HomeMy WebLinkAboutCO2026-001403 /O CHECK LIST
C/O PERMIT# 26
ADDRESS:
BUSINESSNAME:
BUSINESS PROPERTY
','HANGE NAME OWNER
NEW TENANT / C )CCUPAN'T
2.
4.
5.
6
7,
10
11
12
13
"'14
15
16
NEWCONST/ADDITION PEA IT
REMODEL f ALTERATION PERMIT #
ISSUE DATE- FINAL DATE
APPLICATICDN FORM COMPLETED
WORKORDER FORM COMPLETED
ENVIRONMEN"SAL NOTIFIED DArE TIML
(E-MAIL JIMMYEROCK & VALERIE FARRELL, -
HAZARDOUS MATERIAL, SAFETY DATA SHEE'rs TO FIRE DATE
(SCAN TO CIO IN MYGOV - IF LARGE SET, ALSO SCAN TO LF & FORWARD SET TO FIRE)
FIRE DEPARTMENT APPROVAL OF HAZARDOUS MATERIAL DATE--,"'',
ZONING CHECKED A COMPLETED ON APPLICATION
BUILDING INSPECTION SCHEDULED DATE TIME
FIRE DEFT INSPECTION SCHEDULED DATE TIME
FIRE INSPECTOR:
HEALTH INSPECTION NOTIFICATiON DATE:
CITY SECRETARY (ALCOHOL) NOTIFICATIONDATE:
C/O CERTIFICATE ISSUED
E-MAIL DATE--- . ........ . . . . ....... . .. ..
E-MAILDATF.,
DATE
LETTER. YES /
LEFT R YES / NO
DATE OF ISSIJANCE:
CIP"ARTTIFICATE-4(31CCUPANCY RE"JUEST
a
FEE: $50.00
NO FEE REQ UIRED IF THE CERTIFICA TE OF OCCUPANCY IS ASSOCIA TED WITH AN ACTIVE CURRENT B UILDING PERMT,
1J)DRESS OF OCCUPANCY: -7�V Por4- llma�z �� P 6-c� SUITE#15D
A
I
N
0 V I a
I I III III III III III !I! III III III III Ix:: 11 11 111 1 1
I HEREBY CERTIFY THAT THE FOREGOING IS CORRECT TO THE BEST OF MY KNOWLEDGE AND THE SAID
OCCUPANCY IS IN CONFORMANCE WITH THE INFORMATION HEREIN SET FORTH.
(If access to the baril ding/s'°'Orovided at the time of the scheduled inspection, a $50.00 re -inspection fee win be charged)
FOR QUESTIONS 0'r CALL (817) 410-3165 or (817) 410-� 166
SIGNATURE:—Z PRINT NAME:
PHONE#: 61-2 Z 17-1r
EI
Building Services Department
The City of Grapevine * P.O. Box 95104 * Grapevine, Texas 76099
(817) 410-3165 (817) 410-3166
0:1PORMUS PPUCATIONSfEES= APP
11?2lQ4
. . ..........
A "Seller or Retailer" means a person engaged in the business of making sales of "taxable items", the receipts from which are
i ded in the measure of sales or use tax.
The term, "place of business" includes any location at which three or more orders are received by the "SeHer or Retailer
[n a calendar year. If an order is received at the place of business of a retailer in Texas, but delivery or shipment is made
the city where the order was received.
r
ju
Grapevine, Texas if the circumstance applies to my business.
Texas Sales Tax Number:
0!-=
ADDRESS: 7D,
CITY, STATE, ZIP: Ur
1111111 111111 ill 1 1 :1;i��
iiiiiiwmamj I I I iiiii 11111 � I 10"illow
TYPE OF CONSTRUC'TION-,,L!-1 .,X OCCUPANCY: DIVISION:
ZONING DISTRICT: CONDITIONAL USE:
PERMITTED USE: OCCUPANT LOAD:
DATE
BUILDING DEPART:MENT: fi
BUILDING INSPECTOR: DATE.
ZONING APPROVAL: DATE:
FIRE DEPARTMENT: DATE:
LOT DRAINAGE INSPECTION: DATE:
PUBLIC WORKS DEPARTMENT: DATE:
I,T,-:ALTH DEPARTMENT: DATE:
CITY SECRETARY: DATE:
LANDSCAPINGAP OVAL,: DATE:
APPROVAL FOR ISSUANCE, DATE:
11�0 J, T
PO Box 95104 Project # 26-001403
Grapevine, Texas 76099
Project Description: C/O (HVAC) "Texas HVAC Experts LLC"
817) 410-3166
Issued on: 06/02/2026 at 9:31 AM
ADDRESS
INSPECTIONS
4
750 Portamerica PI., 250
1. Final Fire Dept Inspection
3. Landscaping
Grapevine, TX 76051
2. Final Building C/O Inspection
4. C/O APPROVED FOR ISSUANCE
LEGAL
1 metroplace #1 Addition
INFORMATION FIELDS
Blk 2 Lot 2
S
**NAME OF BUSINESS
Texas HVAC Experts LLC
**TENANT NAME (individual)
Kris Tennison
PERMIT HOLDER
**TENANT PHONE NUMBER
682-777-1542
Kris Tennison
Texas HVAC Experts LL
APPLICANT E-MAIL
C
—APPLICANT NAME (individual)
Kris Tennison
(682) 777-1542
**APPLICANT PHONE NUMBER
682-777-1542
OWNERS
Square Footage
12500
- B9 Sequoia Port
*Sales Tax Number
N/A
America Owner, LP
** TYPE OF BUSINESS
HVAC
TENANTS
* CONSTRUCTION TYPE
1113 - SPRINKLERED
Kris Tennison
* OCCUPANCY GROUP
B/S-1
Texas HVAC Experts
26-
LLC
001403750PORTAMERICAPLACESUIT
(682) 777-1542
DOCUMENTS - MISC 01
E250-
HAZARDOUSMATERIALPAPERWOR.
pdf
*Sales Tax
NO
Alcoholic Beverage Sales
NO
Alterations
NO
Change of Business Name
NO
Change of Business Owner
NO
Fire Sprinkler System?
YES
Freight Forwarding Business
NO
Hazardous Material
YES
Industrial Waste
NO
New Building / Addition
NO
New Building / Property Owner
NO
Page 1/2
MYGOV.US 26-001403, 06/02/2026 at 9:31 AM Issued by: Amanda Robeson
INFORMATION F
New Occupant / Tenant
Number of Employees
Outside Refuse/Recycling
Outside Storage
Signs
Square Footage - Office
Square Footage - Warehouse
" CONDITIONAL USE REQUIRED?
* OCCUPANCY LOAD
* PERMITTED USE
* ZONING DISTRICT
YES
1
NO
NO
NO
10500
NO
35
YES
I
***NO OUTDOOR STORAGE
INCLUDING BUT NOT LIMITED TO
COMPANY VEHICLES'"
FEE
TOTAL
PAID
Certificate of Occupancy
$ 50.00
$ 0.00
$50.00
TOTALS
$ 50.00
$ 50.00
$ 0.00
FOREGOINGI HEREBY CERTIFY THAT THE !-- TO THE BEST •
KNOWLEDGEMY AND THAT SAIDp '+ CONFORMANCE
THE INFORMATION HEREINFORTH.
i,> (if access to the building/space is not provided at the time of schedull
inspection, a $50.00 re -inspection fee will be charged)
3165 or 1 +a
Signature
Project # 26-r r
Page 2/2
MYGOV.U5 26-001403, 06/02/2026 at 9:31 AM Issued by: Amanda Robeson
ersion 2
Revision Date: 18.07.2013
-.11 a -I Lei 4 1 1 It 9 If-, w
1.1. Product Identifier
Product name: REFRIGERANT R410A
1.2. 9elevant identified uses of the substance or mixture and uses advised against
NUIONAL
REFRIGERANTS
Use: Refrigerant.
Advised Against: No specific uses advised again have been identified, other than restrictions in the F-Gas
Regulations.
1.3. Details of the supplier of the safety data sheet
Company name:
National Refrigerants Ltd.
4 Watling Close
Sketchley Meadows Business Park
Hinckley LE1 0 3EZ
Tel: +44(0)1455 630790
Fax: +44(0) 1455 630791
Email:
1.4. Emergency telephone number
Emergency Tel: +44(0) 1865 407333
SECTION-2: HAZARDS IDENTIFICATllON
2.1. Classification of the substance of mixture
Classification under Directive This substance is not classified as dangerous according to Directive 67/548/EEC or
67/548/EEC or 1999145/EC: 1999/45/EC.
Most important adverse effect: Rapid evaporation of the liquid may cause frostbite.
Vapour is heavier than air and can cause suffocation.
2.2. Label elements
Directives 67/458/EEC or This substance is not classified as dangerous according to Directive 67/5481EEC or
1999/45/EC: 1999/45/EC.
Special labelling of certain Contains fluorinated greenhouse gases covered by the Kyoto Protocol
mixtures: -
2.3. Other hazards
Hazardous Ingredients:
MITJ
DIFLUORCIMETHANE ,,R32.)
EINECS CAS 67/548/EEC Classification CLP Classification Percent
SAFETY DATA SHEET NATIONAL
Refrigerant Gas R410A REFRIGERANTS
Version 2
Revision Date: 18.07.2013
F+; R12 H220: Flammable gas 48.5 — 50.5%
H280: Pressurised gas
i CAS
i 67/548/EEC Classification CLP Classification Percent
206-557-8 354-33-6
H280: Pressurised 94S- 491.51— 51.5%
. . . . ..... ...... . .
