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HomeMy WebLinkAboutCO2019-0201 Material Safety Data Sheet Chemetall Oakite Ardroxe 188 Version 1.2 Print Date 01/12/2007 Revision Date 11/2312006 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name Ardroe 188 MSDS Number REL 200166 Company OAKITE PRODUCTS INC 675 Central Avenue New Providence, NJ 07974 Telephone +18005264473 Telefax +19084644658 Emergency telephone no CHEMTREC-800-424-9300 SECTION 2. HAZARDOUS COMPONENTS INFORMATION Component CAS-No. Weight% Potassium permanganate 7722-64-7 35.00-40.00 SODIUM HYDROXIDE 1310-73-2 60.00 -65.00 Unidentified ingredients are considered not hazardous under Federal Hazard Communication Standard (29CFR 1910.1200). SECTION 3. HAZARDS IDENTIFICATION Emergency Overview Form powder Colour white Odour none Hazard Summary Strong Oxidant!Causes severe burns.Harmful by inhalation and if swallowed. Route(s) of Entry Inhalation Skin Ingestion yes yes yes Carcinogenicity: NTP No substance in this product is listed by NTP as a carcinogen IARC No substance in this product is listed by IARC as a carcinogen OSHA No substance in this product is regulated by OSHA as a carcinogen SECTION 4. FIRST AID MEASURES Inhalation Remove to fresh air If symptoms persist, call a physician N.D. -Not Determined 1/5 N.A. -Not AoDlicable Material Safety Data Sheet Chemetall Oakite Ardrox® 188 Version 1.2 Print Date 01/12/2007 Revision Date 11/23/2006 Skin contact Wash off immediately with plenty of water for at least 15 minuteslf skin irritation persists, call a physician. Eye contact Rinse immediately with plenty of water for at least 15 minutesKeep eye wide open while rinsingSeek medical advice. Ingestion Rinse mouthDrink plenty of water.Get medical attention immediately SECTION 5. FIRE-FIGHTING MEASURES Flash point Note: does not flash Lower explosion limit Note: not applicable Upper explosion limit Note: not applicable TDG Flammability Class NONE Suitable extinguishing Use extinguishing measures that are appropriate to local media circumstances and the surrounding environment. Special protective Wear self contained breathing apparatus for fire fighting if equipment for fire-fighters necessary. SECTION 6.ACCIDENTAL RELEASE MEASURES Personal precautions Use personal protective equipment. Ventilate the area. Methods for cleaning up Contain and collect spillage with non-combustible absorbent material, (e.g. sand, earth, diatomaceus earth, vermiculite) and place in container for disposal according to local/national regulations (see section 13). Keep in suitable, closed containers for disposal. Additional advice Never return spills in original containers for re-use. SECTION 7. HANDLING AND STORAGE Handling Handling Add this product to surface of solution slowly to avoid spattering Do not add large amounts of product to solution at any one time. N.D. - Not Determined 2/5 N.A. -Not AmAcable Material Safety Data Sheet Chemetall Oakite Ardrox® 188 Version 1.2 Print Date 01/12/2007 Revision Date 11/23/2006 Do not add to hot water warmer than 43 degrees to 49 degrees C (110 degrees to 120 degrees F). Never add liquids to product Storage Requirements for storage Keep containers tightly closed to avoid contamination areas and containers Store indoors in a cool,well-ventilated place Protect from direct contact with water or excessive moisture. Keep container out of sun and away from heat. SECTION 8. EXPOSURE CONTROLS I PERSONAL PROTECTION Component ACGIH OSHA TLV PEL TWA TWA Potassium permanganate N.D. N.D. SODIUM HYDROXIDE 2 mg/m3 2 mg/m3 ceilin N.D. N.D. Eye protection face-shield Chemical resistant goggles must be worn. Hand protection impervious gloves Skin and body protection apron Respiratory protection Respiratorwith combination filter for vapour/particulate. Hygiene measures Avoid contact with skin, eyes and clothing Wear suitable gloves and eye/face protection Wear suitable protective clothing Wash hands before breaks and immediately after handling the product Provide adequate ventilation Avoid breathing dust or vapor. Keep away from food and drink SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES pH 13 at 120 g/INote: +/-0.5 Melting point/range Note: not applicable Boiling point/range Note: not applicable Vapour pressure Note: no data available N.D. - Not Determined 3/5 N.A. - Not Applicable Material Safety Data Sheet Chemetall Oakite Ardroxe 188 , Version 1.2 Print Date 01/12/2007 Revision Date 11/23/2006 Bulk density Note: no data available Water solubility Note: completely soluble Partition coefficient(n- octanol/water) Note: no data available Percent of Volatile by Weight 0 excluding water Relative density Note: no data available Evaporation rate Note: (Water=1) Less than 1 SECTION 10. STABILITY AND REACTIVITY Conditions to avoid Heat, flames and sparks. Exposure to moisture Materials to avoid reducing agents organic materials combustible material acids, Hazardous decomposition sodium oxides products Hydrogen when reacts with certain metal. SECTION 11. TOXICOLOGICAL INFORMATION Toxicity: Mixture; Not Determined. Acute oral toxicity Potassium permanganate LD50, rat Dose: 1,090 mg/kg SECTION 12. ECOLOGICAL INFORMATION Not Available SECTION 13. DISPOSAL CONSIDERATIONS Advice on Disposal Refer to applicable local, state and federal regulations as well as industry standards. N.D. -Not Determined 4/5 N.A. - Not Applicable Material Safety Data Sheet Chemetall Oakite Ardrox® 188 Version 1.2 Print Date 01/1212007 Revision Date 11/23/2006 SECTION 14. TRANSPORT INFORMATION Refer to Bill of Lading. SECTION 15, REGULATORY INFORMATION TSCA Status All components of this material are on the US TSCA Inventory. SARA 313 Components N.D. CERCLA Reportable Quantity Potassium 100 Pounds permanganate SODIUM HYDROXIDE 1,000 Pounds California Prop. 65 N.D NFPA 3 0 3 HMIS 3 0 3 J WHMIS D213: Toxic Material Causing Other Toxic Effects E: Corrosive Material C: Oxidizing Material SECTION 16.OTHER INFORMATION Further information Oakite Products, Inc. warrants that the products described herein will conform with its published specifications. The products supplied by Oakite and information related to them are intended for use by buyers having necessary industrial skill and knowledge. Buyers should undertake sufficient verification and testing to determine the suitability of the Oakite materials for their own particular purpose. Since buyer's conditions of use of products are beyond Oakite's control, Oakite does not warrant any recommendations and information for the use of such products. OAKITE DISCLAIMS ALL OTHER WARRANTIES INCLUDING THE IMPLIED WARRANTY OF MERCHANTABILITY AND FITNESS FOR ANY PARTICULAR PURPOSE IN CONNECTION WITH THE USE OF ITS PRODUCTS. N.D - Not Determined 5/5 N.A. - Not Applicable Material Safety Data Sheet Chemetall ARDROXO 185 Version 1.6 Print Date 10/10/201 Revision Date 07113/2010 SECTION 1. PRODUCT AND COMPANY IDENTIFICATION Product name ARDROX® 185 MSDS Number REL 200155 Company Chemetall US, Inc. 675 Central Avenue New Providence, NJ 07974 Telephone +18005264473 Telefax +19084644658 Emergency telephone no CHEMTREC-800-424-9300 SECTION 2. HAZARDOUS COMPONENTS INFORMATION Component CAS-No. Weight percent Sodium Hydroxide 1310-73-2 50.00-55.00 Unidentified ingredients are considered not hazardous under Federal Hazard Communication Standard (29CFR 1910.1200). SECTION 3. HAZARDS IDENTIFICATION Emergency Overview Form powder Colour white Odour none Hazard Summary Causes severe burns.Harmful by inhalation and if swallowed. Route(s)of Entry Inhalation Skin Ingestion yes yes yes Carcinogenicity: NTP No substance in this product is listed by NTP as a carcinogen IARC No substance in this product is listed by IARC as a carcinogen OSHA No substance in this product is regulated by OSHA as a carcinogen SECTION 4. FIRST AID MEASURES Inhalation Remove to fresh air. If symptoms persist, call a physician. If breathing is irregular or stopped, administer artificial respiration. Skin contact Wash off immediately with plenty of water for at least 15 minutes.Take off contaminated clothing and shoes N.D. - Not Determined 1/5 N.A. -Not Applicable Material Safety Data Sheet Chemetall ARDROX° 185 Version 1.6 Print Date 10110/201 Revision Date 07/13/2010 immediately.Get medical attention immediately if irritation develops and persists Eye contact Rinse immediately with plenty of water for at least 15 minutes.Keep eye wide open while rinsing.Get medical attention immediately Ingestion Rinse mouth.Drink plenty of water.Never give anything by mouth to an unconscious person.Get medical attention immediately SECTION 5. FIRE-FIGHTING MEASURES Flash point Note: does not flash Lower explosion limit Note: not applicable Upper explosion limit Note: not applicable TDG Flammability Class NONE Suitable extinguishing Use extinguishing measures that are appropriate to local media circumstances and the surrounding environment. Special protective Wear self contained breathing apparatus for fire fighting if equipment for fire-fighters necessary. SECTION 6.ACCIDENTAL RELEASE MEASURES Personal precautions Use personal protective equipment. Ventilate the area. Methods for cleaning up Ventilate area. Clean up with inert absorbant material. Keep in suitable, closed containers for disposal. Flush with plenty of water. Additional advice Never return spills in original containers for re-use. SECTION 7. HANDLING AND STORAGE Handling Handling Add this product to surface of solution slowly to avoid spattering Do not add large amounts of product to solution at any one N.D. -Not Determined 2/5 N.A. -Not A licable Material Safety Data Sheet Chemetall ARDRO)& 185 Version 1.6 Print Date 10/10/201 Revision Date 07/13/2010 time. Do not add to hot water warmer than 43 degrees to 49 degrees C (110 degrees to 120 degrees F). Never add liquids to product Storage Requirements for storage Keep containers dry and tightly closed to avoid moisture areas and containers absorption and contamination. Store indoors in a cool, well-ventilated place Protect from direct contact with water or excessive moisture. SECTION 8. EXPOSURE CONTROLSiPERSONAL PROTECTION Component ACGIH OSHA TLV PEL TWA TWA Sodium Hydroxide 2 mg/m3 2 mg/m3 ceilin N.D. N.D. Eye protection Safety glasses with side-shields Face-shield Hand protection Impervious gloves Skin and body protection Apron Respiratory protection If the occupational exposure limits cannot be met, in exceptional cases suitable respiratory equipment should be worn only for a short period of time. Hygiene measures Avoid contact with skin, eyes and clothing. Wear suitable gloves and eye/face protection. Wear suitable protective clothing. Wash hands before breaks and immediately after handling the product. Provide adequate ventilation. Avoid breathing dust or vapor. Keep away from food and drink. SECTION 9. PHYSICAL AND CHEMICAL PROPERTIES pH > 13 Melting point/range Note: not applicable Boiling point/boiling range Note: not applicable Vapour pressure Note: no data available N.D. - Not Determined 3/5 N.A. - Not Applicable Material Safety Data Sheet Chemetall ARDROX° 185 Version 1.6 Print Date 10/10/201 Revision Date 07/13/2010 Bulk density 5.80 lb/gal Water solubility Note: completely soluble Partition coefficient: n- octanol/water Note: no data available Percent of Volatile by Weight Note: no data available excluding water Relative density 0.70 Evaporation rate Note: (Water=1) Less than 1 SECTION 10. STABILITY AND REACTIVITY Conditions to avoid Exposure to moisture. Materials to avoid Acids Hazardous decomposition Carbon oxides products Hydrogen when reacts with certain metal. SECTION 11.TOXICOLOGICAL INFORMATION Toxicity: Mixture; Not Determined. Acute oral toxicity Sodium Hydroxide LDIo, rabbit Dose: 500 mg/kg SECTION 12. ECOLOGICAL INFORMATION Not Available SECTION 13. DISPOSAL CONSIDERATIONS Advice on Disposal Refer to all federal, provincial,state and local regulation prior to disposition of container and unused contents by reuse, recycle or disposal. N.D. - Not Determined 4/5 N.A. - Not A licable Material Safety Data Sheet ChemeMll ARDROX° 185 Version 1.6 Print Date 10/10/201 Revision Date 07/1312010 SECTION 14. TRANSPORT INFORMATION Refer to Bill of Lading. SECTION 15. REGULATORY INFORMATION TSCA Status All components of this material comply with US TSCA requirements. SARA 313 Components N.D. CERCLA Reportable Quantity Sodium Hydroxide 1,000 Pounds California Prop. 65 N.D NFPA 3 0 1 Corrosive Alkaline HMIS 3 0 1 J WHMIS E: Corrosive Material D2B: Toxic Material Causing Other Toxic Effects SECTION 16.OTHER INFORMATION Further information Chemetall US,Inc.warrants that the products described herein will conform with its published specifications. The products supplied by Chemetall and information related to them are intended for use by buyers having necessary industrial skill and knowledge.Buyers should undertake sufficient verification and testing to determine the suitability of the Chemetall materials for their own particular purpose. Since buyer's conditions of use of products are beyond Chemetall's control,Chemetall does not warrant any recommendations and information for the use of such products. CHEMETALL DISCLAIMS ALL OTHER WARRANTIES INCLUDING THE IMPLIED WARRANTY OF MERCHANTABILITY AND FITNESS FOR ANY PARTICULAR PURPOSE IN CONNECTION WITH THE USE OF ITS PRODUCTS. N.D. - Not Determined 5/5 N.A. -Not Applicable L �? SAFETY DATA SHEET 1. Identification Product identifier LPS®HDX(Aerosol) Other means of identification Part Number 01020 Recommended use A degreaser designed to remove grease, oil,dirt and other residues from metal and other hard surfaces near ignition sources. Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Manufacturer Manufacturer Company name ITW Pro Brands Address 4647 Hugh Howell Rd. Tucker, GA 30084 Country (U.S.A.) Tel:+1 770-243-8800 In Case of Emergency 1-800-424-9300 (inside U.S.) +001 703-527-3887 (outside U.S.) Website www.lpslabs.com E-mail 2. Hazard(s) identification Physical hazards Gases under pressure Compressed gas Health hazards Skin corrosion/irritation Category 2 Serious eye damage/eye irritation Category 2A Germ cell mutagenicity Category 2 Carcinogenicity Category 1 B Specific target organ toxicity, single exposure Category 3 narcotic effects Environmental hazards Not classified. OSHA defined hazards Not classified. Label elements Signal word Danger Hazard statement Contains gas under pressure; may explode if heated. Causes skin irritation. Causes serious eye irritation.Suspected of causing genetic defects. May cause cancer. May cause drowsiness or dizziness. Precautionary statement Prevention Obtain special instructions before use. Do not handle until all safety precautions have been read and understood.Avoid breathing gas. Wash thoroughly after handling. Use only outdoors or in a well-ventilated area. Wear protective gloves/protective clothing/eye protection/face protection. Response If on skin:Wash with plenty of water. If inhaled: Remove person to fresh air and keep comfortable for breathing. