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HomeMy WebLinkAboutCO2018-1400 *NTARTFXO Safety Data Sheet Paint Thinner Version 1.1 Revision Date: 04/15/2015 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name Paint Thinner Product Use Descrip- Paint related material. tion Manufacturer or supplier's details Company Nexeo Solutions LLC - STARTEX"° Address 3 Waterway Square Place Suite 1000 Woodlands, Tx. 77380 United States of America Emergency telephone number: Health North America: 1-855-NEXE04U (1-855-639-3648) Health International: 1-855-NEXE04U (1-855-639-3648) Transport North America: CHEMTREC 800.424.9300 Additional Infor- Responsible Party: Product Safety Group mation: E-Mail: msds @nexeosolutions.com SDS Requests: 1-855-429-2661 SDS Requests Fax: 1-281-500-2370 Website: www.nexeosolutions.com SECTION 2. HAZARDS IDENTIFICATION GHS Classification Flammable liquids Category 3 Skin irritation Category 2 Eye irritation Category 2A Carcinogenicity Category 2 Specific target organ tox- Category 3 (Central nervous system) icity - single exposure Aspiration hazard Category 1 GHS Label element Hazard pictograms 1 Signal word Danger MSDS Number: 100000008536 1 / 28 Paint Thinner STARTER" Safety Data Sheet Paint Thinner Version 1.1 Revision Date: 04/15/2015 Hazard statements H226 Flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H319 Causes serious eye irritation. H336 May cause drowsiness or dizziness. H351 Suspected of causing cancer. Precautionary statements Prevention: P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat, hot surfaces, sparks, open flames and other ignition sources. No smoking. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ ventilating/ lighting/ equipment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P261 Avoid breathing dust/ fume/ gas/ mist/ vapours/ spray. P264 Wash skin thoroughly after handling. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/ eye protection/ face protection. P281 Use personal protective equipment as required. Response: P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/ physician. P303 + P361 + P353 IF ON SKIN (or hair): Remove/ Take off immediately all contaminated clothing. Rinse skin with water/ shower. P304 + P340 + P312 IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/ physician if you feel unwell. P305 + P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P308 + P313 IF exposed or concerned: Get medical advice/ attention. P331 Do NOT induce vomiting. P332 + P313 If skin irritation occurs: Get medical advice/ attention. P337 + P313 If eye irritation persists: Get medical advice/ attention. P362 Take off contaminated clothing and wash before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical MSDS Number: 100000008536 2 / 28 Paint Thinner STARTER' Safety Data Sheet Paint Thinner Version 1.1 Revision Date: 04/15/2015 or alcohol-resistant foam for extinction. Storage: P403 + P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. Disposal: P501 Dispose of contents/ container to an approved waste disposal plant. Potential Health Effects Carcinogenicity: IARC Group 213: Possibly carcinogenic to humans 100-41-4 Ethylbenzene 91-20-3 Naphthalene ACGIH No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by ACGIH. OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcinogen by OSHA. NTP Reasonably anticipated to be a human carcinogen 91-20-3 Naphthalene Emergency Overview Appearance liquid Colour clear, colourless Odour mild, characteristic Hazard Summary No information available. SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance/ Mixture Mixture Hazardous components CAS-No. I Chemical Name Concentration % 64742-47-8 1 Distillates (pet), h drotreated li ht 0 - 90 MSDS Number: 100000008536 3 / 28 Paint Thinner S*4 TARTER' Safety Data Sheet Paint Thinner Version 1.1 Revision Date: 04/15/2015 64742-88-7 Solvent naphtha Waliph. 0 - 90 8052-41-3 Stoddard solv e20 - 30 1330-20-7 **Mixed X len1 - 5 95-63-6 **1,2 4-trimet1 - 5 111-84-2 **Nonane 1 - 5 100-41-4 **Eth (benzen0.1 - 1 91-20-3 **Na hthalene 0.1 - 1 Special Notes: Functionally equivalent petroleum streams may be found in this preparation at varying concentrations. ** Other substances in the product which may pre- sent a health or environmental hazard. SECTION 4. FIRST AID MEASURES General advice Move out of dangerous area. Show this safety data sheet to the doctor in attend- ance. Symptoms of poisoning may appear several hours later. Do not leave the victim unattended. If inhaled Consult a physician after significant exposure. If unconscious place in recovery position and seek medical advice. In case of skin contact If skin irritation persists, call a physician. If on skin, rinse well with water. If on clothes, remove clothes. In case of eye contact Immediately flush eye(s) with plenty of water. Remove contact lenses. Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. If swallowed Keep respiratory tract clear. Do NOT induce vomiting. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious per- son. If symptoms persist, call a physician. Take victim immediately to hospital. SECTION S. FIREFIGHTING MEASURES MSDS Number: 100000008536 4 / 28 Paint Thinner *_ 5 TA R TFX`' Safety Data Sheet Paint Thinner Version 1.1 Revision Date: 04/15/2015 Suitable extinguishing Alcohol-resistant foam media Carbon dioxide (CO2) Dry chemical Unsuitable extinguishing High volume water jet media Specific hazards during Do not allow run-off from fire fighting to enter drains firefighting or water courses. Hazardous combustion No hazardous combustion products are known products Specific extinguishing Use a water spray to cool fully closed containers. methods Further information Collect contaminated fire extinguishing water sepa- rately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing wa- ter must be disposed of in accordance with local regu- lations. For safety reasons in case of fire, cans should be stored separately in closed containments. Special protective equip- Wear self-contained breathing apparatus for fire- ment for firefighters fighting if necessary. NFPA Flammable and Combustible Liquids Classification: Combustible Liquid Class II SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, Use personal protective equipment. protective equipment and Ensure adequate ventilation. emergency procedures Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentrations. Vapours can accumulate in low areas. Environmental precau- Prevent product from entering drains. tions Prevent further leakage or spillage if safe to do so. If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials Contain spillage, and then collect with non- for containment and combustible absorbent material, (e.g. sand, earth, cleaning up diatomaceous earth, vermiculite) and place in con- tainer for disposal according to local / national regula- MSDS Number: 100000008536 5 / 28 Paint Thinner 5TARTFT Safety Data Sheet Paint Thinner Version 1.1 Revision Date: 04/15/2015 tions (see section 13). SECTION 7. HANDLING AND STORAGE Advice on safe handling Avoid formation of aerosol. Do not breathe vapours/dust. Avoid exposure - obtain special instructions before use. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the application area. Take precautionary measures against static discharg- es. Provide sufficient air exchange and/or exhaust in work rooms. Open drum carefully as content may be under pres- su re. Dispose of rinse water in accordance with local and national regulations. Conditions for safe stor- No smoking. age Keep container tightly closed in a dry and well- ventilated place. Containers which are opened must be carefully re- sealed and kept upright to prevent leakage. Observe label precautions. Electrical installations/ working materials must com- ply with the technological safety standards. