE: 06112/2017 Page 8 of 12 _ AM ARCHS Inc. incidence of tumors. IARC (international Agency for Research on Cancer) reviewed studies conducted with several hypochlorite salts. IARC has classified hypochlorite salts as having inadequate evidence for carcinogenicity to humans and animals. IARC therefore considers (Group 3 Substance). Ecoloqical Toxicity Values for: Calcium hypochlorite Ecoloqical Toxicity Values for: SODIUM CHLORIDE Daphnia magna (Water flea) - Immobilization 48 h EC50> 100 mg1I Eco|ooica| Toxicity Values for: Calcium chloride Leponniemacrochinus(B|uegiU - Acute toxicity 96hLC5U 10.850noo/ sunfish) Daphnia noaQna(Water flea) - 48hEC50 2.400mm1 Daphnia magne(Water flea) - 48hEC50 144mo/| Ch|ore||avu|gahs(Fresh water - Cell multiplication inhibition test 120h EC1O 140 mg/| algae) '—!--coloqical Toxicity Values for: Calcium hydroxide Gambusia affinis (Mosquito fish) - Acute toxicity 96 h LC50 160 mg/I SECTION 13. DISPOSAL CONSIDERATIOW1. ABI Power Blast 70 REVISION DATE: 06/12/2017 Page 9 of 12 4Mr AM Amh AM Chemicals, A RICH. Inc. CARE MUST BE TAKEN TO PREVENT ENVIRONMENTAL CONTAMINATION FROM THE USE OF THE MATERIAL. THE USER OF THE MATERIAL HAS THE RESPONSIBILITY TO DISPOSE OF UNUSED MATERIAL, RESIDUES AND CONTAINERS IN COMPLIANCE WITH ALL RELEVANT LOCAL, STATE AND FEDERAL LAWS AND REGULATIONS REGARDING TREATMENT, STORAGE AND DISPOSAL FOR HAZARDOUS AND NONHAZARDOUS WASTES. Waste Disposal Summary, If this product becomes a waste, it meets the criteria of a hazardow-, waste as defined under 40 CFR 261 and would have the following EPA hazardous waste number: D001.1f this product becomes a waste, it will be a hazardous waste which is subject to the Land Disposal restrictions under 40 CFR 268 and must be managed accordingly. Disposal Methods As a hazardous solid waste it should be disposed of in accordance with local, state and federal regulations. DOT UN number illr il Class Packing group Labels Emergency Response Guidebook Number TDG UN number Description of the goods Class Packing group Labels IATA UN number Description of the good Class Packing group Labels 7 Ptru cti n aircraft) g in ackin structin I (passenger aircraft) Packing instruction (passenger aircralft) 'AB—lPower Blast 70 REVISION DATE: 06/12/2017 2880 Calcium hypochlorite, hydrated mixtures 5.1 II 5.1 140 2880 CALCIUM HYPOCHLORITE, HYDRATED MIXTURE 5.1 11 5.1 2880 Calcium hypochlorite, hydrated mixture 5.1 11 5.1 562 RM 9M Lmmml=� Arch Chemicals, Inc. 2880 CALCIUM HYPOCHLORITE, HYDRATED MIXTURE 5.1 5.1 F-H S-Q Em This chemical is a •` product registered by the United States Environmental Protectior Agency and is subject to certain labeling requirements under federal pesticide law. These requirements differ from the classification criteria and hazard information required for safety data sheets (SIDS), and for workplace labels of non -pesticide chemicals. Signal word DANGER! Hazard statements Causes substantial but temporary eye injury. Corrosive. Causes skin burns. Corrosive. Causes irreversible eye damage. This pesticide is toxic to fish. CERCLA Reportable Quantity Components CAS -No. Component RQ Calculated (Ibs) product RQ (lbs) Calcium' hypochlorite 7778-54-3 10 13 SARA 311/312 Hazards See above: SECTION 2. Hazard Identification-GHS Classification SARA 302 No chemicals in this material are subject to the reporting requirements of SARA Title 111, Section 302. SARA 313 This material does not contain any chemical components with known CAS numbers that exceed thf., threshold (De Minimis) reporting levels established by SARA Title 111, Section 313. US State • Massachusetts Is To Know Components Calcium hypochlorite Calcium chlorate ABI Power Blast 70 REVISION r• 06/12/2017 Page 11 of 12 CAS -No. 7778-54-3 10137-74-3 Arch Chemicals, Inc. Calcium dihydroxide Calcium carbonate Pennsylvania Right To Know Components Calcium hypochlorite Sodium chloride Calcium chlorate Calcium chloride Calcium dihydroxide Calcium carbonate New Jersey Right To Know 'Components Calcium hypochlorite Sodium chloride Calcium chlorate -Calcium chloride Calcium carbonate Calcium dihydroxide 1305-62-0 CAS -No. 7778-54-3 7647-14-5 10137-74-3 10043-52-4 1305-62-0 471-34-1 California Prop. 65 This product does not contain any chemicals known to State of California to cause cancer, birth defects, or any other reproductive harm. SECTION 16. OTHER INFORMATION SECTIONS REVISED: 1 SECTIONS REVISED: Arch is a wholly -owned subsidiary of Lonza and continues to operate as Arch Chemicals, Inc. Major References Available upon request. THIS MATERIAL SAFETY DATA SHEET (MSDS) HAS BEEN PREPARED IN COMPLIANCE WITH THE FEDERAL OSHA HAZARD COMMUNICATION STANDARD, 29 CFR 1910.1200. THE INFORMATION IN THIS MSDS SHOULD BE PROVIDED TO: ALL WHO WILL USE, HANDLE, STORE, TRANSPORT, OR OTHERWISE BE EXPOSED TO THIS PRODUCT. THIS INFORMATION HAS BEEN PREPARED FOR THE GUIDANCE OF PLANT ENGINEERING, OPERATIONS AND MANAGEMENT AND FOR PERSONS WORKING WITH OR HANDLING THIS PRODUCT. ARCH CHEMICALS BELIEVES THIS INFORMATION TO BE RELIABLE AND UP TO DATE AS OF THE DATE OF PUBLICATION BUT, MAKES NO WARRANTY THAT IT IS. ADDITIONALLY, IF THIS MSDS IS MORE THAN THREE YEARS OLD, YOU SHOULD CONTACT ARCH CHEMICALS MSDS CONTROL AT THE PHONE NUMBER ON THE FRONT PAGE TO MAKE CERTAIN THAT THIS DOCUMENT IS CURRENT ABI Power Blast 70 REVISION DATE: 06/12/2017 Page 12 of 12 Material Safety Data Sheet PROGUARD@ 3" TABLETS - V I ersion: 1.1 Revision Date: 11/10/2010 Product name: Chemical nature I I e""VAl1jQ11WM2= ilk Swimming Pool Product Bio-Lab, Inc. P.O. Box 300002 1irwaw- KJ1IT-10*151111 Emergency telephone CHEMTREC: (24 hours) 800-424-9300, 703-527-3887 number: Poison Control Center (Medical) :: (877) 800-5553 For additional emergency telephone numbers see section 16 of the Safety Data Sheet. Prepared by: Product Safety Deoartment (US) +1 866-430-2775 +011-886-2-2712-5668 MSDSRequest@chemtura.com Hazard Summary Corrosive Oxidizer Causes serious eye damage. Causes skin burns. May be fatal if absorbed through skin. Harmful or fatal if swallowed. May be fatal if inhaled. Causes respiratory tract irritation. Avoid breathing dust or vapor. Do not get in eyes, on skin, or on clothing. SAP 6.0 1/10 SDS Number: 000000004973 Material Safety Data Sheet PROGUARX) 3" TABLETS Version: 1.1 Revision Date: 11/10/2010 Print Date: 03/03/2012 OSHA Hazards THIS MATERIAL IS HAZARDOUS UNDER THE CRITERIA OF THE FEDERAL OSHA HAZARD COMMUNICATION STANDARD 29CFR 1910.1200. UIUTTT��i= Primary Routes of Entry Eye contact Skin contact Inhalation Ingestion Aggravated Medical Respiratory disorders Condition Skin disorders Inhalation May be fatal if inhaled. Causes respiratory tract irritation. Skin May be fatal if absorbed through skin. Causes skin burns. On contact