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If exposed or concerned: Get medical advice/attention. Call a poison center/doctor if you feel unwell. If skin irritation occurs:Get medical advice/attention. If eye irritation persists:Get medical advice/attention.Take off contaminated clothing and wash before reuse. Storage Store in a well-ventilated place. Keep container tightly closed.Store locked up. Protect from sunlight. Material name: LPS®HDX(Aerosol) sos us 01020 Version#:01 Issue date: 10-18-2016 1 /11 Disposal Dispose of contents/container in accordance with local/regional/national/international regulations. Hazard(s)not otherwise None known. classified(HNOC) Supplemental information None known. 3. Composition/information on ingredients Mixtures Chemical name Common name and synonyms CAS number % 1,1,2-trichloroethylene 79-01-6 90- 100 Carbon Dioxide 124-38-9 1 -5 4. First-aid measures Inhalation Remove victim to fresh air and keep at rest in a position comfortable for breathing.Call a POISON CENTER or doctor/physician if you feel unwell. Skin contact Remove contaminated clothing.Wash with plenty of soap and water. If skin irritation occurs:Get medical advice/attention.Wash contaminated clothing before reuse. Eye contact Immediately flush eyes with plenty of water for at least 15 minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Get medical attention if irritation develops and persists. Ingestion Not likely, due to the form of the product. In the unlikely event of swallowing contact a physician or poison control center. Rinse mouth. Most important May cause drowsiness and dizziness. Headache. Nausea,vomiting. Severe eye irritation. symptoms/effects,acute and Symptoms may include stinging,tearing, redness,swelling, and blurred vision.Skin irritation. May delayed cause redness and pain. Indication of immediate Provide general supportive measures and treat symptomatically. Keep victim under observation. medical attention and special Symptoms may be delayed. treatment needed General information IF exposed or concerned: Get medical advice/attention. If you feel unwell, seek medical advice (show the label where possible). Ensure that medical personnel are aware of the material(s) involved, and take precautions to protect themselves.Shaw this safety data sheet to the doctor in attendance. 5. Fire-fighting measures Suitable extinguishing media Water fog. Foam. Dry chemical powder. Carbon dioxide(CO2). Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. media Specific hazards arising from During fire,gases hazardous to health may be formed. the chemical Special protective equipment Self-contained breathing apparatus and full protective clothing must be worn in case of fire. and precautions for firefighters Fire fighting In case of fire: Stop leak if safe to do so. Do not move cargo or vehicle if cargo has been exposed equipment/instructions to heat. Move containers from fire area if you can do so without risk. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not,withdraw and let fire burn out. Specific methods Cool containers exposed to flames with water until well after the fire is out. General fire hazards Contents under pressure. Pressurized container may explode when exposed to heat or flame. 6. Accidental release measures Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of protective equipment and low areas. Many gases are heavier than air and will spread along ground and collect in low or emergency procedures confined areas (sewers, basements,tanks).Wear appropriate protective equipment and clothing during clean-up. Avoid breathing gas. Emergency personnel need self-contained breathing equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing. Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. Use personal protection recommended in Section 8 of the SDS. Material name: UPS®HDX(Aerosol) sos us 01020 Version#:01 Issue date: 10-18-2016 2/11 Methods and materials for Refer to attached safety data sheets and/or instructions for use.Stop leak if you can do so without containment and cleaning up risk. Isolate area until gas has dispersed. Eliminate all ignition sources(no smoking,flares, sparks, or flames in immediate area). Keep combustibles (wood,paper,oil, etc.)away from spilled material.Absorb in vermiculite, dry sand or earth and place into containers. Following product recovery,flush area with water. Small Spills:Wipe up with absorbent material (e.g. cloth,fleece). Clean surface thoroughly to remove residual contamination. Put material in suitable,covered, labeled containers. For waste disposal,see section 13 of the SDS. Environmental precautions Avoid discharge into drains,water courses or onto the ground. 7. Handling and storage Precautions for safe handling Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Pressurized container: Do not pierce or burn,even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut,weld,solder,drill, grind, or expose containers to heat,flame, sparks, or other sources of ignition. Ground and bond containers when transferring material. Do not re-use empty containers.Avoid breathing gas.Avoid contact with eyes, skin,and clothing. Avoid prolonged exposure.Should be handled in closed systems, if possible. Use only in well-ventilated areas.Wear appropriate personal protective equipment. Observe good industrial hygiene practices. Conditions for safe storage, Level 1 Aerosol. including any incompatibilities Store locked up. Contents under pressure. Do not expose to heat or store at temperatures above 120°F/49°0 as can may burst. Do not puncture, incinerate or crush. Do not handle or store near an open flame, heat or other sources of ignition. Store in a well-ventilated place.Stored containers should be periodically checked for general condition and leakage.Store away from incompatible materials(see Section 10 of the SDS). 8. Exposure controls/personal protection Occupational exposure limits The following constituents are the only constituents of the product which have a PEL, TLV or other recommended exposure limit. At this time,the other constituents have no known exposure limits. US.OSHA Table Z-1 Limits for Air Contaminants(29 CFR 1910.1000) Components Type Value Form Butanone (CAS 78-93-3) PEL 590 mg/m3 200 ppm Camphor USP (CAS PEL 2 mg/m3 76-22-2) Carbon Dioxide(CAS PEL 9000 mg/m3 124-38-9) 5000 ppm Diphenyl Oxide(CAS PEL 7 mg/m3 Vapor. 101-84-8) 1 ppm Vapor. Ise amyl acetate (CAS PEL 525 mg/m3 123-92-2) 100 ppm Turpentine (CAS PEL 560 mg/m3 8006-64-2) 100 ppm US.OSHA Table Z-2(29 CFR 1910.1000) Components Type Value 1,1,2-trichlcroethylene Ceiling 200 ppm (CAS 79-01-6) TWA 100 ppm US.ACGIH Threshold Limit Values Components Type Value Form 1,1,2-trichloroethylene STEL 25 ppm (CAS 79-01-6) TWA 10 ppm Butanone (CAS 78-93-3) STEL 300 ppm TWA 200 ppm Material name:LPSO HDX(Aerosol) sos us 01020 Version#1:01 Issue date: 10-18-2016 3/11 US.ACGIH Threshold Limit Values Components Type Value Form Camphor USP (CAS STEL 3ppm 76-22-2) TWA 2 ppm Carbon Dioxide (CAS STEL 30000 ppm 124-38-9) TWA 5000 ppm Diphenyl Oxide(CAS STEL 2 ppm Vapor. 101-84-8) TWA 1 ppm Vapor. Iso amyl acetate (CAS STEL 100 ppm 123-92-2) TWA 50 ppm Turpentine(CAS TWA 20 ppm 8006-64-2) US.NIOSH: Pocket Guide to Chemical Hazards Components Type Value Form 1,1,2-trichloroethylene TWA 25 ppm (CAS 79-01-6) Butanone (CAS 78-93-3) STEL 885 mg/m3 300 ppm TWA 590 mg/m3 200 ppm Camphor USP (CAS TWA 2 mg/m3 76-22-2) Carbon Dioxide (CAS STEL 54000 mg/m3 124-38-9) 30000 ppm TWA 9000 mg/m3 5000 ppm Diphenyl Oxide (CAS TWA 7 mg/m3 Vapor. 101-84-8) 1 ppm Vapor. Iso amyl acetate (CAS TWA 525 mg/m3 123-92-2) 100 ppm Turpentine(CAS TWA 560 mg/m3 8006-64-2) 100 ppm US.Workplace Environmental Exposure Level(WEEL)Guides Components Type Value 1,2 Butylene Oxide(CAS TWA 5.9 mg/m3 106-88-7) 2 ppm Biological limit values ACGIH Biological Exposure Indices Components Value Determinant Specimen Sampling Time 1,1,2-trichloroethylene 15 mg 11 Trichloroacetic Urine (CAS 79-01-6) acid 0.5 mg/I Trichloroethano Blood I,without hydrolysis Butanone (CAS 78-93-3) 2 mg/I MEK Urine *- For sampling details, please see the source document. Appropriate engineering Good general ventilation(typically 10 air changes per hour)should be used. Ventilation rates controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established, maintain airborne levels to an acceptable level. Eye wash facilities and emergency shower must be available when handling this product. Material name:LPSO HDX(Aerosol) soS US 01020 Version#:01 Issue date: 10-18-2016 4/11 Individual protection measures, such as personal protective equipment Eye/face protection Wear safety glasses with side shields (or goggles). Skin protection Hand protection Wear appropriate chemical resistant gloves. Other Wear appropriate chemical resistant clothing. Use of an impervious apron is recommended. Respiratory protection If permissible levels are exceeded use NIOSH mechanical filter/organic vapor cartridge or an air-supplied respirator. Thermal hazards Wear appropriate thermal protective clothing,when necessary. General hygiene Observe any medical surveillance requirements.When using do not smoke. Always observe good considerations personal hygiene measures,such as washing after handling the material and before eating, drinking,and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Gas. Form Aerosol. Color Clear.Colorless. Odor Sweet. Spice. Odor threshold Not established pH Not applicable Melting point/freezing point Not established Initial boiling point and boiling 188.6 of(87 oC) range Flash point Tag Closed Cup(None) Evaporation rate 0.3 (Ethyl Ether= 1) Flammability(solid,gas) Non flammable gas. Upper/lower flammability or explosive limits Flammability limit-lower 8% M Flammability limit-upper 10.5% M Explosive limit-lower(%) Not available. Explosive limit-upper(%) Not available. Vapor pressure 58 mm Hg @ 20oC Vapor density 4.5 Relative density Not available. Solubility(ies) Solubility(water) 0.1 % Partition coefficient 2.4 (n-octanol/water) Auto-ignition temperature >788 of(>420 oC) Decomposition temperature Not established Viscosity 0.53 cP @ 25° C Other information Explosive properties Not explosive. Heat of combustion <20 kJ/g Oxidizing properties Not oxidizing. Percent volatile 100% Specific gravity 1.41 - 1.47 @ 20°C VOC 97.8% Material name:LPSO HDX(Aerosol) sos us 01020 Version#:01 Issue date:10-18-2016 5/11 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous Hazardous polymerization does not occur. reactions Conditions to avoid Heat. Contact with incompatible materials. Incompatible materials Strong oxidizing agents. Hazardous decomposition Carbon oxides. products 11. Toxicological information Information on likely routes of exposure Inhalation May cause drowsiness and dizziness. Headache. Nausea, vomiting. Prolonged inhalation may be harmful. Skin contact Causes skin irritation. Eye contact Causes serious eye irritation. Ingestion Expected to be a low ingestion hazard. Symptoms related to the May cause drowsiness and dizziness. Headache. Nausea,vomiting. Severe eye irritation. physical,chemical and Symptoms may include stinging,tearing, redness, swelling, and blurred vision.Skin irritation. May toxicological characteristics cause redness and pain. Information on toxicological effects Acute toxicity Narcotic effects. Components Species Test Results 1,1,2-trichloroethylene(CAS 79-01-6) Acute Dermal LD50 Rabbit 20 ml/kg Inhalation LC50 Rat 12500 ppm, 4 Hours Oral LD50 Rat 4920 mg/kg 1,2 Butylene Oxide(CAS 106-88-7) Acute Dermal LD50 Rabbit 1.77 ml/kg,24 Hours Inhalation Vapor LC50 Rat >6.3 mg/I, 4 Hours Oral LD50 Rat 1100 pl/kg Butanone(CAS.78-93-3) Acute Dermal LD50 Rabbit > 10 ml/kg Oral LD50 Rat 2054 mg/kg Diphenyl Oxide(CAS 101-84-8) Acute Oral LD50 Rat 2.83 g/kg Material name:LPSO HDX(Aerosol) SDS us 01020 Version 4:01 Issue date: 10-18-2016 6/11 Components Species Test Results Turpentine(CAS 8006-64-2) Acute Dermal LD50 Rabbit >2000 mg/kg, 24 Hours Inhalation Vapor LC50 Rat 13.7 mg/I,4 Hours Oral LD50 Rat 4.6 ml/kg Skin corrosion/irritation Causes skin irritation. Serious eye damage/eye Causes serious eye irritation. irritation Respiratory or skin sensitization ACGIH sensitization Turpentine(CAS 8006-64-2) Dermal sensitization Respiratory sensitization Not a respiratory sensitizer. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity Suspected of causing genetic defects. Carcinogenicity May cause cancer. ACGIH Carcinogens 1,1,2-trichloroethylene (CAS 79-01-6) A2 Suspected human carcinogen. Camphor USP (CAS 76-22-2) A4 Not classifiable as a human carcinogen. Turpentine (CAS 8006-64-2) A4 Not classifiable as a human carcinogen. [ARC Monographs.Overall Evaluation of Carcinogenicity 1,1,2-trichloroethylene (CAS 79-01-6) 1 Carcinogenic to humans. 1,2 Butylene Oxide (CAS 106-88-7) 2B Possibly carcinogenic to humans. OSHA Specifically Regulated Substances(29 CFR 1910.1001-1050) Not regulated. US. National Toxicology Program (NTP)Report on Carcinogens 1,1,2-trichloroethylene(CAS 79-01-6) Reasonably Anticipated to be a Human Carcinogen. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity- May cause drowsiness and dizziness. single exposure Specific target organ toxicity- Not classified. repeated exposure Aspiration hazard Not an aspiration hazard. Chronic effects Prolonged inhalation may be harmful. Prolonged exposure may cause chronic effects. Further information Symptoms may be delayed. 12. Ecological information Ecotoxicity The product is not classified as environmentally hazardous. However,this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Components Species Test Results 1,1,2-trichloroethylene (CAS 79-01-6) Aquatic Fish LC50 Flagfish (Jordanella floridae) 3.1 mg/l, 96 hours Butanone(CAS 78-93-3) Aquatic Crustacea EC50 Water flea(Daphnia magna) 4025- 6440 mg/I, 48 hours Fish LC50 Sheepshead minnow(Cyprinodon >400 mg/l, 96 hours variegatus) Material name:LPSO HDX(Aerosol) so$us 01020 Version#:01 Issue date: 10-18-2016 7/11 Components Species Test Results Diphenyl Oxide(CAS 101-84-8) Aquatic Fish LC50 Sheepshead minnow(Cyprinodon 1.8-3.2 mg/I, 96 hours variegatus) Persistence and degradability Not inherently biodegradable. Bioaccumulative potential Partition coefficient n-octanol/water(log Kew) LPSO HDX(Aerosol) 2.4 1,1,2-trichloroethylene 2.61 Butanone 0.29 Diphenyl Oxide 4.21 Mobility in soil No data available. Other adverse effects None known. 