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Home My WebLink AboutCO2019-2635 Aluminum Chloride Hexahydrate Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 09/27/2007 Revision date: 06/20/2013 Supersedes: 02/10/2011 Version: 1.0 06/20/2013 EN (English) Page 1 SECTION 1: Identification of the substance/mixture and of the company/undertaking 1.1. Product identifier Product form : Substance Substance name : Aluminum Chloride Hexahydrate CAS No : 7784-13-6 Product code : LC10810 Formula : AlCl3·6H2O 1.2. Relevant identified uses of the substance or mixture and uses advised against Use of the substance/mixture : For laboratory and manufacturing use only. 1.3. Details of the supplier of the safety data sheet LabChem Inc Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court 16063 Zelienople, PA - USA T 412-826-5230 - F 724-473-0647 1.4. Emergency telephone number Emergency number : CHEMTREC: 1-800-424-9300 or 011-703-527-3887 SECTION 2: Hazards identification 2.1. Classification of the substance or mixture GHS-US classification Skin Irrit. 2 H315 Eye Irrit. 2A H319 STOT SE 3 H335 Aquatic Acute 3 H402 2.2. Label elements GHS-US labelling Hazard pictograms (GHS-US) : GHS07 Signal word (GHS-US) : Warning Hazard statements (GHS-US) : H315 - Causes skin irritation H319 - Causes serious eye irritation H335 - May cause respiratory irritation H402 - Harmful to aquatic life Precautionary statements (GHS-US) : P261 - Avoid breathing dust, fume P264 - Wash exposed skin thoroughly after handling P271 - Use only outdoors or in a well-ventilated area P273 - Avoid release to the environment P280 - Wear protective gloves, eye protection P302+P352 - IF ON SKIN: Wash with plenty of soap and water P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P312 - Call a POISON CENTER/doctor/…/if you feel unwell P332+P313 - If skin irritation occurs: Get medical advice/attention P337+P313 - If eye irritation persists: Get medical advice/attention P362 - Take off contaminated clothing P403+P233 - Store in a well-ventilated place. Keep container tightly closed P405 - Store locked up P501 - Dispose of contents/container to comply with local, state and federal regulations 2.3. Other hazards Other hazards not contributing to the classification : None. 2.4. Unknown acute toxicity (GHS US) No data available Aluminum Chloride Hexahydrate Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 06/20/2013 EN (English) 2/7 SECTION 3: Composition/information on ingredients 3.1. Substances Substance type : Mono-constituent Name Product identifier % GHS-US classification Aluminum Chloride Hexahydrate (Main constituent) (CAS No) 7784-13-6 100 Skin Irrit. 2, H315 Eye Irrit. 2A, H319 STOT SE 3, H335 Aquatic Acute 3, H402 Full text of H-phrases: see section 16 3.2. Mixture Not applicable SECTION 4: First aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). First-aid measures after inhalation : Remove to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER/doctor/physician if you feel unwell. First-aid measures after skin contact : Wash with plenty of soap and water. Wash contaminated clothing before reuse. If skin irritation occurs: Get medical advice/attention. First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. If eye irritation persists: Get medical advice/attention. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Obtain emergency medical attention. 4.2. Most important symptoms and effects, both acute and delayed Symptoms/injuries after inhalation : May cause respiratory irritation. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms/injuries after eye contact : Causes serious eye irritation. Symptoms/injuries after ingestion : Nausea. Vomiting. Diarrhoea. Chronic symptoms : No specific information available. 4.3. Indication of any immediate medical attention and special treatment needed Obtain medical assistance. SECTION 5: Firefighting measures 5.1. Extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Special hazards arising from the substance or mixture Fire hazard : Not flammable. Explosion hazard : Not applicable. Reactivity : Thermal decomposition generates : Corrosive vapours. 5.3. Advice for firefighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Avoid (reject) fire-fighting water to enter environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. Other information : Not applicable. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures General measures : Use chemically protective clothing. 6.1.1. For non-emergency personnel Protective equipment : Wear chemically protective gloves, lab coat or apron to prevent prolonged or repeated skin contact. Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. Avoid release to the environment. Aluminum Chloride Hexahydrate Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 06/20/2013 EN (English) 3/7 6.3. Methods and material for containment and cleaning up For containment : Take account of toxic/corrosive precipitation water. Methods for cleaning up : On land, sweep or shovel into suitable containers. Minimize generation of dust. Store aways from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapour. Avoid breathing dust, fume. Use only outdoors or in a well-ventilated area. Hygiene measures : Wash exposed skin thoroughly after handling. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep only in the original container in a cool, well ventilated place away from : incompatible materials. Keep container tightly closed. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. Packaging materials : Do not store in corrodable metal. 