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters CAS-No. Components Value type Control parame- Basis (Form of ters/ Permissi- exposure) ble concentra- tion 64742-47-8 Distillates (pet), hy- TWA 500 ppm OSHA Z-1 drotreated light 2,000 m /m3 TWA 200 mg/m3 ACGIH (as total hydro- carbon vapor) TWA 400 ppm OSHA PO 1,600 m /m3 64742-88-7 Solvent naphtha (pet), med TWA 500 ppm OSHA Z-1 ali h. 2,00 mg/m3 MSDS Number: 100000008536 6 / 28 Paint Thinner *1 _15TARTFT Safety Data Sheet Paint Thinner Version 1.1 Revision Date: 04/15/2015 TWA 200 mg/m3 ACGIH (as total hydro- carbon vapor) TWA 400 ppm OSHA PO 1,600 m /m3 8052-41-3 Stoddard solvent TWA 100 plorn ACGIH TWA 350 nn /m3 NIOSH REL C 1,800 nn /m3 NIOSH REL TWA 500 ppm OSHA Z-1 2,900 m /m3 TWA 100 ppm OSHA PO 525 m /m3 1330-20-7 "Mixed Xylenes TWA 100 ppm OSHA Z-1 435 nn /m3 TWA 100 pprn ACGIH STEL 150 ppm ACGIH STEL 150 ppm OSHA PO 655 m /m3 TWA 100 ppm OSHA PO 435 m /m3 95-63-6 1,2,4-trimethylbenzene TWA 25 ppm NIOSH REL 125 m /m3 111-84-2 Nonane TWA 200 ppm ACGIH TWA 200 ppm NIOSH REL 1,050 m /m3 TWA 200 ppm OSHA PO 1,050 mg/m3 100-41-4 Eth (benzene TWA 20 ppm ACGIH STEL 125 ppm ACGIH TWA 100 ppm NIOSH REL 435 mg/m3 ST 125 ppm NIOSH REL 545 m m3 TWA 100 ppm OSHA Z-1 435 m /m3 TWA 100 ppm OSHA PO 435 m /m3 STEL 125 ppm OSHA PO 545 m m3 91-20-3 Naphthalene TWA 10 pprn ACGIH STEL 15 pprn ACGIH TWA 10 ppm NIOSH REL 50 m /m3 ST 15 ppm NIOSH REL 75 m /m3 TWA 10 ppm OSHA Z-1 50 m /m3 TWA 10 ppm OSHA PO 50 m m3 MSDS Number, 100000008536 7 / 28 Paint Thinner STARTER Safety Data Sheet Paint Thinner Version 1.1 Revision Date: 04/15/2015 STEL 15 mp /m3 I OSHA PO Biological occupational exposure limits Components CAS No. Control Biological Sam Permissi- Basis parame- specimen pling ble con- ters time centration "Mixed Xylenes 1330- Methylhip Urine End of 1.5 g/g ACGIH 20-7 puric acids shift creatinine BEI (As soon as possible after expo- sure ceases Ethylbenzene 100-41- Sum of Urine End of 0.7 g/g ACGIH 4 mandelic shift at creatinine BEI acid and end of phenyl work- glyoxylic week acid Personal protective equipment Respiratory protection No personal respiratory protective equipment normally required. In the case of vapour formation use a respirator with an approved filter. Hand protection Remarks The suitability for a specific workplace should be dis- cussed with the producers of the protective gloves. Eye protection Eye wash bottle with pure water Tightly fitting safety goggles Wear face-shield and protective suit for abnormal pro- cessing problems. Skin and body protection impervious clothing Choose body protection according to the amount and concentration of the dangerous substance at the work place. Hygiene measures When using do not eat or drink. When using do not smoke. Wash hands before breaks and at the end of workday. MSDS Number: 100000008536 8 / 28 Paint Thinner 5TARTEX' Safety Data Sheet Paint Thinner Version 1.1 Revision Date: 04/15/2015 SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance liquid Colour clear, colourless Odour mild, characteristic Odour Threshold No data available PH No data available Freezing Point No data available Boiling Point (Boiling 158 - 198 °C (316 - 388 °F) point/boiling range) Flash point 42 - 45 °C (108 - 113 °F) Evaporation rate No data available Flammability (solid, gas) No data available Burning rate No data available Upper explosion limit No data available Lower explosion limit No data available Vapour pressure No data available Relative vapour density No data available Relative density 0.775 - 0.784 @ 20 °C (68 °F) Reference substance: (water = 1) Density No data available Bulk density No data available Solubility(ies) Water solubility negligible Solubility in other sol- No data available vents Partition coefficient: n- No data available octanol/water Auto-ignition temperature 276 °C MSDS Number: 100000008536 9 / 28 Paint Thinner *STARTEX" Safety Data Sheet Paint Thinner Version 1.1 Revision Date: 04/15/2015 Thermal decomposition No data available SECTION 10. STABILITY AND REACTIVITY Reactivity No dangerous reaction known under conditions of normal use. Chemical stability Stable under normal conditions. Possibility of hazardous Vapours may form explosive mixture with air. reactions Conditions to avoid Keep away from heat, flame, sparks and other ignition sources. Incompatible materials oxidizers Peroxides Reducing agents Strong bases Strong oxidizing agents Hazardous decomposition Carbon oxides products SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Product: Acute inhalation toxicity Acute toxicity estimate : > 40 mg/I Exposure time: 4 h Test atmosphere: vapour Method: Calculation method Components: 64742-47-8: Acute oral toxicity LD50 (rat): > 5,000 mg/kg Acute inhalation toxicity Remarks: No data available Acute dermal toxicity LD50 (rabbit, male and female): > 2,000 mg/kg Method: Fixed dose procedure MSDS Number: 100000008536 10 / 28 Paint Thinner STARTER" Safety Data Sheet Paint Thinner Version 1.1 Revision Date: 04/15/2015 GLP: yes 64742-88-7: Acute oral toxicity LD50 (rat): > 5,000 mg/kg Acute inhalation toxicity Remarks: No data available Acute dermal toxicity LD50 (rabbit, male and female): > 2,000 mg/kg GLP: yes Remarks: Information given is based on data obtained from similar substances. 8052-41-3: Acute oral toxicity LD50 (rat, male and female): > 5,000 mg/kg Acute inhalation toxicity LC50 (rat, male and female): >5500 Exposure time: 4 h Assessment: The substance or mixture has no acute inhalation toxicity Acute dermal toxicity LD50 (rabbit): > 3,000 mg/kg Assessment: The substance or mixture has no acute dermal toxicity Skin corrosion/irritation Product: Remarks: Irritating to skin. Comoonents• 64742-47-8: Species: rabbit Exposure time: 24 h Method: In vivo Result: Irritating to skin. 64742-88-7: Species: rabbit Exposure time: 24 h Method: In vivo Result: Irritating to skin. GLP: yes 8052-41-3: Species: rabbit Exposure time: 24 h Method: In vivo Result: Mild skin irritation MSDS Number: 100000008536 11 / 28 Paint Thinner y STARTEX' Safety Data Sheet Paint Thinner Version 1.1 Revision Date: 04/15/2015 Serious eye damage/eye irritation Product: Remarks: Irritating to eyes. Components. 64742-47-8: Species: rabbit Result: No eye irritation Exposure time: 1 s Method: EPA OTS 798.4500 GLP: yes 64742-88-7: Species: rabbit Result: Irritating to eyes. 8052-41-3: Species: rabbit Result: Mild eye irritation Method: In vivo Respiratory or skin sensitisation Components: 64742-47-8: Test Type: Buehler Test Exposure routes: Dermal Species: guinea pig Method: In vivo Result: Did not cause sensitisation on laboratory animals. GLP: yes 64742-88-7: Test Type: Buehler Test Species: guinea pig Method: In vivo Result: Did not cause sensitisation on laboratory animals. GLP: yes Remarks: Based on a similar product formulation. 8052-41-3: Exposure routes: Dermal Species: guinea pig Method: In vivo Result: Did not cause sensitisation on laboratory animals. MSDS Number: 100000008536 12 / 28 Paint Thinner i STARTEX` Safety Data Sheet Paint Thinner Version 1.1 Revision Date: 04/15/2015 Germ cell mutagenicity Components: 64742-47-8: Genotoxicity in vitro Test Type: Mammalian cell gene mutation assay Test species: Mouse lymphoma cells Metabolic activation: with and without metabolic acti- vation Result: negative GLP: yes Genotoxicity in vivo Test Type: Chromosome aberration assay in vivo Test species: rat (male and female) Cell type: Bone marrow Application Route: Intraperitoneal Exposure time: 6 - 48 hrs Dose: 0, 300, 1000, 3000 mg/kg low Result: negative GLP: yes Germ cell mutagenicity- Tests on bacterial or mammalian cell cultures did not Assessment show mutagenic effects. 