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user,the producer and the waste disposal company. D003:Waste Reactive material D040:Waste Trichloroethylene Waste from residues/unused Dispose of in accordance with local regulations. Empty containers or liners may retain some products product residues.This material and its container must be disposed of in a safe manner(see: Disposal instructions). Contaminated packaging Since emptied containers may retain product residue,follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers. 14. Transport information DOT UN number UN1950 UN proper shipping name Aerosols, non-flammable, (each not exceeding 1 L capacity) Transport hazard class(es) Class 2.2 Subsidiary risk 6.1(PG III) Label(s) 2.2 Packing group Not applicable. Environmental hazards Marine pollutant No Special precautions for user Read safety instructions,SIDS and emergency procedures before handling. Packaging exceptions 306 Packaging non bulk None Packaging bulk None IATA UN number UN1950 UN proper shipping name Aerosols, non-flammable Transport hazard class(es) Class 2.2 Subsidiary risk 6.1(PGIII) Packing group Not applicable. Environmental hazards No ERG Code 2L Special precautions for user Read safety instructions,SDS and emergency procedures before handling. Other information Passenger and cargo Allowed with restrictions. aircraft Material name:LPSO HDX(Aerosol) sos us 01020 Version#:01 Issue date:10-18-2016 8/11 Cargo aircraft only Allowed with restrictions. IMDG UN number UN1950 UN proper shipping name AEROSOLS Transport hazard class(es) Class 2.2 Subsidiary risk 6.1(PGIII) Packing group Not applicable. Environmental hazards Marine pollutant No EmS F-D,S-U Special precautions for user Read safety instructions,SDS and emergency procedures before handling. Transport in bulk according to Not applicable. Annex II of MARPOL 73/78 and the IBC Code DOT PG III s IATA;IMDG 6 General information Avoid transport on vehicles where the load space is not separated from the driver's compartment. Ensure vehicle driver is aware of the potential hazards of the load and knows what to do in the event of an accident or an emergency. Before transporting product containers: Ensure that containers are firmly secured. Ensure cylinder valve is closed and not leaking. Ensure valve outlet cap nut or plug (where provided) is correctly fitted. Ensure valve protection device(where provided) is correctly fitted. Ensure adequate ventilation. Ensure compliance with applicable regulations. 15. Regulatory information US federal regulations This product is a"Hazardous Chemical"as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b) Export Notification (40 CFR 707,Subpt.D) 1,1,2-trichloroethylene(CAS 79-01-6) 0.1 %One-Time Export Notification only. CERCLA Hazardous Substance List(40 CFR 302.4) 1,1,2-trichloroethylene(CAS 79-01-6) Listed. 1,2 Butylene Oxide (CAS 106-88-7) Listed. Butanone (CAS 78-93-3) Listed. Ise amyl acetate(CAS 123-92-2) Listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances (29 CFR 1910.1001-1050) Not regulated. Material name: LPSO HDX(Aerosol) sos us 01020 Version#:01 Issue date: 10-18-2016 9/11 Superfund Amendments and Reauthorization Act of 1986(SARA) Hazard categories Immediate Hazard-Yes Delayed Hazard-Yes Fire Hazard- No Pressure Hazard-Yes Reactivity Hazard-No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous Yes chemical SARA 313(TRI reporting) Chemical name CAS number %by wt. TRICHLOROETHYLENE 79-01-6 97.25 Other federal regulations Clean Air Act(CAA)Section 112 Hazardous Air Pollutants(HAPs)List 1,1,2-trichloroethylene (CAS 79-01-6) 1,2 Butylene Oxide (CAS 106-88-7) Clean Air Act(CAA)Section 112(r) Accidental Release Prevention(40 CFR 68.130) Not regulated. Safe Drinking Water Act Not regulated. (SDWA) Drug Enforcement Administration(DEA). List 2,Essential Chemicals(21 CFR 1310.02(b)and 1310.04(f)(2)and Chemical Code Number Butanone(CAS 78-93-3) 6714 Drug Enforcement Administration(DEA). List 1 &2 Exempt Chemical Mixtures(21 CFR 1310.12(c)) Butanone(CAS 78-93-3) 35%W V DEA Exempt Chemical Mixtures Code Number Butanone(CAS 78-93-3) 6714 FEMA Priority Substances Respiratory Health and Safety in the Flavor Manufacturing Workplace Butanone(CAS 78-93-3) Low priority Diphenyl Oxide (CAS 101-84-8) Low priority Ise amyl acetate (CAS 123-92-2) Low priority US state regulations WARNING:This product contains a chemical known to the State of California to cause cancer and birth defects or other reproductive harm. US-California Proposition 65-CRT: Listed date/Carcinogenic substance 1,1,2-trichloroethylene (CAS 79-01-6) Listed:April 1, 1988 US-California Proposition 65-CRT: Listed date/Developmental toxin 1,1,2-trichloroethylene (CAS 79-01-6) Listed:Jan 31, 2014 US-California Proposition 65-CRT: Listed date/Male reproductive toxin 1,1,2-trichloroethylene(CAS 79-01-6) Listed:Jan 31, 2014 US.California.Candidate Chemicals List.Safer Consumer Products Regulations(Cal.Code Regs,tit.22,69502.3, subd.(a)) 1,1,2-trichloroethylene (CAS 79-01-6) 1,2 Butylene Oxide(CAS 106-88-7) Butanone(CAS 78-93-3) International Inventories Country(s)or region Inventory name On inventory(yes/no)' Australia Australian Inventory of Chemical Substances (AICS) Yes Canada Domestic Substances List(DSL) Yes Canada Non-Domestic Substances List(NDSL) No China Inventory of Existing Chemical Substances in China(IECSC) Yes Europe European Inventory of Existing Commercial Chemical Yes Substances(EINECS) Europe European List of Notified Chemical Substances (ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) Yes Korea Existing Chemicals List (ECL) Yes Material name: LPSO HDX(Aerosol) sos us 01020 Version#:01 Issue date: 10-18-2016 10/11 Country(s)or region Inventory name On inventory(yes/no)* New Zealand New Zealand Inventory Yes Philippines Philippine Inventory of Chemicals and Chemical Substances Yes (PICCS) United States& Puerto Rico Toxic Substances Control Act(TSCA) Inventory Yes *A"Yes"indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A"No"indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 10-18-2016 Version# 01 Disclaimer ITW Pro Brands cannot anticipate all conditions under which this information and its product, or the products of other manufacturers in combination with its product, may be used. It is the user's responsibility to ensure safe conditions for handling,storage and disposal of the product, and to assume liability for loss, injury,damage or expense due to improper use.The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication.The information given is designed only as a guidance for safe handling, use, processing,storage,transportation,disposal and release and is not to be considered a warranty or quality specification.The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Revision information This document has undergone significant changes and should be reviewed in its entirety. Material name: LPSO HDX(Aerosol) sos us 01020 Version#:01 Issue date: 10-18-2016 11 /11 PROy SAFETY DATA SHEET BRANDS 1. Identification Product identifier LPS®2(Aerosol) Other means of identification Part Number 00216 Recommended use An industrial lubricant designed to displace moisture from equipment,provide heavy-duty lubrication and rust prevention. Recommended restrictions None known. Manufacturer/Importer/Supplier/Distributor information Manufacturer Manufacturer Company name ITW Pro Brands Address 4647 Hugh Howell Rd. Tucker, GA 30084 Country (U.S.A.) Tel:+1 770-243-8800 In Case of Emergency 1-800-424-9300 (inside U.S.) +001 703-527-3887(outside U.S.) Website www.lpslabs.com E-mail 2. Hazard(s) identification Physical hazards Flammable aerosols Category 1 Gases under pressure Compressed gas Health hazards Not classified. Environmental hazards Not classified. OSHA defined hazards Not classified. Label elements Signal word Danger Hazard statement Extremely flammable aerosol. Contains gas under pressure; may explode if heated. Precautionary statement Prevention Keep away from heat/sparks/open flames/hot surfaces. -No smoking. Do not spray on an open flame or other ignition source. Pressurized container: Do not pierce or burn, even after use. Response Wash hands after handling. Storage Protect from sunlight. Store in a well-ventilated place. Do not expose to temperatures exceeding 50°C/122°F. Disposal Dispose of waste and residues in accordance with local authority requirements. Hazard(s)not otherwise Combustible. classified(HNOC) Supplemental information None known. 3. Composition/information on ingredients Mixtures Material name: LPS®2(Aerosol) sos us 00216 Version#:02 Revision date:09-20-2017 Issue date: 11-01-2016 1 /9 Chemical name Common name and synonyms CAS number % Distillates Petroleum Hydrotreated 64742-47-8 70-80 Light Petroleum Oil 64742-52-5 10-20 Carbon Dioxide 124-38-9 1 -5 4. First-aid measures Inhalation Move to fresh air. Call a physician if symptoms develop or persist. Skin contact No adverse effects due to skin contact are expected. Eye contact No specific first aid measures noted. Ingestion Not likely,due to the form of the product. Most important Direct contact with eyes may cause temporary irritation. symptoms/effects,acute and delayed Indication of immediate Provide general supportive measures and treat symptomatically. medical attention and special treatment needed General information Ensure that medical personnel are aware of the material(s)involved,and take precautions to protect themselves. 5. Fire-fighting measures Suitable extinguishing media Water fog. Alcohol resistant foam. Dry chemical powder. Dry chemicals.Carbon dioxide (CO2). Unsuitable extinguishing Do not use water jet as an extinguisher, as this will spread the fire. media Specific hazards arising from Contents under pressure. Pressurized container may explode when exposed to heat or flame. the chemical During fire, gases hazardous to health may be formed. Special protective equipment Firefighters must use standard protective equipment including flame retardant coat, helmet with and precautions for firefighters face shield,gloves, rubber boots, and in enclosed spaces, SCBA. Fire fighting In case of fire:Stop leak if safe to do so. Do not move cargo or vehicle if cargo has been exposed equipment/instructions to heat. Move containers from fire area if you can do so without risk. Cool containers exposed to heat with water spray and remove container, if no risk is involved. Containers should be cooled with water to prevent vapor pressure build up. For massive fire in cargo area, use unmanned hose holder or monitor nozzles, if possible. If not,withdraw and let fire burn out. Specific methods Use standard firefighting procedures and consider the hazards of other involved materials. Move containers from fire area if you can do so without risk. In the event of fire and/or explosion do not breathe fumes. General fire hazards Extremely flammable aerosol. Contents under pressure. Pressurized container may explode when exposed to heat or flame.Combustible. 6. Accidental release measures Personal precautions, Keep unnecessary personnel away. Keep people away from and upwind of spill/leak. Keep out of protective equipment and low areas. Many gases are heavier than air and will spread along ground and collect in low or emergency procedures confined areas(sewers,basements,tanks).Wear appropriate protective equipment and clothing during clean-up. Emergency personnel need self-contained breathing equipment. Do not touch damaged containers or spilled material unless wearing appropriate protective clothing.Ventilate closed spaces before entering them. Local authorities should be advised if significant spillages cannot be contained. Use personal protection recommended in Section 8 of the SDS. Methods and materials for Refer to attached safety data sheets and/or instructions for use. Stop leak if you can do so without containment and cleaning up risk. Use water spray to reduce vapors or divert vapor cloud drift. Isolate area until gas has dispersed. Eliminate all ignition sources(no smoking,flares,sparks, or flames in immediate area). Keep combustibles (wood, paper, oil, etc.)away from spilled material. For waste disposal, see section 13 of the SDS. Environmental precautions Avoid discharge into drains,water courses or onto the ground. 7. Handling and storage Precautions for safe handling Pressurized container: Do not pierce or burn, even after use. Do not use if spray button is missing or defective. Do not spray on a naked flame or any other incandescent material. Do not smoke while using or until sprayed surface is thoroughly dry. Do not cut,weld,solder, drill, grind,or expose containers to heat,flame, sparks, or other sources of ignition.All equipment used when handling the product must be grounded. Do not re-use empty containers.Avoid prolonged or repeated contact with skin.Avoid prolonged exposure. Use only in well-ventilated areas. Wear appropriate personal protective equipment.Observe good industrial hygiene practices. Material name:UPS®2(Aerosol) sos us 00216 Version#:02 Revision date:09-20-2017 Issue date:11-01-2016 2/9 Conditions for safe storage, Level 3 Aerosol. including any incompatibilities Pressurized container. Protect from sunlight and do not expose to temperatures exceeding 50°C/122 °F. Do not puncture, incinerate or crush. Dc not handle or store near an open flame, heat or other sources of ignition.This material can accumulate static charge which may cause spark and become an ignition source.Store in a well-ventilated place. Stored containers should be periodically checked for general condition and leakage. Store away from incompatible materials (see Section 10 of the SDS). Level 3 Aerosol. 8. Exposure controls/personal protection Occupational exposure limits The following constituents are the only constituents of the product which have a PEL,TLV or other recommended exposure.limit. At this time,the other constituents have no known exposure limits. U.S.-OSHA Components Type Value Form Distillates Petroleum PEL 5 mg/m3 Oil mist Hydrotreated Light(CAS 64742-47-8) Petroleum Oil (CAS PEL 5 mg/m3 Oil mist 64742-52-5) White Mineral Oil (CAS TWA 5 mg/m3 Oil mist. 8042-47-5) US.OSHA Table 2-1 Limits for Air Contaminants(29 CFR 1910.1000) Components Type Value Carbon Dioxide(CAS PEL 9000 mg/m3 124-38-9) 5000 ppm ACGIH Components Type Value Form Distillates Petroleum TWA 5 mg/m3 Oil mist Hydrotreated Light(CAS 64742-47-8) Petroleum Oil (CAS TWA 5 mg/m3 Oil mist 64742-52-5) White Mineral Oil (CAS TWA 5 mg/m3 Respirable fraction. 8042-47-5) US.ACGIH Threshold Limit Values Components Type Value 2-Methyl Butyl Acetate STEL 100 ppm (CAS 624-41-9) TWA 50 ppm Carbon Dioxide(CAS STEL 30000 ppm 124-38-9) TWA 5000 ppm U.S.-NIOSH Components Type Value Form White Mineral Oil (CAS TWA 5 mg/m3 Mist. 8042-47-5) US.NIOSH: Pocket Guide to Chemical Hazards Components Type Value Carbon Dioxide(CAS STEL 54000 mg/m3 124-38-9) 30000 ppm TWA 9000 mg 1m3 5000 ppm Biological limit values No biological exposure limits noted for the ingredient(s). Appropriate engineering Good general ventilation (typically 10 air changes per hour)should be used.Ventilation rates controls should be matched to conditions. If applicable, use process enclosures, local exhaust ventilation, or other engineering controls to maintain airborne levels below recommended exposure limits. If exposure limits have not been established,maintain airborne levels to an acceptable level. Material name: LPSO 2(Aerosol) sos us 00216 Version#:02 Revision date:09-20-2017 Issue date: 11-01-2016 3/9 Individual protection measures,such as personal protective equipment Eye/face protection Wear safety glasses with side shields(or goggles). Skin protection Hand protection Wear appropriate chemical resistant gloves. Other Wear suitable protective clothing. Respiratory protection If permissible levels are exceeded use NIOSH mechanical filter/organic vapor cartridge or an air-supplied respirator. Thermal hazards Wear appropriate thermal protective clothing,when necessary. General hygiene When using do not smoke.Always observe good personal hygiene measures, such as washing considerations after handling the material and before eating,drinking,and/or smoking. Routinely wash work clothing and protective equipment to remove contaminants. 