7.3. Specific end use(s) No additional information available SECTION 8: Exposure controls/personal protection 8.1. Control parameters 8.2. Exposure controls Appropriate engineering controls : Emergency eye wash fountains and safety showers should be available in the immediate vicinity of any potential exposure. Provide adequate general and local exhaust ventilation. Personal protective equipment : Avoid all unnecessary exposure. Hand protection : Wear protective gloves. Eye protection : Chemical goggles or safety glasses. Skin and body protection : Wear suitable protective clothing. Respiratory protection : Wear appropriate mask. Environmental exposure controls : Avoid release to the environment. Other information : Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Solid Molecular mass : 241.43 g/mol Colour : Colourless. Odour : characteristic. Odour threshold : No data available pH : No data available pH solution : 2.5 - 3.5 20°C Relative evaporation rate (butylacetate=1) : No data available Melting point : 100 °C Freezing point : No data available Boiling point : 182 °C Flash point : No data available Self ignition temperature : No data available Decomposition temperature : No data available Flammability (solid, gas) : No data available Vapour pressure : 1 hPa 100°C Relative vapour density at 20 °C : No data available Relative density : No data available Density : 2.398 g/cm³ Aluminum Chloride Hexahydrate Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 06/20/2013 EN (English) 4/7 Solubility : Soluble in water. Soluble in ether. Soluble in ethanol. Soluble in glycerol. Water: 111 g/100ml Ethanol: 25 g/100ml Log Pow : No data available Log Kow : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosive properties : No data available. Oxidising properties : No data available. Explosive limits : No data available 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity Thermal decomposition generates : Corrosive vapours. 10.2. Chemical stability Hygroscopic. 10.3. Possibility of hazardous reactions Not established. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong oxidizers. Strong bases. 10.6. Hazardous decomposition products fume. Hydrogen chloride. SECTION 11: Toxicological information 11.1. Information on toxicological effects Acute toxicity : Not classified Aluminum Chloride Hexahydrate ( \f )7784-13-6 LD50 oral rat 3311 mg/kg Skin corrosion/irritation : Causes skin irritation. Serious eye damage/irritation : Causes serious eye irritation. Respiratory or skin sensitisation : Not classified Germ cell mutagenicity : Not classifiedBased on available data, the classification criteria are not met Carcinogenicity : Not classified Reproductive toxicity : Not classifiedBased on available data, the classification criteria are not met Specific target organ toxicity (single exposure) : May cause respiratory irritation. Specific target organ toxicity (repeated exposure) : Not classifiedBased on available data, the classification criteria are not met Aspiration hazard : Not classifiedBased on available data, the classification criteria are not met Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. Symptoms/injuries after inhalation : May cause respiratory irritation. Symptoms/injuries after skin contact : Causes skin irritation. Symptoms/injuries after eye contact : Causes serious eye irritation. Symptoms/injuries after ingestion : Nausea. Vomiting. Diarrhoea. Chronic symptoms : No specific information available. SECTION 12: Ecological information 12.1. Toxicity Ecology - water : Harmful to aquatic life. Aluminum Chloride Hexahydrate (7784-13-6) LC50 fishes 1 27.1 mg/l EC50 Daphnia 1 27.3 mg/l Aluminum Chloride Hexahydrate Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 12.2. Persistence and degradability Aluminum Chloride Hexahydrate (7784-13-6) Persistence and degradability Not established. 12.3. Bioaccumulative potential Aluminum Chloride Hexahydrate (7784-13-6) Bioaccumulative potential Not established. 12.4. Mobility in soil No additional information available 12.5. Other adverse effects Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Waste treatment methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to comply with local, state and federal regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information In accordance with ADR / RID / ADNR / IMDG / ICAO / IATA 14.1. UN number UN-No.(DOT) : 1726 DOT NA no. UN1726 14.2. UN proper shipping name DOT Proper Shipping Name : Aluminum chloride, anhydrous Department of Transportation (DOT) Hazard Classes : 8 - Class 8 - Corrosive material 49 CFR 173.136 Hazard labels (DOT) : 8 - Corrosive substances Packing group (DOT) : II - Medium Danger DOT Special Provisions (49 CFR 172.102) : IB8 - Authorized IBCs: Metal (11A, 11B, 11N, 21A, 21B, 21N, 31A, 31B and 31N); Rigid plastics (11H1, 11H2, 21H1, 21H2, 31H1 and 31H2); Composite (11HZ1, 11HZ2, 21HZ1, 21HZ2, 31HZ1 and 31HZ2); Fiberboard (11G); Wooden (11C, 11D and 11F); Flexible (13H1, 13H2, 13H3, 13H4, 13H5, 13L1, 13L2, 13L3, 13L4, 13M1 or 13M2). IP2 - When IBCs other than metal or rigid plastics IBCs are used, they must be offered for transportation in a closed freight container or a closed transport vehicle. IP4 - Flexible, fiberboard or wooden IBCs must be sift-proof and water-resistant or be fitted with a sift-proof and water-resistant liner. T3 - 2.65 178.274(d)(2) Normal............. 