SE SURFS
P'rip 4: W 1113 ME ST 4
4.1. Description of first aid measures
Skin contact:
Take off all contaminated clothing immediately if not stuck to the skin. Flush area with
lukewarm water. Do not use hot water. If frostbite has occurred call a physician.
Eye contact:
Hold eyelids apart and flush eyes with plenty of water for at least 15 minutes. Get medical
attention.
Ingestion:
This is not considered a potential route of exposure.
Inhalation:
Remove from exposure, lie down. Move to fresh air. Keep patient warm and at rest. Artificial
respiration and/or oxygen may be necessary. Consult a physician.
General Advice
Never give anything by mouth to an unconscious person. When symptome persist or in all
cases of doubt seek medical advice.
4.2. Most important symptoms and effects, both acute and delayed
Skin contact:
Low exposure will cause redness and pain. High exposure will cause frostbite, blisters and
severe pain.
Eye contact:
Cause severe pain and cornea damage.
Ingestion:
Not a route of exposure.
Inhalation:
Shortness of breath, severe headache, dizziness, nausea, weakness, and unconsciousness.
Irregular cardiac activity.
Treatment:
Do not give adrenaline or similar drugs.
4.3. Indication of any Immediate medical
attention and special treatment needed
Immediate/special treatment:
Burns pack should be available on the premises.
SEqP0N 1; FIRE-FIGMNG,WA$URES
5.1. Extinguishing media
Extinguishing media:
Water spray, Foam, Dry chemical Carbon dioxide (CO2)- Use extinguishing measures that are
appropriate to local and surrounding environment. Cool cylinders/tanks with water spray.
5.2. Special hazards arising from the
substance or mixture
Special hazards arising from
Vapours may form explosive mixtures with air. Vapours are heavier than air and may spread
the mixture
along floors. Vapours or gases may travel considerable distances to ignition source and flash
back. Fire or intense heat may cause violent rupture of packages.
Hazardous thermal decomposition products: carbon oxides, hydrogen fluoride, carbonyl
fluoride.
5.3. Advice for fire-fighters
Advice for f! re-f ig hters: In the event of fire wear self-contained breathing apparatus.
Use personal protective equipment.
Wear neoprene gloves during cleaning work after a fire.
4009:11111WAI @0 ~W'glm-
1
Version 2
Revision Date: 18.07.2013
. .. i 1tTo11:1nL-W
e> 4, NATIONAL
REFRIGERANTS
Personal precautions:
Evacuate personnel to safe areas. Ventilate the area, especially low or enclosed places where
heavy vapours might collect.
6.2. Environmental precautions
Environmental precautions:
Should not be released into the atmosphere.
6.3. Methods and material for containment and cleaning up
Clean-up procedures:
Material evaporates.
6.4. Reference to other sections
Reference to other sections:
Refer to Section 7 of SDS. Refer to Section 8 of SDS.
SECTION 7:-HANDUING AND STORAGE
7.1. Precautions for rate handling
Handling requirements:
Advice on handling: Avoid breathing vapours or mist. Avoid liquid contact with skin and
clothing. Provide sufficient air exchange and/or exhaust in work rooms.
Advice on protection against fire and explosion: No special measures against fire required.
7.2. Conditions for safe storage, including
any incompatibilities
Storage conditions:
Do not drag, slide or roll cylinders. Never attempt to lift cylinder by its cap. Use a check valve
or trap in the discharge line to prevent hazardous back flow into the cylinder. Keep at
temperature not exceeding 52°C. Keep cylinders tightly closed in a dry, cool and well -
ventilated place.
Suitable packaging:
Store in original cylinder only.
Protect from contamination.
Storage temperature:
Less than 520C
7.3. Specific end use(s)
Specific end use(s)
No data available.
§]ECTFON 8:"POSLIRE _CONTROLS / PERSONAL PROTECTION
If subsection is empty then no values are applicable
8.1. Control parameters
Hazardous ingredients:
PENTAFLUOROETHAN (HFC125)
Workplace exposure - limits
State
8 hour TWA 15 min. STEL
UK
1000 ppm
(4900 rnq/M3s
8.2. Derived No Effect Level
Difluoromethane
Type of Application (Use): Workers
Exposure routes: Inhalation
�W
Version 2
Revision Date: 18.07.2013
NUIONAt
REFRIGERANTS
Health effects: Chronic effects, Systemic toxicity
Value: 7035 mg/m3
Type of application (Use); Consumers
Exposure routes: Inhalation
Health effects: Chronic effects, Systemic toxicity
Value: 750 Mg/M3
Pentafluoroethane
Type of Application (Use): Workers
Exposure routes: Inhalation
Health effects: Chronic effects, Systemic toxicity
Value: 16444 Mg/M3
Type of application (Use): Consumers
Exposure routes: Inhalation
Health effects: Chronic effect, Systemic toxicity
Value; 1753 Mg/M3
8.3 Predicted No Effect Concentration
Difluoromethane
Value: 0.142 mg/I
Compartment: Fresh water
Value: 1.42 mgA
Compartment: Water
Remarks; Intermittent use/release
Value: 0.534 mg/I
Compartment: Fresh water sediment
Pentafluoroethane
Value; 0.1 mg/I
Compartment: Fresh water
Value: 1 mg/I
Compartment: Water
Remarks; Intermittent use/release
Value: 0.6 mg/I
Compartment: Fresh water sediment
8.4 Exposure controls
Engineering measures:
Ensure adequate ventilation, especially in confined areas. Local exhaust should be used when
large amounts are released.
Respiratory protection:
For rescue and maintenance work in storage tanks use self-contained breathing apparatus.
Vapours are heavier than air and can cause suffocation by reducing oxygen available for
breathing.
Hand protection:
Heat insulating gloves
Eye protection:
Safety glasses with side shields. Wear a face shield in addition where the possibility exists for
face contact due to splashing, spraying or airborne contact with this material.
Skin protection:
Wear impervious clothing that covers legs and arms.
Protective measures
When using do not smoke
Hygiene measures
Handle in accordance with good industrial hygiene and safety practice.
Environmental:
Gas escapes to be kept to the minimum by engineering processes and operating methods.
fiE HEI.0 MAL
Tp" P PfQTIS
9.1. Information on basic physical and chemical properties
State:
Liquefied gas under pressure.
Colour:
Clear colourless liquid and vapour.
Odour:
Ethereal
Molecular weight:
72.59 g/mole
_TM1 -
Version 2
Revision Date: 18.07.2013
NATIONAI
REFRIGERANTS
Boiling Polnt/range:
- 51.2 to -51.1 OC (boiling range)
Flash Point:
Does not flash. Non-flammable
Vapour pressure:
14.706 Bar (14706 hPa) at 20°C
Liquid Density:
1081 kg/m3 at 20°C
SE�C,Ti 0. TABILITY AND
REACTIVITY
10.1. Reactivity
Reactivity:
Stable under recommended storage and transport conditions.
10.2. Chemical stability
Chemical stability:
Stable under normal conditions.
10.3. Possibility of hazardous
reactions
Hazardous reactions:
Hazardous reactions will not occurs under recommended storage and transport conditions.
May react with aluminium.
10.4. Conditions to avoid
Conditions to avoid:
Heat, hot surfaces, flames.
The product is not flammable in air under ambient conditiond of temperature and pressure.
When pressurised with air or oxygen, the mixture may become flammable or reactive under
certain conditions.
10.3. Incompatible material
Materials to avoid: Alkali metals, alkaline earth metals, powdered metals, powdered metal salts.
10.6. Hazardous decomposition products
Hazardous decomposition Thermal decomposition yields toxic products which can be corrosive in the presence of
products moisture.
11.1. Information on toxicological effects
OUT=
Inhalation
Difluoromethane:
Pentafluoroethane:
H-10
Not tested on animals.
Classification: Not classified as irritant.
Result: No skin irritation.
Not expected to cause skin irritation based on expert review of the properties of the substance.
Pentafluoroethane:
Version 2
Wevision Date: 18.07.2013
NATIONAL
REFRIGERANTS
Classification: Not classified as irritant
Result: No skin irritation.
Not expected to cause skin irritation bases on expert review of the properties of the substance.
Eye irritation
Difluorometa ne: Not tested on animals.
Classification: Not classified as irritant
Result: No eye irritation.
Not expected to cause eye irritation bases on expert review of the properties of the substance.
Pentafluoroethane: Not tested on animals.
Classification: Not classified as irritant
Result: No eye irritation.
Not expected to cause eye irritation bases on expert review of the properties of the substance.
ZMT�1
Difluoromethane: Not tested on animals.
Classification: Not a skin irritant
Result: Does not cause skin sensitisation.
Not expected to cause skin sensitisation bases on expert review of the properties of the
substance.
There are reports of human respiratory sensitisation.
Pentafluoroethane: Not tested on animals.
Classification: Not a skin irritant
Result: Does not cause skin sensitisation.
Not expected to cause skin sensitisation bases on expert review of the properties of the
substance.
Difluoromethane:
Inhalation rat
No toxicologically significant effects were found,
Pentafluoroethane:
Inhalation rat
No toxicologically significant effects were found,
Mutagenic assessment
Difluoromethane:
Animal testing did not show any mutagenic effects.
Tests on bacteria or mammalian cell cultures did not show mutagenic effects.
Pentafluoroethane:
Animal testing did not show any mutagenic effects.
Tests on bacteria or mammalian cell cultures did not show mutagenic effects.
Carcinogenicity Assessment
Difluoromethane:
Not classifiable as a human carcinogen.
Pentafluoroethane:
Not classifiable as a human carcinogen -
Toxicity to reproduction assessment
Difluoromethane:
No toxicity to reproduction.
Pentafluoroethane:
No toxicity to reproduction.