9. Physical and chemical properties Appearance Physical state Gas. Form Aerosol. Color Brown. Odor Slight petroleum odor. Cherry. Odor threshold Not established pH Not applicable Melting point/freezing point <-58 °F(<-50°C) Initial boiling point and boiling 383 °F It 95°C) @ 101 kPa range Flash point 174.2°F(79.0 °C)Tag Closed Cup(dispensed liquid) Evaporation rate <0.1 BuAc Flammability(solid,gas) Flammable gas. Upper/lower flammability or explosive limits Flammability limit-lower 0.6% (%) Flammability limit-upper 7% (%) Explosive limit-lower(%) Not available. Explosive limit-upper(%) Not available. Vapor pressure <0.05 mm Hg @ 20°C (dispensed liquid) Vapor density 4.7(air= 1) Relative density Not available. Solubility(ies) Solubility(water) <3% Partition coefficient < 1 (n-octanol/water) Auto-ignition temperature >442.4°F(>228°C) Decomposition temperature Not established Viscosity <7 cSt Viscosity temperature 77-F(25°C) Other information Explosive properties Not explosive. Heat of combustion >30 kJ/g Oxidizing properties Not oxidizing. Percent volatile 92-95% Specific gravity 0.82-0.86 @ 20oC Material name:LPSO2(Aerosol) sos us 00216 Version 4:02 Revision date:09-20-2017 Issue date:11-01-2016 4/9 10. Stability and reactivity Reactivity The product is stable and non-reactive under normal conditions of use, storage and transport. Chemical stability Material is stable under normal conditions. Possibility of hazardous Hazardous polymerization does not occur. reactions Conditions to avoid Heat. Avoid temperatures exceeding the flash point.Contact with incompatible materials. Incompatible materials Strang oxidizing agents. Hazardous decomposition Carbon oxides. products 11. Toxicological information Information on likely routes of exposure Inhalation Prolonged inhalation may be harmful. Skin contact No adverse effects due to skin contact are expected. Eye contact Direct contact with eyes may cause temporary irritation. Ingestion Expected to be a low ingestion hazard. Symptoms related to the Direct contact with eyes may cause temporary irritation. physical,chemical and toxicological characteristics Information on toxicological effects Acute toxicity Not expected to be acutely toxic. Components Species Test Results Distillates Petroleum Hydrotreated Light(CAS 64742-47-8) Acute Dermal LD50 Rabbit >2000 mg/kg Inhalation Vapor LC50 Rat >4.5 mg/I,4 Hours Petroleum Oil (CAS 64742-52-5) Acute Dermal LD50 Rabbit >2000 mg/kg Inhalation LC50 Rat >3.9 mg/I, 4 Hours Oral LD50 Rat >2000 mg/kg White Mineral Oil (CAS 8042-47-5) Acute Dermal LD50 Rabbit >2000 mg/kg, 24 Hours Inhalation LC50 Rat 2.18 mg/I, 4 Hours Skin corrosion/irritation Prolonged skin contact may cause temporary irritation. Serious eye damage/eye Direct contact with eyes may cause temporary irritation. irritation Respiratory or skin sensitization Respiratory sensitization Not a respiratory sensitizer. Skin sensitization This product is not expected to cause skin sensitization. Germ cell mutagenicity No data available to indicate product or any components present at greater than 0.1%are mutagenic or genotoxic. Carcinogenicity This product is not considered to be a carcinogen by IARC,ACGIH, NTP, or OSHA. Material name:LPSO 2(Aerosol) sos us 00216 Version#:02 Revision date:09-20-2017 Issue date:11-01-2016 5/9 IARC Monographs.Overall Evaluation of Carcinogenicity Not listed. OSHA Specifically Regulated Substances(29 CFR 1910.1001-1050) Not regulated. US.National Toxicology Program (NTP) Report on Carcinogens Not listed. Reproductive toxicity This product is not expected to cause reproductive or developmental effects. Specific target organ toxicity- Not classified. single exposure Specific target organ toxicity- Not classified. repeated exposure Aspiration hazard Not likely, due to the form of the product. Chronic effects Prolonged inhalation may be harmful. Further information None known. 12. Ecological information Ecotoxicity The product is not classified as environmentally hazardous. However,this does not exclude the possibility that large or frequent spills can have a harmful or damaging effect on the environment. Components Species Test Results Distillates Petroleum Hydrotreated Light(CAS 64742-47-8) Aquatic Fish LC50 Rainbow trout,donaldson trout 2.9 mg/I, 96 hours (Oncorhynchus mykiss) Persistence and degradability Bioaccumulative potential Partition coefficient n-octanol/water(log Kow) LPS®2(Aerosol) < 1 Mobility in soil No data available. Other adverse effects None known. 13. Disposal considerations Disposal instructions Collect and reclaim or dispose in sealed containers at licensed waste disposal site. Contents under pressure. Do not puncture, incinerate or crush. Dispose of contents/container in accordance with local/regional/national/international regulations. Local disposal regulations Dispose in accordance with all applicable regulations. Hazardous waste code The waste code should be assigned in discussion between the user,the producer and the waste disposal company. D003:Waste Reactive material Waste from residues/unused Dispose of in accordance with local regulations. Empty containers or liners may retain some products product residues.This material and its container must be disposed of in a safe manner(see: Disposal instructions). Contaminated packaging Since emptied containers may retain product residue,follow label warnings even after container is emptied. Empty containers should be taken to an approved waste handling site for recycling or disposal. Do not re-use empty containers. 14. Transport information DOT UN number UN1950 UN proper shipping name Aerosols,flammable Transport hazard class(es) Class 2.1 Subsidiary risk - Label(s) 2.1 Packing group Not available. Environmental hazards Marine pollutant No Special precautions for user Read safety instructions,SIDS and emergency procedures before handling. Packaging exceptions 306 Material name: LPS®2(Aerosol) sos us 00216 Version#:02 Revision date:09-20-2017 Issue date:11-01-2016 6/9 Packaging non bulk None Packaging bulk None IATA UN number UN1950 UN proper shipping name Aerosols,flammable Transport hazard class(es) Class 2.1 Subsidiary risk - Label(s) 2.1 Packing group Not available. Environmental hazards No. ERG Code 10L Special precautions for user Read safety instructions,SDS and emergency procedures before handling. Other information Passenger and cargo Allowed with restrictions. aircraft Cargo aircraft only Allowed with restrictions. IMDG UN number UN1950 UN proper shipping name AEROSOLS,flammable Transport hazard class(es) Class 2.1 Subsidiary risk - Label(s) 2.1 Packing group Not available. Environmental hazards Marine pollutant No EmS Not available. Special precautions for user Read safety instructions, SIDS and emergency procedures before handling. Transport in bulk according to Not applicable. Annex II of MARPOL 73178 and the IBC Code DOT A& IATA; IMDG 4 General information Avoid transport on vehicles where the load space is not separated from the driver's compartment. Ensure vehicle driver is aware of the potential hazards of the load and knows what to do in the event of an accident or an emergency. Before transporting product containers: Ensure that containers are firmly secured. Ensure cylinder valve is closed and not leaking. Ensure valve outlet cap nut or plug (where provided) is correctly fitted. Ensure valve protection device (where provided) is correctly fitted. Ensure adequate ventilation. Ensure compliance with applicable regulations. Material name:LPS®2(Aerosol) sos us 00216 Version#:02 Revision date:09-20-2017 Issue date: 11-01-2016 719 15. Regulatory information US federal regulations This product is a"Hazardous Chemical"as defined by the OSHA Hazard Communication Standard, 29 CFR 1910.1200. TSCA Section 12(b)Export Notification (40 CFR 707,Subpt. D) Not regulated. CERCLA Hazardous Substance List(40 CFR 302.4) Not listed. SARA 304 Emergency release notification Not regulated. OSHA Specifically Regulated Substances(29 CFR 1910.1001-1050) Not regulated. Superfund Amendments and Reauthorization Act of 1986(SARA) Hazard categories Immediate Hazard- No Delayed Hazard-No Fire Hazard-Yes Pressure Hazard-Yes Reactivity Hazard-No SARA 302 Extremely hazardous substance Not listed. SARA 311/312 Hazardous Yes chemical SARA 313(TRI reporting) Not regulated. Other federal regulations Clean Air Act(CAA)Section 112 Hazardous Air Pollutants(HAPs)List Not regulated. Clean Air Act(CAA)Section 112(r)Accidental Release Prevention (40 CFR 68.130) Not regulated. Safe Drinking Water Act Not regulated. (SDWA) US state regulations WARNING:This product contains a chemical known to the State of California to cause cancer. US.California.Candidate Chemicals List.Safer Consumer Products Regulations(Cal.Code Regs,tit.22,69502.3, subd.(a)) Petroleum Oil (CAS 64742-52-5) International Inventories Country(s)or region Inventory name On inventory(yes/no)* Australia Australian Inventory of Chemical Substances(AICS) Yes Canada Domestic Substances List(DSL) Yes Canada Non-Domestic Substances List(NDSL) No China Inventory of Existing Chemical Substances in China(IECSC) No Europe European Inventory of Existing Commercial Chemical Yes Substances (EINECS) Europe European List of Notified Chemical Substances(ELINCS) No Japan Inventory of Existing and New Chemical Substances (ENCS) No Korea Existing Chemicals List (ECL) Yes New Zealand New Zealand Inventory No Philippines Philippine Inventory of Chemicals and Chemical Substances Yes (PICCS) United States& Puerto Rico Toxic Substances Control Act(TSCA) Inventory Yes *A"Yes"indicates that all components of this product comply with the inventory requirements administered by the governing country(s) A"No"indicates that one or more components of the product are not listed or exempt from listing on the inventory administered by the governing country(s). 16. Other information, including date of preparation or last revision Issue date 11-01-2016 Material name:LPSO2(Aerosol) sos us 00216 Version fi:02 Revision date:09-20-2017 Issue date:11-01-2016 8/9 Revision date 09-20-2017 Version# 02 Disclaimer ITW Pro Brands cannot anticipate all conditions under which this information and its product,or the products of other manufacturers in combination with its product, may be used. It is the user's responsibility to ensure safe conditions for handling,storage and disposal of the product,and to assume liability for loss, injury, damage or expense due to improper use. The information provided in this Safety Data Sheet is correct to the best of our knowledge, information and belief at the date of its publication. The information given is designed only as a guidance for safe handling, use, processing, storage,transportation, disposal and release and is not to be considered a warranty or quality specification.The information relates only to the specific material designated and may not be valid for such material used in combination with any other materials or in any process, unless specified in the text. Revision information This document has undergone significant changes and should be reviewed in its entirety. Material name: LPS®2(Aerosol) sos us 00216 Version#:02 Revision date:09-20-2017 Issue date: 11-01-2016 9/9 sasoL � 0 reaching new frontiers Material Safety Data Sheet Methyl Ethyl Ketone Version 1.08 Revision Date 28.03.2007 1. Identification of the substance/preparation and of the company/undertaking Trade name Methyl Ethyl Ketone Synonyms Methyl Ethyl Ketone, 2-Butanone, 3-Butanone, Methyl acetone, Ethyl methyl ketone Use For industrial use only., Solvents, raw material for printing inks and printing ink additives, Paint related material Company Saso/Solvents A division of Sasol Chemical Industries Sturdee Avenue 2 ZA 2196 Rosebank Information (Product safety) Telephone: +27112800000 Fax:+27112800198 Emergency telephone Europe, Israel, Africa, Americas +44(0)208 762 8322 number Middle East, Arabic African +9613 487 287 countries Asia Pacific +65 633 44 177 China +86 10 5100 3039 South Africa +27(0)17 610 4444 2. Composition/information on ingredients butanone;ethyl methyl ketone Contents: <= 99.50 %WAN CAS-No. 78-93-3 Index-No. 606-002-00-3 EC-No. 201-159-0 Symbol(s)F,Xi R-phrase(s) -R11 -R36-R66-R67 For the full text of the R phrases mentioned in this Section, see Section 16. Print Date 28.03.2007 100000000637 117 sasoL reaching new frontiers Material Safety Data Sheet Methyl Ethyl Ketone Version 1.08 Revision Date 28.03.2007 3. Hazards identification Identification of the risks R11 Highly flammable. R36 Irritating to eyes. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. Particular risks to human beings and the environment Highly flammable. 4. First aid measures General advice When symptoms persist or in all cases of doubt seek medical advice. Inhalation Move to fresh air in case of accidental inhalation of vapours. If breathing is irregular or stopped, administer artificial respiration. Call a physician immediately. Skin contact Wash off immediately with soap and plenty of water while removing all contaminated clothes and shoes. Wash contaminated clothing before re-use. If skin irritation persists, call a physician. Eye contact Rinse thoroughly with plenty of water for at least 15 minutes and consult a physician. Ingestion If swallowed, seek medical advice immediately and show this container or label. Do not induce vomiting without medical advice. Never give anything by mouth to an unconscious person. 5. Fire-fighting measures Suitable extinguishing Water spray,Alcohol-resistant foam, Dry chemical, Carbon media dioxide(CO2) Extinguishing media No information available. which must not be used for safety reasons Specific hazards during Vapours may form explosive mixtures with air. Flash back fire fighting possible over considerable distance. Special protective Wear self-contained breathing apparatus and protective suit. equipment for fire- fighters Further information Cool containers/tanks with water spray. Print Date 28.03.2007 100000000637 2/7 sasoL reaching new frontiers Material Safety Data Sheet Methyl Ethyl Ketone Version 1.08 Revision Date 28.03.2007 6. Accidental release measures Personal precautions Keep people away from and upwind of spill/leak. Remove all sources of ignition. Do not breathe vapours or spray mist. Material can create slippery conditions. Environmental Should not be released into the environment. Prevent further precautions leakage or spillage if safe to do so. Methods for cleaning up Soak up with inert absorbent material and dispose of as hazardous waste. 