178.275(d)(2) TP33 - The portable tank instruction assigned for this substance applies for granular and powdered solids and for solids which are filled and discharged at temperatures above their melting point which are cooled and transported as a solid mass. Solid substances transported or offered for transport above their melting point are authorized for transportation in portable tanks conforming to the provisions of portable tank instruction T4 for solid substances of packing group III or T7 for solid substances of packing group II, unless a tank with more stringent requirements for minimum shell thickness, maximum allowable working pressure, pressure-relief devices or bottom outlets are assigned in which case the more stringent tank instruction and special provisions shall apply. Filling limits must be in accordance with portable tank special provision TP3. Solids meeting the definition of an elevated temperature material must be transported in accordance with the applicable requirements of this subchapter. DOT Packaging Exceptions (49 CFR 173.xxx) : 154 DOT Packaging Non Bulk (49 CFR 173.xxx) : 212 DOT Packaging Bulk (49 CFR 173.xxx) : 240 14.3. Additional information Other information : No supplementary information available. Overland transport No additional information available 06/20/2013 EN (English) 5/7 Aluminum Chloride Hexahydrate Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Transport by sea DOT Vessel Stowage Location : A - The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a passenger vessel. DOT Vessel Stowage Other : 40 - Stow ‘‘clear of living quarters’’ Air transport DOT Quantity Limitations Passenger aircraft/rail (49 CFR 173.27) : 15 kg DOT Quantity Limitations Cargo aircraft only (49 CFR 175.75) : 50 kg SECTION 15: Regulatory information 15.1. US Federal regulations Aluminum Chloride Hexahydrate (7784-13-6) Listed on the United States TSCA (Toxic Substances Control Act) inventory SARA Section 311/312 Hazard Classes Immediate (acute) health hazard 15.2. International regulations CANADA Aluminum Chloride Hexahydrate (7784-13-6) WHMIS Classification Class D Division 2 Subdivision B - Toxic material causing other toxic effects EU-Regulations No additional information available Classification according to Regulation (EC) No. 1272/2008 [CLP] Not classified Classification according to Directive 67/548/EEC or 1999/45/EC Not classified 15.2.2. National regulations No additional information available 15.3. US State regulations Aluminum Chloride Hexahydrate(7784-13-6) State or local regulations U.S. - Minnesota - Chemicals of High Concern U.S. - Pennsylvania - RTK (Right to Know) List SECTION 16: Other information Indication of changes : Revision - See : *. Other information : None. Full text of H-phrases: see section 16: ------ Aquatic Acute 3 Hazardous to the aquatic environment — AcuteHazard, Category 3 ------ Eye Irrit. 2A Serious eye damage/eye irritation, Category 2A ------ Skin Irrit. 2 Skin corrosion/irritation, Category 2 ------ STOT SE 3 Specific target organ toxicity — Single exposure, Category 3, Respiratory tract irritation ------ H315 Causes skin irritation ------ H319 Causes serious eye irritation ------ H335 May cause respiratory irritation ------ H402 Harmful to aquatic life NFPA health hazard : 2 - Intense or continued exposure could cause temporary incapacitation or possible residual injury unless prompt medical attention is given. NFPA fire hazard : 0 - Materials that will not burn. 06/20/2013 EN (English) 6/7 Aluminum Chloride Hexahydrate Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 06/20/2013 EN (English) 7/7 NFPA reactivity : 0 - Normally stable, even under fire exposure conditions, and are not reactive with water. HMIS III Rating Health : 2 Moderate Hazard - Temporary or minor injury may occur Flammability : 0 Minimal Hazard Physical : 0 Minimal Hazard Personal Protection : E SDS US (GHS HazCom 2012) Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc assumes no liability resulting from the use of this SDS. The user must determine suitability of this information for his application. MATERIAL SAFETY DATA SHEET FERRIC SUBSULFATE SOLUTION MSDS Number: 480S --- Effective Date: 11/10 1. Product Identification Synonyms: Ferric sulphate, basic, solution; iron hydroxide sulfate; Monsel's solution CAS No.: 1310-45-8 Molecular Weight: 737.7 Chemical Formula: Fe4(OH)2(SO4)5 (approx.) solution 2. Composition/Information on Ingredients Ingredient CAS No Percent Hazardous --------------------------------------- ------------ ------- --------- Ferric Subsulfate 1310-45-8 40 - 70% Yes Water 7732-18-5 30 - 60% No 3. Hazards Identification Emergency Overview -------------------------- CAUTION! MAY BE HARMFUL IF SWALLOWED. MAY CAUSE IRRITATION TO SKIN, EYES, AND RESPIRATORY TRACT. -------------------------------------------------------------------------------------------------------- --- Health Rating: 1 - Slight Flammability Rating: 0 - None Reactivity Rating: 0 - None Contact Rating: 2 - Moderate Lab Protective Equip: GOGGLES; LAB COAT; VENT HOOD; PROPER GLOVES Storage Color Code: Orange (General Storage) -------------------------------------------------------------------------------------------------------- --- Potential Health Effects ---------------------------------- Although little information is available in the literature, it is expected that the health hazards for iron compounds reflect those for this material. Inhalation: May cause irritation to the respiratory tract. Ingestion: Low toxicity in small quantities but larger dosages may cause nausea, vomiting, diarrhea, and black stool. Pink urine discoloration is a strong indicator of iron poisoning. Liver damage, coma, and death from iron poisoning has been reported. Skin Contact: No adverse effects expected. Eye Contact: Splashes may cause irritation. Chronic Exposure: No information found. Aggravation of Pre-existing Conditions: Persons with pre-existing skin disorders or eye problems, or impaired liver, kidney or respiratory function may be more susceptible to the effects of the substance. 4. First Aid Measures Inhalation: Remove to fresh air. Get medical attention for any breathing difficulty. Ingestion: Induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. Skin Contact: Wash exposed area with soap and water. Get medical advice if irritation develops. Eye Contact: Wash thoroughly with running water. Get medical advice if irritation develops. 