64742-88-7: Genotoxicity in vitro Test Type: Mammalian cell gene mutation assay Test species: Mouse lymphoma cells Metabolic activation: with and without metabolic acti- vation Result: negative GLP: yes Remarks: Information given is based on data obtained from similar substances. Genotoxicity in vivo Test Type: DNA damage and/or repair Test species: mouse (male) Application Route: Intraperitoneal Exposure time: 20 -22 h Dose: 0, 400, 2000, 4000 mg/kg Result: negative GLP: yes Germ cell mutagenicity- Mutagenicity classification not possible from current Assessment data 8052-41-3: Germ cell mutagenicity- Mutagenicity classification not possible from current Assessment data MSDS Number: 100000008536 13 / 28 Paint Thinner OTARTET' Safety Data Sheet Paint Thinner Version 1.1 Revision Date: 04/15/2015 Carcinogenicity Components: 64742-47-8: Species: mouse, (male and female) Application Route: Dermal Exposure time: 105 wks Dose: 0, 25 mg/application Frequency of Treatment: 3 days/week LOAEL: 25 Result: Limited evidence of carcinogenic effects Symptoms: Local irritation, Dermal tumours Carcinogenicity - As- Not classifiable as a human carcinogen. sessment 64742-88-7: Carcinogenicity - As- Not classifiable as a human carcinogen. sessment 8052-41-3: Carcinogenicity - As- Carcinogenicity classification not possible from current sessment data. 100-41-4: Carcinogenicity - As- Not classifiable as a human carcinogen. sessment Reproductive toxicity Components: 64742-47-8: Effects on fertility Test Type: Fertility Species: rat, male and female Application Route: Oral Dose: 0, 375, 750, 1500 mg/kg/d General Toxicity - Parent: NOAEL: 750 mg/kg body weight General Toxicity Fl: NOAEL: 750 mg/kg body weight Fertility: NOAEL: >= 1,500 mg/kg body weight Symptoms: Reduced maternal body weight gain. Re- duced offspring weight gain. Result: No reproductive effects. Effects on foetal devel- Species: rat opment Application Route: Oral Dose: 0, 500, 1000, 1500, 2000mg/kg Duration of Single Treatment: 10 d General Toxicity Maternal: NOAEL: 500 mg/kg body MSDS Number: 100000008536 14 / 28 Paint Thinner STARTER" Safety Data Sheet Paint Thinner Version 1.1 Revision Date: 04/15/2015 weight Teratogenicity: NOAEL: 2,000 mg/kg body weight Developmental Toxicity: NOAEL: 1,000 mg/kg body weight Symptoms: Reduced body weight Method: OECD Test Guideline 414 Result: Developmental toxicity occurred at maternal toxicity dose levels, No teratogenic effects. Reproductive toxicity - Animal testing did not show any effects on fertility. Assessment Embryotoxicity classification not possible from current data. 64742-88-7: Effects on fertility Test Type: Fertility Species: rat, female Application Route: Oral Dose: 0, 325, 750, 1500 mg/kg/day Duration of Single Treatment: 147 d General Toxicity - Parent: NOAEL: 750 mg/kg body weight General Toxicity Fl: NOAEL: 750 mg/kg body weight Fertility: NOAEL: >= 1,500 mg/kg body weight Symptoms: Reduced maternal body weight gain. Re- duced offspring weight gain. Result: Animal testing did not show any effects on fertility., Embryotoxic effects and adverse effects on the offspring were detected. GLP: yes Effects on foetal devel- Species: rat opment Application Route: Oral Dose: 0, 500, 1000, 1500, 2000 milligram per kilo- gram Duration of Single Treatment: 10 d General Toxicity Maternal: NOAEL: 500 mg/kg body weight Teratogenicity: NOAEL: 2,000 mg/kg body weight Developmental Toxicity: NOAEL: 1,000 mg/kg body weight Symptoms: Reduced body weight Method: OECD Test Guideline 414 Result: Developmental toxicity occurred at maternal toxicity dose levels, No teratogenic effects. Reproductive toxicity - Animal testing did not show any effects on fertility. Assessment Did not show teratogenic effects in animal experi- ments. 8052-41-3: Reproductive toxicity - Fertility classification not possible from current data. MSDS Number: 100000008536 IS / 28 Paint Thinner STARTER" Safety Data Sheet Paint Thinner Version 1.1 Revision Date: 04/15/2015 Assessment Embryotoxicity classification not possible from current data. STOT - single exposure Product:No data available Comoonents• 64742-47-8: Exposure routes: Target Organs: As Remarks: Inhalation Central nervous May cause drowsi- system ness or dizziness., The substance or mixture is classified as specific target organ toxicant, sin- gle exposure, cate- gory 3 with narcotic effects. 64742-88-7: Ex osure routes: Tar et Or ans: Assessment, Re'. Inhalation Central nervous May cause drowsi- system ness or dizziness., The substance or mixture is classified as specific target organ toxicant, sin- gle exposure, cate- gory 3 with narcotic effects. 8052-41-3: Ex osure routes: Ta et O ans: . .Assessment: Remarks: Inhalation Central nervous May cause drowsi- system ness or dizziness., The substance or mixture is classified as specific target organ toxicant, sin- gle exposure, cate- gory 3 with narcotic effects. 1330-20-7:No data available 95-63-6:No data available MSDS Number: 100000008536 16 / 28 Paint Thinner *NTARTFXO Safety Data Sheet Paint Thinner Version 1.1 Revision Date: 04/15/2015 111-84-2:No data available 100-41-4:No data available 91-20-3:No data available STOT - repeated exposure Product:No data available Components: 64742-47-8:No data available 64742-88-7:No data available 8052-41-3:No data available 1330-20-7:No data available 95-63-6:No data available 111-84-2:No data available 100-41-4:No data available 91-20-3:No data available Repeated dose toxicity Components: 64742-47-8: Species: rat, male LOAEL: 750 mg/kg Application Route: Oral Exposure time: 70 - 90 days Number of exposures: daily Dose: 0, 750, 1500, 3000 mg/kg/d GLP: yes Symptoms: weight loss, Liver effects, Stomach/intestinal disorders MSDS Number: 100000008536 17 / 28 Paint Thinner *NTARTEX' Safety Data Sheet Paint Thinner Version 1.1 Revision Date: 04/15/2015 Species: rat, female NOAEL: 750 mg/kg Application Route: Oral Exposure time: 21 wks Number of exposures: daily Dose: 0, 325, 750, 1500 mg/kg/d GLP: yes Symptoms: weight loss, Liver effects, Stomach/intestinal disorders Species: mouse, male and female NOAEL: >= 1000 Application Route: inhalation (vapour) Exposure time: 90 d Number of exposures: 24 h/d, daily Dose: 0, 500, 1000 mg/m3 GLP: No data available Species: rat, male and female NOAEL: >=0,5 Application Route: Dermal Exposure time: 28 d Number of exposures: 6 h/d, 5 d/wk Dose: 0, 0.01, 0.05, 0.5 ml/kg bw/d Method: OECD Test Guideline 410 GLP: yes Symptoms: Local irritation Repeated dose toxicity - Causes skin irritation. Assessment 64742-88-7: Species: rat, male LOAEL: 750 mg/kg Application Route: Oral Exposure time: 70 - 90 d Number of exposures: Daily Dose: 0, 750, 1500, 3000 mg/kg/day GLP: yes Symptoms: weight loss, Local irritation Species: rat, female NOAEL: 750 mg/kg Application Route: Oral Exposure time: 21 wks Number of exposures: Daily Dose: 0, 325, 750, 1500 mg/kg/day GLP: yes Symptoms: weight loss, Local irritation Species: rat, male and female MSDS Number: 100000008536 18 / 28 Paint Thinner i STARTEX` Safety Data Sheet Paint Thinner Version 1.1 Revision Date: 04/15/2015 NOAEL: >= 24 Application Route: Inhalation Test atmosphere: vapour Exposure time: 4 wks Number of exposures: 6 h/d, 5 d/wk Dose: 0, 24 mg/m3 GLP: yes Remarks: Information given is based on data obtained from similar substances. Species: rat, male and female NOAEL: >= 0.5 mg/1 Application Route: Dermal Exposure time: 4 wks Number of exposures: 6 h/d, 5 d/wk Dose: 0, 1.01, 0.05, 0.5 ml/kg/day Method: OECD Test Guideline 410 GLP: yes Remarks: Information given is based on data obtained from similar substances. Repeated dose toxicity - Causes skin irritation. Assessment 8052-41-3: Species: rat, male and female NOAEL: 275 Application Route: Inhalation Exposure time: 14 wks Number of exposures: 6 h/d, 5 d/wk Dose: 138, 275, 550, 1100, 2200mg/m3 Group: yes Symptoms: nasal symptoms, Testicular effects, Kidney disorders Remarks: male rat hydrocarbon nephropathy not relevant to humans Species: mouse, male and female LOAEL: 138 Application Route: Inhalation Exposure time: 14 wks Number of exposures: 6 h/d, 5 d/wk Dose: 138, 275, 550, 1100, 2200mg/m3 Group: yes Symptoms: Spleen effects Aspiration toxicity Product: May be fatal if swallowed and enters airways. Components: 64742-47-8: MSDS (dumber: 100000008536 19 / 28 Paint Thinner STARTER" Safety Data Sheet Paint Thinner Version 1.1 Revision Date: 04/15/2015 May be fatal if swallowed and enters airways. 64742-88-7: May be fatal if swallowed and enters airways. 8052-41-3: May be fatal if swallowed and enters airways. Further information Product: Remarks: Symptoms of overexposure may be headache, dizziness, tiredness, nau- sea and vomiting., Concentrations substantially above the TLV value may cause nar- cotic effects., Solvents may degrease the skin. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Components: 64742-47-8: Toxicity to fish LL50 (Oncorhynchus mykiss (rainbow trout)): 25 mg/I Exposure time: 96 h Test Type: static test Analytical monitoring: yes Method: OECD Test Guideline 203 GLP: yes Toxicity to daphnia and EL50 (Daphnia magna (Water flea)): 1.4 mg/1 other aquatic inverte- Exposure time: 48 h brates Test Type: static test Analytical monitoring: yes Method: OECD Test Guideline 202 GLP: yes Toxicity to algae EL50 (Pseudokirchneriella subcapitata (green algae)): 1 mg/I End point: Growth rate Exposure time: 72 h Test Type: static test Analytical monitoring: yes Method: OECD Test Guideline 201 GLP: yes Ecotoxicology Assessment Acute aquatic toxicity Toxic to aquatic life. MSDS Number: 100000008536 20 / 28 Paint Thinner STARTER`' Safety Data Sheet Paint Thinner Version 1.1 Revision Date: 04/15/2015 Chronic aquatic toxicity Toxic to aquatic life with long lasting effects. 