7. Handling and storage Handling Safe handling advice Provide sufficient air exchange and/or exhaust in work rooms. Wear personal protective equipment. Ensure all equipment is electrically grounded before beginning transfer operations. Take precautionary measures against static discharges. Advice on protection Keep away from heat and sources of ignition. Use explosion- against fire and explosion proof equipment. Storage Requirements for storage Keep containers tightly closed in a dry, cool and well-ventilated areas and containers place. 8. Exposure controls/personal protection Components with workplace control parameters NATIONAL OCCUPATIONAL EXPOSURE LIMITS EUROPEAN OCCUPATIONAL EXPOSURE LIMITS Components Type Control Update Basis parameters BUTANONE TWA 600 mg 1,m3 052003 EU Exposure Limit Values TWA 200 ppm 052003 EU Exposure Limit Values STEL 900 mg/m3 052003 EU Exposure Limit Values STEL 300 ppm 052003 EU Exposure Limit Values Engineering measures Provide sufficient air exchange and/or exhaust in work rooms. Personal protective equipment Print Date 28.03.2007 100000000637 317 sasoL 4 'P reaching ne.v frontier; 4�e Material Safety Data Sheet Methyl Ethyl Ketone Version 1.08 Revision Date 28.03.2007 Respiratory protection In case of insufficient ventilation wear suitable respiratory equipment. Hand protection gloves suitable for permanent contact: Material:butyl-rubber Breakthrough time 4 h Material thickness:0.5 mm unsuitable gloves Material:Polyvinylchloride, leather nitrile rubbednitrile latex, natural rubber/natural latex Eye protection Safety glasses with side-shields Skin and body protection Protective suit, Safety shoes Hygiene measures Wash hands before breaks and immediately afterhandling the product. Protective measures Wear suitable protective equipment. 9. Physical and chemical properties Form liquid state of matter liquid Colour colour less Odour mint-like pH no data available Melting point/range -86.3 °C Boiling point/range 79.6 °C Flash point -9 °C,closed cup Flash point 9 °C;open cup Autoignition temperature 515 °C Lower explosion limit 1.4 %(V) Upper explosion limit 11.4 %(V) Vapourpressure 121.323 hPa; 25 °C Density 0.805 g1cm3 Water solubility partly miscible Viscosity, dynamic 0.41 mPa.s Viscosity, kinematic 0.51 mm2/s Relative vapour density 2.5(Air= 1.0) Print Date 28.03.2007 100000000637 417 sasoL 4 '0 reaching new frontiers Ole Material Safety Data Sheet Methyl Ethyl Ketone Version 1.08 Revision Date 28.03.2007 10. Stability and reactivity Materials to avoid Strong oxidizing agents, Incompatible with acids., Halogenated compounds Hazardous Carbon oxides decomposition products Hazardous reactions Hazardous polymerisation does not occur. 11. Toxicological information Acute oral toxicity LD50 rat. 2,737 mg/kg;literature value Acute inhalation toxicity LC50 rat 23,500 mg/m3,, 8 h,literature value Acute dermal toxicity LD50 rabbit. 6,480 mg/kg;literature value Skin irritation rabbit:moderately irritating,literature value Eye irritation rabbit:irritating,literature value 12. Eco logical information Ecotoxicity effects Toxicity to fish LC50 Bluegill sunfish:4,467 mg1l,96 h,literature value LC50 Poecilia reticulata: 5,700 mg/l;24 I literature value LC50 Pimephales promelas:3,200 mg/I; 96 h;literature value Toxicity to daphnia and LC50 Daphnia magna: <520 mg11;48 h,literature value other aquatic invertebrates. 13. Disposal considerations Product In accordance with local and national regulations., Do not contaminate ponds, waterways or ditches with chemical or used container., The product should not be allowed to enter drains, watercourses or the soil. Contaminated packaging Do not burn, or use a cutting torch on, the empty drum., Triple rinse containers., Can be offered for recycling, re-conditioning or puncture. 14. Transport information ADR UN-No.: 1193; Class:3;Packaging group:11, F1;Description of the goods:METHYL ETHYL KETONE RID UN-No.: 1193; Class:3; Packaging group:11, F1;Description of the goods:METHYL ETHYL KETONE Print Date 28.03.2007 100000000637 517 sasoL * 0 op reaching new frontiers 4�e Material Safety Data Sheet Methyl Ethyl Ketone Version 1.08 Revision Date 28.03.2007 ADNR UN-No.: 1193; Class:3,Packaging group:fl, Fl;Description of the goods:METHYL ETHYL KETONE IMDG UN-No.: 1193; Class:3;Em S:F-E, S-D;Packaging group:11, Description of the goods:METHYL ETHYL KETONE ICAO/IATA UN-No. : 1193; Class:3;Packaging group:11,Description of the goods:Methyl ethyl ketone 15. Regulatory information Labelling Regulatory base 6715481EEC Symbol(s) F.:Highly flammable Xi.: Irritant R-phrase(s) R11:Highly flammable. R36:Irritating to eyes. R66:Repeated exposure may cause skin dryness or cracking. R67: Vapours may cause drowsiness and dizziness. S-phrase(s) S 2:Keep out of the reach of children. S 9:Keep container in a well-ventilated place. S16:Keep away from sources of ignition-No smoking. Hazardous components butanone; ethyl methyl ketone which must be listed on the label 16. Other information Full text of R-phrases referred to under sections 2 and 3 Print Date 28.03.2007 100000000637 6/7 sasoL 444 reaching new frontiers 4e Material Safety Data Sheet Methyl Ethyl Ketone Version 1.08 Revision Date 28.03.2007 Rll Highly flammable. R36 Irritating to eyes. R66 Repeated exposure may cause skin dryness or cracking. R67 Vapours may cause drowsiness and dizziness. All reasonable efforts were exercised to compile this MSDS in accordance with ISO 11014 and ANSIZ400.1.1993. The MSDS provides information regarding the health, safety and environmental hazards, at the date of issue, to facilitate the safe receipt, use and handling of the product in the workplace. Since Sasol and its subsidiaries cannot anticipate or control all conditions under which the product may be handled, used and received in the workplace, it remains the obligation of each user, receiver or handler to, prior to usage, review this MSDS in the context within which the product will be received, handled or used in the workplace. The user, handler or receiver must ensure that the necessary mitigating measures are in place as regards health and safety. This does not substitute the need or requirement for any relevant risk assessments to be conducted. It further remains the responsibility of the receiver, handler or user to communicate such information to all relevant parties that may beinvolved in the receipt, use or handling of the product. Although all reasonable efforts were exercised in the compilation of this MSDS, Sasol does not expressly warrant the accuracy or assume any liability for the incompleteness of the information contained herein or any advice given. The product is sold and risk passes in accordance with the specific terms and conditions of sale. The MSDS was created by:Aneshia(AA)Saban The MSDS was approved by: MSDS may be not approved Print Date 28.03.2007 100000000637 717 Science Lah .com o Chemicals&Laboratory Equipment Reactivity 0 Personal H Protection Material Safety Data Sheet Stoddard solvent MSDS Section 1: Chemical Product and Company Identification Product Name: Stoddard solvent Contact Information: Catalog Codes: SLS3688 Sciencelab.com, Inc. 14025 Smith Rd. CAS#: 8052-41-3 Houston, Texas 77396 RTECS: WJ8925000 US Sales: 1-800-901-7247 TSCA: TSCA 8(b) inventory: Stoddard solvent International Sales: 1-281-441-4400 Order Online: Sciencel-ab.com CI#: Not available. CHEMTREC (24HR Emergency Telephone), call: Synonym: 1-800-424-9300 Chemical Name: Not available. International CHEMTREC, call: 1-703-527-3887 Chemical Formula: Not available. For non-emergency assistance, call: 1-281-441-4400 Section 2: Composition and Information on Ingredients Composition: Name CAS# % by Weight Stoddard solvent 8052-41-3 100 Toxicological Data on Ingredients: Stoddard solvent LD50: Not available. LC50: Not available. Section 3: Hazards Identification Potential Acute Health Effects: Very hazardous in case of ingestion. Hazardous in case of skin contact (irritant), of eye contact(irritant), of inhalation. Potential Chronic Health Effects: Very hazardous in case of ingestion. Hazardous in case of skin contact(irritant), of eye contact(irritant), of inhalation. CARCINOGENIC EFFECTS: Not available. MUTAGENIC EFFECTS: Not available. TERATOGENIC EFFECTS: Not available. DEVELOPMENTAL TOXICITY: Not available. The substance is toxic to lungs, the nervous system, mucous membranes. Repeated or prolonged exposure to the substance can produce target organs damage. Section 4: First Aid Measures Eye Contact: Check for and remove any contact lenses. Do not use an eye ointment. Seek medical attention. Skin Contact: P. 1 After contact with skin, wash immediately with plenty of water. Gently and thoroughly wash the contaminated skin with running water and non-abrasive soap. Be particularly careful to clean folds, crevices, creases and groin. Cover the irritated skin with an emollient. If irritation persists, seek medical attention. Wash contaminated clothing before reusing. Serious Skin Contact: Wash with a disinfectant soap and cover the contaminated skin with an anti-bacterial cream. Seek medical attention. Inhalation: Allow the victim to rest in a well ventilated area. Seek immediate medical attention. Serious Inhalation: Evacuate the victim to a safe area as soon as possible. Loosen tight clothing such as a collar, tie, belt or waistband. If breathing is difficult, administer oxygen. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek medical attention. Ingestion: Do not induce vomiting. Loosen tight clothing such as a collar, tie, belt or waistband. If the victim is not breathing, perform mouth-to-mouth resuscitation. Seek immediate medical attention. Serious Ingestion: Not available. Section 5: Fire and Explosion Data Flammability of the Product: Flammable. Auto-Ignition Temperature: 210°C (410°F) Flash Points: CLOSED CUP: 38°C (100.4°F). Flammable Limits: LOWER: 0.8% UPPER: 5% Products of Combustion: Not available. Fire Hazards in Presence of Various Substances: Slightly flammable to flammable in presence of oxidizing materials. Explosion Hazards in Presence of Various Substances: Risks of explosion of the product in presence of mechanical impact: Not available. Risks of explosion of the product in presence of static discharge: Not available. Slightly explosive to explosive in presence of oxidizing materials. Fire Fighting Media and Instructions: Flammable liquid, insoluble in water. SMALL FIRE: Use DRY chemical powder. LARGE FIRE: Use water spray or fog. Cool containing vessels with water jet in order to prevent pressure build-up, autoignition or explosion. Special Remarks on Fire Hazards: Not available. Special Remarks on Explosion Hazards: Not available. Section 6: Accidental Release Measures Small Spill:Absorb with an inert material and put the spilled material in an appropriate waste disposal. Large Spill: Flammable liquid, insoluble in water. Keep away from heat. Keep away from sources of ignition. Stop leak if without risk. Absorb with DRY earth, sand or other non-combustible material. Do not get water inside container. Do not touch spilled material. Prevent entry into sewers, basements or confined areas; dike if needed. Eliminate all ignition sources. Call for assistance on disposal. Be careful that the product is not present at a concentration level above TLV. Check TLV on the MSDS and with local authorities. Section 7: Handling and Storage Precautions: p. 2 Keep away from heat. Keep away from sources of ignition. Ground all equipment containing material. Do not breathe gas/ fumes/vapour/spray. Wear suitable protective clothing In case of insufficient ventilation, wear suitable respiratory equipment If you feel unwell, seek medical attention and show the label when possible.Avoid contact with skin and eyes Storage: Flammable materials should be stored in a separate safety storage cabinet or room. Keep away from heat. Keep away from sources of ignition. Keep container tightly closed. Keep in a cool, well-ventilated place. Ground all equipment containing material. Keep container dry. Keep in a cool place. Section 8: Exposure Controls/Personal Protection Engineering Controls: Provide exhaust ventilation or other engineering controls to keep the airborne concentrations of vapors below their respective threshold limit value. Ensure that eyewash stations and safety showers are proximal to the work-station location. Personal Protection: Splash goggles. Lab coat.Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Gloves. Personal Protection in Case of a Large Spill: Splash goggles. Full suit. Vapor respirator. Boots. Gloves. A self contained breathing apparatus should be used to avoid inhalation of the product. Suggested protective clothing might not be sufficient; consult a specialist BEFORE handling this product. Exposure Limits: TWA: 100 (ppm)from ACGIH (TLV) TWA: 525 (mg/m3)from ACGIHConsult local authorities for acceptable exposure limits. Section 9: Physical and Chemical Properties Physical state and appearance: Liquid. Odor: Not available. Taste: Not available. Molecular Weight: Not available. Color: Clear Colorless. pH (1% soin/water): Not applicable. Boiling Point: Not available. Melting Point: Not available. Critical Temperature: Not available. Specific Gravity: 0.78 (Water= 1) Vapor Pressure: 2 mm of Hg (@ 20°C) Vapor Density: 5 (Air= 1) Volatility: Not available. Odor Threshold: 1 ppm Water/Oil Dist. Coeff.: Not available. tonicity (in Water): Not available. Dispersion Properties: Not available. Solubility: Insoluble in cold water. Section 10: Stability and Reactivity Data p. 3 Stability: The product is stable. Instability Temperature: Not available. Conditions of Instability: Not available. Incompatibility with various substances: Not available. Corrosivity: Non-corrosive in presence of glass. Special Remarks on Reactivity: Not available. Special Remarks on Corrosivity: Not available. Polymerization: No. Section 11: Toxicological Information Routes of Entry: Eye contact. Inhalation. Ingestion. Toxicity to Animals: LD50: Not available. LC50: Not available. Chronic Effects on Humans: The substance is toxic to lungs, the nervous system, mucous membranes. Other Toxic Effects on Humans: Very hazardous in case of ingestion. Hazardous in case of skin contact (irritant), of inhalation. Special Remarks on Toxicity to Animals: Not available. Special Remarks on Chronic Effects on Humans: Not available. Special Remarks on other Toxic Effects on Humans: Not available. Section 12: Ecological Information Ecotoxicity: Not available. BOD5 and COD: Not available. Products of Biodegradation: Possibly hazardous short term degradation products are not likely. However, long term degradation products may arise. Toxicity of the Products of Biodegradation: The products of degradation are more toxic. Special Remarks on the Products of Biodegradation: Not available. Section 13: Disposal Considerations Waste Disposal: Section 14: Transport Information DOT