with moisture, this material readily hydrolyzes to acid which may result in burns if not promptly removed. Eyes Causes serious eye damage. Ingestion Harmful or fatal if swallowed. Chronic Exposure None known. SECTION 3. COMPOSITIONIIN FORMATION ON INGREDIENTS Hazardous components Component Trichloro-s-triazinetrione SECTION 4.FIRST AID MEASURES First aid procedures Inhalation Remove to fresh air. If person is not breathing, call 911 or an ambulance., then give artificial respiration, preferably mouth-to-mouth, if possible. Call a physician or poison control centre immediately. SAP 6.0 2/10 SDS Number: 000000004973 99 % Material Safety Data Sheet PROGUARD@ 3" TABLETS Version: 1 .1 Revision Date: 11/10/2010 Print Date: 03/03/2012 Skin contact Remove contaminated clothing and shoes. Rinse immediately with plenty of water for at least 15 minutes. Call a physician or poison control centre immediately. Eye contact Rinse immediately with plenty of water, also under the eyelids, for at least 15 minutes. Remove contact lenses, if present, after 5 minutes, then continue rinsing eye. Call a physician or poison control centre immediately. Ingestion Call a physician or poison control centre immediately. Have person sip a glass of water if able to swallow. DO NOT induce vomiting unless directed to do so by a physician or poison control center. Do not give anything by mouth to a convulsing or unconscious person. Notes to physician Treatment Probable mucosal damage may contraindicate the use of gastric lavage. umffm�, �= Fire fighting 507,•�' 1 .• ABC powder Dry powder Risk of violent reaction. Further information Do not let fire burn. Nitrogen trichloride can be generated slowly by the reaction of small quantities of water with a high concentration of this product. Nitrogen trichloride can present an explosion hazard. Immediately after a fire has been extinguished, check for wet or damp material. Any spilles. material from burned or broken containers should be assumed contaminated. Neutralize to a non -oxidizing material for safe disposal. Do not attempt to re -close broken containers, even for movement to the disposal area. They should be left open to disperse any nitrogen trichloride that may form. Material which appears undamaged except for being damp on the outside, should be opened and inspected immediately. If the plastic liner (where applicable) of the container is damaged or the material is damp, the material should be chemically treated if allowable, to a non -oxidizing material for safe disposal. Bulging containers require extreme care. Contact the fire department. Protective equipment and precautions for firefighters Specific hazards during fire Under extreme heat (greater than 400F), this product will evolve noxious chlorine__.____ SAP 6.0 3/10 SDS Number: 000000004973 Material Safety Data Sheet PROGUARD@ 3" TABLETS Version.l Revision Date: 11 /10/2010 Print Date: 03/03/2012 -—: -'l'*- fighting containing gases. Special protective equipment In the event of fire, wear self-contained breathing apparatus. for f i re -fig hters Thoroughly decontaminate fire fighting equipment including all fire fighting wearing apparel after the incident. SECTION 6. ACCIDENTAL RELEASE MEASURES Environmental precautions Do not flush into surface water or sanitary sewer system. Methods for containment Using appropriate protective clothing and safety equipment, contain spilled Methods for cleaning up material. Do not add water to spilled material. Using clean dedicated equipment, sweep and scoop all spilled material, contaminated soil, and other contaminated material and place into clean dry containers for disposal. Do not close containers containing wet or damp material. They should be left open to disperse any hazardous gases that may form. Additional advice Do not use floor sweeping compounds to clean up spills. Do not transport wet or damp material. Do not contaminate water, food or feed by storage or disposal or cleaning of equipment. t i Treat recovered material as described in the section "Disposal considerations". Handling Handling procedures Strong oxidizing agent. Avoid contact with skin, eyes and clothing. Avoid breathing dust. Avoid breathing vapors. Do not mix with other chemicals. Mix only with water. Never add water to this product. Always add product to large quantities of water. Use only clean and dry utensils. Do not add this product to any dispensing devices containing remnants of any other product. Such use may cause a violent reaction leading to fire or explosion. Contamination with moisture, organic matter or other chemicals may start a chemical reaction and generate heat, hazardous as, possible fire and explosion. In case of contamination or decomposition, do not reseal container. If possible, isolate container in open air or well ventilated area. Flood with large volumes of water. Wash hands thoroughly with soap and water after handling and before eating, drinking or using tobacco. Do not handle until all safety precautions have been read and understood. SAP 6.0 4/10 SDS Number: 000000004973 Material Safety Data Sheet PROGUARD@ 3" TABLETS 1 [Version:slow 1A Revision Date: 11110/2o-lo Print Date: 03/03/2012 Requirements for storage Store in original container. areas and containers Temperature not to exceed 52 C (1 25F) for 24 hours. Store in a cool, dry, well ventilated area away from heat or open flame. Keep out of reach of children. Keep away from animals. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Exposure Guidelines Engineering measuresi Personal protective equipment Eye protection Hand protection Respiratory protection Ensure that eyewash stations and safety showers are close to the workstation location. Use with adequate ventilation. = i - A respiratory protection program that meets OSHA 1910.134 and ANSI Z88.2 requirements must be followed whenever workplace conditions warrant a respirator's use. Avoid contact with skin, eyes and clothing. Avoid breathing dust or vapor. Wash contaminated clothing before reuse. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance Form Colour Odour Safety data Flash point pH SAP 6.0 tablet white AwLef&I Note: not applicable 3-3.5 9E PROGUARD@ 3" TABLETS Material Safety Data Sheet Version: 1.1 Revision Date: 11/10/2010 Boiling point/boiling range Vapour pressure Density Water solubility 21=11i!1=1111=1� at Note: 1% Solution 437 - 446 ®F (225 - 230 -C) Note: Decomposes Note: not applicable Note: Not Available 1111111112113M 1 - 1.2 g/l at 77 'F (25 'C) Note: Not Available Print Date: 03103/201Z Conditions to avoid Remarks: High temperatures. Poor ventilation. Contamination Moisture/high humidity. Materials to avoid Remarks: Avoid contact with water on concentrated material in the container. Avoid contact with easily oxidizable material; ammonia, urea, or similar nitrogen containing compounds; inorganic reducing compounds; floor sweeping compounds; calcium ochlorite; other swimming pool/spa chemicals in their concentrated form; alkalis. Avoid contact with all other chemicals. Hazardous decomposition Note: Chlorine containing gases can be produced. products Thermal decomposition 225 - 230 ®C Hazardous reactions Hazardous polymerisation does not occur. 