ZEEMME=
F271171-T&UP77=
Rapid evaporation of the liquid may cause frostbite. May cause cardiac arrhythmia.
SAFETY DATA SHEET
Refrigerant Gas R410A
Version 2
Revision Date: 18.07.2013
ECOLOGICAL INFORMATION
12.1. Toxicity
Toxicity to fish:
Difluoromethane:
LC50/96 h/Fish: 1507 mg/I
Pentafluoroethane:
LC50/96 h/Oncorhynchus (rainbow trout): > 81.2 mg/1
Information given is based on data obtained from similar substances.
LC50/96 h/Danio rerio (zebra fish): > 200 mg/I
Information given is based on data obtained from similar substances.
LC50/96 h/Oncorhynchus mylkiss (rainbow trout): 450 mg/l
Information given is based on data obtained from similar substances.
Toxicity to Aquatic plants:
Difluoromethane:
LC50/96 h/Algae: 142 mg1I
Pentafluoroethane:
LC5a/72 h/Pseudokirchneriella subcapitata (green algae): >1 18 mg/I
Information given is based on data obtained from similar substances.
I-CgM h/Pseudolkirchneriella subcapitata (green algae): >1 14 mg/1
Information given is based on data obtained from similar substances.
LC50/96 h/Algae: 142 mg/l
Information given is based on data obtained from similar substances.
Toxicity to aquatic invertebrates
Difluoromethane
EC50/48 h/Daphnia: 652 mg1I
Pentafluoroethane
EC50/48 h/Daphnia magna (Water flea): > 200 mg/l
Information given is based on data obtained from similar substances.
EC5a98 h/Daphnia magna (Water flea): > 97.9 mg/l
Information given is based on data obtained from similar substances.
EC5d48 h/Daphnia magna (Water flea): > 97.9 mg/1
Information given is based on data obtained from similar substances.
Ecotoxic values:
When discharged may contribute to the greenhouse effect.
Global Warming Potential
0 (CO2
(GWP)
Ozone Depletion Potential
1980 (1111 = 1)
loop)
12.2. Persistence and degradability
Persistence and degradability:
No data available.
12.3. Blo, accumulative potential
Blo-accumulative potential:
No data available.
12.4. Mobility in soil
Mobility:
No data available.
12.5. Results of PT and vPvB assessment
NATIONAI
REFRIGERANTS
i�M
1 0 ,
•
13.1. Waste treatment methods
NATIONAL
REFRIGERANTS
Disposal operations: Do not allow product to be released into the environment.
Recovery Operations: Consult the manufacturer or supplier for information regarding recovery and recycling of the
product. If recovery is not possible, incinerate at a licensed installation.
Disposal of packaging: De -gas and return cylinders to suppliers.
N.B. The user's attention is drawn to the possible existence of regional or national regulations
regarding disposal.
14 -NSPQRT i"FoRmArON
--
fflilliff-TON
UN Number:
3163
Class:
2
Classification code:
2A
Hazard Identification Number:
20
Labelling Number:
2.2
Proper Shipping Name:
Liquefied Gas N.O.S. (Dif luo ro methane, Pentafluoroethane)
Tunnel code:
(C/E)
fflyx�
UN Number: 3163
Class: 2
Labelling Number: 2.2
Proper Shipping Name: Liquefied Gas N.O.S. (Difluoromethane, Pentafluoroethal
MPFUU
LIN Number:
3163
Class:
2
Labelling Number:
2.2
EmS:
F-C, S-V
Proper Shipping Name:
Liquefied Gas N.O.S. (Difluoromethane, Pentafluoroethane)
Marine Pollutant:
No
0 k i 11 0 i 0 . 1 6
15.1. Safety, health and environment regulationsilegislation specific for the substance or mixture
Special labelling of certain Contains fluorinated greenhouse gases covered by the Kyoto Protocol.
mixtures:
15.2. Chemial Safety Assessment
Chemical safety assessment: A chemical safety assessment has not been carried out by the supplier of this mixture.
Other information: This safety sheet is prepared in accordance with Commission Regulation (EU) No. 453/2010.
* Indicates text in SDS which has changed since the last revision
Text of R-phrases mentioned in R1 2 Extremely flammable
Section 3:
Full text of H-statements H220 Extremely flammable it
referred under Section 3: H280 Contains gas under pressure; may explode if heated.
Version 2
12evision Date: 18.07.2013
NUIONAI
REFRIGERANTS
Version 2
Tevision Date: 18.07.2013
the storage of Cylinders.
for the identification of the Cylinder contents.
Ascertain the identity of the gas before using it.
Know and understand the properties and hazards
associated with each gas before using it.
for a particular gas contact the supplier.
Wear stout gloves.
Never lift a Cylinder by the cap or guard unless the
supplier states it is designed for that purpose.
Use trolley or other suitable device or technique for
transporting heavy Cylinders, even for a short distance.
the gas being used,
MAP M,
Employ suitable pressure regulating device on all
Cylinders when gas is being emitted to systems with
lower pressure rating than that of the Cylinder.
Ascertain that all electrical systems in the area are
suitable for service with each gas.
Never use direct flame or electrical heating devices to
subjected to temperatures above 45C.
supplier. Never attempt to transfer gases from one
Cylinder to another.
Do not use Cylinders as rollers or supports, or for any
Never permit oil, grease or other readily combustible
§W�*5k-x
containing oxygen or other oxidants.
NUIONAL
REFRIGERANTS
0 1"
"STAL6Z-L1Ma-t1,FA'
6011-M. M-1
immediately to the supplier.
Close the Cylinder valve whenever gas is not required
even if the Cylinder is still connected to the equipment.
from sources of heat and ignition. Designate as a no
smoking area,
'SMTXOTMW�1�1 -
9ccording to the various categories.
The storage area should be kept clear and access
*Ml�41-�tt-VI-Otf-�4-tit-24*MA.-:,��v-xl-lm-il�g�lln
ghould be clearly marked as a storage area and
Toxic etc.).
to a minimum.
Flammable gases should be stored away from other
combustible materials.
for general condition and leakage.
Cylinders in storage should be properly secured to
prevent toppling or rolling.
designed for this.
Cylinder valves should be tightly closed and, where
appropriate, valves should be capped or plugged.
extremes of weather.
Cylinders should not be stored in conditions likely to
encourage corrosion.
Store full and empty Cylinders separately and arrange
full Cylinders so that the oldest stock is used first,
L
000000025450
Version 1.0
Product name
Number
Product Use Description
Manufacturer or supplier's
details
For more information call
0903��=
111TITIMITITIvi %V
Refrigerant
Honeywell International Inc.
115 Tabor Road
Morris Plains, NJ 07950-2546
800-522-8001
+1-973-455-6300(Monday-Friday, 9:00am-5:00pm)
Medical: 1-800-498-5701 or +1 -303-389-1414
IZ-
527-3887
SECTION 2. HAZARDS IDENTIFICATION
Emergency Overview
Form Liquefied gas
Color colourless
Odor slight ether -like
Classification of the substance or mixture
Classification of the Flammable gases, Category 1
substance or mixture Gases under pressure, Liquefied g
Simple Asphyxiant I
GHS Label elements, including precautionary statements
Page 1 / 17
SAFETY DATA SHEET
77 70-V M-TQ- I Q W W
100000025450
Version 1.0
Revision Date 10/07/2020 Print to 12/03/2021
Symbol(s)
Signal word
Danger
Hazard statements
Extremely flammable gas.
Contains gas under pressure; may explode if heated.
May displace oxygen and cause rapid suffocation.
Precautionary statements
Prevention:
Keep away from heat/ sparks/ open flames/ hot surfaces. No
smoking.
Response:
Leaking gas fire: Do not extinguish, unless leak can be stopped
safely.
Eliminate all ignition sources if safe to do so.
Storage:
Protect from sunlight. Store in a well -ventilated place.
Carcinogenicity
No component of this product present at levels greater than or equal to 0.1 % is identified as a known
or anticipated carcinogen by NTP, IARC, or OSHA.
SECTION 3. COMPOSITIOWINFORMATION ON INGREDIENTS
Chemical name
Difluoromethane
Page 2 / 17
CAS -No, Concentration
75-10-5 68.90%
?AI
SAFETY DATA SHEET
Solstice@ 454B
000000025450
Version 1.0 Revision Date 10/07/2020 Print Date 12/0312021
SECTION 4. FIRST AID MEASURES
General advice
First aider needs to protect himself. Move out of dangerous
area. Takeo all contaminated clothing immediately.
Inhalation
Remove to fresh air. If not breathing, give artificial respiration.
If breathing is difficult, give oxygen. Use oxygen as required,
provided a qualified operator is present. Call a physician.
Skin contact
Rapid evaporation of the liquid may cause frostbite. If they is
evidence of frostbite, bathe (do not rub) with lukewarm (not
hot) water. If water is not available, cover with a clean, soft
cloth or similar covering. Wash contaminated clothing before
re -use. Consult a physician.
Eye contact
Rinse immediately with plenty of water, also under the eyelids,
for at least 15 minutes. In case of frostbite water should be
lukewarm, not hot. Call a physician.
Ingestion
Unlikely route of exposure. As this product is a as, refer to the
inhalation section. Do not induce vomiting without medical
advice. If conscious, drink plenty of water. Never give anything
by mouth to an unconscious person. Call a physician
immediately.
Indication of immediate Treat frost-bitten areas as needed. Treat symptomatically.
medical attention and
special treatment needed, if
necessary
Suitable extinguishing media In case of fire, allow gas to burn if to cannot be shut off
immediately.
Apply water from a safe distance to of container and protect
surrounding area,
Use water spray, alcohol -resistant foam, dry chemical or
carbon dioxide.