Classification: Class 3: Flammable liquid. Identification: : Petroleum distillate, n.o.s. (Stoddard solvent) : UN1268 PG: III Special Provisions for Transport: Not available. Section 15: Other Regulatory Information p. 4 Federal and State Regulations: Pennsylvania RTK: Stoddard solvent Massachusetts RTK: Stoddard solvent TSCA 8(b)inventory: Stoddard solvent Other Regulations: OSHA: Hazardous by definition of Hazard Communication Standard (29 CFR 1910.1200). Other Classifications: WHMIS (Canada): CLASS B-3: Combustible liquid with a flash point between 37.8°C (1007) and 93.3°C (200T). DSCL (EEC): R10-Flammable. R36/38- Irritating to eyes and skin. HMIS (U.S.A.): Health Hazard: 2 Fire Hazard: 2 Reactivity: 0 Personal Protection: h National Fire Protection Association (U.S.A.): Health: 2 Flammability: 2 Reactivity: 0 Specific hazard: Protective Equipment: Gloves. Lab coat.Vapor respirator. Be sure to use an approved/certified respirator or equivalent. Wear appropriate respirator when ventilation is inadequate. Splash goggles. Section 16: Other Information References: Not available. Other Special Considerations: Not available. Created: 10/11/2005 12A0 PM Last Updated: 05/21/2013 12:00 PM The information above is believed to be accurate and represents the best information currently available to us. However, we make no warranty of merchantability or any other warranty, express or implied, with respect to such information, and we assume no liability resulting from its use. Users should make their own investigations to determine the suitability of the information for their particular purposes. In no event shall ScienceLab.com be liable for any claims, losses, or damages of any third party or for lost profits or any special, indirect, incidental, consequential or exemplary damages, howsoever arising, even if ScienceLab.com has been advised of the possibility of such damages. P. 5 ENTRON-AE—SAFETY DATA SHEET(SDS) Document:2631-4, Issue Date:2-17-15 SAFETY DATA SHEET ENTRON-AE® Non-Flammable Asphalt Extraction Solvent 1. Product and Company Information: Product Name: ENTRON-AE Chemical Family: Akyl Bromide Product General Use: Non-Flammable Solvent for Asphalt Extractions and Other Industrial Uses Manufacturer: Reliance Specialty Products,Inc., 855 Morse Ave.,Elk Grove Village,IL 60007 Ph. 847-640-8923 www.relspec.com Emergency Telephone Number: CHEM-TEL 24 HOUR EMERGENCY RESPONSE USA and CANADA: Ph. (800)255-3924 Non-Emergency Telephone Number: Reliance Technical Support Dept.at 847-640-8923 2. Hazards Identification Signal Word Danger Symbol 1 Hazard May damage fertility(reduced sperm motility and increased estrous cycle length) Statements May cause cancer in animals-with unknown relevance to humans May cause damage to the central nervous system through prolonged or repeated over-exposure May cause serious eye irritation May cause respiratory irritation May cause skin irritation May cause drowsiness or dizziness Harmful to aquatic life—Do not dispose into public sewer or waterways Precautionary Keep away from heat/sparks/open flames/hot surfaces.-No smoking Statements Do not breathe dust/fume/gas/mist/vapors/spray Wear protective gloves/protective clothing/eye protection/face protection Avoid release to the environment IF ON SKIN(or hair):Take off immediately all contaminated clothing.Rinse skin with water/shower In case of fire:Use carbon dioxide,dry chemical powder,alcohol foam or polymer foam for extinction IF IN EYES:Rinse cautiously with water for several minutes.Remove contact lenses,if present and easy to do.Continue rinsing IF INHALED:Remove person to fresh air and keep comfortable for breathing Call a POISON CENTER or doctor/physician if you feel unwell Store in a well-ventilated place.Keep container tightly closed Dispose of contents/container in accordance with national and international Regulations Occupation Exposure Limits: See Section 8 of this SDS Additional Toxicological Information: See Section I I of this SDS OReliance Specialty Products,Inc.2004—2015 1 ENTRON-AE—SAFETY DATA SHEET(SDS) Document:2631-4, Issue Date:2-17-15 3. Composition and Ingredient Information Component CAS Number Weight Percentage n Propyl Bromide(stabilized) 106-94-5 >90.0% (synonym: 1-B romopropane) 1,2 Butylene Oxide 106-88-7 <2.0% (synonym: 1,2 Epoxybutane) Proprietary Components-Trade Secret N/A <8.0% 4. First Aid Measures Eye contact: Holding the eyelids apart,flush eyes promptly with copious flowing water for at least 20 minutes. Get medical attention immediately. Skin contact:Remove contaminated clothing. Wash skin thoroughly with mild soap and plenty of water for at least 15 minutes. Wash clothing before reuse.Get medical attention immediately. Inhalation: In case of mist inhalation or breathing fumes released from heated material,remove person to fresh air.Keep him quiet and warm.Apply artificial respiration if necessary and get medical attention immediately. Ingestion:If swallowed,wash mouth thoroughly with plenty of water.Get medical attention immediately. ------------------------------------------------------------------------------------ NOTE:Never give an unconscious person anything to drink -------------------------------------------------------------------------------------- Most important symptoms and effects of short term overexposure: Eye: Causes serious eye irritation Skin: Causes skin irritation Inhalation: May cause respiratory irritation. May cause drowsiness or dizziness Ingestion:Large doses or repeated intake of bromides may affect the central nervous system. Symptoms of short-term overexposure: Symptoms of short-term overexposure may include drowsiness,dizziness,muscular incoordination and respiratory depression. 5. Fire Fighting Measures FLASH POINT: NONE by ASTM D-56 TC NONE by ASTM D-92 COC NONE by ASTM D-93 TCC FLAMMABLE LIMITS: 3.0 to 9.0%by volume in air AUTO-IGNITION TEMPERATURE:490'C Extinguishing Media: Use dry chemical,chemical foam,or carbon dioxide as dictated by the surrounding circumstances. Special Fire Fighting Procedures: Wear NIOSH approved self-contained breathing apparatus(set on positive pressure mode)and personal protective equipment. Avoid skin and eyes contact in fire situations. Unusual Fire and Explosions Hazard:In fires,toxic and corrosive gases may be released. Vapor will form a flammable mixture in a narrow concentration range of 3.0%to 9.0%by volume in air. 6. Accidental Release Measures Contain spillage or leakage with dikes or absorbent material to prevent migration into sewer or waterway. Absorb spill with an inert material and place in a chemical waste container for disposal. For large spills,evacuate and ventilate the area. Wear self-contained breathing apparatus and recommended personal protective equipment. Observe government regulations. 7. Handling and Storage Store in well ventilated,cool,dry area.Store in original container only. Keep container closed when not in use.Minimize introduction of water or moisture into the product. OReliance Specialty Products,Inc.2004—2015 2 ENTRON-AE—SAFETY DATA SHEET(SDS) Document:2631-4, Issue Date:2-17-15 8. Exposure Controls and Personal Protection Weight Non-Governmental U.S.Federal Component Percentage Recommendations Workplace Exposure Limits/ Workplace Exposure Recommendations n Propyl Bromide(stabilized) >90.0% ACGIH TLV: A3,0.10 ppm OSHA PEL:Not Established CAS No. 106-94-5 ACGIH TLV-STEL:None OSHA STEL/Ceiling:Not Established (synonym: 1-Bromopropane) US EPA SNAP Program: 18 to 25 ppm 1,2 Butylene Oxide <2.0% ACGIH TLV:None OSHA PEL:Not Established CAS No. 106-88-7 ACGHI TLV-STEL:None OSHA STEL/Ceiling:Not Established (synonym: 1,2 Epoxybutane) US EPA SNAP Program:Not Applicable Proprietary Components-Trade <8.0% ACGIH TLV: 20 ppm OSHA PEL: 100 ppm Secret ACGHI TLV-STEL:None OSHA STELiCeiling:Not Established US EPA SNAP Program:Not Applicable RESPIRATORY PROTECTION: Use NIOSH approved organic vapor respirator if ventilation is not sufficient. Of particular concern is when filling,emptying,operating or maintaining your cleaning equipment and at other instances where there is a likelihood of inhalation of solvent vapors. VENTALATION AND PROPER EQUIPMENT CONTROLS: Exposure to the product can be minimized through use of appropriate ventilation and emission controls and proper equipment maintenance- CLOTHING/GLOVES: Wear safety glasses.Use of gloves is recommended.Viton or Silvershield gloves offer the best extended protection.Nitrile,neoprene,or butyl gloves offer less protection and should be used for incidental splash protection only.DO NOT use natural rubber gloves when handling this product. EYE PROTECTION:Always wear safety goggles or full face shield. WORK/HYGIENIC PRACTICES:Do not eat,drink,or smoke while working with this product.Launder soiled clothes. Provide emergency eye bath and safety shower. 9. Physical Properties FLASH POINT: NONE by ASTM D-56,D-92 and D-93 FLAMMABLE LIMITS: 3.0 to 9.0%by volume in air AUTO-IGNITION TEMPERATURE: 490'C APPEARANCE: clear liquid VAPOR PRESSURE: (mm.Hg @ 25°C): 139 ODOR:Ether/Alcohol Like RELATIVE VAPOR DENSITY: (Air=1):4.3 pH:6.5 to 7.5 SOLUBILITY IN WATER:Negligible(0.25 g/100ml) MELTING POINT/FREEZING POINT: -110'C BOILING POINT: (760 mm Hg): 160°F(71 °C) PARTION COEFFICIENT; N-OCTANOL/WATER: Not Determined EVAPORATION RATE: (n-Butyl Acetate= 1):4.5 DECOMPOSITION TEMPERATURE: Not Determined VISCOSITY: cps at 25°C: 0.5 SPECIFIC GRAVITY: (25/25°C,H2O= 1): 1.26 to 1.31 REACTIVITY IN WATER: Not Readily Hydrolyzed 10. Stability and Reactivity STABILITY: Stable under normal conditions. CONDITIONS TO AVOID:Avoid open flame,electric arc and other high energy ignition sources.Prolonged contact with free water may result in diminished stabilizer and corrosion. ©Reliance Specialty Products,Inc.2004—2015 3 ENTRON-AE—SAFETY DATA SHEET(SDS) Document:2631-4, Issue Date.2-17-15 INCOMPATIBILITY: Incompatible with strong alkalis,oxidizers,bases,reactive metals and natural rubber. HAZARDOUS DECOMPOSITION: Thermal decomposition produces carbon monoxide,carbon dioxide,and hydrogen bromide. HAZARDOUS POLYMERIZATION: Will not occur. 11. Toxicological Information n-Propel bromide LD50 Oral/Rat>2,000 mg/kg LD50 Dermal/Rat>2000 mg/kg LC50 Inhalation/Rat=72,306 mg/m' Chronic Toxicity: Chronic or Prolonged over-exposure may cause adverse affects to the liver,kidneys,reproductive system and central nervous system Reproductive: Mate:BMDL of reduced sperm motility FO at 282ppm-rat/inhalation* Female:LOAEL of increased estrous cycle length at 250ppm-rat/inhalation* *USEPA SNAP Proposal conclusions based on outcome of Wil(2001). Mutagenicity: Not mutagenic by the Ames Test Carcinogenicity: IARC:Not listed ACG1H: A3—Animal carcinogen with unknown relevance to humans Teratogenicity: NOEL is 100 ppm for maternal and fetal toxicity and for teratogenicity is 996 ppm(inhalation,rat, 6F'day,gestation day 6-I9) L2 Butylene Oxide LD50 Oral/Rat= 1,180 mg/kg LD50 Dermal/Rabbit= 1,760 mg/kg LC50 Inhalation/Rat—6,300 mg/m'—4 hours Carcenogeni city: IARC:213 Symptoms of Over-exposure: Short Term Over-exposure: Symptoms of short-term overexposure may include drowsiness,dizziness,muscular incoordination and respiratory depression. Long Term/Chronic Over-exposure: Long term chronic over-exposure may cause adverse effects in the liver,respiratory system, kidney,reproductive system and central nervous system. 12. Ecological Information Ozone Depletion Potential(ODP): The ODP of n-propyl bromide has been determined to be in the range of 0.006 to 0.013 Aquatic Toxicity: 96 Hour-LC50 Fish,23.3 mg/1(rainbow trout) 48 Hour—EC50,Daphnia magna 99.3 mg/I Mobility: Due to low affinity to soil and sediment(low Koc),expected to be mobile in soil Persistence and degradability: Not readily biodegradable. n Propyl Bromide was shown to degrade in water by hydrolysis with a half-live of 562 hours(23.4 days). Bio-accumulative Potential: Predicted BCF's are significantly below 2000,indicating a negligible potential for bioaccumulation or subsequent bio-magnification in the food chain. 13. Disposal Considerations Follow all Federal, State and Local governmental regulations.DO NOT flush into sanitary sewer or waterway. 14. Transportation Information CLASSIFICATION:Not regulated for transportation by US DOT or USPS PROPER SHIPPING NAMES:Cleaning Solvent Mixture &)Reliance Specialty Products,Inc.2004—2015 4 ENTRON-AE—SAFETY DATA SHEET(SDS) Document:2631-4, Issue Date:2-17-15 15. Regulatory Information TCSA: All of the components of this product are in the EPA TSCA inventory. NESHAP:N/A RCRA:N/A HAP:N/A SARA: Section 364(RQ):None of the components have a RQ Section 302(TPQ): None of the Components have a TPQ Section 313: The following components are subject to the reporting requirements of Section 313 of SARA Title III: 1,2 Butylene Oxide(106-88-7). CERCLA:RQ of 100 lbs.for 1,2,Butylene Oxide(CAS 106-88-7),Note:that an RQ of 100 Ibs at the component's weight%in composition requires approximately 1,500 gallons of ENTRON mixture to reach RQ's threshold. USEPA SNAP PROGRAM: - FINAL USE APPROVAL: USEPA SNAP Program Final Approval was received in May 2007 for use in Metal Cleaning, Electronics Cleaning and Precision Cleaning. - INTERIM USE AUTHORIZATION: USEPA SNAP Program interim authorization for use in the Use Sectors in Carriers, Adhesive Carriers and Aerosols was issued in 2003 pending a final determination by the SNAP Program for continued use in those Use Sectors. EEC(EINECS):Ingredients Listed CANADA(DSL): Ingredients Listed STATE REGULATION: Listed Ingredients: CA,MA,NJ,PA 16. Other Information HMIS RATING(Scale 0 to 4): HMIS Health 2 Flammability 1 0 Physical Hazards 0 *Chronic Hazard(Long-term health effects may result from repeated overexposure.) 