220mmi= LD50: :t• mg/kg Species: rat Acute inhalation toxicity Remarks: Direct contact with wet material or moist skin may cause severe irritation, pain and possibly burns. This material in the form as sold is not expected to produce respiratory effects. If ground or otherwise in a powdered form, effects similar to a corrosive 11 SAP 6.0 6/10 SDS Number: 000000004973 Material Safety Data Sheoti PROGUARD@ 3" TABLETS Version: 1.1 Revision Date: 11/10/2010 Print Date: 03/03/2012 substance may occur. May cause severe irritation of the respiratory tract with coughing, choking, pain and possibly burns of the mucous membranes. Acute dermal toxicity > 2,000 mg/kg Species: rabbit Skin irritation Remarks: Direct contact with wet material or moist skin may cause severe irritation, pain and possibly burns. Eye irritation I Remarks: Causes serious eye damage. Toxicity to fish Trichloro-s-triazinetrione LC50: 0.24 mg/l Exposure time: 96 h Toxicity to daphnia and other aquatic invertebrates. Trichloro-s-triazinetrione LC50: 0.21 mg/l Exposure time: 48 h Species: Daphnia magna (Water fleall pig M-1 MI 0 0 1 SAP 6.0 Toxic to fish. Toxic to aquatic organisms. Do not discharge effluent containing this product into lakes, streams, ponds or estuaries, oceans, or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination System (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Do not discharge effluent containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance contact your State Water Board or Regional Office of the EPA. 7/10 SDS Number: 000000004973 Material Safety Data Sheet PROGUARN) 31' TABLETS Version: 1.1 Revision Date: 11/10/2010 Print Date: 03/03/2012 SECTION 13. DISPOSAL CONSIDERATIONS Further information Dispose of waste material in compliance with all federal, state, and local regulations. If these wastes cannot be disposed of by use according to label instructions, contact your Environmental Control Agency or the Hazardous Waste Representative at the nearest EPA Regional Office for guidance. For registered pesticides, contact your State Pesticide Agency. Do not contaminate ponds, waterways or ditches with chemical or used container. Do not put product, spilled product, or filled or partially filled containers into the trash or waste compactor. Contact with incompatible materials could cause a reaction or fire. Improper disposal of excess product, spray mixture or rinsate is a violation of Federal Law. Contaminated packaging Do not re -use empty containers. Rinse thoroughly before discarding in tras! DOT UN number Description of the goods Class Packing group ERG Code FATA UN number Description of the goods Class Packing group IMDG UN number Description of the goo• Class Packing group EmS Letter I EmS Letter 2 Marine pollutant SAP 6.0 2468 Trichloroisocyanuric acid, dry 5.1 11 140 2468 Trichloroisocyanuric acid, dry 5.1 11 2468 TRICHLOROISOCYANURIC ACID, DRY 5.1 11 F-A S-Q W AMU SDS Number: 000000004973 Material Safety Data Sheet PROGUARD@) 3" TABLETS Version: 1.1 evision Date: 11 /10/2010 Trichloro-s-triazinetrione Not recommended for shipment by air Not regulated by DOT and TDG if shipped or transported in packaging less than 400KG by road and/or rail. Limited Quantity exemption possible ORM-D Consumer Commodity exemption possible Print Date: 03/03/2012 SECTION 15. REGULATORY INFORMATION OSHA Hazards This material is hazardous under the criteria of the Federal OSHA Hazard Communication Standard 29CFR 1910.1200. SARA 3111312 Hazards Fire Hazard Acute Health Hazard Reactivity Hazard The components of this product are reported in the following inventories: TSCA Note: Listed SECTION 16. OTHER INFORMATION Further information HIMIS Classification Health hazard: 3 Flammability: 0 Reactivity: 1 PPI:Ask supervisor or safety specialist for handling instructions SDS Number. 000000004973 Material Safety Data Sheet PROGUARD@ 3" TABLETS Version: 1.1 Revision Date: 11/10/2010 . ....... . . NFPA Classification Health hazard: 3 Fire Hazard: 0 Reactivity Hazard: 1 Specific hazards: OX Class 1 Oxidizer gMrZfflRMKM3M2=MMI Latin America: Brazil +52 113 7119144 All other countries +44 (0)208 762 8322 Mexico: +52 555 004 87 63 The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage, transportation, disposal and release and is not to be considered a warranty or quality specification. The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. SAP 6.0 SDS Number: 000000004973 PT-IM2 IFVOL= A Hasa Inc. P. 0. Box 802736 Santa Clarita, CA 91355 �g4 .0 j Fax 661.259.153R L1114"ILIMMIJ:401912L I- L 1.1 Product Identification: 1.1.1 Product Name: HASA MURIATIC ACID 1.1.2 CAS # (Chemical Abstracts 7647-01-0 Service): 1.1.3 RTECS (Registry of Toxic MW4025000 Effects of Chemical -,Substances)_.__ 1.1.4 EINECS (European Inventory 231-595-7 of Existing Chemical Substances): 1.1.5 Synonym: Hydrochloric Acid, Spirits of Salt 1.1.6 Chemical Name: Hydrochloric Acid 1.1.7 Chemical Formula: HCI 1. A—ec—omm e--nd ei-d-AU-s-e—s: Household cleaning, swimming pool water pH control and neutralization. 1.3 Company Identification: Hasa Inc. P.O. Box 802736 Santa Clarita, CA 91355 1.4 Emergency Telephone Number: CHEMTREC: 1-800-424-9300 (24 hour) 1.5 Non -Emergency Assistance: 661-259-5848 (8,-AM - 5 PM PST / PDT) nevision Date: 09/01/2018 (supersedes previous revisions) Page 1 of 10 Physical Hazard Symbols P-1 Zoii d w z Acute Toxicity (Oral) Skin corrosion / irritation: Serious eye damage irritation Specific Target Organ joxicLity_(Single exposure) Corrosive to metals. "Al ,P Category 3 (respiratory tract irritation) Category 1 0 DANGER -bauses severe skin burns & eye damag Harmful if swallowed. May cause respiratory irritation. Maybe corrosive to metals. I Prevention Wear protective gloves/protective clothing/eye protection/face protection. Do not eat, drink or smoke when using this product. Do not breathe mist or vapor. Use only outdoors or in a well -ventilated area. Wash hands thoroughly after handling. Keep only in original container. Response If swallowed: Rinse mouth. Do NOT induce vomiting. If inhaled: Remove person to fresh air and keep comfortable for breathing. If on skin (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center/doctor. Wash contaminated clothing before reuse. Absorb spillage to prevent material damage. Storage Store locked up. Store in a corrosive resistant container. Store in a well -ventilated place. Keep container tightly closed. Disposal - 7- Dispose of container/contents in �ccordance with local, regional, national, internatioonsas.specified. SECTION 3: COMPOSITION / INFORMATION ON INGREDIENTS Ingredient CAS No. Weight % (Approx.) 