XMum
�Mn
I I I I I I I I I
MQM01911111 I
111 111111! 11111111RKRMKMM��
firefighting Contents under pressure.
Vapours are heavier than air and can cause suffocation by
reducing oxygen available for breathing.
Vapors may travel to areas away from work site before
igniting/flashing back to vapor source.
Fire or intense heat may cause violent rupture of packages.
Cool closed containers exposed to fire with water spray.
Do not allow run-off from fire fighting to enter drains or water
courses.
In case of fire hazardous decomposition products may be
produced such as:
Hydrogen fluoride
Carbonyl halides
Carbon monoxide
Carbon dioxide (CO2)
Special protective equipment : In the event of fire and/or explosion do not breathe fumes.
'or firefighters
Wear self-contained breathing apparatus and protective suit.
No unprotected exposed skin areas.
Further information Evacuate personnel to safe areas.
Leaking gas fire: Do not extinguish, unless leak can be
stopped safely.
Eliminate all ignition sources if safe to do so.
Personal precautions, Immediately evacuate personnel to safe areas.
protective equipment and Keep people away from and upwind of spill/leak.
emergency procedures Wear personal protective equipment. Unprotected persons
must be kept away.
Wear self-contained breathing apparatus and protective suit.
Eliminate all ignition sources if safe to do so.
Avoid skin contact with leaking liquid (danger of frostbite).
Ventilate the area.
Vapors may travel to areas away from or site before
igniting/flashing back to vapor source.
Vapours are heavier than air and can cause suffocation by
reducing oxygen available for breathing.
Avoid accumulation of vapours in low areas.
Unprotected personnel should not return until air has been
tested and determined safe.
Page 4 / 17
0000=00025450
Version 1.0
7- PeFk" _tMlr I 71ITTV.
The product evaporates readily.
Discharge into the environment must be avoided.
Use explosion -proof equipment.
Ventilate the area.
Allow to evaporate.
Precautions for safe Handle with care.
handling Wear personal protective equipment.
Do not breathe vapour.
Avoid contact with skin, eyes and clothing.
Use only in well -ventilated areas.
Pressurized container. Protect from sunlight and do not expose
to temperatures exceeding 50 'C.
Follow all standard safety precautions for handling and use of
compressed as cylinders.
Use authorized cylinders only.
Protect cylinders from physical damage.
Do not puncture or drop cylinders, expose the to open flame
or excessive heat.
Do not remove screw cap until immediately ready for use.
Always replace cap after use.
Advice on protection Container hazardous when empty.
against fire and explosion Vapours may for flammable mixture with air.
Keep product and empty container away from heat and
sources of ignition.
Do not pressurize, cut, weld, braze, solder, drill, grind or
expose containers to heat or sources of ignition.
Take measures to prevent the build up of electrostatic charge.
Electrical equipment should be protected to the appropriate
standard.
Use explosion -proof equipment.
No sparking tools should be used.
No smoking.
SAFETY DATA SHEET
Solstice@ 454B
000000025450
Version 1.0 Revision Date 10/07/2020 Print to 12/03/2021
Storage
Conditions for safe storage, Pressurized container: protect from sunlight and do not expose
including any to temperatures exceeding 50 OC. Do not pierce or burn, even
incompatibilities afteruse.
Keep containers tightly closed in a dry, cool and well -ventilated
place.
Keep away from heat and sources of ignition.
Storage rooms must be properly ventilated.
Ensure adequate ventilation, especially in confined areas.
Protect cylinders from physical damage.
or away from incompatible substances.
Store in original container.
• I - # . 11Z •
Protective measures Ensure that eyewash stations and safety showers are close to
the workstation location.
Do not breathe vapour.
Avoid contact with skin, eyes and clothing.
Engineering measures
Use with local exhaust ventilation.
Eye protection
Safety goggles
Hand protection
Protective gloves
Gloves must be inspected prior to use.
Replace when worn.
Skin and body protection
Avoid skin contact with leaking liquid (danger of frostbite).
Wear suitable protective equipment.
Respiratory protection
No personal respiratory protecfive equipment normally
required.
When workers are facing concentrations above the exposure
limit they must use appropriate certified respirators.
Use NIOSH approved respiratory protection.
Hygiene measures
Handle in accordance with good industrial hygiene and safety
practice.
Ensure adequate ventilation, especially in confined areas.
When using do not eat, drink ors o e.
Page 6 / 17
2'
SAFETY DATA SHEET
Solstice@ 454B
000000025450
Version 1.0 Revision Date 10/07/2020 Print Date 12/03/2021
Remove and wash contaminated clothing before re -use.
Keep working clothes separately.
Do not breathe vapour.
Avoid contact with skin, eyes and clothing.
Exposure Guidelines
Components CAS -No.
Value Control
i Darameters
TWA: 2,200 mg/m3
Time (1,000 ppm)
weighted
average
Upda Basizt
te I
2007 'WEEL US. •
WEELs Workplace
Environmental
Exposure Level
Guide, as amended
Difluoromethane
75-10-5
TWA:
(1,000 ppm)
1994
Honeywell1imit
Time
established by
weighted
Honeywell
average
International Inc.
12,3,3,3-
754-12-1
TWA:
1(500 ppm)
12009
WEEL. US. OARS.
Tetrafluoroprop-
Time
i
EELs Workplace
1-ene
weighted
Environmental
average
Exposure Level
Guide, as amended
2,3,3,3-
754-12-1
'TWA:
I (500 ppm)
0315
Honeywell' Limit
Tetrafluoroprop-
Time
2010
'established by
1-ene
weighted
Honeywell
average
International Inc.
2,333-
754-12-1
STEL:
(1,500 ppm)
0315
HoneywelLCimit
Tetrafluoroprop- i
Short
2010
1 established by
1-ene
term
11-Ioneywell
exposure
International Inc.
limit
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
Physical state Liquefied gas
Page 7 / 17
7r7 q.1
SAFETY DATA SHEET
Solstice@ 454B
000000025450
Version 1.0 Revision Date 10/07/2020 Print Date 12/03/2021
Color
colourless
Odor
slight ether -like
Odor threshold
Note: No data available
pH
Note: neutral
Melting point/range
Note: No data available
Boiling point/boiling range
-50.9 *G
Flash point
Note: Not applicable
Evaporation rate
> 1
Method: Compared to CC14.
Flammability
Flammable gas.
Lower flammability limit 11.25 %(V) at 23 OC
Upper flammability limit 22 %(V) at 23 'C
Vapor pressure 1,411 kPa
at 21 'C(70 'F)
Vapor density 2.2 Note: (Air = 1.0)
Density Note: No data available
Water solubility Note: No data availabl:_�
Partition coefficient: n- Note: No data available
Page 8 / 17
1�
000000025450
Version 1.0
octanol/water
tA (a vrt6 I n XaTato5x-
Viscosity, dynamic
V*scosij%, kinematic
;�# �. - tM
496 *C
Note: No data available
Note: No data available
1 6 . -0 . 0 0
SECTION 10. STABILITY AND REACTIVITY
Reactivity : Not classified as a reactivity hazard.
Chemical stability
Stable under normal conditions.
Possibility of hazardous
Hazardous polymerisation does not occur.
reactions
Conditions to avoid
Keep away from heat and sources of ignition.
Pressurized container. Protect from sunlight and do not
expose to temperatures exceeding 50 'C.
Do not pressurize, cut, weld, braze, solder, drill, grind or
expose containers to heat or sources of ignition.
Decomposes under high temperature.
Some risk may be expected of corrosive and toxic
decomposition products.
Incompatible materials
Alkali metals
Oxidizers (e.g. peroxide residues present in insufficiently
cured rubbers)
Finely divided metal powders such as aluminum, magnesium,
or zinc.
Hazardous decomposition
In case of fire hazardous decomposition products may be
products
produced such as:
Hydrogen fluoride
Carbonyl halides
Carbon monoxide
Carbon dioxide (CO2)
Page 9 / 17
Solstice@ 454B
000000025450
Version 1.0 Revision Date 10/07/2020
,SECTION 11. TOXICOLOGICAL INFORiLATIOI. 11
Difluoromethane LC50: > 520000 ppm
Exposure time: 4 h
Species: Rat
2,3,3,3-Tetrafluoroprop-1 - LC50: > 400000 ppm
ene Exposure time: 4 h
Species: Rat
Method: OECD Test Guideline 403
Skin irritation
2,3,3,3-Tetrafluoroprop-1 - Note: Not applicable
ene study technically not feasibi
Eye irritation
2,3,3,3-Tetrafluoroprop-1 - Note: Not applicable
ene study technically not feasibi
Difluoromethane Cardiac sensitization
Species: dogs
Note: No -observed -effect level
>350 000 ppm
2,3,3,3-Tetrafluoroprop-1 - Dermal
ene Note: Not applicable, as this product is a gas.
study technically not feasible
Repeated dose toxicity Species: Rat
Difluoromethane
Application Route: Inhalation
Exposure time: (90 d)
NOEL: 50000 ppm
Subchronic toxicity
Page 10 / 17
SAFETY DATA SHEEN
RVIMV' l;� ,�
VraiffrSTIM K I
ene
I
Species: Rat
Application Route: Inhalation
Exposure time: (2 Weeks)
No -observed -effect level: 50000 pprn
Method: OECD Test Guideline 412
Species: Rat
Application Route: Inhalation
Exposure time: (4 Weeks)
NOAEL (No observed adverse effect level): 50000 ppm
Method: OECD Test Guideline 412
Application Route: Inhalation
Exposure time: (13Weeks)
NOAEL (No observed adverse effect level): 50000 ppm
Method: OECD Test Guideline 413
Species: Rabbit, male
Application Route: Inhalation
Exposure time: (28 d)
No -observed -effect level: 500 ppm
Method: OECD Test Guideline 412
classification as a specific target organ toxicant.