0=Minimal Hazard, 1=Slight Hazard,2=Moderate Hazard,3=Serious Hazard,4=Severe Hazard Reliance Specialty Products,Inc.'s offers the information and opinions contained in this Safety Data Sheet as a guide to the physical characteristics and use of this Product and believe it to be accurate as of the date of this document. However,it is the responsibility of the user to establish the suitability of the Product for their particular application and to establish the conditions for safe use of the product and compliance with all applicable laws and regulations. Reliance Specialty Products,Inc. disclaims all warranties,express or implied,including merchantability,fitness for a particular purpose or of any other nature in connection with the opinions and information contained herein and the use of the Product. END OF SDS OReliance Specialty Products,Inc.2004-2015 5 x{ Material Safety Data Sheet 1 -Chemical Product and Company Identification Manufacturer: WD40 Company Address: 1061 Cudahy Place(92110) Chemical Name: Organic Mixture P.O. Box 80607 San Diego, California, USA Trade Name:WD-40 Bulk Liquid 92138-0607 Telephone: Product Use: Lubricant, Penetrant, Drives Out Emergency only: 1-888-324-7596(PROSAR) Moisture, Removes and Protects Surfaces Information: 1-888-324-7596 From Corrosion Chemical Spills: 1-800-424-9300 (Chemtrec) 1-703-527-3887(International Calls) MSDS Date Of Preparation: 3/11110 2—Hazards Identification Emergency Overview: DANGER! Harmful or fatal if swallowed. Combustible Liquid. If swallowed, may be aspirated and cause lung damage. May cause eye irritation. Avoid eye contact. Use with adequate ventilation. Keep away from heat, sparks and all other sources of ignition. Symptoms of Overexposure: Inhalation: High concentrations may cause nasal and respiratory irritation and central nervous system effects such as headache, dizziness and nausea. Intentional abuse may be harmful or fatal. Skin Contact: Prolonged and/or repeated contact may produce mild irritation and defatting with possible dermatitis. Eye Contact: Contact may be irritating to eyes. May cause redness and tearing. Ingestion: This product has low oral toxicity. Swallowing may cause gastrointestinal irritation, nausea, vomiting and diarrhea. This product is an aspiration hazard. If swallowed, can enter the lungs and may cause chemical pneumonitis, severe lung damage and death. Chronic Effects: None expected. Medical Conditions Aggravated by Exposure: Preexisting eye, skin and respiratory conditions may be aggravated by exposure. Suspected Cancer Agent: Yes No X 3 -Composition/Information on Ingredients Ingredient CAS# Weight Percent Aliphatic Hydrocarbon 64742-47-8 45-50 Petroleum Base Oil 64742-58-1 <25 64742-53-6 64742-56-9 64742-65-0 LVP Aliphatic Hydrocarbon 64742-47-8 12-18 Surfactant Proprietary <2 Non-Hazardous Ingredients Mixture <10 See Section 8 for Exposure Limits 4—First Aid Measures Ingestion (Swallowed): Aspiration Hazard. DO NOT induce vomiting. Call physician, poison control center or the WD-40 Safety Hotline at 1-888-324-7596 immediately. Page 1 of 4 Eye Contact: Flush thoroughly with water. Remove contact lenses if present after the first 5 minutes and continue flushing for several more minutes. Get medical attention if irritation persists. Skin Contact:Wash with soap and water. If irritation develops and persists, get medical attention. Inhalation (Breathing): If irritation is experienced, move to fresh air. Get medical attention if irritation or other symptoms develop and persist. 5—Fire Fighting Measures Extinguishing Media: Use water fog, dry chemical, carbon dioxide or foam. Do not use water jet or flooding amounts of water. Burning product will float on the surface and spread fire. Special Fire Fighting Procedures: Firefighters should always wear positive pressure self-contained breathing apparatus and full protective clothing. Cool fire-exposed containers with water. Unusual Fire and Explosion Hazards: Combustible liquid and vapor. Vapors are heavier than air and may travel along surfaces to remote ignition sources and flash back. 6—Accidental Release Measures Wear appropriate protective clothing (see Section 8). Eliminate all sources of ignition and ventilate area. Contain and collect liquid with an inert absorbent and place in a container for disposal. Clean spill area thoroughly. Report spills to authorities as required. 7—Handling and Storage Handling:Avoid contact with eyes. Avoid prolonged contact with skin. Avoid breathing vapors or aerosols. Use with adequate ventilation. Keep away from heat, sparks, hot surfaces and open flames. Wash thoroughly with soap and water after handling. Keep containers closed when not in use. Keep out of the reach of children. Storage: Store in a cool, well-ventilated area, away from incompatible materials. NFPA 30 Class II Liquid. 8— Exposure Controls/Personal Protection Chemical Occupational Exposure Limits Aliphatic Hydrocarbon 1200 mg/m3 TWA(manufacturer recommended) Petroleum Base Oil 5 mg 1m3 (inhalable)TWA 5 mg/m3 TWA OSHA PEL LVP Aliphatic Hydrocarbon 1200 mg/m3 TWA(manufacturer recommended) Surfactant None Established Non-Hazardous Ingredients I None Established The Following Controls are Recommended for Normal Consumer Use of this Product Engineering Controls: Use in a well-ventilated area. Personal Protection: Eye Protection: Avoid eye contact. Safety glasses or goggles recommended. Skin Protection: Avoid prolonged skin contact. Chemical resistant gloves recommended for operations where skin contact is likely. Respiratory Protection: None needed for normal use with adequate ventilation. For Bulk Processing or Workplace Use the Following Controls are Recommended Engineering Controls: Use adequate general and local exhaust ventilation to maintain exposure levels below that occupational exposure limits. Personal Protection: Eye Protection: Safety goggles recommended where eye contact is possible. Skin Protection: Wear chemical resistant gloves. Respiratory Protection: None required if ventilation is adequate. If the occupational exposure limits are exceeded, wear a NIOSH approved respirator. Respirator selection and use should be based on contaminant type, form and concentration. Follow OSHA 1910.134, ANSI Z88.2 and good Industrial Hygiene practice. Work/Hygiene Practices: Wash with soap and water after handling. Page 2 of 4 9—Physical and Chemical Properties Boiling Point: 361 -369°F (183 - Specific Gravity: 0.8—0.82 @ 60°F 187°C Solubility in Water: Insoluble pH: Not Applicable Vapor Pressure: 1 psi @38°C (100°F) Vapor Density: Greater than 1 ASTM D323 Percent Volatile: 70-75% VOC: 412 grams/liter 49.5%) Coefficient of Water/Oil Not Determined Appearance/Odor Light amber liquid/mild Distribution: odor Flash Point: 122°F (49°C) Tag Open Flammable Limits: LEL: 0.6% UEL: 8.0% Cup (Solvent Portion) Pour Point: -63°C (-81.4°F) ASTM Kinematic Viscosity: 2.79-2.96cSt @ 100°F D-97 10—Stability and Reactivity Stability: Stable Hazardous Polymerization: Will not occur. Conditions to Avoid: Avoid heat, sparks, flames and other sources of ignition. Incompatibilities: Strong oxidizing agents. Hazardous Decomposition Products: Carbon monoxide and carbon dioxide. 11 —Toxicological Information The oral toxicity of this product is estimated to be greater than 5,000 mg/kg based on an assessment of the ingredients. This product is not classified as toxic by established criteria. It is an aspiration hazard. None of the components of this product is listed as a carcinogen or suspected carcinogen or is considered a reproductive hazard. 12—Ecological Information No data is currently available. 13 -Disposal Considerations If this product becomes a waste, it would be expected to meet the criteria of a RCRA ignitable hazardous waste (D001). However, it is the responsibility of the generator to determine at the time of disposal the proper classification and method of disposal. Dispose in accordance with federal, state, and local regulations. 14—Transportation Information DOT Surface Shipping Description: Excepted from Hazmat(49CFR 173.150 (F)) in non-bulk packagings. Bulk Packagings: NA1993, Combustible Liquid, n.o.s. (contains Petroleum Distillates), PG III IMDG Shipping Description: UN1268, Petroleum Distillates, n.o.s. 3, PG III 15—Regulatory Information U.S. Federal Regulations: CERCLA 103 Reportable Quantity: This product is not subject to CERCLA reporting requirements, however, oil spills are reportable to the National Response Center under the Clean Water Act and many states have more stringent release reporting requirements. Report spills required under federal, state and local regulations. SARA TITLE III: Hazard Category For Section 311/312: Acute Health, Fire Hazard Section 313 Toxic Chemicals: This product contains the following chemicals subject to SARA Title III Section 313 Reporting requirements: None Section 302 Extremely Hazardous Substances(TPQ): None Page 3 of 4 EPA Toxic Substances Control Act(TSCA) Status: All of the components of this product are listed on the TSCA inventory California Safe Drinking Water and Toxic Enforcement Act(Proposition 65): This product does not contain chemicals regulated under California Proposition 65. VOC Regulations: This product complies with the consumer product VOC limits of CARB, the US EPA and states adopting the OTC VOC rules. Canadian Environmental Protection Act: One of the components is listed on the NDSL. All of the other ingredients are listed on the Canadian Domestic Substances List or exempt from notification. Canadian WHMIS Classification: Class B-3 (Combustible Liquid) This MSDS has been prepared according to the criteria of the Controlled Products Regulation (CPR) and the MSDS contains all of the information required by the CPR. 16—Other Information: HMIS Hazard Rating: Health— 1 (slight hazard), Fire Hazard—2 (moderate hazard), Reactivity—0 (minimal hazard) Revision Date: March 2010 Supercedes: January 2010 SIGNATURE: TITLE: Director of Global Quality Assurance REVISION DATE: March 2010 SUPERSEDES: August 2009 Page 4 of 4 MATERIAL SAFETY DATA SHEET X13/1 z Mousemilk Penetrating Oil PM fo V.S OSH ANSI,Caradai at4lsS Aratrefei atrkSm4 Indiu9wSfntderC,1S Z 725R2Wa aNE nV*n REACHR " , Y ON : PRODUCT PRODUCT NAME: MOUSemilk Penetrating Oil CHEMICAL FAMILY NAME: Oil Treatment PRODUCT USE: Oil Treatment U.N.DANGEROUS GOODS CLASS: See Section 14 SUPPLIERIMANUFACTURER'S NAME: Worldwide Filter,Inc ADDRESS: 1689 Abram Court San Leandro,CA 94577 USA BUSINESS PHONE: (510)483-5122 EMERGENCY PHONE: (800)535-5053 Infotrac Contract#79544 WEB SITE: www,mousemilk.com DATE OF PREPARATION: December 13,2011 DATE OF LAST REVISION: New EMERGENCY OVERVIEW:Product Description: This product is a colorless to light amber liquid with a sweet pungentodor. Health Hazards: Harmful if swallowed.Prolonged exposure can cause irritation to skin,eyes and respiratory tract. Flammability Hazards:This product is a Flammable Liquid. Reactivity Hazards: Negligible. Environmental Hazards: This product has not been Investigated for its environmental effects at this time. Emergency Considerations: Emergency responders must wear the proper personal protective equipment(and have appropriate fire-_suppression equipment)suitable for the situation to which they are responding. US DOT SYMBOLS CANADA(WHIM IS)SYMBOLS EUROPEAN and (GHS)Hazard Symbols aoT O Signal Word:Danger) EU LABELING AND CLASSIFICATION: Classification of the substance or mixture according to Regulation i;EC)No127212008 EC#203-625-9 Annex 1 Index#601-021-00-3 EC#200.661-7 Annex 1 Index#603-117-00-0 EC#203.550-1 Annex 1 Index#606-00400-4 EC#265-156-6 Annex 1 Index#649-466-00-2 This product meets the EU requirement of having less than 3% DMSO extract. According to European Directive 671548/EEC. Substances not listed either individually or in group entries must be self classified. GHS Classifications, Flammable Category 2 Reproductive Toxicity Category 1 Aspiration Toxicity Category 1 Skin Irritant Category 2 Eye Irritant Category 2 Acute Toxicity Category 4 STOT RE Category 2 STOT BE Category 3 December 2011 Page 1 of 8 MATERIAL SAFETY DATA SHEET Lsl»I Elements: Mousemilk Penetrating Oil Pictogram 4 Signal Ward:Dangerl Hazard Statement(s): H225:Highly flammable liquid and vapor H304:May be fatal if swallowed and enters airways H315:Causes skin irritation H318:Causes serious eye damage H319:Causes serious eye irritation H332:Harmful If inhaled H335:May cause respiratory irritation H336:May cause drowsiness or dizziness H361:Suspected of damaging fertility or the unborn chid H373:Causes damage to organs through prolonged or repeated exposure Precautionary Stasernent(s): P210:Keep away from heat/sparkslopen flames/hot surfaces.—No smoking P233:Keep container tightly dosed P243:Take precautionary measures against static discharge P260:Do not breath dusftme/gas/mist/vapo/spray P264:Wash skin after handling P281:Use personal protective equipment as required EU Hazard Classification Per Directive 19991451EC: [F)FLAMMABLE,[17 TOXIC,[Xn)HARMFUL,NJ IRRITANT Risk Phrases: R11:Highly flammable,R20:Harmful by inhalation,R48120:Harmful:danger of serious damage to health by prolonged exposure through inhalation,R3657138: Initafing to eyes, respiratory system and skin, R45:May cause cancer, R65: Harmful: may cause lung damage if swallowed, R66: Repeated exposure may cause skin dryness or cracking, R67: Vapors may cause dizziness or drowsiness. Safety phrases:$10:Keep away from sources of Ignition,S24/25:Avoid contact with skin and eyes,S26:In case of contact with eyes,rinse immediately with plenty of water and seek medical advice, S45:In case of accident or if you feet unwell,seek medical attention immediately,553:Avoid exposure. HEALTH HAZARDS OR RISKS FROM EXPOSURE: SYMPTOMS OF OVER-EXPOSURE BY ROUTE OF EXPOSURE The most significant route of over-exposure for this product is by inhalation,skin contact and eye contact. INHALATION: Vapors may be irritating to the respiratory tract. SKIN: Repeated or prolonged contact may cause skin Irritation. EYE CONTACT: Contact may severe irritation to eyes,resulting in redness,watering and pain. INGESTION: Ingestion may cause gastrointestinal irritation with nausea and diarrhea. HEALTH EFFECTS OR RISKS FROM EXPOSURE:An Explanation in Lay Terms. Over-exposure to this product may cause the fallowing health effects: ACUTE: Excessive exposure may result in eye, skin or respiratory irritation. Harmful if swallowed —possible aspiration hazard that could be fatal.Inhalation of vapors may cause dizziness or drowsiness. CHRONIC: Skin Dermatitis December 2011 Page 2 of 8 MATERIAL SAFETY DATA SHEET Mousemilk Penetrating Oil r �,:, T10N�l;1H�REDI�NTS HAZ RDOl1S CAS 0 6NECS a ICSC r Wr% HAZARD CLASSIFICATION; a1GREdENT3: .... RISK PHRAsEs- HP2ARD CLASSIFICATION:[FIFiammable,Repr.Cat Toluene 109-68-3 203-625-9 0076 50-60% 3,P(n)Harmful,Pq Irritant RISK PHRASES:R11,tT63,R4&20,R65 R38 R67 HAZARD CLASSIFICATION:[FIFFammable,p0] Isopropyl 99 67-63-0 200-661-7 0554 1-10% Irritant RISK PHRASES:Rit,R36,R87 HAZARD CLASSIFICATION:[F]Flammable,prnl Methyl IsobuAyl Ketone 108-10.1 203550-1 0511 1-10% Harmful,[xq Irritant RISK PHRASES:RI 1 R20,836137,Free Distillates(petroleum), Light CLASSIFICATION:Cam.Cat 2,117 TOXIC Severely Hytlrotreeted LlpM 61742-538 288-758-8 Not Listed 35-45% N Mhernc I I RISK PHRASES:845 Balance of other Ingredients are non-hazardous or less than 1%in concentration(or 0.1%for mrctnogens,reproductive towns,or respiratory sernifters). NOTE: ALL WHMIS required information Is included In appropriate sections based on the ANSI Z400.1-2004 formal.This product has been classified In accordance with the hazard criteria of the CPR and the MSDS contains all the information required by the CPR, EU Directives and the Japanese Industrial Standard JISZ 7250:2000. Sea Sec Jon 2 for full text of Ingredient Risk Phrases and Safety Phrases. � Nr -4 its INHALATION: If chemical is inhaled,or breathing is difficult, remove victim to fresh air. If necessary,use aR t-icial respiration to support vital functions.Seek medical attention. SKIN: Wash contacted area with soap and water. Remove exposed or contaminated clothing,taking care not to contaminate eyes.Seek medical attention H irritation develops and persists. EYE CONTACT: If chemical contacts the eyes,open victim's eyes while under gentle running water. Use