64742-88-7: Toxicity to fish LL50 (Oncorhynchus mykiss (rainbow trout)): 2 mg/I Exposure time: 96 h Test Type: semi-static test Analytical monitoring: yes Method: OECD Test Guideline 203 GLP: yes Remarks: Information given is based on data obtained from similar substances. Toxicity to daphnia and EL50 (Daphnia magna (Water flea)): 1.4 mg/I other aquatic inverte- Exposure time: 48 h brates Test Type: static test Analytical monitoring: yes Method: OECD Test Guideline 202 GLP: yes Toxicity to algae EL50 (Pseudokirchneriella subcapitata): 1 mg/I End point: Growth rate Exposure time: 72 h Test Type: static test Method: OECD Test Guideline 201 GLP: yes Remarks: Information given is based on data obtained from similar substances. Ecotoxicology Assessment Acute aquatic toxicity Toxic to aquatic life. Chronic aquatic toxicity Toxic to aquatic life with long lasting effects. 8052-41-3: Toxicity to fish Remarks: No data available Toxicity to daphnia and LL50 (Chaetogammarus marinus (Amphipod)): 3.5 other aquatic inverte- mg/I brates Exposure time: 96 h Toxicity to algae EbL50 (Pseudokirchneriella subcapitata (green algae)): 2.5 mg/I End point: Biomass Exposure time: 72 h Ecotoxicology Assessment Acute aquatic toxicity Toxic to aquatic life. Chronic aquatic toxicity Toxic to aquatic life with long lasting effects. MSDS Number: 100000008536 21 / 28 Paint Thinner t � STARTEX' Safety Data Sheet Paint Thinner Version 1.1 Revision Date: 04/15/2015 Persistence and degradability Components: 64742-47-8: Biodegradability aerobic Concentration: 101 mg/I Biodegradation: 61 Exposure time: 28 d GLP: yes Remarks: Readily biodegradable 64742-88-7: Biodegradability aerobic Concentration: 101 mg/I Biodegradation: 61 Testing period: 10 d Exposure time: 28 d Lag phase: 5 d Test substance: Solvent naphtha (petroleum), heavy aromatic GLP: yes 8052-41-3: Biodegradability Remarks: No data available Bioaccumulative potential Components• 1330-20-7: Partition coefficient: n- log Pow: 2.77 - 3.15 octanol/water 95-63-6: Partition coefficient: n- Remarks: No data available octanol/water 91-20-3: Partition coefficient: n- log Pow: 3.4 (25 °C) octanol/water pH: 7 - 7.5 Mobility in soil Components: 64742-88-7: Stability in soil Remarks: Adsorbs on soil. MSDS Number: 100000008536 22 / 28 Paint Thinner *5TARTEY Safety Data Sheet Paint Thinner Version 1.1 Revision Date: 04/15/2015 Other adverse effects No data available Product: Regulation 40 CFR Protection of Environment; Part 82 Protection of Stratospheric Ozone - CAA Section 602 Class I Sub- stances Remarks This product neither contains, nor was manufactured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A, App.A + B). Additional ecological in- An environmental hazard cannot be excluded in the formation event of unprofessional handling or disposal., Toxic to aquatic life with long lasting effects. SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues Dispose of in accordance with all applicable local, state and federal regulations. For assistance with your waste management needs - including disposal, recycling and waste stream reduc- tion, contact NEXEO's Environmental Services Group at 800-637-7922. Contaminated packaging Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on, the empty drum. SECTION 14. TRANSPORT INFORMATION IATA (International Air Transport Association): UN1268, PETROLEUM DISTILLATES, N.O.S., 3, III, Flash Point:42 - 45 °C(108 - 113 °F) IMDG (International Maritime Dangerous Goods): UN1268, PETROLEUM DISTILLATES, N.O.S., 3, III, Marine Pollutant(PETROLEUM DISTILLATE, HYDROTREATED LIGHTSTODDARD SOLVENT) DOT (Department of Transportation): UN1268, PETROLEUM DISTILLATES, N.O.S., CBL, III Special Notes: The flash point for this material is greater than 100 F MSDS Number: 100000008536 23 / 28 Paint Thinner *STARTEX' Safety Data Sheet Paint Thinner Version 1.1 Revision Date: 04/15/2015 (38 C). Therefore, in accordance with 49 CFR 173.150(f) non-bulk containers (<450L or <119 gal- lon capacity) of this material may be shipped as non- regulated when transported solely by land, as long as the material is not a hazardous waste, a marine pollu- tant, or specifically listed as a hazardous substance. SECTION 15. REGULATORY INFORMATION OSHA Hazards Combustible Liquid, Carcinogen, Harmful by skin absorption., Moderate skin irritant, Moderate eye irritant, Moderate respiratory irritant, Aspiration hazard WHMIS Classification 133: Combustible Liquid D2A: Very Toxic Material Causing Other Toxic Effects D213: Toxic Material Causing Other Toxic Effects EPCRA - Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity Components CAS-No. Component Calculated product R Ibs) RO Obs) **Mixed X lenes 1330-20-7 100 2505 SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RQ. SARA 311/312 Fire Hazard Hazards Chronic Health Hazard Acute Health Hazard SARA 302 SARA 302: No chemicals in this material are subject to the reporting requirements of SARA Title III, Section 302. SARA 313 The following components are subject to reporting levels established by SARA Title III, Section 313: 1330-20-7 **Mixed Xylenes 3.9925 91-20-3 **Naphthalene 0.1797 100-41-4 **Ethylbenzene 0.1797 95-63-6 **1,2,4- 1.0075 % tri methyl benzene Clean Air Act MSDS Number: 100000008536 24 / 28 Paint Thinner *NTARTEX" Safety Data Sheet Paint Thinner Version 1.1 Revision Date: 04/15/2015 The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61): 1330-20-7 **Mixed Xylenes 3.9925 100-41-4 **Ethylbenzene 0.1797 91-20-3 **Naphthalene 0.1797 98-82-8 **Cumene 0.079 108-88-3 **Toluene 0.079 71-43-2 **Benzene 0.079 This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r) for Accidental Release Prevention (40 CFR 68.130, Subpart F). The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's (40 CFR 60.489): 1330-20-7 **Mixed Xylenes 3.9925 98-82-8 **Cumene 0.079 108-88-3 **Toluene 0.079 71-43-2 **Benzene 0.079 100-41-4 **Ethylbenzene 0.1797 Clean Water Act The following Hazardous Substances are listed under the U.S. Clean Water Act, Sec- tion 311, Table 116.4A: 1330-20-7 **Mixed Xylenes 3.9925 100-41-4 **Ethylbenzene 0.1797 91-20-3 **Naphthalene 0.1797 108-88-3 **Toluene 0.079 71-43-2 **Benzene 0.079 The following Hazardous Chemicals are listed under the U.S. Clean Water Act, Section 311, Table 117.3: 1330-20-7 **Mixed Xylenes 3.9925 100-41-4 **Ethylbenzene 0.1797 91-20-3 **Naphthalene 0.1797 % 108-88-3 **Toluene 0.079 71-43-2 **Benzene 0.079 This product does not contain any toxic pollutants listed under the U.S. Clean Water Act Section 307 US State Regulations Massachusetts Right To Know 8052-41-3 Stoddard solvent 20 - 30 1330-20-7 **Mixed Xylenes 1 - 5 95-63-6 **1,2,4-tri methyl benzene 1 - 5 111-84-2 **Nonane 1 - 5 71-43-2 **Benzene 0 - 0.1 % Pennsylvania Right To Know 64742-47-8 Distillates (pet), hydrotreated light 0 - 90 64742-88-7 Solvent naphtha (pet), med aliph. 0 - 90 8052-41-3 Stoddard solvent 20 - 30 1330-20-7 **Mixed Xylenes 1 - 5 MSDS Number: 100000008536 25 / 28 Paint Thinner I STARTER`' Safety Data Sheet Paint Thinner Version 1.1 Revision Date: 04/15/2015 95-63-6 **1,2,4-trimethylbenzene 1 - 5 % 111-84-2 **Nonane 1 - 5 % 91-20-3 **Naphthalene 0 - 1 % 100-41-4 **Ethylbenzene 0 - 1 % 98-82-8 **Cumene 0 - 0.1 % 108-88-3 **Toluene 0 - 0.1 71-43-2 **Benzene 0 - 0.1 New Jersey Right To Know 64742-47-8 Distillates (pet), hydrotreated light 0 - 90 64742-88-7 Solvent naphtha (pet), med al!ph. 0 - 90 % 8052-41-3 Stoddard solvent 20 - 30 1330-20-7 **Mixed Xylenes 1 - 5 95-63-6 **1,2,4-tri methyl benzene 1 - 5 % 111-84-2 **Nonane 1 - 5 % 100-41-4 **Ethylbenzene 0.1 - 1 % 91-20-3 **Naphthalene 0.1 - 1 % California Prop 65 WARNING! This product contains a chemical known to the State of California to cause cancer. 100-41-4 Ethylbenzene 91-20-3 Naphthalene 98-82-8 **Cumene 71-43-2 **Benzene 100-41-4 **Ethylbenzene 91-20-3 **Naphthalene WARNING: This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. 