Species: Rabbit, female
Application Route: Inhalation
Exposure time: (28 d)
No -observed -effect level: 1000 ppm
Method: OECD Test Guideline 412
classification as a specific target organ toxicant.
Species: Mini -pig
Application Route: Inhalation
Exposure time: (28 it
NOAEL (No observed adverse effect level): 10000pprn
highest exposure tested
Test Method: Ames test
Page 11 / 17
- SAFETY DATA SHEEI
I I I I I I I I I
k1fro7ff WIN
ZMMIIT��M
FSZUI. �4%11111
Result: negative
2,3,3,3-Tetrafluoroprop-1 - Test Method: Ames test
ene Result: 20% and higher, positive in TA 100 and e. cell WP2
uvrA, negative in TA98, TAII 00, and TAI 535.
Method: OECD Test Guideline 471
Cell type: Human lymphocytes
Result: negative
. Wa—ti-a'al ' . j -
Result: negative
Cell type: Human lymphocytes
Result: negative
Method: OECD Test Guideline 473
Note: Dose 760,000 ppm
Difluoromethane Species: Mouse
Cell type: one marrow
Method: Mutagenicity (micronucleus test)
Result: negative
2,3,3,3-Tetrafluoroprop-1 - Species: Mouse
ene Cell type: Micronucleus
Dose: up to 200,000 ppm (4 hour)
Method: OECD Test Guideline 474
Result: negative
. 6 I
Dose: up to 50,000 ppm (4 weeks)
Method: OECD Test Guideline 486
Result: negative
Species: Rat
Cell type: Micronucleus
Result: negative
riiiililiT
Version 1.0
P, VWN0V7-WP#T? 707fr^P
ene
101119i1
Reon Date 10/07/2020
Species: Rat
Note: Not classified as a human carcinogen. Substance not
expected to be a carcinogen based on available data.
Species: Rat
Dose: NOEL - 50,000 ppm
Note: Did not show teratogenic effects in animal experiments.
Species: Rabbit
Dose: NOEL - 50,000 ppm
SECTION 12. ECOLOGICAL INFORMATION
2,3,3,3-Tetrafluoroprop-1 - LC50: > 197 mg/l
ene Exposure time: 96 h
Species: Cyprinus carpio (Carp)
Method: OECD Test Guideline 203
Note: No demonstrable toxic effect in saturated solution.
Toxicity to daphnia and other aquatic invertebrates
2,3,3,3-Tetrafluoroprop-1 - EC50: > 83 mg/l
ene Exposure time: 48 h
Species: Daphnia magna (Water fie
Method: OECD Test Guideline 202 1
11=i .':-
Bloaccumelation
2,3,3,3-Tetrafluoroprop-1 -
EC50: > 100 mg/l
Species: Scenedesmus capricornutum (fresh water algae)
Method: OECD Test Guideline 201
RMTZITMTTUGf. f
000000025450
Version 1.0
511M
Biodegradability
Difluoromethane
M.
Revision Date 10/07/2020 Print Date 12/03/2021
accumulation in organisms is not expected.
Note: Minimal
Result: Not readily biodegradable.
Method: OECD Test Guideline 301 F
Further information on ecology
SCTI 13. DISPOSAL CONSIDERATIONS
Disposal methods Observe all Federal, State, and Local Environmental
regulations.
DOT UN/ID No.
UN 3161
Proper shipping name
LIQUEFIED GAS, FLAMMABLE, N.O.S.
(Difluoromethane, R-1234yf)
Class
2.1
Packing group
Hazard Labels
2.1
IATA UN/ID No.
UN 3161
Description of the goods
LIQUEFIED GAS, FLAMMABLE, N.O.S.
(Difluoromethane, R-1234yf)
Class
2.1
Hazard Labels
2.1
Packing instruction (cargo
200
aircraft)
IMDG UN/ID No.
UN 3161
Description of the goods
LIQUEFIED GAS, FLAMMABLE, N.O.S.
(DIFLUOROMETHANE, R-1234yf)
Class
2.1
Hazard Labels
2.1
EmS Number
F-D, S-U
Marine pollutant
no
Page 14 / 17
SAFETY DATA SHEET
971 " M5 -7 Q-1 W Q 11
000000025450
Version 1.0
j Is] kq 5 [-A :4*111 WA to] Z
i
Print Date 12/03/2021
US. Toxic Substances
On TSCA Inventory
Control Act
Australia. Industrial
On the inventory, or in compliance with the inventory
Chemical (Notification and
Assessment) Act
Canada. Canadian
All components of this product are on the Canadian DSL
Environmental Protection
Act (CPA). Domestic
Substances List (DSL)
Japan. Kashin-Hou Law
On the inventory, or in compliance with the inventory
List
Korea. Existing Chemicals On the inventory, or in compliance with the inventory
Inventory (KECI)
Philippines. The Toxic On the inventory, or in compliance with the inventory
Substances and Hazardous
and Nuclear Waste Control
Act
China. Inventory of Existing On the inventory, or in compliance with the inventory
Chemical Substances
(IECSC)
New Zealand. Inventory of On the inventory, or in compliance with the inventory
Chemicals (NZIoC), as
published by ERMA New
Zealand
TSCA 12B US. Toxic Substances Control Act (TSCA) Section 12(b) Export
Notification (40 CFR 707, Subpt D)
2,3,3,3-Tetrafluoroprop-1 -ene 754-12-1
National regulatory information
Page 15 / 17
000000025450
Version 1.0 1
SARA 302 Components
"1414T.T171-7-TIT =1
SARA 311/312 Hazards
OF gy
Print Date 12/03/2021
ffliVS77=1 •. . T
requirements of SARA Title III, Section 302.
MUM r
- - M-
I's 0 [:ITL:l M-7m 410116111:16 0!1TAtffm H ra 11 RiMMSTIM ra.
Fire Hazard
Acute Health Hazard
California Prop. 65 A
:ZLWARNING:This product can expose you to chemicals,
listed below, known to the State of California to cause cancer
and birth defects or other reproductive harm. For more
information go to www.P65Warnings.ca.gov.
Dichloromethane 75-09-2
Chloromethane 74-87-3
Massachusetts RTK Dichloromethane 75-09-2
Pennsylvania RTK Difluoromethane 75-10-5
SECTION 16. OTHER INFORMATION
HMIS III NFPA
Health hazard 1 2
Flammability 4 4
Physical Hazard 0
Instability 0
Hazard rating and rating systems (e.g. HMISO III, NFPA): This information is intended solely for the
use of individuals trained in the particular system.
IrrAT17=1 r. =1
The information provided in this Safety Data Sheet is correct to the best of our knowledge,
information and belief at the date of its publication. The information given is designed only as a
guidance for safe handling, use, processing, storage, transportation, disposal and release and is not
Page 16 / 17
Solstice@ 454B
000000025450
Version 1.0 Revision at 10107/2020 Print Date 12/03/2021
to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text. Final determination of suitability of any
material is the sole responsibility of the user. This information should not constitute a guarantee for
any specific product properties.
Changes since the last version are highlighted in the margin. This version replaces all previous
versions.
Prepared by Honeywell Performance Materials and Technologies Product Stewardship Group
Page 17 / 17
SAFETY DATA SHEET
Version Revision Date: SDS Number:
2.0 2025-05-06 800001031707
SECTION 1. IDENTIFICATION
Product name Propane
Product code 002D3442
Manufacturer/Supplier
Calgary AB T2G IIA6
Canada
Telephone (+1)8006611600
Telefax (+1)4033848345
Emergency telephone num- CHEMTREC (24 hr): 1 (703) 527-3887 or 1 (800) 424-9300
ber (US)
Recommended use of the chemical and restrictions on use
Recommended use Intermediate Refinery Stream.
Used as a domestic, commercial, industrial and automotive
fuel, a feedstock in chemical processes.
1 nis proaxa-mts TIWIAI I- '
listed in Section I without first seeking the advice of the sup-
plier.
Flammable gases Category 1A
Gases under pressure Liquefied gas
GHS label elements
M-11
SAFETY DATA SHEET
Version Revision Date: SDS Number: Print Date: 2025-05-07
2.0 2025-05-06 800001031707 Date of last issue: 04.05.2022
Date of first issue: 04.05.2022
Hazard pictograms
Signal word Danger
Hazard statements PHYSICAL HAZARDS:
H220 Extremely flammable gas.
H280 Contains gas under pressure; may explode if heated.
HEALTH HAZARDS:
Not classified as a health hazard under GHS criteria.
ENVIRONMENTAL HAZARDS:
Not classified as an environmental hazard under GHS criteria.
• statements ►
es. •. smoking.
P243 Take ► to • static discharges.
Response:
P377 Leaking gas fire: Do not extinguish, unless leak can be
stopped safely.
P381 Eliminate all ignition sources if safe to do so.
Storage:
P41 0 + P403 Protect from sunlight. Store in a well -ventilated
place.
Disposal:
No precautionary phrases.
Other hazards which do not result in classification
Vapours are heavier than air. Vapours may travel across the ground and reach remote ignition
sources causing a flashback fire danger.
High gas concentrations will displace available air; unconsciousness and death may occur sud-
denly from lack • oxygen.
Exposure to rapidly expanding gases may cause frost burns to eyes and/or skin.
This material has the potential to be a static accumulator.
Even with •i•` grounding and bonding, this material can still accumulate an electrostatic
charge.