sufficient force to open eyelids. Have victim"roll'eyes. Minimum flushing is for 15 minutes. Remove nontaet lenses,If wom.Seek medical attention If irritation persists, INGESTION: If chemical Is swallowed,call physician or poison control center for most current information. If professional advice is not available,do not Induce vomiting. Never induce vomiting or give diluente(milk or water)to someone who is unconscious,having convulsions,or who cannot swallow, Victims of chemical exposure must be taken for medical attention- Rescuers should be taken for medical attention,if necessary. Take a copy of the label and MSDS with the victim to the health professional. MEDICAL CONDITIONS AGGRAVATED BY EXPOSURE:Skin,eye or respiratory disorders may be aggravated by prolonged overexposures to this product RECOMMENDATIONS TO PHYSICIANS: Treat symptoms and reduce over-exposure. a FLASH PONT: >40°F(>4.44°C)Toluene AUTOIGNITION TEMPERATURE: Not established FLAMMABLE LIMITS(in air by volume,°h): Lower(LEL): 1.1% Upper(LIEU: 7.1% FIRE EXTINGUISHING MATERIALS: Dry chemical,carbon dioxide,foam. Water spray may be used to keep fire exposed containers cool,dilute spills to non-flammable mixtures. UNUSUAL FIRE AND EXPLOSION HAZARDS: Above flash point,vapor air mixtures are explosive within flammable limits noted above.Vapor can flow along surfaces to distant ignition sources and flash back. Combustion products include carbon monoxide and carbon dioxide. Explosion Sensitivity to Mechanical Impact: Not Sensitive. Explosion Sensitivity to Static Dischame: Sensitive. December 2011 Page 3 of 8 MATERIAL SAFETY DATA SHEET Mousemilk Penetrating Oil SPECIAL FIRE-FIGHTING PROCEDURES: Structural fire-fighters must wear Self-Contained Breathing Apparatus and full protective equipment. NFPA RATING SYSTEM MMIS RATING SYSTEM Flammability HAZARDOUS MATERIAL 10 ON SYSTEM He88h 0 Reactivity PHYSICAL HAZARD (YELLOY1n 0 PROTECTIVE EQUIPMENT EYES RESPIRATORY I HAND$ BOGY �a�r See 0 See Sert.a Seq a Other For RSUtix InGuWial UeeaM Hendl A iWioee HazaM_Scale: 0-MnImal 1=Slight 2=Moderate 3=Serious 4-Severe '=Chronic hazard SPILL RESPONSE: Evacuate unprotected personnel from the area.Maintain adequate ventilation.Follow personal protective equipment recommendations found in section 8.Contain and recover liquid if possible.Use non-sparking tools and equipment. Cover or absorb spilled liquid with sand,earth or other inert material.Clean up spill immediately and place in appropriate containers.Do not discharge to sewers and surface waters.Notify authorities if entry occurs.Remove all sources of ignition. Dispose of In accordance with applicable Federal,State,and local regulatory procedures V-0 WORK PRACTICES AND HYGIENE PRACTICES: As with all chemicals,avoid getting this product ON YOU or IN YOU.Wash thoroughly after handling this product Do not eat,drink,smoke,or apply cosmetics while handling this product. Keep locked up. Keep away from heat.Keep away from sources of ignition.Ground all equipment containing material.Do not ingest Do not breathe gas/fumes/vapor/spray. Wear suitable protective clothing.If Ingested,seek medical advice immediately and show the container or the label. Avoid contact with skin and eyes.Keep away from incompatibles such as oxidizing agents STORAGE AND HANDLING PRACTICES: Store in a segregated and approved area(flammables area).Keep container in a cool,well-ventilated area.Keep container tightly closed and sealed until ready for use.Keep away from direct sunlight and heat and avoid all possible sources of ignition (spark or flame). EXPOSURE LIMITS/GUIDELINES: - Based u on Above listed in redients Component Nave CAS Number ACGIH OSHA NIOSH WEEL TLV PEL Toluene 108-88-3 ZO ppm 200 ppm 100 pLxn 50 ISO 89 67-03-0 200 ppm 400 ppm 400 ppm Nat Listen Methyl Isobutyl Ketone 108-10.1 50 ppm 100 ppm SO ppm Not Listed Diatillates (petroleum),Severely HydMireated light 84742-536 5 mgM1e 5 mg/m, S mglm' Not Listed Napbthenic December 2011 Page 4 of 8 MATERIAL SAFETY DATA SHEET Mousemilk Penetrating Oil Currentty, International exposure limits are not established for the components of this product.Please check with competent authority in each country for the most recent limits in place. VENTILATION AND ENGINEERING CONTROLS: Use with adequate ventilation to ensure exposure levels are maintained below the limits provided above. Use local exhaust ventilation, and process enclosure if necessary, to control airborne vapor. Ensure eyewash/safety shower stations are available near areas where this product is used. RESPIRATORY PROTECTION: A NIOSH approved air-purifying respirator equipped with organic vapor/acid gas cartridge.Use supplied air if hydrogen sulphide is present. Use supplied air respiratory protection if Oxygen levels are below 19.5%,or unknown,during emergency response to a release of this product.If respiratory protection is needed,use only protection authorized in the U.S. Federal OSHA Standard(29 CFR 1910.134),applicable U.S.State regulations,or the Canadian CSA Standard 294.4.93 and applicable standards of Canadian Provinces.Oxygen levels below 19.16.33%are considered IDLH by OSHA. In such atmospheres,use of a full-facepiece pressureldemand SCBA or a full facepiece,supplied air respirator with auxiliary self-contained air supply is required under OSHA's Respiratory Protection Standard(1910.134-1998). EYE PROTECTION: Splash goggles or safety glasses wig side shields recommended. if necessary, refer to U.S. OSHA 29 CFR 1910.133, Canadian Standards,and the European Standard EN766,Australian Standards,or relevant Japanese Standards, HAND PROTECTION: Compatible protective gloves recommended, Wash hands after removing gloves. If necessary, refer to U.S. OSHA 29 CFR 1910.138, the European Standard DIN EN 374, the appropriate Standards of Canada, Australian Standards, or relevant Japanese Standards. BODY PROTECTION: Use body protection appropriate for task, If necessary, refer to appropriate Standards of Canada, or appropriate Standards of the EU, Australian Standards,or relevant Japanese Standards. If a hazard of injury to the feet exists due to falling objects, rolling objects,where objects may pierce the soles of the feet or where employee's feet may be exposed to electrical hazards,use foot protection,as described in U.S.OSHA 29 CFR 1910,138. C/,�.PFtO�ERTIES` VAPOR DENSITY(AIR-1): 3.2 BOILING POINT: 231-232°F FREEZINGIMELTING POINT(@ 10 psig): Not Established SPECIFIC GRAVITY(air=1)@ 70°F(21.11C): 0.725 PH: Not Established SOLUBILITY IN WATER: Negligible EVAPORATION RATE(nBuAc=1): 1.9 ODOR THRESHOLD: Mild VAPOR PRESSURE: 22 mmHg @ 20°C APPEARANCE,ODOR AND COLOR: This product is a colorless to light amber colored liquid with a sweet,pungent odor. VOC% 394 Grams per Liter AW STABILITY: Stable DECOMPOSITION PRODUCTS: When heated to decomposition,oxides of carbon and toxic fumes are emitted. CONDITIONS TO AVOID: Incompatible materials and ignition sources MATERIALS WITH WHICH Oxidizing agents,acids and bases,alkali metals,aldehydes and SUBSTANCE IS INCOMPATIBLE: halogens which can generate heat,fires,explosions and release toxic fumes. HAZARDOUS POLYMERIZATION: Will not occur. December 2011 Page 6 of 8 MATERIAL SAFETY DATA SHEET Mousemiik Penetrating Oil !—*4k. x i p a� r o A�rtox TOXICITY DATA: ACUTE ORAL TOXICITY: Isopropyl 99 LD50=5,045 mg/kg Rat Methyl Isobutyl Ketone LD50=2,080 mg/kg Rat Toluene LD50=5,000 mg/kg Rat Hydrotreated petroleum distillates LD50=>5,000 mg/kg Rat ACUTE INHALATION TOXICITY: Isopropyl 99 LC50=15,000 ppm 8/Hr Rat Methyl Isobutyl Ketone LC50= 10,000 ppm 4/Hr Guinea pig Toluene LC50=8,000 ppm 4/Hr Rat SUSPECTED CANCER AGENT: The components of these products are not listed as carcinogenic by National Toxicology Program, I.A.R.C. or OSHA tracking the carcinogenic potential of chemical compounds.CAS#64742-53-6 is classified per EU Directive 671548/EEC as a carcinogen,category 2,however this material meets the requirement of having less than 3%DMSO extract IRRITANCY OF PRODUCT: This product may irritate skin,respiratory system and eyes SENSITIZATION OF PRODUCT: This product is not a sensitizer. REPRODUCTIVE TOXICITY INFORMATION: Listed below is information concerning the effects of this product on the human reproductive system.Mutacenicity:Has not been reported to cause mutagenic effects in humans.Embryotoxicity:Has not been reported to cause embryotoxic effects in humans.Teratogenicihr: Has not been reported to cause teratogehic effects in humans. Reproductive Toxicity: Has not been reported to cause adverse reproductive effects in humans. A mutagan is a chemical which causes permanent changes to genetic material(ONA).such that the changes will propagate through generation lines.An embrvotoxin is a chemical which causes damage to a developing embryo(i.e. within the first eight weeks of pregnancy in humans),but the damage does not propagate across generational lines.A teretogen is a chemical which causes damage to a developing fetus,but the damage does not propagate across generational lines.A reproductive toxin is any substance which interferes in anyway with the reproductive process. BIOLOGICAL EXPOSURE INDICES(BEls): Currently,Biological Exposure Indices(BEIs)have not been determined for this product. . ... NFt�iR11�►-WN ALL WORK PRACTICES MUST BE AIMED AT ELIMINATING ENVIRONMENTAL CONTAMINATION.+ ENVIRONMENTAL FATE: This product has not been investigated for its environmental effects at this time. ENVIRONMENTAL TOXICITY: In water this substance volatilizes and biodegrades. Biodegradation is possible within 90 to 120 days in aerobic environments at temperatures above 70°F. PREPARING WASTES FOR DISPOSAL: Waste disposal must be in accordance with appropriate Federal, State, and local regulations,those of Canada,Australia, EU Member States and Japan. RCRA WASTE CODE:D001,U161, U220 EU WASTE CODE:13 07 03 December 2011 Page 6 of 8 MATERIAL SAFETY DATA SHEET Mousemilk Penetrating Oil '01W � Try US DOT.IATA.IMO.ADR: THIS PRODUCT IS HAZARDOUS AS DEFINED BY THE U.S.DEPARTMENT OF TRANSPORTATION. PROPER SHIPPING NAME: Flammable Liquid,n.o.s. (Toluene, Isopropanol,Methyl Isobutyl Ketone) HAZARD CLASS NUMBER Class 3 Flammable and DESCRIPTION: UN IDENTIFICATION UN1993 NUMBER: PACKING GROUP: PGIII DOT LABELS)REQUIRED: Flammable MARINE POLLUTANT: This product is not classified by the DOT as a Marine Pollutant(as defined by 49 CFR 172.101,Appendix B). U.S.DEPARTMENT OF TRANSPORTATION(DOT)SHIPPING REGULATIONS: This product is classified as dangerous goods,per U.S.DOT regulations,under 49 CFR 172.101. TRANSPORT CANADA TRANSPORTATION OF DANGEROUS GOODS REGULATIONS: This product is classified as Dangerous Goods,per regulations of Transport Canada. INTERNATIONAL AIR TRANSPORT ASSOCIATION(IATA): This product is classified as Dangerous Goods,by rules of IATA: For Domestic Air this product may be shipped as an ORM-D in limited Quantities of less than 66 pounds. For Intemational Air shipments less than 1 pint this product can ship as Comsumer Commodity,Class 9,ID8000 For International Air shipments larger than 1 pint this product must ship as Flammable Liquid,n.o.s.,Class 3,PGIII INTERNATIONAL MARITIME ORGANIZATION(IMO)DESIGNATION: This product is classified as Dangerous Goods by the International Maritime Organization. For Ocean shipments this product must ship as a Flammable Liquid,n.o.s., Class 3 PGIII EUROPEAN AGREEMENT CONCERNING THE INTERNATIONAL CARRIAGE OF DANGEROUS GOODS BY ROAD(ADR): This product is classified by the United Nations Economic Commission for Europe to be dangerous goods. FOB ac UNITED STATES REGULATIONS SARA REPORTING This product is not subject to the reporting requirements of Sections 302, 304 and REQUIREMENTS 313 of Title III of the Superfund Amendments and Reauthorization Act., as follows: SARA 313 Reporting—Toluene CAS#108-88-3 and Methyl Isobutyl Ketone CAS# 108-10-1 TSCA All components in this product are listed on the U S Toxic Substances Control Act (TSCA)inventory of chemicals. SARA 3111312: Acute Health: Yes Chronic Health: No Fire: Yes Reactivity: No U.S.SARA THRESHOLD PLANNING QUANTITY: There are no specific Threshold Planning Quantities for this gas, The default Federal MSDS submission and inventory requirement filing threshold of 10,000 lb(4,540 kg)may apply, per 40 CFR 370.20. U.S.CERCLA REPORTABLE QUANTITY(RQ): Toluene CAS# 108-88-3 1,000 lbs., Methyl Isobutyl Ketone CAS# 108-10-1 5,000 lbs. U.S.STATE REGULATORY INFORMATION: This product not listed. CALIFORNIA SAFE DRINKING WATER AND TOXIC ENFORCEMENT ACT(PROPOSITION 65): This product does contain a component above the 0.1%level which is listed as a California Proposition 65 chemical. WARNINGI This product contains an ingredient that is known to the State of California to cause cancer or reproductive harm. December 2011 Page 7 of 8 MATERIAL SAFETY DATA SHEET Mousemilk Penetrating Oil CANADIAN REGULATIONS: CANADIAN DSL/NDSL INVENTORY STATUS:All of the components of this product are on the DSL Inventory CANADIAN ENVIRONMENTAL PROTECTION ACT(CEPA)PRIORITIES SUBSTANCES LISTS:No component of this product is on the CEPA First Priorities Substance Lists. CANADIAN WHMIS CLASSIFICATION and SYMBOLS: This product is classified as a Class B Division 2 Flammable Liquid and Class D Division 2B Materials having other toxic effects as per the Controlled Product Regulations EUROPEAN ECONOMIC COMMUNITY INFORMATION: EU LABELING AND CLASSIFICATION: Classification of the substance or mixture according to Regulation(EC)Not 27212008.See section 2 for details. AUSTRALIAN INFORMATION FOR PRODUCT: AUSTRALIAN INVENTORY OF CHEMICAL SUBSTANCES(AICS)STATUS: All components of this product are listed on the AICS. STANDARD FOR THE UNIFORM SCHEDULING OF DRUGS AND POISONS: Nat applicable. JAPANESE INFORMATION FOR PRODUCT: JAPANESE MINISTER OF INTERNATIONAL TRADE AND INDUSTRY(MITI)STATUS: The components of this product are not listed as Class I Specified Chemical Substances, Class II Specified Chemical Substances,or Designated Chemical Substances by the Japanese MITI. INTERNATIONAL CHEMICAL INVENTORIES: Listing of the components on individual country Chemical Inventories is as follows: Listed Asia-Pac: Listed Australian Inventory of Chemical Substances(AICS): Listed Korean Existing Chemicals List(ECL): Japanese Existing National Inventory of Chemical Substances(ENCS): Listed Philippines Inventory if Chemicals and Chemical Substances(PICCS): Listed Swiss Giftllste List of Toxic Substances: Listed U.S.TSCA: Listed PREPARED BY: Paul Eigbrett MSDS Authoring Services Disclaimer:The information in this MSDS relates to the product as sold,and to the best of our knowledge,such information is believed to be accurate and reliable at the time this document was prepared. However,no representation,warranty,or guarantee,either expressed or implied,is made as to its accuracy,reliability,or completeness. It is the responsibility of the user of this product to determine if this product is suitable for their intended purpose,to include both safety and regulatory perspectives. December 2011 Page 6 of 8