5. Fire Fighting Measures Fire: Not considered to be a fire hazard. Explosion: Not considered to be an explosion hazard. Fire Extinguishing Media: Use any means suitable for extinguishing surrounding fire. Special Information: In the event of a fire, wear full protective clothing and NIOSH-approved self- contained breathing apparatus with full facepiece operated in the pressure demand or other positive pressure mode. 6. Accidental Release Measures Ventilate area of leak or spill. Wear appropriate personal protective equipment as specified in Section 8. Spills: Pick up and place in a suitable container for reclamation or disposal, using a method that does not generate dust. 7. Handling and Storage Store in a tightly closed container. Protect against physical damage, direct sunlight, and freezing. Containers of this material may be hazardous when empty since they retain product residues (vapors, liquid); observe all warnings and precautions listed for the product. 8. Exposure Controls/Personal Protection Airborne Exposure Limits: -ACGIH Threshold Limit Value (TLV): 1 mg/m3 (TWA) soluble iron salt as Fe Ventilation System: A system of local and/or general exhaust is recommended to keep employee exposures below the Airborne Exposure Limits. Local exhaust ventilation is generally preferred because it can control the emissions of the contaminant at its source, preventing dispersion of it into the general work area. Please refer to the ACGIH document, Industrial Ventilation, A Manual of Recommended Practices, most recent edition, for details. Personal Respirators (NIOSH Approved): If the exposure limit is exceeded, a half-face dust/mist respirator may be worn for up to ten times the exposure limit or the maximum use concentration specified by the appropriate regulatory agency or respirator supplier, whichever is lowest. A full-face piece dust/mist respirator may be worn up to 50 times the exposure limit, or the maximum use concentration specified by the appropriate regulatory agency, or respirator supplier, whichever is lowest. For emergencies or instances where the exposure levels are not known, use a full-facepiece positive-pressure, air-supplied respirator. WARNING: Air-purifying respirators do not protect workers in oxygen-deficient atmospheres. Skin Protection: Wear protective gloves and clean body-covering clothing. Eye Protection: Use chemical safety goggles. Maintain eye wash fountain and quick-drench facilities in work area. 9. Physical and Chemical Properties Appearance: Reddish-brown liquid. Odor: Nearly odorless. Solubility: Miscible in water. Specific Gravity: ca. 1.54 pH: Acidic to litmus. % Volatiles by volume @ 21C (70F): No information found. Boiling Point: Decomposes. Melting Point: No information found. Vapor Density (Air=1): No information found. Vapor Pressure (mm Hg): No information found. Evaporation Rate (BuAc=1): No information found. 10. Stability and Reactivity Stability: Freezes at cool temperatures. Light sensitive. Hazardous Decomposition Products: Oxides of sulfur and the contained metal. Hazardous Polymerization: Will not occur. Incompatibilities: No incompatibility data found. Conditions to Avoid: Light and low temperatures. 11. Toxicological Information No LD50/LC50 information found relating to normal routes of occupational exposure. --------\Cancer Lists\------------------------------------------------------ ---NTP Carcinogen--- Ingredient Known Anticipated IARC Category ------------------------------------ ----- ----------- ------------- Ferric Subsulfate (1310-45-8) No No None Water (7732-18-5) No No None 12. Ecological Information Environmental Fate: No information found. Environmental Toxicity: No information found. 13. Disposal Considerations Whatever cannot be saved for recovery or recycling should be managed in an appropriate and approved waste disposal facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. 14. Transport Information Not regulated. 15. Regulatory Information --------\Chemical Inventory Status - Part 1\--------------------------------- Ingredient TSCA EC Japan Australia ----------------------------------------------- ---- --- ----- --------- Ferric Subsulfate (1310-45-8) Yes Yes No Yes Water (7732-18-5) Yes Yes Yes Yes --------\Chemical Inventory Status - Part 2\--------------------------------- --Canada-- Ingredient Korea DSL NDSL Phil. ----------------------------------------------- ----- --- ---- ----- Ferric Subsulfate (1310-45-8) Yes Yes No No Water (7732-18-5) Yes Yes No Yes --------\Federal, State & International Regulations - Part 1\---------------- -SARA 302- ------SARA 313------ Ingredient RQ TPQ List Chemical Catg. ----------------------------------------- --- ----- ---- -------------- Ferric Subsulfate (1310-45-8) No No No No Water (7732-18-5) No No No No --------\Federal, State & International Regulations - Part 2\---------------- -RCRA- -TSCA- Ingredient CERCLA 261.33 8(d) ----------------------------------------- ------ ------ ------ Ferric Subsulfate (1310-45-8) No No No Water (7732-18-5) No No No Chemical Weapons Convention: No TSCA 12(b): No CDTA: No SARA 311/312: Acute: Yes Chronic: No Fire: No Pressure: No Reactivity: No (Mixture / Liquid) Australian Hazchem Code: No information found. Poison Schedule: No information found. WHMIS: This MSDS has been prepared according to the hazard criteria of the Controlled Products Regulations (CPR) and the MSDS contains all of the information required by the CPR. 16. Other Information NFPA Ratings: Health: 1 Flammability: 0 Reactivity: 0 Label Hazard Warning: CAUTION! MAY BE HARMFUL IF SWALLOWED. MAY CAUSE IRRITATION TO SKIN, EYES, AND RESPIRATORY TRACT. Label Precautions: Avoid contact with eyes, skin