3.1 Hydrochloric Acid 7647-01-0 31.45% 3.2 Water 7732-18-5 68.55% Revision Date: 09/01/2018 (supersedes previous revisions) Page 2 of 10 n 4.2.' . ......... SECTION 4: FIRST -AID MEASURES IF IN EYES 9 Hold eye open and rinse slowly and gently with water for 15-20 minutes. e Remove contact lenses, if present, after the first 5 minutes, then continue rinsing eye. - Call a pqison control center or doctor for treatment advice. IF ON SKIN OR ® Take off contaminated clothing. CLOTHING * Rinse skin immediately with plenty of water for 15-20 minutes. 9 ('all a poison control center or doctor for treatment advice. 4.3: IF INHALED Move person to fresh air. If person is not breathing, call 911 or an ambulance, then give artificial respiration, preferably mouth-to-mouth if possible. C all "oison control center or doctor for further treatment advice 4.4.i IF SWALLOWED Call a poison control center or doctor immediately for treatment advice. Have person sip a glass of water if able to swallow. Do not induce vomiting unless of to do so by a poison control center or doctor. Do not give -anything by of to -an unconscious person. HOT LINE NUMBER Have the product container or label with you when calling a poison control center or doctor, or going for treatment. You may also contact 1-800-424-9300 fore er enc edical treatment information. Probable mucosal damage may contraindicate the use of gastric lavage- 5.1 Products of Combustion: Hydrogen and chlorine Hazards in Presence of Reacts with any metals to liberate hydrogen gas is Vari s can for explosive mixtures with air. 5.3 Explosion Hazards: Not sensitive. 5.4 it Fighting Media 5.4.1 Extinguishing Media: Use extinguishing measures appropriate to local circumstances and the surrounding environment. 5.4.2 Sim—a-1-10ires: Use carbon dioxide, dry chemical, dry sand, alcohol - resistant foam or water Sp 5.4.3 Large Fires: Water spray, fog or alcohol -resists t foam. Move containers from fire area if you can do it without risk. Use water spray or fog; do not use straight streams. Dike fire -control water for later disposal; do not scatter the material. 5 .5, it involi Ing TaniOd—ars i Fe v Fight fire from maximum distance or use unmanned hose Trailer Loads: holders or monitor nozzles. Do not get water inside containers. Cool containers with flooding quantities of water until well after fire is out. Withdraw immediately in case of rising sound from venting safety devices or discoloration of tank. ALWAYS stay away from tanks engulfed in fire. I Revision Date: 09/01/2018 (Supersedes previous revisions) Page 3 of 10 SECTION 6: ACCIDENTAL RELEASE MEASURES 6.1, Small Spill: Gather up with a squeegee and place in pool and spa. If this is not possible, absorb with sand, diatomaceous earth or similar products and _securely _.bag,.'and.place in trash for collection. 6.2' Large Spill: Steps to be taken in case material is released orspilled: Spills or discharges into the environment involving large quantities of Hydrochloric Acid should be controlled and cleaned -up according to a pre -determined, affirmative written Spill Prevention and Control Program. Refer to Section 15 fors ill/release reporting information. Spills should be handled immediately by neutralization and dilution of the spilled product by the use of Soda Ash (Sodium Carbonate), Lime (Calcium Hydroxide), or Limestone (Calcium Carbonate) with large amounts of water. For an interior (inside a closed space) spill be are that the use of Soda Ash, Lime and Limestone will evolve heat and carbon dioxide and that ample ventilation must be provided. If possible without personal risk, stop leak. Try to prevent the materials from entering drains, waterways, or sewers and dispose of in accordance with local regulations. Rinse exposed area with dilute sodium carbonate solution. SECTION 7: HANDLING AND STORAGE Keep away from skins and eyes. Do not inhale or swallow. Do not mix with chlorine type bleaches or other household chemicals. Whenever handling muriatic acid, wear protective clothing (goggles, old clothing and rubber gloves). Remove protective clothing and wash before reuse. store muriatic acid in a clean, dry place in the upright position. Kee,# out of reach of children, pets and other animals. Rinse empty container thoroughly before discarding, IN Revision Date: 09/01/2018 (Supersedes previous revisions) Page 4 of im SECTION 8: EXPOSURE CONTROLS / PERSONAL PROTECTION 8.1 Engineering Controls: Local exhaust to maintain levels below Permissible Exposure -.Limit 8.2 Personal Protection: When necessary, wear splash goggles or safety glasse an-d qloves. ig'I me is. If 8.3 Personal Protection in case of a Wear splash goggles or safety glasses and I Large Spill: natural ventilation is insufficient, wear a NIOSH approve .g respirator. 8.4 Exposure Guidelines: 8.4.1 ACGIIH (American '5 ppm (7 mglml) Ceiling Conference of Governmental and Industrial Hygienists) TLV (Threshold Limit Value) 8.4.2 iPEL (OSHA Permissible 5 ppm (7 Mg/M3) Ceiling Limit Exposure Limit) 8.4.3 IDLH (NIOSH Immediate 50 ppm (75 mg/ml) Danger to Life &,Health) 8.4.4 AlHA (American Industrial ERPG — 1 (The maximum airborne concentration below which Hygiene Association) it is believed nearly all individuals could be exposed for up to one hour without experiencing other than mild transient adverse health effects or perceiving a clearly defined objectionable odor.): 3 pprn ERPG — 2 (The maximum airborne concentration below which it is believed nearly all individuals could be exposed for up to one hour without experiencing or developing irreversible or other serious health effects or symptoms that could impair an individual's ability to take protective action.): 20 ppm ERPG — 3 (The maximum airborne concentration below which it is believed nearly all individuals could be exposed for up to one hour without experiencing or developing life -threatening health effects.): Revision Date: 09/01/2018 (Supersedes previous revisions) Page 5 of 10 9.1 Appearance: Colorless_�iquicl. 9.2 Odor: Irritating and punclent odor. 9.3 Odor tivr-�e66-1d: 4.7 ppm e�at 25 OC 9.4 pH: 95.� -TMe11:t6ng Point: it --140�tppocable. 9.6 i Freezinq point: -46.90C (-52.5 OF) 9.7 Boilin Point & Boiling Range: 85 OC (1185 OF) 9.8 Flash Point: No i nformation avail -able. 9.9 Evaporation Rate: No information available. 