108-88-3 **Toluene 71-43-2 **Benzene The components of this product are reported in the following inventories: United States TSCA Inventory y (positive listing) (On TSCA Invento- ry) Canadian Domestic Substances List (DSL) y (positive listing) (All components of this product are on the Canadian DSL.) Australia Inventory of Chemical Substances (AICS) y (positive listing) (On the inventory, or in compliance with the inventory) MSDS Number: 100000008536 26 / 28 Paint Thinner *STARTFT Safety Data Sheet Paint Thinner Version 1.1 Revision Date: 04/15/2015 Korea. Korean Existing Chemicals Inventory (KECI) y (positive listing) (On the inventory, or in compliance with the inventory) Philippines Inventory of Chemicals and Chemical y (positive listing) Substances (PICCS) (On the inventory, or in compliance with the inventory) China. Inventory of Existing Chemical Substances in y (positive listing) China (IECSC) (On the inventory, or in compliance with the inventory) Switzerland. New notified substances and declared y (positive listing) preparations (The formulation contains substances listed on the Swiss Inventory) SECTION 16. OTHER INFORMATION Further information NFPA: HMIS III: Flammability HEALTH 2* L � N d O Q FLAMMABILITY 2 = PHYSICAL HAZARD p 0 = not significant, 1 =Slight, Special hazard. 2 = Moderate, 3 = High 4 =Extreme, * = Chronic The information accumulated is based on the data of which we are aware and is believed to be correct as of the date hereof. Since this information may be ap- plied under conditions beyond our control and with which we may be unfamiliar and since data made become available subsequently to the date hereof, we do not assume any responsibility for the results of its use. Recipients are advised to confirm in advance of need that the information is current, applicable, and suita- MSDS Number: 100000008536 27 / 28 Paint Thinner 5TARTEX" Safety Data Sheet Paint Thinner Version 1.1 Revision Date: 04/15/2015 ble to their circumstances. This MSDS has been prepared by NEXEOT" Solutions EHS Product Safety Department (1-855-429-2661) MSDS @nexeosolutions.com. Material number: 16056385, 16056384 Kev or legend to abbreviations and acron ms used in the safety data sheet ACGIH American Conference of Gov- LD50 Lethal Dose 50% ernment Industrial H ienists AICS Australia, Inventory of Chem- LOAEL Lowest Observed Adverse Effect ical Substances Level DSL Canada, Domestic Substanc- NFPA National Fire Protection Agency es List NDSL Canada, Non-Domestic Sub- NIOSH National Institute for Occupational stances List Safety & Health CNS Central Nervous System NTP National Toxicology Program CAS Chemical Abstract Service NZIoC New Zealand Inventory of Chemicals EC50 Effective Concentration NOAEL No Observable Adverse Effect Level EC50 Effective Concentration 56% NOEC No Observed Effect Concentration EGEST EOSCA Generic Exposure OSHA Occupational Safety & Health Admin- Scenario Tool istration EOSCA European Oilfield Specialty PEL Permissible Exposure Limit Chemicals Association EINECS European Inventory of Exist- PICCS Philipines Inventory of Commercial ing Chemical Substances Chemical Substances MAK Germany Maximum Concen- PRNT Presumed Not Toxic tration Values GHS Globally Harmonized System RCRA Resource Conservation Recovery Act >= Greater Than or Equal To STEL Short-term Exposure Limit IC50 Inhibition Concentration 50% SARA Superfund Amendments and Reau- thorization Act. IARC International Agency for Re- TLV Threshold Limit Value search on Cancer IECSC Inventory of Existing Chemi- TWA Time Weighted Average cal Substances in China ENCS Japan, Inventory of Existing TSCA Toxic Substance Control Act and New Chemical Substanc- es KECI Korea, Existing Chemical In- UVCB Unknown or Variable Compositon, ventory Complex Reaction Products, and Biological Materials <= Less Than or Equal To WHMIS Workplace Hazardous Materials In- formation System 1_C50 Lethal Concentration 50% MSDS Number: 100000008536 28 / 28 Paint Thinner 5TARTEX Safety Data Sheet Startex Lacquer Thinner Version 1.5 Revision Date 05/19/2017 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name Startex Lacquer Thinner Manufacturer or supplier's details Company Nexeo Solutions LLC-STARTEXTM Address 3 Waterway Square Place Suite 1000 The Woodlands, TX. 77380 United States of America Emergency telephone number: Health North America: 1-855-NEXEO4U (1-855-639-3648) Health International: 1-855-NEXEO4U (1-855-639-3648) Transport North America: CHEMTREC (1-800-424-9300) Additional Information: Responsible Party: Product Safety Group E-Mail: msds @nexeosolutions.com SIDS Requests: 1-855-429-2661 SIDS Requests Fax: 1-281-500-2370 Website:www.nexeosolutions.com SECTION 2. HAZARDS IDENTIFICATION GHS Classification Flammable liquids Category 2 Acute toxicity(Inhalation) Category 4 Skin irritation Category 2 Eye irritation Category 2A Reproductive toxicity Category 2 Specific target organ toxicity Category 1 (Eyes, Central nervous system) -single exposure Specific target organ toxicity Category 3 (Central nervous system) - single exposure Specific target organ toxicity Category 2 (Central nervous system, Peripheral nervous sys- -repeated exposure tem) Specific target organ toxicity Category 2 (Auditory system, Eyes) -repeated exposure(Inhala- tion) Aspiration hazard Category 1 GHS Label element SDS Number: 100000007506 1 /18 Startex Lacquer Thinner *5TARTM Safety Data Sheet Startex Lacquer Thinner Version 1.5 Revision Date 05/19/2017 Hazard pictograms < > 4> < > F1 ! Signal word Danger Hazard statements H225 Highly flammable liquid and vapour. H304 May be fatal if swallowed and enters airways. H315 Causes skin irritation. H319 Causes serious eye irritation. H332 Harmful if inhaled. H336 May cause drowsiness or dizziness. H361 Suspected of damaging fertility or the unborn child. H370 Causes damage to organs. H373 May cause damage to organs through prolonged or re- peated exposure if inhaled. Precautionary statements Prevention: P201 Obtain special instructions before use. P202 Do not handle until all safety precautions have been read and understood. P210 Keep away from heat/sparks/open flames/hot surfaces. No smoking. P233 Keep container tightly closed. P240 Ground/bond container and receiving equipment. P241 Use explosion-proof electrical/ventilating/lighting/equip- ment. P242 Use only non-sparking tools. P243 Take precautionary measures against static discharge. P260 Do not breathe dust/fume/gas/mist/vapours/spray. P264 Wash skin thoroughly after handling. P270 Do not eat, drink or smoke when using this product. P271 Use only outdoors or in a well-ventilated area. P280 Wear protective gloves/protective clothing/eye protection/ face protection. Response: P301 + P310 IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. P303 + P361 + P353 IF ON SKIN (or hair): Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+ P340+ P312 IF INHALED: Remove person to fresh air and keep comfortable for breathing. Call a POISON CENTER or doctor/physician if you feel unwell. P305+P351 + P338 IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. P307 + P311 IF exposed: Call a POISON CENTER or doctor/ physician. P331 Do NOT induce vomiting. P332 + P313 If skin irritation occurs: Get medical advice/atten- tion. P337+ P313 If eye irritation persists: Get medical advice/atten- tion. SIDS Number: 100000007506 2118 Startex Lacquer Thinner ���STARTEX, Safety Data Sheet Startex Lacquer Thinner Version 1.5 Revision Date: 05/19/2017 P362 Take off contaminated clothing and wash before reuse. P370 + P378 In case of fire: Use dry sand, dry chemical or alco- hol-resistant foam to extinguish. Storage: P403+ P233 Store in a well-ventilated place. Keep container tightly closed. P403 + P235 Store in a well-ventilated place. Keep cool. P405 Store locked up. Disposal: P501 Dispose of contents/container to an approved waste dis- posal plant. Other hazards The following percentage of the mixture consists of ingredient(s)with unknown acute toxicity: 6.765% SECTION 3. COMPOSITION/INFORMATION ON INGREDIENTS Substance/Mixture Mixture Hazardous components CAS-No. Chemical Name Weight% 108-88-3 Toluene 30 -50 68410-97-9/ Distillates, pet, It dist hydrotreat process, low-boil 20 -30 64742-49-0/ AND/OR Naphtha(pet), hydrotreated It AND/OR 64742-89-8 Solvent naphtha (pet), It ali h. 67-64-1 Acetone 10 -20 142-82-5 **He tane 5 - 10 111-76-2 2-Butoxy ethanol 1 -5 67-56-1 Methanol 1 - 5 78-93-3 Meth I ethyl I ketone 1 -5 Any Concentration shown as a range is due to batch variation. SECTION 4. FIRST AID