and clothing. Keep container closed. Use with adequate ventilation. Wash thoroughly after handling. INTENDED FOR FDA APPROVED USE ONLY. NOT ON THE TSCA INVENTORY. Label First Aid: If swallowed, induce vomiting immediately as directed by medical personnel. Never give anything by mouth to an unconscious person. If inhaled, remove to fresh air. Get medical attention for any breathing difficulty. In case of contact, immediately flush eyes or skin with plenty of water for at least 15 minutes. Product Use: For Food and Drug or Research and Development use Revision Information: No changes. Disclaimer: ************************************************************************ ************************ City Chemical LLC. provides the information contained herein in good faith but makes no representation as to its comprehensiveness or accuracy. This document is intended only as a guide to the appropriate precautionary handling of the material by a properly trained person using this product. Individuals receiving the information must exercise their independent judgment in determining its appropriateness for a particular purpose. CITY CHEMICAL LLC. MAKES NO REPRESENTATIONS OR WARRANTIES, EITHER EXPRESS OR IMPLIED, INCLUDING WITHOUT LIMITATION ANY WARRANTIES OF MERCHANTABILITY, FITNESS FOR A PARTICULAR PURPOSE WITH RESPECT TO THE INFORMATION SET FORTH HEREIN OR THE PRODUCT TO WHICH THE INFORMATION REFERS. ACCORDINGLY, CITY CHEMICAL LLC. WILL NOT BE RESPONSIBLE FOR DAMAGES RESULTING FROM USE OF OR RELIANCE UPON THIS INFORMATION. From:S Amin To:Brittany Coughlin Cc:Creel, Christopher; Kim Vu Subject:Re: Grapevine Suite LL40 - Contact information needed Date:Wednesday, June 26, 2019 6:01:24 PM I’m sorry here it is: 1)Alcohol 1 litre 2)acetone 8 ounces 3)trichloroacetic acid 8 ounces 4)aluminum chloride 8 ounces 5)ferrous subsulfate 8 ounces 6)isopropanol wipes (not liquid) 7)chlorhexidine 32 ounces I’ll have Kim email you the MSDS in a separate email. She is cc:d on this. I’ll have a total of 5 employees. Thank you! On Wednesday, June 26, 2019, 4:36:20 PM CDT, Brittany Coughlin <brittany@clementsinc.net> wrote: Dr. Amin, we cannot apply for CO until we have all of the required information. Please see the email below from yesterday on additional information we need. Please let me know if there are any questions. Brittany Coughlin, Kinetronics Corporation Phone 941-951-2432 4363 Independence Court Fax 941-955-5992 Sarasota, Florida 34234 Web Site: Isopropyl Alcohol: Material Safety Data Sheet 1 Material Safety Data Sheet Isopropyl Alcohol PRODUCT & COMPANY IDENTIFICATION In case of Emergency call CHEMTREC 1-800-424-9300 Supplier Simchem Corporation, 311 Sarasota Center Blvd., P.O. Box 697, Osprey, Florida, 34229-0697 (941) 377-9935 Fax (941) 377-9539 CAS Number 67-63-0 Synonyms Isopropanol; sec-propyl alcohol; sec-propanol; dimethylcarbinol Formula (CH3)2CHOH TRANSPORTATION DATA US Department of Transportation – 49 CFR Proper Shipping Name Isopropanol UN Number UN1219 Hazard Class 3 Packing Group II Labels Flammable Liquid PHYSICAL/CHEMICAL DATA Appearance Clear, colorless liquid Odor Rubbing alcohol Boiling Point 82 ºC Melting Point -89 ºC Vapor Pressure 44 @ 25 ºC (mm Hg) Vapor Density (Air = 1) 2.1 Specific Gravity 0.79 @ 20 ºC / 4 ºC Solubility in Water Miscible in water Volatile by Volume 100% @ 21 ºC Evaporation Rate 2.83 (BuAc =1) REACTIVITY DATA Stability Stable Incompatibility Heat, flame, strong oxidizers, acetaldehyde, acids, chlorine, ethylene oxide, isocyanates. Hazardous Decomposition Products Carbon dioxide and carbon monoxide may form when heated to decomposition. Conditions to Avoid Heat, flame, ignition sources and incompatibles. Hazardous Polymerization Will not occur. Kinetronics Corporation Phone: (941) 951-2432 4363 Independance Ct. Fax: (941) 955-5992 Sarasota, FL 34234 Web Site: Isopropyl Alcohol: Material Safety Data Sheet 2 FIRE AND EXPLOSION HAZARD DATA Flash Point 12 ºC Auto Ignition Temperature 399 ºC Flammable Limits LEL: 2.0 UEL: 12.7 Fire Extinguishing Spray Water spray, dry chemical, alcohol foam, or carbon dioxide. Water spray may be used to keep fire exposed containers cool, dilute spills and nonflammable mixtures, protect personnel attempting to stop leak and disperse vapors. Explosion Above flash point, vapor air mixtures are explosive within flammable limits noted above. Contact with strong oxidizers may cause fire or explosion. Vapors can flow along surfaces to distant ignition source and flash back. Sensitive to static discharge. Special Information In the event of a fire, wear full protective clothing and NIOSH-approved self- contained breathing apparatus with full face piece operated in the pressure demand for other positive pressure mode. PRECAUTIONS FOR SAFE HANDLING & USE to be Taken in Case Material is Steps Spilled or Released Ventilate area of leak or spill. Remove all sources of ignition. Wear appropriate personal protective equipment as specified on section 5. Isolate hazard area. Keep unnecessary and unprotected personnel from entering. Contain and recover liquid when possible Use non-sparking tools and equipment. Collect liquid in an appropriate container or absorb with an inert material and place in a chemical waste container. Do not use combustible materials, such as saw dust. Do not flush to sewer! If a leak or spill has not ignited, use water spray to disperse the vapors, to protect personnel attempting to stop leak, and to flush spills away from exposures. Disposal Method Whatever cannot be saved for recovery or recycling should be handled as hazardous waste and sent to a RCRA approved incinerator or disposed in a RCRA approved waste facility. Processing, use or contamination of this product may change the waste management options. State and