9.10 Flamm�!Mlity (solid, gas): m- combustible. Nonffa rnai•l0�and non 9.11 Upper / Lower Flammability or Not applicable. Explosive Limits: 9.12 Vapor Pressure: 40 mm Hg 0 300C (86017N OU IJ 9.13 Vapqr_Density.� No informati.on available. 9.14 Relative Density (Specific Gravity)- 1. 16 @ 15.5 OC (60 OF) 9.15 Solubility in -Water: Mixes with water in all concentrations. 9.16 Partition Coefficient: (n-octanol Not applicable. 9.17 Auto ignition Temperature: Not -applicable. 9.18 DecomppionTemp ature: 850C. Rate of decomposition increases with heat. 9.19 a"I 'c-ular Weight: 36.46 q/mole 9.20 Viscosity., 1.55 centipoises 0 301C (86'F) SECTION 10: STABILITY AND REACTIVITY 10.1 Stability: Stable under normal conditions of storage, handling, i. and use. 10.2 Instability Temperature: 10.3 Conditions of Instability: 10.4 Incompatibty with Various Substances: 10.5 1 Special Remarks on Reactivity: 10.6 � Hazardous Polymerization: 850C. Rate of decompmsion increas-es with heat. High heat, ultraviolet light. Oxidizing agents, acids, nitrogen containing organic, metals, iron, copper, nickel, cobalt, organic materials, and ammonia. Corrosive to most metals with evolution of hydrogen gaswhich may form expLosLve mixtures -with air. Rate of decomposition increases with heat. Will not occur. W • W • Jw� Revision Date: 09/01/2018 (Supersedes previous revisions) Page 6 of ill 11.1 Routes of Entry: Eyes, skin, ingestion. 11—.2 Eye damage & skin corrosion: Causes eye burns. Contact with this material will cause burns to the skin, eyes and mucous membranes. Permanent eye damage including blindness could result. 11.3 to Oral Toxicity (LD50): NIOSH: 900 mg/kg (rabbit) 11.4 Acute Inhalation Toxicity (LC50): 3124 mg/l, 1 Hour (rat) 11.5 Toxic Effects on Humans: Harmful if swallowed. Causes digestive tract burns. Ingestion may produce burns to the lips, oral cavity, upper airway, esophagus and possibly digestive tract. ------ _the 11.6 Carcinogenic [Cancer Potentiall Information: NTP (National Toxicological Program 61h Not Listed. Annual Report on'Carcinogens): IARC (international Agency for Research Not Listed. on Cancer Monographs, V. 1 - 100): Proposition 65, California only: Not Listed. (Safe Drinking Water and Toxic Enforcement Act of 1986): m - WA i qiTi Qj-, e n I —601-6-cTs-: INO ble to VAwjF-a.jP-pnQUuLaAA-dLLy-- � .1 RMTJ�, -� 11.9 Medical Conditions Generally Aggravated by Exposure: 11.10 Health Hazards (Acute and Chronic): components present at greare—r=47"o are mutqq_qniq or qenotoxic. Exposure to hydrochloric acid may cause severe burns at the contact points. Exposure to fumes may aggravate dermatitis and breathinq disorders. Hydrogen Chloride, both as a gas and in a solution as Hydrochloric Acid, is a corrosive substance and can cause severe and painful burns on contact with any part of the body or if taken internally. The mucous membranes of the eyes and the upper respiratory tract are especially susceptible to the irritating effects of high atmospheric concentrations of Hydrogen Chloride - The gas or vapor is so penetrating and pungent that when high concentrations do occur, those exposed should immediately leave the contaminated area. W "W Revision Date: 09/01/2018 (Supersedes previous revisions) Page 7 of 10 IM .......... _ _ ......... . ...... .. _ ____ _", . ........... — --- --- SECTION 12: ECOLOGICAL INFORMATION Ecotoxicity This product is toxic to fish and aquatic organisms. Do not contaminate General: water containing this product to sewer systems without previously notifying the local sewage treatment plant authority. For guidance, contact your State Water Board or Regional Office -of the EPA. Ecotoxicological LC5o Shrimp 100 to 330 ppm/48 hr (salt water) Information: LC50Mosquito Fish 282 mg/L (24 to 96 hours) LC5o Green crabs 100 mg/L (96 hr produced no stress effects) LC5o Gold fish 180 mg/L (96 hours) Aquatic Hazard Concern Level : moderate Persistence and When hydrochloric acid is spilled onto soil, it will begin to infiltrate. The Degradation: presence of water in the soil will influence the rate of chemical movement in the soil. During transport through the soil, hydrochloric acid will dissolve some of the soil material, in particular those of a carbonate base. The acid will be expected to remain for transport down toward the ground water table. Hydrogen chloride in water dissociates almost completely, with the hydrogen ion captured by the water molecules to form the hvdronium ion. 12.4 Products of Biodegradation: 121110M mo- 011M.1111 SECTION 13: DISPOSAL CONSIDERATIONS Do not contaminate food or feed by storage, disposal, or cleaning of equipment. Product or rinsatw, that cannot be used should be diluted with water before disposal in a sanitary sewer. Do not discharge effluent containing this product into lakes, streams, ponds, estuaries, oceans, or other waters unless in accordance with the requirements of a National Pollutant Discharge Elimination system (NPDES) permit and the permitting authority has been notified in writing prior to discharge. Dispose of in accordance with all applicable local, county, State, and Federal regulations. SECTION 14: TRANSPORT INFORMATION 14.1 Shipping Name: Hydrochloric Acid 14.2 Hazard Class / Division: 14.3 Identification No.: UN 1789 1 4174 Packing Group: PG 14.5 Reportable Quantity (130): '; 5,000 lb (1643 gallons) 14.6 Deposrt'lPails, Carboys and The shipping description for return of empty deposit pails, Drums: carboys, and drum is "RESIDUE: LAST CONTAINED UN1789, HYDROCHLORIC ACID, 8, PGII" .-1-4--.7---M-i-ter—iali—of'-Tr—ad--e—(—M'- -0--T—)--E-x—cep—ti--o--n--s-.---- Certain hazardous materials transported in small quantities as part of a business are subject Is, bject as to less regulation, because of the limited hazard they pose. These materials are known as Materials of Trade. The regulations that apply to MOTS are found in 49 CFR a-tion is not intended to convey all specific regulatory or operational requirements / information This Is relating to this product. It is the responsibility of the transporting organization to follow all applicable laws, ,.