MEASURES General advice Move out of dangerous area. Consult a physician. Show this safety data sheet to the doctor in attendance. Symptoms of poisoning may appear several hours later. Do not leave the victim unattended. If inhaled Call a physician or poison control centre immediately. If unconscious place in recovery position and seek medical advice. In case of skin contact If skin irritation persists, call a physician. If on skin, rinse well with water. If on clothes, remove clothes. In case of eye contact Immediately flush eye(s)with plenty of water. Remove contact lenses. SDS Number: 100000007506 3/18 Startex Lacquer Thinner /1 STARTEX Safety Data Sheet Startex Lacquer Thinner Version 1.5 Revision Date: 05/19/2017 Protect unharmed eye. Keep eye wide open while rinsing. If eye irritation persists, consult a specialist. If swallowed Keep respiratory tract clear. Do NOT induce vomiting. Do not give milk or alcoholic beverages. Never give anything by mouth to an unconscious person. If symptoms persist, call a physician. Take victim immediately to hospital. SECTION 5. FIREFIGHTING MEASURES Suitable extinguishing media Alcohol-resistant foam Carbon dioxide (CO2) Dry chemical Unsuitable extinguishing High volume water jet media Specific hazards during fire- Do not allow run-off from fire fighting to enter drains or water fighting courses. Hazardous combustion prod- No hazardous combustion products are known ucts Specific extinguishing meth- Use a water spray to cool fully closed containers. ods Further information Collect contaminated fire extinguishing water separately. This must not be discharged into drains. Fire residues and contaminated fire extinguishing water must be disposed of in accordance with local regulations. For safety reasons in case of fire, cans should be stored sepa- rately in closed containments. Special protective equipment Wear self-contained breathing apparatus for firefighting if nec- for firefighters essary. Use personal protective equipment. SECTION 6. ACCIDENTAL RELEASE MEASURES Personal precautions, protec- : Use personal protective equipment. tive equipment and emer- Ensure adequate ventilation. gency procedures Remove all sources of ignition. Evacuate personnel to safe areas. Beware of vapours accumulating to form explosive concentra- tions.Vapours can accumulate in low areas. Environmental precautions Prevent product from entering drains. Prevent further leakage or spillage if safe to do so. SDS Number: 100000007506 4/18 Startex Lacquer Thinner 4�~STARTEX' Safety Data Sheet Startex Lacquer Thinner Version 1.5 Revision Date: 05/19/2017 If the product contaminates rivers and lakes or drains inform respective authorities. Methods and materials for Contain spillage, and then collect with non-combustible ab- containment and cleaning up sorbent material, (e.g, sand, earth, diatomaceous earth, ver- miculite) and place in container for disposal according to local /national regulations (see section 13). SECTION 7. HANDLING AND STORAGE Advice on protection against Do not spray on a naked flame or any incandescent material. fire and explosion Take necessary action to avoid static electricity discharge (which might cause ignition of organic vapours). Use only explosion-proof equipment. Keep away from open flames, hot surfaces and sources of ignition. Advice on safe handling Avoid formation of aerosol. Do not breathe vapours/dust. Avoid exposure- obtain special instructions before use. Avoid contact with skin and eyes. For personal protection see section 8. Smoking, eating and drinking should be prohibited in the ap- plication area. Take precautionary measures against static discharges. Provide sufficient air exchange and/or exhaust in work rooms. Container may be opened only under exhaust ventilation hood. Open drum carefully as content may be under pressure. Dispose of rinse water in accordance with local and national regulations. Conditions for safe storage Prevent unauthorized access. No smoking. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Observe label precautions. Electrical installations/working materials must comply with the technological safety standards. SECTION 8. EXPOSURE CONTROLS/PERSONAL PROTECTION Components with workplace control parameters CAS-No. Components Value type Control parame- Basis (Form of ters/Permissible exposure) concentration 108-88-3 Toluene TWA 20 ppm ACGIH TWA 100 ppm NIOSH REL 375 mg/m3 ST 150 ppm NIOSH REL SDS Number: 100000007506 5/18 Startex Lacquer Thinner J�'NTARTEX` Safety Data Sheet Startex Lacquer Thinner Version 1.5 Revision Date: 05/19/2017 r37 m /m3 TWA m OSHA Z-2 CEIL m OSHA Z-2 Peak m OSHA Z-2 TWA ppm OSHA PO m /m3 STEL ppm OSHA PO 560 m /m3 68410-97-9/ Distillates, pet, It disc hydrotreat TWA 500 ppm OSHA Z-1 64742-49-0/ process, low-boil AND/OR 2,000 mg/m3 64742-89-8 Naphtha (pet), hydrotreated It AND/OR Solvent naphtha (pet), It ali h. TWA 400 ppm OSHA PO 1,600 mg/m3 67-64-1 Acetone TWA 250 ppm ACGIH STEL 500 pprn ACGIH TWA 250 ppm NIOSH REL 590 mg/m3 TWA 1,000 ppm OSHA Z-1 2,400 m /m3 TWA 750 ppm OSHA PO 1,800 mg/m3 STEL 1,000 ppm OSHA PO 2,400 mg/m3 142-82-5 **Heptane TWA 85 ppm NIOSH REL 350 mg/m3 C 440 ppm NIOSH REL 1,800 mg/m3 TWA 500 ppm OSHA Z-1 2,000 mg/m3 TWA 400 ppm OSHA PO 1,600 mg/m3 STEL 500 ppm OSHA PO 2,000 mg/m3 TWA 400 pprn ACGIH STEL 500 ppm ACGIH 111-76-2 2-Butoxy ethanol TWA 20 opm ACGIH TWA 5 ppm NIOSH REL 24 mg/m3 TWA 50 ppm OSHA Z-1 240 m2/m3 TWA 25 ppm OSHA PO 120 mg/m3 67-56-1 Methanol TWA 200 ppm ACGIH STEL 250 pprn ACGIH TWA 200 ppm NIOSH REL 260 mg/m3 ST 250 ppm NIOSH REL 1325 mg/m3 TWA 200 ppm OSHA Z-1 260 mg/m3 STEL 250 oDrn OSHA PO SDS Number: 100000007506 6118 Startex Lacquer Thinner 5 STARTEX` Safety Data Sheet Startex Lacquer Thinner Version 1.5 Revision Date: 05/19/2017 325 mg/m3 TWA 200 ppm OSHA PO 1260 mg/m3 78-93-3 Methyl ethyl ketone TWA 200 plorn ACGIH STEL 300 ppm ACGIH TWA 200 ppm NIOSH REL 590 mg/m3 ST 300 ppm NIOSH REL 885 mg/m3 TWA 200 ppm OSHA Z-1 590 mg/m3 TWA 200 ppm OSHA PO 590 mg/m3 STEL 300 ppm OSHA PO 885 mg/m3 Personal protective equipment Hand protection Remarks The suitability for a specific workplace should be discussed with the producers of the protective gloves. Eye protection Eye wash bottle with pure water Tightly fitting safety goggles Wear face-shield and protective suit for abnormal processing problems. Skin and body protection Impervious clothing Choose body protection according to the amount and concen- tration of the dangerous substance at the work place. Hygiene measures Avoid contact with skin, eyes and clothing. When using do not eat or drink. When using do not smoke. Wash hands before breaks and immediately after handling the product. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES Appearance liquid Colour Clear, Colorless Odour solvent-like Odour Threshold No data available pH No data available Freezing Point No data available Boiling Point(Boiling 56- 172 °C (133-342 °F) SDS Number: 100000007506 7118 Startex Lacquer Thinner *"TARTEV Safety Data Sheet Startex Lacquer Thinner Version 1.5 Revision Date: 05/19/2017 point/boiling range) Flash point -16°C (3 °F) Method: Tag closed cup Evaporation rate 1.4 (Butyl Acetate= 1) Flammability(solid, gas) No data available Upper explosion limit No data available Lower explosion limit 1.8 %(V) Vapour pressure 1.1589 PSI @ 20 °C (68 °F) Relative vapour density 2.7(Air= 1.0) Relative density 0.817 @ 20-25 °C (68-77 °F) Reference substance: (water= 1) Density No data available Water solubility No data available Solubility in other solvents No data available Partition coefficient: n- No data available octanol/water Auto-ignition temperature 290 °C Thermal decomposition No data available VOC 80.4%/ 657.12 g/I / 5.45 lb/gal Non VOC 19.6% / 160.09 g/I / 1.34 lb/gal VOC Vapor Pressure 0.9319 PSI @ 20°C (68 °F) Hazardous Air Pollutants 51.5% / 338.22 g/I / 2.82 lb/gal (NAPS) SECTION 10. STABILITY AND REACTIVITY Reactivity No dangerous reaction known under conditions of normal use. Chemical stability Stable under normal conditions. Possibility of hazardous reac- No hazards to be specially mentioned. tions Conditions to avoid Keep away from heat,flame,sparks and other ignition sources. SIDS Number: 100000007506 8118 Startex Lacquer Thinner "Vj'STARTEY Safety Data Sheet Startex Lacquer Thinner Version 1.5 Revision Date: 05/19/2017 Incompatible materials Strong oxidizing agents SECTION 11. TOXICOLOGICAL INFORMATION Acute toxicity Product: Acute oral toxicity Acute toxicity estimate: 2,504 mg/kg Acute inhalation toxicity Acute toxicity estimate: 2641 ppm Exposure time: 4 h Test atmosphere: gas Acute dermal toxicity Acute toxicity estimate: > 5,000 mg/kg Components: 111-76-2: Acute oral toxicity LD50(Rat): 745 mg/kg Assessment: The component/mixture is moderately toxic after single ingestion. 