OW(ble-10100-m-glate electrostatic discharve and i-vnition of flammable
vapour mixtures can •
Breathing of high vapour concentrations may cause central nervous system (CNS) depression
resulting in dizziness, light-headedness, headache, nausea and loss of coordination. Continued
inhalation may result in unconsciousness and death.
7FI-91,11 JA F-1% 0 [OIL, 1101 k, I U, [Ci N =I I I Um
Substance / Mixture . Substance
UNE.
SAFETY DATA SHEET
Version Revision Date:
SDS Number: Print Date: 2025-05-07
2.0 2025-05-06
800001031707 Date of last issue: 04.05.2022
Date of first issue: 04.05.2022
. ..... ....
Chemical nature
A complex combination of hydrocarbons produced by the dis-
tillation of crude oil. It consists of hydrocarbons having carbon
numbers predominantly in the range of C3 through C7 and
boiling in the range of approximately -40 'C to 80 'C (-40 'F to
176 'F).
It may also contain one or more of the following additives:
odourants (usually ethyl mercaptan), anti -icing agents.
Substance name
68814-67-5
WTEM �.Ill MAMMMTWOIM�"
Chemical name
Common
ICAS-No. Concentration (% w/w)
Name/Synonym
I _
gases (petroleum),
Gases (petrole-
68814-67-5 100
refinery
um), refinery
Further infonnation
Contains:
Fdkemical name
Identification number I Concentration (% w/w)
propane
74-98-6
0-100
1 butane
106-97-8
0-80
I isobutane
75-28-5
0-80
Lpropylene
115-07-1
0-5
Butene
1 25167-67-3
0-2.5
If inhaled Call emergency number for your location / facility.
Remove to fresh air. Do not attempt to rescue the victim un-
less proper respiratory protection is worn. If the victim has
difficulty breathing or tightness of the chest, is dizzy, vomiting,
or unresponsive, give 100% oxygen with rescue breathing or
Card io-Pu I monary Resuscitation as required and transport to
the nearest medical facility.
In case of skin contact In the event of frostbite, slowly warm the exposed area by
rinsing with warm water.
Seek medical advice.
Transport to the nearest medical facility for additional treat-
ment.
In case of eye contact Flush eye with copious quantities of water.
Remove contact lenses, if present and easy to do. Continue
rinsing.
If persistent irritation occurs, obtain medical attention.
In the event of frostbite, slowly warm the exposed area by
3/18
SAFETY DATA SHEET
W� • • i • • i W 9 14
Version Revision Date: SDS Number: Print Date: 2025-05-07
2.0 2025-05-06 800001031707 Date of last issue: 04.05.2022
Date of first issue: 04.05.2022
rinsing with warm water.
Transport to the nearest medical facility for additional treat-
ment.
If swallowed In the unlikely event of ingestion, obtain medical attention
immediately.
Most important symptoms High gas concentrations will displace available air; • effects, •• acute and • and •` may occur suddenly from lack of oxy-
delayed gen.
Rapid release of gases which are liquids under pressure may
cause frost burns of exposed tissues (skin, eye) due to evapo-
rative cooling.
Jlrrotectlon of first-aiders When administering first aid, ensure that you are wearing ft
appropriate personal protective equipment according to the
dent, injury and surroundings.
Notes to physician IMMEDIATE TREATMENT IS EXTREMELY IMPORTANT!
Potential for cardiac sensitisation, particularly in abuse situa-
tions. Hypoxia • negative inotropes may enhance these ef-
fects. Consider: oxygen therapy.
Call a doctor or poison control center for guidance.
Treat symptomatically.
FT•
Suitable extinguishing media
Shut off supply. If not possible and no risk to surroundings, let
the fire burn itself out.
Use foam, water fog for major fires.
Use dry chemical powder, carbon dioxide, sand or earth for
minor fires.
Unsuitable extinguishing
Do not use direct water jets on the burning product as they
media
could cause a steam explosion and spread of the fire.
Simultaneous use of foam and water on the same surface is
to be avoided as water destroys the foam.
Specific hazards during fire-
Hazardous combustion products may include:
fighting
Carbon monoxide may be evolved if incomplete combustion
occurs.
Unidentified organic and inorganic compounds.
Sustained fire attack on vessels may result in a Boiling Liquid
Expanding Vapor Explosion (BLEVE).
Contents are under pressure and can explode when exposed
to heat or flames.
The vapour is heavier than air, spreads along the ground and
distant ignition is possible.
Specific extinguishing meth-
Use extinguishing measures that are appropriate to local cir-
ods
cumstances and the surrounding environment.
Special protective equipment
Proper protective equipment including chemical resistant
4/18
SAFETY DATA SHEET
Version Revision Date:
SDS Number: Print Date: 2025-05-07
2.0 2025-05-06
800001031707 Date of last issue: 04,05.2022
Date of first issue: 04.05.2022
for firefighters
gloves are to be worn; chemical resistant suit is indicated if
large contact with spilled product is expected. Self -Contained
Breathing Apparatus must be worn when approaching a fire in
a confined space. Select fire fighter's clothing approved to
relevant Standards (e.g. Europe: EN469).
Further information
Clear fire area of all non -emergency personnel.
Keep adjacent containers cool by spraying with water.
If possible remove containers from the danger zone.
If the fire cannot beextinguished the only course of action is
to evacuate immediately.
Personal precautions, protec-
Shut off leaks, if possible without personal risks. Remove all I
tive equipment and emer-
possible sources of ignition in the surrounding area and evacs
,v,ency procedures
uate all personnel. Attempt to disperse the gas or to direct its=
3
flow to a safe location for example by using fog sprays. Take
precautionary measures against static discharge. Ensure ele
trical continuity by bonding and grounding (earthing) all
equipment. Monitor area with combustible gas meter.
Test atmosphere for flammable gas concentrations to ensur
1
safe working conditions before personnel are allowed to ent
the area.
Environmental precautions
1
Use appropriate containment to avoid environmental contarn
nation.
Methods and materials for - Allow to evap#rate.
containment and cleaning up Attempt to disperse the gas or to direct its flow to a safe loca-
tion, for example by using fog sprays.
Take precautionary measures against static discharges.
Additional advice For guidance on selection of personal protective equipment
see Section 8 of this Safety Data Sheet.
Notify authorities if any exposure to the general public or the
environment occurs or is likely to occur.
For guidance on disposal of spilled material see Section 13 of
this Safety Data Sheet.
Vapour may form an explosive mixture with air.
Risk of explosion. Inform the emergency services if product
enters surface water drains.
SAFETY DATA SHEET
Version Revision Date: SDS Number:
Co 2025-05-06 800001031707
Print Date: 2025-05-07
A
9XIMns
Technical measures Avoid breathing of • direct contact with material. Only use in
well ventilated areas. Wash thoroughly after handling. For
guidance on selection of personal protective equipment see
Section 8 of this Safety Data Sheet.
Use the information in this data sheet as input to a risk as-
sessment • local circumstances to help determine appropri-
ate controls for safe handling, storage and disposal of this
material.
Air-dry contaminated clothing in a well -ventilated area before
laundering.
Use • exhaust ventilation if there is risk of inhalation ♦';
vapours, mists or aerosols.
Take precautionary measures against static discharges.
Advice on safe handling Ensure that all local regulations regarding handling and stor-
age facilities are followed.
This product is intended for use in closed systems •
This product can create a low temperature exposure hazard
when released as a liquid.
Extinguish any naked flames. Do not smoke. Remove ignition
sources. Avoid sparks.
Avoid prolonged or repeated contact with skin.
Electrostatic charges may be generated during pumping. Elec-
trostatic discharge may cause fire.
Earth all equipment.
Use ♦ exhaust ventilation if there is risk ♦ inhalation •i
vapours, mists • aerosols.
Avoidance of contact Strong oxidising agents.
Product Transfer Refer to guidance under Handling section. Do not use com-
pressed air for filling discharge or handling. Electrostatic
charges may be generated during pumping. Electrostatic
charge may cause fire. Delivery lines may become cold
enough to present a cold burns hazard. Ensure electrical con-
tinuity by bonding and grounding (earthing) all equipment.
Restrict line velocity during pumping in order to avoid genera-
tion of electrostatic discharge.
Further information on stor- Store only in purpose -designed, appropriately labelled pres-
age stability sure vessels or cylinders.
Must be stored in a well -ventilated area, away from sunlight,
ignition sources and other sources of heat.
Do not store near cylinders containing compressed oxygen or
other strong oxidizers.
The vapours in the head space of the storage vessel may lie
in the flammable/explosive range and hence may be •l`
Refer • section 15 for any additional •_.: legislation cov-
ering the packaging and storage of this product.
ARN
SAFETY DATA SHEET
Version Revision Date:
SCS Number: Print Date: 2025-05-07
2.0 2025-05-06
800001031707 Date of last issue: 04.05.2022
Date of first issue: 04.05.2022
Packaging material
Suitable material: For containers and container linings, use
materials specifically approved for use with this product., Ex-
amples of suitable materials are: PA-1 1, PEEK, PVDF, PTFE,
GRE (Epoxy), GRVE (vinyl ester), Viton (FKM), type F and
GB, Neoprene (CR).
Unsuitable material: Some forms of cast iron., Examples of
materials to avoid are: ABS, of et etas late
(PMMA), polyethylene (PE / HDPE), polypropylene (PP),
PVC, natural rubber (NR), Nitrile (NBR) ethylene propylene
rubber (EPDM), Butyl (11R), Hypalon (CSM), polystyrene, pol-
yvinyl chloride (PVC), polyisobutylene., For containers and
container linings, aluminium should not be used if there is a
risk of caustic contamination of the product.