-,regulations and rules relating to the transportation of the material. Revision Date: 09/01/2018 (Supersedes previous revisions) Page 3 of 10 SECTION 15: REGULATORY INFORMATION U.S. Regulations: 15.1.1 OSHA HAZCOM (Hazard Communication) 15.1.2 OSHA PSM (Process Safety Management): 15.1.3 EP_A___tVcJR_A (EPA Emergency Planninq and Community Right -to -know Act): 15.1.4 EPA TSCA (Toxic Substance Control Act): 15.1.5 EPA CERCLA (Comprehensive Environmental Response, Compensation, and Liability _Act): 15.1 e6 EPA FIFRA (Federal Insecticide, Fungicide, Fungicide, and Rodenticide Act): 15.1.7 & A RMP (Risk Management Plan): State of California Regulations: 52.1 CDPR (California Department of Pesticide Regulation) 15.2.2 --_'_____.._(California Accidental Release Prevention): 15.3 Canada Regulations: 15.3.1 WHMIS (Workplace Hazardous Materialr Information System): 115.3.2 DSL (Domestic Substances List): 1 international Inventory: 15.4.1 AIdS (Australian Inventory of Chemical Substances): 715 4-2 k1fC1 (Korean Existing Chemicals Inventory): 15.4.3 PICCS (Philippine Inventory of Chemicals and Chemical Substances 15.4.4 lEdSC_ (inventory of Existing Chemical Substances in China): 15A.5 NZIoC (New Zealand Inventory of Chemicals)� This material is considered hazardous under the HAZCOM standard (29 CFR 1910.1200. Not regulated under PSM standard (29 CFR Not listed on Extremely Hazardous Substances and Their Threshold Planning Quantitie p S (A•pendix A to 4-0-CFR Part-3-55)_ All components are listed or exempted. TSCA 12(b): This product is not subject to export notification. ]-Rep o.-h-a—ble buantity (RQ) —uncle—r 5000 lbs. (1643 gallons). Registration No: 10897-50008-AA (spray adjuvantJ_ _ Not regulated. WHMIS classification: D1 A - Poisonous and infectious material - Immediate and serious effects - Very toxif# E - Corrosive Materials All components of this product are on the DSL. 323mum= On inventory or in compliance with inventory. On inventory or in compliance with inventory. On inventory or in compliance with inventory. OWA Revision Date: 09/01/2018 (Supersedes previous revisions) Page 9 of 10 SECTION 16: OTHER INFORMATION 16.1 HIVIIS III (Hazardous Materials Identification System): PM 16. 1 .3 v . ..... "A 3 9 PERSONAL PROTECTION - 1 '-16.2 See Section 8 N'�PA 7 04 (National Fire Protection Association): 16.2.1 Health 3 16.2.21, Flammability 0- 16.2.3 Instability 16.2.41 Special None 16.3 International Fire Codef International Corrosive Liquid. Building Code: 16.ANSI (American National Standards Institute): 4 16.4.1 Hazardous Industrial Chemicali- Complies with ANSI Z400.1 — 2004- IVISDSs- Preparation: 16.4.2 Hazardous Industrial Chemicals - Complies with ANSI Z129.1 — 2006. Precautionary Labeling: N ppM to Mg/M3: ote: To convert concentrations in air (at 250C) from mg/m3 = (ppm) x (molecular weight of the compound) 3 For hydrochloric acid: 1 ppm = 1.49 mg/m . I i The information contained herein, while not guaranteed, was prepared by competent technical personnel and is true and accurate to the best of our knowledge and belief. NO WARRANTY OR GUARANTEE, express or implied, is made regarding the product performance, product stability, or as to any other condition of use, handling, transportation, and storage. Customer use, handling, transportation, and storage may involve additional safety and/or performance considerations. Our technical personnel will be happy to respond to questions regarding safe handling, storage, transportation, and use procedures. The safe handling, storage, transportation, and use procedures remain the sole responsibility of the customer. No suggestions for handling, storage, transportation, or use are intended as or to be construed as recommendations which may infringe on any existing patents or violate any Federal, State, and/or local law and/or regulation, ordinance, standard, etc. This Safety Data Sheet has been prepared by Hasa, Inc. staff from test reports and other information available in the public domain. Revision Date: 09/01/2018 (Supersedes previous revisions) Page 10of lit 111^� OXY Occidental Chemical Corporation Nk.O-O/ A subsidiary of Occidental Petroleum Corporation SDS No.: M31032 SIDS Revision Date: 12-Nov-2014 1. CHEMICAL PRODUCT AND COMPANY IDENTIFICATION Company Identification: Occidental Chemical Corporation 5005 LBJ Freeway P.O. Box 809050 Dallas, TX 75380-9050 1-800-752-5151 24 Hour Emergency Telephone 1-800-733-3665 or 1-972-404-3228 (USA); CHEMTREC (within USA and Number: Canada): 1-800-424-9300; CHEMTREC (outside USA and Canada): +1 703-527-3887; CHEMTREC Contract No: CCN16186 To Request an SDS: MSDS@oxy.com or 1-972-404-3245 Customer Service: 1-800-752-5151 or 1-972-404-3700 Product Identifier, CYANURIC ACID, DRY Synonyms: 1,3,5-Triazine-2,4,6 (1 1-1,31-1,51-1)-trione, CYA, Cyanuric acid, 2,4,6-Trihydroxy-s-triazine, lsocyanuric acid, Symmetrical triazinetrione Product Use: Chlorine stabilizer for swimming pools, Flame retardant, Chemical Intermediate Uses Advised Against: None identified. 2. HAZARDS IDENTIFICATION Print date: 12-Nov-2014 1 of 12 M� Z OSHA REGULATORY STATUS: This material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). reme Appearance: Odor: Solid PAW41 P I M1610111- practices include but are not limited to: wearing suitable gloves and/or eye protection; washing hands and affected skin immediately after handling, before breaks, and at the end of the workday; regularly cleaning work area and clothing; etc. I GHS CLASSIFICATION: Note: There is not a GHS classification associated with this non -hazardous material. iGHS: CARCINOGENICITY: This product is not classified as a carcinogen by NTP, IARC or OSHA. UNKNOWN ACUTE TOXICITY: Not applicable. This product was tested as a whole. This information only pertains to untested mixtures. GHSSYMBOL: None I kq I A 24 Lei 9014 M F-111 m F�M V D i � I None identified I =1161A 15401 KeTeINTIME99KOLIM Eel � I Print date: 12-Nov-2014 2 of 12 SDS No.: M31032 SDS Revision Date: 12-Nov-2014 - - ------- - 3. COMPOSITIONIIN FORMATION ON INGREDIENTS Synonyms: 1,3,5-Triazine-2,4,6 (1 1-1,31-1,51-1)-trione, CYA, Cyanuric acid, 2,4,6-Trihydroxy-s-triazine, Isocyanuric acid, Symmetrical triazinetrione Component._....._.,.. Percent °/® CAS Number Cyanuric acid 98-100 108-80-5 INHALATION: No effects expected. If adverse effects occur, remove to uncontaminated area. IF SYMPTOMS OF OVEREXPOSURE OCCUR, GET MEDICAL ATTENTION. SKIN CONTACT: Wash contaminated areas with soap and water. IF IRRITATION PERSISTS, GET MEDICAL ADVICE/ATTENTION. EYE CONTACT: Solids should be removed, Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF IRRITATION OCCURS, GET MEDICAL ATTENTION. INGESTION: No effect expected. IF LARGE AMOUNTS ARE INGESTED, GET MEDICAL ATTENTION. Inhalation (Breathing): Inhaling powder or fine particulates of this material may cause respiratory tract irritatiol cough. Skin: Skin Irritation: Exposure to powder or fine particulates of this material may cause slight skin redness, irritation. Eye: Eye Irritation: Eye exposure may cause mild irritation of the eye lids and conjunctiva. Ingestion (Swallowing): No known effects. Delayed Symptoms/Effects: kki KIT and respiratory conditions including asthma and other breathing disorders. Protection of First-Aiders: Avoid contact with skin and eyes. Use personal protective equipment. Refer to Section for specific personal protective equipment recommendations. At minimum, treating personnel should utilize PPE sufficient for prevention of bloodborne pathogen transmission. Notes to Physician: This material causes mild irritation to skin and eyes. Removing the material via irrigation is -Rff�Z . 