67-56-1: Acute oral toxicity LDLo (Humans): 143 mg/kg Assessment: The component/mixture is toxic after single in- gestion. Acute inhalation toxicity Assessment: The component/mixture is toxic after short term inhalation. Remarks: Supporting toxicological evidence is limited for this classification. This harmonized classification will replace the indicated classification due to industry leaders and the EU Harmonized Classification (Annex VII). Acute dermal toxicity LDLo (Monkey): 393 mg/kg Assessment: The component/mixture is toxic after single con- tact with skin. Skin corrosion/irritation Components: 108-88-3: Species: Rabbit Exposure time: 4 h Result: Irritating to skin. 68410-97-9/64742-49-0/64742-89-8: Species: Rabbit Exposure time: 4 h Result: Irritating to skin. SIDS Number: 100000007506 9/18 Startex Lacquer Thinner STARTER` Safety Data Sheet Startex Lacquer Thinner Version 1.5 Revision Date: 05/19/2017 Serious eye damage/eye irritation Components- 108-88-3: Species: Rabbit Result: Irritating to eyes. 67-64-1: Species: Rabbit Result: Irritating to eyes. Exposure time: 24 h 111-76-2: Species: Rabbit Result: Irritating to eyes. 78-93.3: Species: Rabbit Result: Irritating to eyes. Exposure time: 24 h Germ cell mutagenicity Components: 108-88-3: Germ cell mutagenicity- Tests on bacterial or mammalian cell cultures did not show Assessment mutagenic effects. 68410-97-9/64742-49-0/64742.89-8: Germ cell mutagenicity- Mutagenicity classification not possible from current data Assessment Carcinogenicity Components: 108-88.3: Carcinogenicity-Assess- No evidence of carcinogenicity in animal studies. ment 68410-97-9/64742-49-0/64742-89-8: Carcinogenicity-Assess- Not classifiable as a human carcinogen. ment IARC No component of this product present at levels greater than or equal to 0.1% is identified as probable, possible or confirmed human carcinogen by]ARC. OSHA No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino- gen by OSHA. NTP No component of this product present at levels greater than or SDS Number: 100000007506 10118 Startex Lacquer Thinner ?� STARTER Safety Data Sheet Startex Lacquer Thinner Version 1.5 Revision Date 05/19/2017 equal to 0.1% is identified as a known or anticipated carcinogen by NTP. ACGIH No component of this product present at levels greater than or equal to 0.1% is identified as a carcinogen or potential carcino- gen by ACGIH. Reproductive toxicity Components: 108-88-3: Effects on foetal develop- Species: Rat ment Application Route: inhalation (vapour) Dose: 0, 250, 750, 1500, 3000 ppm Duration of Single Treatment: 10 d Frequency of Treatment: 6 hr/day General Toxicity Maternal: NOAEC: 750 ppm Developmental Toxicity: NOAEC: 750 ppm Symptoms: Maternal toxicity, Reduced body weight, Skeletal malformations Teratogenicity-Assessment Some evidence of adverse effects on development, based on animal experiments. Reproductive toxicity-As- No toxicity to reproduction sessment 68410-97-9/64742-49-0/64742-89-8: Reproductive toxicity-As- Some evidence of adverse effects on sexual function and sessment fertility, based on animal experiments. Teratogenicity-Assessment Embryotoxicity classification not possible from current data. STOT-single exposure Components: 108-88-3: Exposure routes: Inhalation Target Organs: Central nervous system Assessment: May cause drowsiness or dizziness., The substance or mixture is classified as specific target organ toxicant, single exposure, category 3 with narcotic effects. 68410-97-9/64742-49-0/64742-89-8: Target Organs: Central nervous system Assessment:The substance or mixture is classified as specific target organ toxicant, single ex- posure, category 3 with narcotic effects. 67-64-1: Exposure routes: Inhalation Target Organs: Central nervous system SDS Number: 100000007506 11 /18 Startex Lacquer Thinner 5TARTEX' Safety Data Sheet Startex Lacquer Thinner Version 1.5 Revision Date: 05/19/2017 Assessment: May cause drowsiness or dizziness., The substance or mixture is classified as specific target organ toxicant, single exposure, category 3 with narcotic effects. 67-56-1: Target Organs: Eyes, Central nervous system Assessment: The substance or mixture is classified as specific target organ toxicant, single ex- posure, category 1. 78-93-3: Target Organs: Central nervous system Assessment: The substance or mixture is classified as specific target organ toxicant, single ex- posure, category 3 with narcotic effects. STOT -repeated exposure Components: 108-88-3: Exposure routes: Inhalation Target Organs:Auditory system, Eyes Assessment: May cause damage to organs through prolonged or repeated exposure., The sub- stance or mixture is classified as specific target organ toxicant, repeated exposure, category 2. Aspiration toxicity Components: 108-88-3: May be fatal if swallowed and enters airways. 68410.97-9/64742.49-0 164742-89-8: May be fatal if swallowed and enters airways. Further information Product: Remarks: Symptoms of overexposure may be headache, dizziness,tiredness, nausea and vom- iting. Concentrations substantially above the TLV value may cause narcotic effects. Solvents may degrease the skin. SECTION 12. ECOLOGICAL INFORMATION Ecotoxicity Components: 108-88-3: Toxicity to fish LC50(Oncorhynchus mykiss (rainbow trout)): 5.5 mg/I Exposure time: 96 h Test Type: flow-through test Toxicity to daphnia and other LC50(Ceriodaphnia dubia): 3.78 mg/I SDS Number: 100000007506 12/18 Startex Lacquer Thinner STARTER' Safety Data Sheet Startex Lacquer Thinner Version 1.5 Revision Date: 05/19/2017 aquatic invertebrates Exposure time: 48 h Test Type: Renewal Toxicity to daphnia and other NOEC: 0.74 mg/I aquatic invertebrates (Chron- Exposure time: 7 d is toxicity) Acute aquatic toxicity-As- Toxic to aquatic life. sessment Chronic aquatic toxicity-As- Harmful to aquatic life with long lasting effects. sessment 68410-97-9/64742-49-0/64742-89-8: Toxicity to fish LC50(Oncorhynchus mykiss (rainbow trout)): 10 mg/I Exposure time: 96 h LC50(Oncorhynchus mykiss (rainbow trout)): 8.2 mg/I Exposure time: 96 h Test Type: semi-static test LC50(Pimephales promelas (fathead minnow)): 8.2 mg/I Exposure time: 96 h Toxicity to daphnia and other EC50(Daphnia magna (Water flea)): 4.5 mg/I aquatic invertebrates Exposure time:48 h Test Type: Immobilization Toxicity to algae EC50(Pseudokirchneriella subcapitata (green algae)): 3.1 mg/I Exposure time: 72 h EC50(Pseudokirchneriella subcapitata (green algae)): 3.7 mg/I Exposure time: 96 h Test Type: static test Toxicity to fish (Chronic tox- NOELR (Pimephales promelas (fathead minnow)): 2.6 mg/I icity) Exposure time: 14 d Toxicity to daphnia and other NOELR (Daphnia magna(Water flea)): 2.6 mg/I aquatic invertebrates (Chron- Exposure time: 21 d is toxicity) Chronic aquatic toxicity-As- Toxic to aquatic life with long lasting effects. sessment Persistence and degradability No data available Bioaccumulative potential Components: 108-88-3: Partition coefficient: n- log Pow:2.73(20 °C) SDS Number: 100000007506 13/18 Startex Lacquer Thinner STARTER Safety Data Sheet Startex Lacquer Thinner Version 1.5 Revision Date: 05/19/2017 octanol/water pH: 7 68410-97-9164742-49-0/64742-89-8: Partition coefficient: n- log Pow:2.13-4.85(25 °C) octanol/water Mobility in soil No data available Other adverse effects Product: Ozone-Depletion Potential Regulation:40 CFR Protection of Environment; Part 82 Pro- tection of Stratospheric Ozone- CAA Section 602 Class I Substances Remarks: This product neither contains, nor was manufac- tured with a Class I or Class II ODS as defined by the U.S. Clean Air Act Section 602 (40 CFR 82, Subpt. A,App.A+ B). Additional ecological infor- An environmental hazard cannot be excluded in the event of mation unprofessional handling or disposal. Toxic to aquatic life with long lasting effects. SECTION 13. DISPOSAL CONSIDERATIONS Disposal methods Waste from residues Dispose of in