Specific end use(s)
Specific use(s)
Not applicable.
American Petroleum Institute 2003 (Protection Against Igni-
tions Arising out of Static, Lightning and Stray Currents) or
on Static Electricity).
IEC/TS 60079-32-1: Electrostatic hazards, guidance
Components with workplace control parameters
Components CAS -No.
Value type
Control parame-
Basis
(Form of
ters / Permissible
exposure)
concentration
butane 106-97-8
STEL
1,000 P Pm
ACGIH
isobutane 75-28-5
TWA
1,000 PPM
CA BC OEL
STEL
[1,00P
] ACGIH
k13-r_o_oy1ene 115-07-1
50PPM
ACGI H
utene 25167-67-
A
250 ppm
AC H
Biological occupational exposure limits
IMEMMMM=
rt
INN
11111
,I,a-Fla-are-CFex—puslf-[P-Iilp.�rneriL 1110U]"Vitts 51 WWI fflsi�lt
ples analysed by an accredited laboratory.
tact the supplier. Further national methods may be available.
WME.
SAFETY DATA SHEET
Tersion Revision Date: SDS Number: Print Date: 2025-05-07
2.0 2025-05-06 800001031707 Date of last issue: 04.05.2022
Date of first issue: 04.05.2022
National Institute of Occupational Safety and Health (NIOSH), USA: Manual of Analytical Meth-
ods hffp://www.cdc.gov/niosh/
Occupational Safety, and Health Administration (OS+IA)� 59A.69,?
http://www.osha.gov/ U%
Health and Safet� Executive �HSE
es hftp://Www.hse.gov.uk/
Institut fijr Arbeitsschutz Deutschen Gesetzlichen Unfallversicherung (IFA) , Germany
http://www.dguv.de/inhalt/index.jsp
'-'Institut National de Recherche et de Securitd, (INRS), France hftp://www.inrs.fr/accueil
Frigineering measures The level of protection and types of controls necessary will
vary depending upon potential exposure conditions. Select
controls based on a risk assessment of local circumstances.
Appropriate measures include:
Use sealed systems as far as possible.
Adequate explosion -proof ventilation to control airborne con-
centrations below the exposure guidelines/limits.
Local exhaust ventilation is recommended.
Eye washes and showers for emergency use.
Always observe good personal hygiene measures, such as
W,2SkiKg k2A45 ?.Rp-r k2AViAg tke m2terial a&r iefitm dating;
drinking, and/or smoking. Routinely wash work clothing and
protective equipment to remove contaminants. Discard con-
taminated clothing and footwear that cannot be cleaned.
Practice good housekeeping.
Define procedures for safe handling and maintenance of
controls.
Educate and train workers in the hazards and control
measures relevant to normal activities associated with this
product.
Ensure appropriate selection, testing and maintenance of
eouinment used to control . o I ;Wjtz%&�2
,w.2.
equipment, local exhaust ventilation.
Drain down system prior to equipment break-in or mainte-
nance.
subsequent recycle.
fir:: i gest. If swallowed, then seek immediate medical
assistance
Personal protective equipment
kespiratory protection If engineering controls do not maintain airborne concentra-
tions to a level which is adequate to protect worker health,
select respiratory protection equipment suitable for the spe-
cific conditions of use and meeting relevant legislation.
Check with respiratory protective equipment suppliers.
Where air -filtering respirators are unsuitable (e.g. airborne
concentrations are high, risk of oxygen deficiency, confined
space) use appropriate positive pressure breathing appa-
8/18
SAFETY DATA SHEET
according to the Hazardous Products Regulations
Propane
Version Revision Date: SDS Number:
2.0 2025-05-06 800001031707
%no FTO` #"
Print Date: 2025-05-07
Agg iii -- i .
1110, Misim
ratus.
VVhar6 air-filtaring resAirat*rs ara
priate combination of mask and filter.
point <65 'C (149 'F)l
Remarks Where hand contact with the product may occur the use of
gloves approved to relevant standards (e.g. Europe: EN374,
US: F739) made from the following materials may provide
suitable chemical protection. Neoprene rubber. Nitrile rubber
If contact with liquefied product is possible or anticipated,
gloves should be thermally insulated to prevent cold burns.
For continuous contact we recommend gloves with break-
through time of more than 240 minutes with preference for >
480 minutes where suitable gloves can be identified. For
short-term/splash protection we recommend the same but
recognize that suitable gloves offering this level of protection
may not be available and in this case a lower breakthrough
time maybe acceptable so long as appropriate maintenance
and replacement regimes are followed. Glove thickness is not
a good predictor of glove resistance to a chemical as it is
dependent on the exact composition of the glove material.
Glove thickness should be typically greater than 0.35 mm
depending on the glove make and model.
Suitability and durability of a glove is dependent on usage,
e.g. frequency and duration of contact, chemical resistance of
glove material, dexterity. Always seek advice from glove sup-
pliers. Contaminated gloves should be replaced. Personal
hygiene is a key element of effective hand care. Gloves must
only be worn on clean hands. After using gloves, hands
should be washed and dried thoroughly. Application of a non -
perfumed moisturizer is recommended.
9 =k r
FOO
General advice
96.57
face shield with chin guard.
Local guidelines on emission limits for volatile substances
must be observed for the discharge of exhaust air containing
vapour.
Minimise release to the environment. An environmental as-
AME
SAFETY DATA SHEET
Propane
Version Revision Date: SDS Number: Print Date: 2025-05-07
2.0 2025-05-06 800001031707 Date of last issue: 04.05.2022
Date of first issue: 04.05.2022
ronmental legislation.
Information on accidental release measures are to be found in
section 6.
SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES
9.1 Information on basic physical and chemical properties
Physical state Liquid under pressure.
Colour colourless
Odour Unstenched
Odour Threshold Data not available
Freezing point -190 'C
Initial boiling point and boiling -42 *C
range
Flammability (solid, gas)
Extremely flammable.
Upper explosion limit / Upper
Typical 10 %(V)
flammability limit
Lower explosion limit / Lower
Typical 2 %(V)
flammability limit
Flash point
ca. -108 ®C
Auto -ignition temperature
Data not available
1ecom position temperature : Data not availab Z,
pH Not applicable
Viscosity
Viscosity, kinematic Data not available
10/18
SAFETY DATA SHEET
Propane
Version Revision Date: SDS Number: Print Date: 2025-05-07
2.0 2025-05-06 800001031707 Date of last issue: 04.05.2022
Date of first issue: 04.05.2022
Solubility(ies)
Water solubility negligible
Solubility in other solvents : Data not available
Partition coefficient: n- Data not available
octanol/water
Vapour pressure 1,300 kPa (38.0 'C)
Method: Unspecified
Relative density Data not available
Density : 500 - 550 kg/m3 (15.0 'C)
Relative vapour density Data not available
Particle characteristics
Particle size Data not available
9.2 her information
Explosives Classification Code: Not classified.
Evaporation rate i Data not available
Conductivity Low conductivity:< 100 pS/m
Reactivity No, product will not become self -reactive.
Chemical stability Stable under normal conditions of use.
Possibility of hazardous reac- No hazardous reaction is expected when handled and stored
11/18
SAFETY DATA SHEET
I .. - F til
Version Revision Date:
2.0 2025-05-06
tions
f1c-liVit
Incompatible materials
W
16319101101
SDS Number: Print Date: 2025-05-07
800001031707 Date of last issue: 04.05.2022
Date of first issue: 04.05.2022
according to provisions
Heat, open flames, sparks and flammable atmospheres.
In certain circumstances product can ignite due to static elec-
tricity.
Strong oxidising agents.
Hazardous decomposition products are not expected to form
during normal storage.
SECTION 11. TOXICOLOGICAL INFORMATION
Basis for assessment : Information given is based on product testing.
Information on likely routes of exposure
Inhalation is the primary route of exposure although exposure may occur through skin or eye con-
tact.
Acute toxicity
Product:
Acute oral toxicity Remarks: Not applicable
Acute inhalation toxicity LC 50 (Rat): >20000 it
Exposure time: 4 h
Remarks: Low toxicity
Acute dermal toxicity Remarks: Not applicable
Skin corrosion/irritation
Product:
Remarks Not irritating to skin.
Serious eye damage/eye irritation
Product:
Remarks Essentially non -irritating to eyes.
Respiratory or skin sensitisation
Product:
Remarks Not a sensitiser.
Based on available data, the classification criteria are not met.
12/18
SAFETY DATA SHEET
according to the Hazardous Products Regulations
Propane
Version Revision Date: SDS Number:
M 2025-05-06 800001031707
Print Date: 2025-05-07
Germ cell mutagenicity
Product:
Genotaxicity in vivo Remarks: on mutagenic
Based on available data, the classification criteria are not met.
Product:
Remarks Not a carcinogen.
Based on available data, the classification criteria are not met.
IARC No component of this product present at levels greater than or equal to 0.1% is
identified as probable, possible or confirmed human carcinogen by IARC.
OSHA No componentof this product present at levels greaterthan or equal to 0.1% is
on OSHA's list of regulated carcinogens.
NTP No componentof this product present at levels greater than or equal to 0.1% is
identified as a known or anticipated carcinogen by NTP.
Reproductive toxicity
Remarks Not a developmental toxicant.
Does not impair fertility.
Based on available data, the classification criteria are not met.
Product:
Remarks High concentrations may cause central nervous system de-
pression resulting in headaches, dizziness and nausea; con-
tinued inhalation may result in unconsciousness.
STOT - repeated exposure
Product:
Remarks Low systemic toxicity on repeated exposure.