local disposal regulations may differ from federal disposal regulations. Dispose of container and unused contents in accordance with federal, state and local requirements. Handling and Storage Protect against physical damage. Store in a cool, dry well-ventilated location, away from any area where the fire hazard may be acute. Outside or detached storage is preferred. Separate from incompatibles. Containers should be bonded and grounded for transfers to avoid static sparks. Storage and use areas should be No Smoking areas. Use non-sparking type tolls and equipment, including explosion proof ventilation. Containers of this material may be hazardous when empty since they retain product residues. Kinetronics Corporation Phone: (941) 951-2432 4363 Independance Ct. Fax: (941) 955-5992 Sarasota, FL 34234 Web Site: www.Kinetronics.com Isopropyl Alcohol: Material Safety Data Sheet 3 HEALTH HAZARD DATA Potential Health Effects: Inhalation Inhalation of vapors irritates the respiratory tract. Exposure to high concentrations has a narcotic effect, producing symptoms of dizziness, drowsiness, headache, staggering, unconsciousness and possibly death. Ingestion Ingestion can cause drowsiness, unconsciousness, and death. Gastrointestinal pain, cramps, nausea, vomiting, and diarrhea may also result. The single lethal dose for a human adult = about 250 mls (8 ounces). Skin Contact May cause skin irritation with redness and pain. May be absorbed through the skin with possible systemic effects. Eye Contact Vapors cause eye irritation. Splashes caused severe irritation, possible corneal burns and eye damage. First Aid Measures: Inhalation In case of Inhalation, remove to fresh air. In not breathing, give artificial respiration. If breathing is difficult, give oxygen. Call a physician. Ingestion Give large amounts of water to drink. Never give anything by mouth to an unconscious person. Get medical attention. Skin Contact Immediately flush skin with plenty of water for at least 15 minutes. Call a physician if irritation develops. Eye Contact Immediately flush eyes with plenty of water for at least 15 minutes, lifting lower and upper eyelids occasionally. Get medical attention immediately. Personal Protective Equipment: Skin Protection Were impervious protective clothing, including boots, gloves, lab coat, apron or coveralls, as appropriate, to prevent skin contact. Neoprene and nitrile rubber are recommended materials. Eye Protection Use chemical safety goggles and/or a full face shield where splashing is possible. Maintain eye wash fountain and quick-drench facilities in work area. ADDITIONAL INFORMATION Always comply with all applicable international, federal, state and local regulations regarding the transportation, storage, use and disposal of this chemical. Due to the changing nature of regulatory requirements, the regulatory information listed in Section X this document should not be considered all-inclusive or authoritative. International, Federal, State Local regulations should be consulted to determine with all required reporting requirements. The information in this MSDS was obtained from sources, which we believe are reliable. However, the information is provided without any warranty, express or implied, regarding its correctness. The conditions or methods of handling, storage, use, and disposal of the product are beyond our control and may be beyond our knowledge. For this and other reasons, we do not assume responsibility and expressly disclaim liability for loss, damage or expense arising out of or in any way connected with the handling, storage, use or disposal of the product. This MSDS was prepared and is to be used only for this product. If the product is used as a component in another product, MSDS information may not be applicable. Acetone Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 11/12/1998 Revision date: 04/24/2018 Supersedes: 04/24/2018 Version: 1.3 04/23/2019 EN (English US) Page 1 SECTION 1: Identification 1.1. Identification Product form : Substance Substance name : Acetone Chemical name : 2-Propanone CAS-No. : 67-64-1 Product code : LC10420, LC10425 Formula : C3H6O Synonyms : 2-propanone / beta-ketopropane / dimethyl formaldehyde / dimethyl ketone / dimethylketal / DMK (=dimethyl ketone) / keto propane / methyl ketone / pyroacetic acid / pyroacetic ether / pyroacetic spirit 1.2. Recommended use and restrictions on use Use of the substance/mixture : Solvent Cleaning product Chemical raw material Recommended use : Laboratory chemicals Restrictions on use : Not for food, drug or household use 1.3. Supplier LabChem, Inc. Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court Zelienople, PA 16063 - USA T 412-826-5230 - F 724-473-0647 1.4. Emergency telephone number Emergency number : CHEMTREC: 1-800-424-9300 or +1-703-741-5970 SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Flammable liquids Category 2 H225 Highly flammable liquid and vapour Serious eye damage/eye irritation Category 2A H319 Causes serious eye irritation Specific target organ toxicity (single exposure) Category 3 H336 May cause drowsiness or dizziness Full text of H statements : see section 16 2.2. GHS Label elements, including precautionary statements GHS US labeling Hazard pictograms (GHS US) : GHS02 GHS07 Signal word (GHS US) : Danger Hazard statements (GHS US) : H225 - Highly flammable liquid and vapour H319 - Causes serious eye irritation H336 - May cause drowsiness or dizziness Precautionary statements (GHS US) : P210 - Keep away from heat, hot surfaces, open flames, sparks. - No smoking. P233 - Keep container tightly closed. P240 - Ground/bond container and receiving equipment. P241 - Use explosion-proof electrical, lighting, ventilating equipment P242 - Use only non-sparking tools. P243 - Take