19]Rufficoent. There is no antidote. Coanuric acid is readilN removed from the bodkj via the renal system, and is n�io bioaccumulated. Treatment is supportive care. I Print date: 12-Nov-2014 3 of 12 Fire Hazard: Negligible fire hazard. Extinguishing Media: Use extinguishing agents appropriate for surrounding fire. Fire Fighting: Move container from fire area if it can be done without risk. Avoid inhalation of material or combustion by-products. Stay upwind and keep out of low areas. Wear NIOSH approved positive -pressure self-contained breathing apparatus operated in pressure demand mode. Aazardous Combustion Products: Cyanic acia, Art] Sensitivity to Mechanical Impact: Not sensitive. Sensitivity to Static Discharge: Not sensitive. Lower Flammability Level (air): Not flammabl,!-� Upper Flammability Level (air): Not flammable Flash point: Not flammable Auto -ignition Temperature: Not applicable I R =I 4 =F.11,41 I A a Personal Precautions: Avoid contact with eyes. Avoid generating dust. When handling this material, wear appropriate personal protective equipment recommended in Section 8, Exposure Controls / Personal Protection, of the SDS. Methods and Materials for Containment and Cleaning Up: Collect spilled material in appropriate container for disposal. Environmental Precautions: Keep out of water supplies and sewers. Releases should be reported, if required, to appropriate agencies. 7. HANDLING AND STORAGE Print date: 12-Nov-2014 4 of 12 Precautions for Safe handling: Use methods to minimize dust. Observe good personal hygiene practices and recommended procedures. Wash thoroughly after handling. Wear personal protective equipment as described in Exposure Controls/Personal Protection (Section 8) of the MSDS. Safe Storage Conditions: Store and handle in accordance with all current regulations and standards. Store in a cool, dry area. Store in a well -ventilated area. Keep separated from incompatible substances (see below or Section 10 of the Safety Data Sheet). . I - rMAMI# U oxidizing agents IF MUMM23M 1111, 7111111 1 en 7, JiE lf� ILIJIMMMOME3620 Non-Regulatoty United States Occupational Safety and Health Administration (OSHA) limits, if shown, are the Vacated 1989 PEL's (vacated by 58 FR 35338, June 30, 1993). Additional Advice: Even though this material is not classified as hazardous according to US OSHA's 2012 Hazard Communication Standard, good hygiene and safety practices should be followed. Good hygiene practices include bul are not limited to: wearing suitable gloves and/or eye protection; washing hands and affected skin immediately after handling, before breaks, and at the end of the workday; regularly cleaning work area and clothing; etc. ENGINEERING CONTROLS: General or local exhaust ventilation and other forms of engineering controls are the preferred means for controlling exposures. Ensure compliance with applicable exposure limits. Eye Protection: Use good hygiene practices when handling this material. If eye contact is likely, wear chemical resistant safety goggles. 1 Ma 1 r-A practice, wear praTMA[Ve LAUL111111Y LV IIIIIIIIIIIII/-C tiKIIII LAIMaA r_V'reTaffW, safety footwear. Contaminated clothing should be removed and laundered before reuse. Print date: 12-Nov-2014 5 of 12 Respiratory Protection: No personal respiratory protective equipment normally required. A NIOSH approved respirator with N95 (dust, fume, mist) cartridges may be permissible under certain circumstances where airborne . I♦- of overexposure. In dusty or misty atmospheres use an approved particulate respirator. A respiratory protection program that meets 29 CFR 1910.134 must be followed whenever workplace conditions warrant use of a respirator. Physical state Appearance: Color: Odor: Molecular Weight: Molecular Formula: Decomposition Temperature: Boiling Point/Range: Freezing Point/Range: Melting PointlRange'. Vapor Pressure: Vapor Density Relative Density - Specific Gravity (water--1): Density: Bulk Density: Water Solubility: pH: Volatility: Evaporation Rate (ether--1): Partition Coefficient (n-octanollwater): Flash point: Flammability (solid, gas): TkP Auto -ignition Temperature: Viscosity: I Solid Granules, Powder White tooff-white Odorless 129.08 H3C3N3O3 662-680 'F (350 - 360 OC) (sublimes) Not applicable to solids Not applicable to solids. Decomposes without melting 0.000001 Pa @ 25 'C Not applicable 175 III � illi�illillilill , llppilllt111 IF Print date: 12-Nov-2014 6 of 12 SDS No.: M31032 SDS Revision Date: 112-Nov-2014 Possibility of Hazardous Reactions: Conditions to Avoid: (e.g., static discharge, shock, or vibration) - None known. .ncompatibi I !ties/ Materials to Avoid: #,xidizing agents I , �iili WOMEN � ill I lilllllill -1 i ill I a I IRRITATION: Contact with this material may cause mild, reversible irritation •to the eys and skin. Based on the mild reaction seen in the test animals, it is not classified as an irritant by OSHA. LD50 Oral: LD50 Dermal: j LC50 Inhalation: 3400 mg/kg (Mouse), 7700 mg/kg > 5000 mg/kg (Rabbit) > 5.25 mg/L (4 hr - Rat) (Rat) COMPONENT TOXICITY DATA: Component f LD50 Oral: LD50 Dermal: i LC50 Inhalation: Cyanuric acid 7700 mg/kg (Rat) i 2000 mg/kg (Rabbit) 'I 108-80-5 Eye contact: May cause mild eye irritation. Skin contact: May cause slight skin irritation. Inhalation: No known effects. Inhalation of powder or fine particulates may cause irritation, cough. Ingestion: No known effects. Print date: 12-Nov-2014 7 of 12 X1 MIMMILI 14-IRK1�1i]IM! Inhalation (Breathing): Inhaling powder or fine particulates of this material may cause respiratory tract irritatiol cough. Skin: Skin Irritation: Exposure to powder or fine particulates of this material may cause slight skin redness, irritation. Eye: Eye Irritation: Eye exposure may cause mild irritation of the eye lids and conjunctiva. Ingestion (Swallowing): No known effects. TOXICITT: This material is believed to be non -toxic by inhalation, dermal exposure and ingestion. Monosodium cyanurate wa administered via drinking water to rats for 104 weeks at concentrations of 0, 400, 1200, 2400, and 5375 ppm ja&&Ja� water consu Pferts oti bodv weights, clinical signs of toxicitv or food or rzil ple.T491-Ael rQ& -------- GHS HEALTH HAZARDS: azard Communication Standard 29 CFR 1910.1200) There is not a GHS classification associated with this non -hazardous material GHS: CARCINOGEMMY: I ' 13y: 111IJ _1 MUTAGENIC DATA: Not classified as a mutagen per GHS criteria. Not mutagenic in 5 Salmonella strains and 1 E. coli strain with or without mammalian microsomal