Aspiration toxicity
Product:
Further information
Product:
Remarks High gas concentrations will displace available air; uncon-
sciousness and death may occur suddenly from lack of oxy-
gen.
Exposure to very high concentrations of similar materials has
13/18
SAFETY DATA SHEET
Version Revision Date: SDS Number: Print Date: 2025-05-07
2.0 2025-05-06 800001031707 Date of last issue: 04.05.2022
Date of first issue: 04.05.2022
been associalea TV irreg1trar
rest.
Remarks Rapid release of gases which are liquids under pressure may
cause frost burns of exposed tissues (skin, eye) due to evapo-
rative cooling.
Remarks Classifications by other authorities under varying regulatory
frameworks may exist.
W : Incomplete ecotoxicological data are available for this produ
.asis for assessment
The information given below is based partly on a knowledge
the components and the ecotoxicology of similar
products.Physical properties indicate that hydrocarbon gase
will rapidly volatilise from the aquatic environment and that
acute and chronic effects would not be observed in practice.]
•
Product:
Toxicity to fish Remarks: LC/EC/IC50> 100mg/I
Practically non toxic:
Based on available data, the classification criteria are not met.
Toxicity to daphnia and other r
aquatic invertebrates Remarks: LUEL/11_50 > 100 mg/I
Practically non toxic:
Based on available data, the classification criteria are not met.
IMM-23=
plants
Remarks: LC/EC/IC50 > 100 mg/1
Practically non toxic:
Based on available data, the classification criteria are not met.
Toxicity to fish (Chronic tox-
Remarks: Data not available
icity)
Toxicity to daphnia and other
Remarks: Data not available
aquatic invertebrates (Chron-
ic toxicity)
Toxicity to microorganisms
Remarks: LUIEL/11_50 > 100 mg/I
Practically non toxic:
Based on available data, the classification criteria are not met.
Persistence and degradability
Product:
Biodegradability Remarks: Oxidises rapidly by photo -chemical reactions in air.
irlwa
SAFETY DATA SHEET
Version Revision Date: SIDS Number: Print Date: 2025-05-07
2.0 2025-05-06 800001031707 Date of last issue: 04.05.2022
Date of first issue: 04.05.2022
Bioaccumulative potential
Product:
Bioaccumulation Remarks: Does not bioaccumulate significantly.
LEM=
Product:
Mobility Remarks: Because of their extreme volatility, air is the only
environmental compartment that hydrocarbon gases will be
found.
Other adverse effects
Product:
Additional ecological infor- In view of the high rate of loss from solution, the product is
mation unlikely to pose a significant hazard to aquatic life.
Waste from residues Given the nature and uses of this product, the need for dis-
posal seldom arises. If necessary, dispose by controlled co
bustion in purpose -designed equipment. If this is not possibi
contact the supplier.
It is the responsibility of the waste generator to determine th
toxicity and physical properties of the material generated to
determine the proper waste classification and disposal meth
ids: in compliance with applicable regulations.
Do not dispose into the environment, in drains or in water
courses.
Waste arising from a spillage or tank cleaning should be dis-
posed of in accordance with prevailing regulations, preferabl
to a recognised collector or contractor. The competence of t
collector or contractor should be established beforehand.
MARPOL - see International Convention for the Prevention
Pollution from Ships (MARPOL 73/78) which provides tech-
nical aspects at controlling pollutions from ships.
Contaminated packaging Drain container thoroughly.
After draining, vent in a safe place away from sparks and fire.
Residues may cause an explosion hazard.
Do not pollute the soil, water or environment with the waste
container.
Return part -used or empty cylinders to the supplier.
For tanks seek specialist advice from suppliers.
Dispose in accordance with prevailing regulations, preferably
to a recognized collector or contractor. The competence of
15/18
SAFETY DATA SHEET
�g=
Version Revision Date: SDS Number: Print Date: 2025-05-07
2.0 2025-05-06 800001031707 Date of last issue: 04.05.2022
to of first issue: 04.05.2022
. . .... . .. ....
Local legislation
Remarks Disposal should be in accordance with applicable regional,
national, and local laws and regulations.
Local regulations may be more stringent than regional or na-
tional requirements and must be complied with.
TDG
LIN number 1965
Proper shipping name HYDROCARBON GAS MIXTURE, LIQUEFIED, N.O.S.
(Propane, Butane)
Class 2.1
Packing group Not Assigned
Labels 2.1
Marine pollutant no
International Regulations
UN/ID No. UN 1965
Proper shipping name HYDROCARBON GAS MIXTURE, LIQUEFIED, N.O.S.
(Propane, Butane)
Class 2.1
Packing group Not Assigned
Labels 2.1
IMDG-Code
LIN number LIN 1965
Proper shipping name HYDROCARBON GAS MIXTURE, LIQUEFIED, N.O.S.
(Propane, Butane)
Class 2.1
Packing group Not Assigned
Labels 2.1
Marine pollutant no
Maritime transport in bulk according to IMO instruments
MARPOL Annex 1 rules apply for bulk shipments by sea.
Not applicable
SAFETY DATA SHEET
Version Revision Date: SDS Number:
2.0 2025-05-06 800001031707
• 15. REGULATORY INFORMATION
Safety, health and environmental regulationsilegislation specific for the substance or
mixture
this material.
This product has been classified in accordance with the hazard criteria of the Hazardous
The components • this product are reported in the following inventories:
imp
Full text of other abbreviations
ACGIH
CA BC OEL
ACGIH I TWA
ACGIH / STEL
CA BC OEL / TWA
11[f]IM1111161IN Is,
&Iis
aw
16161 (11(rol
I
-
•. British Columbia •
• time -weighted average
• exposure limit
8-hour time weighted average
[Ifffirc
SAFETY DATA SHEET
4 L
Version Revision Date: SDS Number: Print Date: 2025-05-07
2.0 2025-05-06 800001031707 Date of last issue: 04.05.2022
Date of first issue: 04.05.2022
menuaiions SdIlger'J"Ab 6—FIROUI e'1j_e_61WI`I5yey"r6
lative; WHMIS - Workplace Hazardous Materials Information System
9. -
1111 =L*=
W11
I I
The information provided in this Safety Data Sheet is correct to the best of our knowledge, infor-
mation and belief at the date of its publication. The information given is designed only as a guid-
ance for safe handling, use, processing, storage, transportation, disposal and release and is not
to be considered a warranty or quality specification. The information relates only to the specific
material designated and may not be valid for such material used in combination with any other
materials or in any process, unless specified in the text.
CA/ EN
9-im
. .... ...
A Member of The Linde Group
pffa;
Acetylene
Please ensure that this SDS is received by the appropriate persons
Review Date: 18/0712022 v01 Emergency: 0860 02 02 02 Document Number: AFX-SDS-0003
Product
Acetylene
Synonym
Ace_ lens
Chemicaf—
C2112
Formula
fiaiiei kame
Technical Acetylene
Acetylene Portapack
Baseline Ace lens
®lour inMaroon
Product ad e-
1-5--bif
16-DA
508103-DC-C
Company
dcan en it
Identification
Grayston Office Park Building 7
128 Peter Roandown, Sandton,
www,afrox.com
Emergency 0860 02 02 02 (Afrox)
Numbers
2. 'i4A`2A7k5_1b&T_iFICAT109
Classification Classification under South African
Hazardous Chemical Substances
Regulations subsequently amended.
(HCS)
Classification under the Globally
Harmonized System of classification and
labelling of chemicals (GHSj_
Emergency Colour: one
Overview Odour: one
Taste: None
Physical State: Compressed Gas
Form: Gas under pressure
-All cylinders are portable gas containers
and must be regarded as pressure vessels
at all times.
-Acetylene does not support life.
Adverse Health - Asphixiant
Effects
Chemical
Flammable explosive
Hazards
Biological
The greatest physiological effect of
Hazards
Apqtylens js to caysq_2sp iation.
Vapour
Asphyxiation
Inhalation
GHS
as under pressure
Classification
GHS Pictograrn
0
do*-,
GHS Signal Danger
Words
GHS Hazard
Extremely flammable gas.
Statements
Contains gas under pressure; may
expIce if heated
Astmomm
Precautionary
P403: Store in a well -ventilated place.
Statements
Prevention:
: Wear protective gloves/eye
protection/face protection.
a2Eponse:
one
02 trial
one
Other Hazards
- Asphyxlant in high concentrations
that do not
result in
classification
3. C0MP0S_1Tf6N OF ING ' REDIENTS
dh �al War��
Acetylene
Chem
Acttyllene�_
CAS No
74-86-2
UN No
1001 (gas)
Eilid N�
i i
Yazi,rd class
Class 2.1
[4. FIRST AID MEASURES
♦
_-Ri—ins--ethe eye with water immediately.
Remove contact lenses, if present and
easy to do. Continue Hnsing.
Flush thoroughly with water for at least 15
minutes.
Get immediate medical assistance. If
medical assistance is not immediately
available, flush an additional 15 min ut es.
[�;r exposure to' liquid, immediately warm
frostbite area with warm water not to
exceed 41'C. Water temperature should be
tolerable to normal skin.
Maintain skin warming for at least 15
minutes or until normal colouring and
sensation have retumed to the affected
area.
in case of massive exposure, remove
clothing while showering with warm water.
Seek medical evaluation and treatment as
soon as possible.
Ingestion
- Ingestion is not considered a potential
route of exposure.
In "al tion
- In high concentrations may cause
asphyxiation. Symptoms may include loss
of mobility/consciousness. Victim may not
be aware of asphyxiation.
- Remove victim to uncontaminated area
wearing self-contained breathing
apparatus.
Keep victim warm and rested. Seek
-if
medical attention. Apply artificial respiration
breathin sto e