precautionary measures against static discharge. P261 - Avoid breathing mist, spray, vapors. Acetone Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 04/23/2019 EN (English US) 2/10 P264 - Wash exposed skin thoroughly after handling. P271 - Use only outdoors or in a well-ventilated area. P280 - Wear eye protection, face protection, protective clothing, protective gloves. P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 - IF INHALED: Remove person to fresh air and keep comfortable for breathing. P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P312 - Call a POISON CENTER or doctor/physician if you feel unwell. P337+P313 - If eye irritation persists: Get medical advice/attention. P370+P378 - In case of fire: Use dry chemical powder, alcohol-resistant foam, carbon dioxide (CO2) to extinguish P403+P233 - Store in a well-ventilated place. Keep container tightly closed. P405 - Store locked up. P501 - Dispose of contents/container to comply with local, state and federal regulations P235 - Keep cool. 2.3. Other hazards which do not result in classification Other hazards not contributing to the classification : None. 2.4. Unknown acute toxicity (GHS US) Not applicable SECTION 3: Composition/Information on ingredients 3.1. Substances Substance type : Mono-constituent Name Product identifier % GHS-US classification Acetone (Main constituent) (CAS-No.) 67-64-1 100 Flam. Liq. 2, H225 Eye Irrit. 2A, H319 STOT SE 3, H336 Full text of hazard classes and H-statements : see section 16 3.2. Mixtures Not applicable SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures general : Check the vital functions. Unconscious: maintain adequate airway and respiration. Respiratory arrest: artificial respiration or oxygen. Cardiac arrest: perform resuscitation. Victim conscious with labored breathing: half-seated. Victim in shock: on his back with legs slightly raised. Vomiting: prevent asphyxia/aspiration pneumonia. Prevent cooling by covering the victim (no warming up). Keep watching the victim. Give psychological aid. Keep the victim calm, avoid physical strain. Depending on the victim's condition: doctor/hospital. First-aid measures after inhalation : Remove the victim into fresh air. Respiratory problems: consult a doctor/medical service. First-aid measures after skin contact : Wash immediately with lots of water. Soap may be used. Do not apply (chemical) neutralizing agents. Remove clothing before washing. Take victim to a doctor if irritation persists. First-aid measures after eye contact : Rinse immediately with plenty of water. Remove contact lenses, if present and easy to do. Continue rinsing. Do not apply neutralizing agents. Take victim to an ophthalmologist if irritation persists. First-aid measures after ingestion : Rinse mouth with water. Immediately after ingestion: give lots of water to drink. Do not give milk/oil to drink. Do not induce vomiting. Give activated charcoal. Call Poison Information Centre (www.big.be/antigif.htm). Consult a doctor/medical service if you feel unwell. Ingestion of large quantities: immediately to hospital. Doctor: gastric lavage. 4.2. Most important symptoms and effects (acute and delayed) Symptoms/effects : Not expected to present a significant hazard under anticipated conditions of normal use. Symptoms/effects after inhalation : EXPOSURE TO HIGH CONCENTRATIONS: Feeling of weakness. Irritation of the respiratory tract. Nausea. Vomiting. Headache. Central nervous system depression. Dizziness. Narcosis. Excited/restless. Drunkenness. Disturbed motor response. Respiratory difficulties. Disturbances of consciousness. Symptoms/effects after skin contact : ON CONTINUOUS EXPOSURE/CONTACT: Dry skin. Cracking of the skin. Symptoms/effects after eye contact : Irritation of the eye tissue. Acetone Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 04/23/2019 EN (English US) 3/10 Symptoms/effects after ingestion : Dry/sore throat. Risk of aspiration pneumonia. Symptoms similar to those listed under inhalation. AFTER ABSORPTION OF LARGE QUANTITIES: Irritation of the gastric/intestinal mucosa. Change in the blood composition. Change in urine output. Renal disease. Enlargement/disease of the liver. Symptoms/effects upon intravenous administration : Not available. Chronic symptoms : ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Red skin. Skin rash/inflammation. Dry/sore throat. Headache. Nausea. Feeling of weakness. Loss of weight. Possible inflammation of the respiratory tract. 4.3. Immediate medical attention and special treatment, if necessary Obtain medical assistance. SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media : Quick-acting ABC powder extinguisher. Quick-acting BC powder extinguisher. Quick-acting class B foam extinguisher. Quick-acting CO2 extinguisher. Class B foam (alcohol-resistant). Water spray if puddle cannot expand. Unsuitable extinguishing media : Water (quick-acting extinguisher, reel); risk of puddle expansion. Water; risk of puddle expansion. 5.2. Specific hazards arising from the chemical Fire hazard : DIRECT FIRE HAZARD. Highly flammable liquid and vapour. Gas/vapor flammable with air within explosion limits. INDIRECT FIRE HAZARD. May be ignited by sparks. Gas/vapor spreads at floor level: ignition hazard. Reactions involving a fire hazard: see "Reactivity Hazard". Explosion hazard : DIRECT EXPLOSION HAZARD. Gas/vapour explosive with air within explosion limits. INDIRECT EXPLOSION HAZARD. Heat may cause pressure rise in tanks/drums: explosion risk. may be ignited by sparks. Reactions with explosion hazards: see "Reactivity Hazard". Reactivity : Violent to explosive reaction with many compounds. Prolonged storage: on exposure to light: release of harmful gases/vapours. 