accordance with all applicable local, state and federal regulations. For assistance with your waste management needs-including disposal, recycling and waste stream reduction, contact NEXEO's Environmental Services Group at 800-637-7922. Dispose of in accordance with all applicable local, state and federal regulations. For assistance with your waste management needs-including disposal, recycling and waste stream reduction, contact NEXEO's Environmental Services Group at 800-637-7922. Contaminated packaging Empty remaining contents. Dispose of as unused product. Do not re-use empty containers. Do not burn, or use a cutting torch on,the empty drum. SECTION 14. TRANSPORT INFORMATION DOT(Department of Transportation): UN1263, PAINT RELATED MATERIAL, 3, II SDS Number: 100000007506 14/18 Startex Lacquer Thinner 1X STARTEY Safety Data Sheet Startex Lacquer Thinner Version 1.5 Revision Date: 05/19/2017 IATA(International Air Transport Association): UN1263, PAINT RELATED MATERIAL, 3, II IMDG(International Maritime Dangerous Goods): UN1263, PAINT RELATED MATERIAL, 3, Il, Marine Pollutant(TOLUENE, MIXTURE OF PETROLEUM DISTILLATES) , Flash Point:-16 °C(3 °F) SECTION 15. REGULATORY INFORMATION WHMIS Classification B2: Flammable liquid D1A: Very Toxic Material Causing Immediate and Serious Toxic Effects D1B: Toxic Material Causing Immediate and Serious Toxic Effects D2A: Very Toxic Material Causing Other Toxic Effects D213: Toxic Material Causing Other Toxic Effects EPCRA-Emergency Planning and Community Right-to-Know Act CERCLA Reportable Quantity Components CAS-No. Component RQ Calculated product RQ Ibs Ibs Toluene 1 108-88-3 1 1000 2081 SARA 304 Extremely Hazardous Substances Reportable Quantity This material does not contain any components with a section 304 EHS RC. SARA 311/312 Hazards Fire Hazard Immediate (Acute) Health Hazard Chronic(Delayed) Health Hazard SARA 302 No chemicals in this material are subject to the reporting re- quirements of SARA Title III, Section 302. SARA 313 The following components are subject to reporting levels es- tablished by SARA Title III, Section 313: 108-88-3 Toluene 111-76-2 2-Butoxy ethanol 67-56-1 Methanol Clean Air Act The following chemical(s) are listed as HAP under the U.S. Clean Air Act, Section 12 (40 CFR 61): 108-88-3 Toluene 67-56-1 Methanol This product does not contain any chemicals listed under the U.S. Clean Air Act Section 112(r)for Accidental Release Prevention (40 CFR 68.130, Subpart F). The following chemical(s) are listed under the U.S. Clean Air Act Section 111 SOCMI Intermediate or Final VOC's(40 CFR 60.489): 108-88-3 Toluene 67-64-1 Acetone SDS Number: 100000007506 16/18 Startex Lacquer Thinner STARTER` Safety Data Sheet Startex Lacquer Thinner Version 1.5 Revision Date: 05/19/2017 111-76-2 2-Butoxy ethanol 67-56-1 Methanol 78-93-3 Methyl ethyl ketone Clean Water Act The following Hazardous Substances are listed under the U.S. CleanWater Act, Section 311, Table 116AA: 108-88-3 Toluene 110-82-7 **Cyclohexane 100-41-4 Ethylbenzene 71-43-2 Benzene The following Hazardous Chemicals are listed under the U.S. CleanWater Act, Section 311, Table 117.3: 108-88-3 Toluene 110-82-7 **Cyclohexane 100-41-4 Ethylbenzene 71-43-2 Benzene This product contains the following toxic pollutants listed under the U.S. Clean Water Act Section 307 108-88-3 Toluene US State Regulations Massachusetts Right To Know 108-88-3 Toluene 30-50% 67-64-1 Acetone 10-20 % 142-82-5 **Heptane 5- 10 % 111-76-2 2-Butoxy ethanol 1 _ 5% 67-56-1 Methanol 1 -5 % 78-93-3 Methyl ethyl ketone 1 _5% 71-43-2 Benzene 0- 0.1 % Pennsylvania Right To Know 108-88-3 Toluene 30-50% 68410-97-9/ Distillates, pet, It dist hydrotreat process, 20-30 % 64742-49-0/ low-boil AND/OR Naphtha(pet), hy- 64742-89-8 drotreated It AND/OR Solvent naphtha (pet), It aliph. 67-64-1 Acetone 10-20% 142-82-5 **Heptane 5- 10% 111-76-2 2-Butoxy ethanol 1 -5% 67-56-1 Methanol 1 _ 5% 78-93-3 Methyl ethyl ketone 1 - 5% 110-82-7 **Cyclohexane 0.1 - 1 % 71-43-2 Benzene 0-0.1 % 100-41-4 Ethylbenzene 0- 0.1 % New Jersey Right To Know 108-88-3 Toluene 30- 50% 68410-97-9/ Distillates, pet, It dist hydrotreat process, 20- 30% 64742-49-0/ low-boil AND/OR Naphtha (pet), hy- 64742-89-8 drotreated It AND/OR Solvent naphtha (pet), It aliph. 67-64-1 Acetone 10-20 % 142-82-5 **Heptane 5- 10% 111-76-2 2-Butoxy ethanol 1 -5 % SIDS Number: 100000007506 16118 Startex Lacquer Thinner *5TARTEV Safety Data Sheet Startex Lacquer Thinner Version 1.5 Revision Date: 05/19/2017 67-56-1 Methanol 1 -5 % 78-93-3 Methyl ethyl ketone 1 -5% California Prop 65 WARNING!This product contains a chemical known to the State of California to cause cancer. 100-41-4 Ethylbenzene 71-43-2 Benzene 98-82-8 Cumene WARNING! This product contains a chemical known to the State of California to cause birth defects or other reproductive harm. 108-88-3 Toluene 67-56-1 Methanol 71-43-2 Benzene The components of this product are reported in the following inventories: TSCA On TSCA Inventory DSL All components of this product are on the Canadian DSL AICS On the inventory, or in compliance with the inventory NZIoC On the inventory, or in compliance with the inventory ENCS Not in compliance with the inventory KECI On the inventory, or in compliance with the inventory PICCS On the inventory, or in compliance with the inventory IECSC On the inventory, or in compliance with the inventory SECTION16. OTHER INFORMATION NFPA: HMIS III: Flammability HEALTH 2" r � 0 FLAMMABILITY 3 PHYSICAL HAZARD 0 0=not significant, 1 =Slight, Special hazard. 2=Moderate,3=High 4=Extreme, `=Chronic The information accumulated is based on the data of which we are aware and is believed to be correct as of the date hereof. Since this information may be applied under conditions beyond our control and with SDS Number: 100000007506 17118 Startex Lacquer Thinner STARTEX 11 Safety Data Sheet Startex Lacquer Thinner ,- Version 1.5 Revision Date: 05/19/2017 which we may be unfamiliar and since data made become available subsequently to the date hereof, we do not assume any responsibility for the results of its use. Recipients are advised to confirm in advance of need that the information is current, applicable, and suitable to their circumstances. This MSDS has been prepared by NEXEOTM Solutions EHS Product Safety Department(1-855-429-2661) MSDS@ nexeosol uti o n s.com. Revision Date 05/19/2017 Material number: 16067620, 16067619, 16067618, 16067617, 16067616, 16067615, 16057350, 16057349, 16057347, 16057346, 16057345, 16057344, 16057343 Key or leg end to abbreviations and acron ms used in the safe data sheet ACGIH American Conference of Gov- LD50 Lethal Dose 50% ernment Industrial Hygienists AICS Australia, Inventory of Chemical LOAEL Lowest Observed Adverse Effect Level Substances DSL Canada, Domestic Substances NFPA National Fire Protection Agency List NDSL Canada, Non-Domestic Sub- NIOSH National Institute for Occupational Safety stances List & Health CNS Central Nervous System NTP National Toxicology Program CAS I Chemical Abstract Service NZIoC New Zealand Inventory of Chemicals EC50 Effective Concentration NOAEL No Observable Adverse Effect Level EC50 Effective Concentration 50% NOEC No Observed Effect Concentration EGEST EOSCA Generic Exposure Sce- OSHA Occupational Safety& Health Administra- nario Tool tion EOSCA European Oilfield Specialty PEL Permissible Exposure Limit Chemicals Association EINECS European Inventory of Existing PICCS Philippines Inventory of Commercial Chemical Substances Chemical Substances MAK Germany Maximum Concentra- PRNT Presumed Not Toxic tion Values GHS Globally Harmonized System RCRA Resource Conservation Recovery Act >= Greater Than or E ual To STEL Short-term Exposure Limit IC50 Inhibition Concentration 50% SARA Superfund Amendments and Reauthori- zation Act. ARC International Agency for Research TLV Threshold Limit Value on Cancer IECSC Inventory of Existing Chemical TWA Time Weighted Average Substances in China ENCS Japan, Inventory of Existing and _TSCA Toxic Substance Control Act New Chemical Substances KECI Korea, Existing Chemical Invento- UVCB Unknown or Variable Composition, Com- ry plex Reaction Products, and Biological Materials <= Less Than or Equal To WHMIS Workplace Hazardous Materials Infor- mation System LC50 Lethal Concentration 50% SDS Number: 100000007506 18/18 Startex Lacquer Thinner