activation. REPRODUCTIVE TOXICITY: Not classified as a reproductive toxin per GHS criteria imp-9 12. ECOLOGICAL INFORMATION Aquatic Toxicitv: , ?h- xi?ijs %,PlipmP4 ta Wip nr t 101-to. Print date: 12-Nov-2014 8 of 12 411-11Zt� .Algae Toxicity: EC50 Green algae: 655-712 mg/L (96 hour) EC50 Navicula pelliculosa: >3780 mg/L (96 hour) BIODEGRADATION: Cyanuric acid biodegrades readily under a wide variety of natural conditions, and particularly well in systems of either low or zero dissolved -oxygen levels. PERSISTENCE: This material is believed not to persist in the environment. Cyanuric acid has an estimated Henry's Law Constant of 1.36 X 110(-18) atm-m3/mol. Atmosphere half-life is estimated to be 102 days. Cyanuric acid will have a high soil mobility based on KOC values ranging from 66 to 124. BIOCONCENTRATION: Aquatic bioconcentration and adsorption are not expected to be important fate processes for cyanuric acid. The BCF for cyanuric acid is <0.5 at 1 mg1L for a 6-week duration. MOBILITY IN SOIL: Cyanuric acid will have a high soil mobility based on KOC values ranging from 66 to 124- ADDITIONAL ECOLOGICAL INFORMATION: Cvanuric acid is toxic to certain plants including barley and radish-" due to acidic nature of material. I Waste from material: Reuse or recycle if possible. Dispose in accordance with all applicable regulations. Container Management: Dispose of container in accordance with applicable local, regional, national, and/or international regulations. Container rinsate must be disposed of in compliance with applicable regulations. MMIRMI�E Print date: 12-Nov-2014 9 of 12 611&Alt: OSHA REGULATORY STATUS: This material is not considered hazardous by the OSHA Hazard Communication Standard (29 CFR 1910.1200). ©L SECTIONS 102a/103 HAZARDOUS SUBSTANCES (40 CFR 302.4); Not regulated. Not regulated 1 11! ljG;j Not regulated. OSHA PROCESS SAFETY (PSMI (29 CFR 1910.116M Not regulated I U.S. INVENTORY STATUS: Toxic Substance Control Act (TSCA): All components are listed or exempt. Alm CANADIAN REGULATIONS I This product has been cl re'&'Kmil SDS contains all the information required by the Controlled Products Regulations. Print date: 12Nov-2014 10 of 12 SDS No.: M31032 SDS Revision Date: 12-Nov-2014 WHIVIIS - Classifications of Substances: • Not a controlled product under Canada's Workplace Hazardous Information System Health Rating: 1 Flammability Rating: 0 NFPA 704 - Hazard Identification Ratings (SCALE 0-4) Health Rating: 1 Flammability: A Reason for Revision: • Three year review • Changed the North American sub -format name from "NA" to "ANSI" • Updated the (M)SDS header • Updated 24 Hour Emergency Telephone Number: SEE SECTION 1 • Product Identifier has been added or updated: SEE SECTION 1 • Added synonym(s): SEE SECTION 1 • Updated Uses Advised Against information: SEE SECTION 1 • Added OSHA Status: SEE SECTION 2 • The Emergency Overview Signal word has been added or changed. SEE SECTIONI-Q, • Added GHS Information: SEE SECTION 2 • Added synonym(s): SEE SECTION 3 • Updated First Aid Measures: SEE SECTION 4 • Modified Fire Fighting Measure Recommendations: SEE SECTION 5 • Revised Accidental Release Measures: SEE SECTION 6 • Revised Handling and Storage Recommendations: SEE SECTION 7 • Revised Exposure Controls/Personal Protection information: SEE SECTION 8 • Updated Physical and Chemical Properties. SEE SECTION 9 • Stability and Reactivity recommendations: SEE SECTION 10 • Toxicological Information has been revised: SEE SECTION 11 • Ecological Information has been modified: SEE SECTION 12 • Updated Disposal Considerations. SEE SECTION 13 • Regulatory Information Changes: SEE SECTION 15 • Revised Preparer Information: SEE SECTION 16 • Added SDS Revision D. SEE SECTION 16 • A component has been added to the formulation. SEE SECTION 2. Print date: 12-Nov-2014 11 of 12 IMPORTAOIT: The information presented herein, while not guaranteed, was prepared by technical personnel and is true and accurate to the best of our knowledge. NO WARRANTY OF MERCHANTABILITY OR OF FITNESS FOR A PARTICULAR PURPOSE, OR WARRANTY OR GUARANTY OF ANY OTHER KIND, EXPRESSED OR IMPLIED, IS MADE REGARDING PERFORMANCE, SAFETY, SUITABILITY, STABILITY OR OTHERWISE. This information is not intended to be all-inclusive as to the manner and conditions of use, handling, storage, disposal and other factors that may involve other or additional legal, environmental, safety or performance considerations, and OxyChem assumes no liability whatsoever for the use of or reliance upon this information. While our technical personnel will be happy to respond to questions, safe handling and use of the product remains the responsibility of the customer. No suggestions for use are intended as, and nothing herein shall be construed as, a recommendation to infringe any existing patents or to violate any Federal, State, local or foreign laws to written records. We request that you, and it is your legal duty to, make all information in this Safety Data Sheet available to your employees 7ROIVVWMMZT�� Print date: 12-Nov-2014 12 of 12 PRODUCT DATASHEET AQUASALT' FOR SALT WATER SWIMMING POOLS -EVAPORATED FOOD OUALITY _90#1911[10b Evaporated Food Quality AQUASALT R is intended for use in swimming pools with a chlorine generator or salt water sanitizing systern and not for hurnan consumption. AQUASALT IV is greater than 99%e sodium chloride or NACL The purity and crystal size are designed to produce the fastest dissolve rate in swimming pools and spas with chlorine generators. PROCESS The product is made in the mechanical vapor recompression evaporating system from saturated brine. The salt is dried and screened for even distribution and dissolving. ZRTZRRKM9R��= AQUASALT @ should be distributed over the greatest water surface area possible to result in the fastest dissolve rate. Follow the Chlorine Generator Manufacturer guidelines for quantity and frequency of adding salt. Avoid piling the salt on the pool surface and brush as necessary until fully dissolved. "94us Aki 76-80 lbs, per cubic foot PACKAGE The product is packaged in recyclable polyethylene film bags. The bag has a built in soft handle. TYPICAL CHEMICAL ANALYSIS Constituent Weight Percent Sodium Chloride 99.9 PACKAGING BAG SIZE (1i UPC CODE DIMENSIONS WxLxH 40 0-41430-08368-3 15.5" x 25.0" x 3ff' PALL ETIZATION Bags/Pallet Dimensions WxLxH Gross Wt. (Lbs.)** 63 40" x 48" x 34" 2600 CUBE (W) 0.52 Pallet Pattern (Tiers) i 9 tiers of 7 DISCLAIMER: This information is accurate to the best of our knowledge but is not intended as a specification, and no warranty, expressed or implied, is given. AQUASALT 0 , LLC 4800 San Felipe Houston, TX 77056 USA Toll free: (866) 549-POOL (7665) Updated� 8/24/09 www.aquasait.com aquainfo@aquasaltcom Page I of 1