5.3. Special protective equipment and precautions for fire-fighters Firefighting instructions : Cool tanks/drums with water spray/remove them into safety. Physical explosion risk: extinguish/cool from behind cover. Do not move the load if exposed to heat. After cooling: persistant risk of physical explosion. Protection during firefighting : Heat/fire exposure: compressed air/oxygen apparatus. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Protective equipment : Gloves. Protective goggles. Protective clothing. Large spills/in enclosed spaces: compressed air apparatus. Emergency procedures : Keep upwind. Mark the danger area. Consider evacuation. Seal off low-lying areas. Close doors and windows of adjacent premises. Stop engines and no smoking. No naked flames or sparks. Spark- and explosion-proof appliances and lighting equipment. Keep containers closed. Wash contaminated clothes. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. 6.2. Environmental precautions Prevent spreading in sewers. 6.3. Methods and material for containment and cleaning up For containment : Contain released substance, pump into suitable containers. Plug the leak, cut off the supply. Dam up the liquid spill. Try to reduce evaporation. Measure the concentration of the explosive gas-air mixture. Dilute/disperse combustible gas/vapour with water curtain. Provide equipment/receptacles with earthing. Do not use compressed air for pumping over spills. Methods for cleaning up : Take up liquid spill into inert absorbent material, e.g.: sand, earth, vermiculite. Scoop absorbed substance into closing containers. Spill must not return in its original container. Carefully collect the spill/leftovers. Damaged/cooled tanks must be emptied. Do not use compressed air for pumping over spills. Clean contaminated surfaces with an excess of water. Take collected spill to manufacturer/competent authority. Wash clothing and equipment after handling. Acetone Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 04/23/2019 EN (English US) 4/10 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Use spark-/explosionproof appliances and lighting system. Take precautions against electrostatic charges. Keep away from naked flames/heat. Keep away from ignition sources/sparks. Measure the concentration in the air regularly. Work under local exhaust/ventilation. Comply with the legal requirements. Remove contaminated clothing immediately. Clean contaminated clothing. Handle uncleaned empty containers as full ones. Thoroughly clean/dry the installation before use. Do not discharge the waste into the drain. Do not use compressed air for pumping over. Keep container tightly closed. Hygiene measures : Do not eat, drink or smoke when using this product. Wash contaminated clothing before reuse. Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. 7.2. Conditions for safe storage, including any incompatibilities Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Heat sources, Direct sunlight, incompatible materials. Keep container closed when not in use. Incompatible products : Strong bases. Strong acids. Incompatible materials : Sources of ignition. Direct sunlight. Storage temperature : 15 - 20 °C Heat-ignition : KEEP SUBSTANCE AWAY FROM: heat sources. ignition sources. Prohibitions on mixed storage : KEEP SUBSTANCE AWAY FROM: oxidizing agents. reducing agents. strong acids. (strong) bases. halogens. amines. Storage area : Store in a cool area. Keep out of direct sunlight. Store in a dry area. Store in a dark area. Ventilation at floor level. Fireproof storeroom. Provide for an automatic sprinkler system. Provide for a tub to collect spills. Provide the tank with earthing. Meet the legal requirements. Special rules on packaging : SPECIAL REQUIREMENTS: closing. with pressure relief valve. clean. opaque. correctly labelled. meet the legal requirements. Secure fragile packagings in solid containers. Packaging materials : SUITABLE MATERIAL: steel. stainless steel. carbon steel. aluminium. iron. copper. nickel. bronze. glass. MATERIAL TO AVOID: synthetic material. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Acetone (67-64-1) ACGIH ACGIH TWA (ppm) 250 ppm ACGIH ACGIH STEL (ppm) 500 ppm NIOSH NIOSH REL (TWA) (mg/m³) 590 mg/m³ NIOSH NIOSH REL (TWA) (ppm) 250 ppm 8.2. Appropriate engineering controls Appropriate engineering controls : Emergency eye wash fountains should be available in the immediate vicinity of any potential exposure. 8.3. Individual protection measures/Personal protective equipment Personal protective equipment: Safety glasses. Gloves. Protective clothing. Face shield. High gas/vapor concentration: gas mask with filter type A. Materials for protective clothing: GIVE GOOD RESISTANCE: butyl rubber. tetrafluoroethylene. GIVE LESS RESISTANCE: chlorosulfonated polyethylene. natural rubber. neoprene. polyurethane. PVA. styrene-butadiene rubber. GIVE POOR RESISTANCE: nitrile rubber. polyethylene. PVC. viton. nitrile rubber/PVC Acetone Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 04/23/2019 EN (English US) 5/10 Hand protection: Gloves Eye protection: Safety glasses Skin and body protection: Head/neck protection. Protective clothing Respiratory protection: Full face mask with filter type AX at conc. in air > exposure limit Other information: Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Liquid. : Colourless : Aromatic odour Sweet odour Fruity odour Odor threshold : No data available pH : 7 (10 g/l) Melting point : -95 °C Freezing point : No data available Boiling point : 56 °C Critical temperature : 235 °C Critical pressure : 47010 hPa Flash point : -17 °C (Closed cup) Relative evaporation rate (butyl acetate=1) : 6 Relative evaporation rate (ether=1) : 2 Flammability (solid, gas) : Non flammable. Vapor pressure : 247 hPa (20 °C) Vapor pressure at 50 °C : 828 hPa Relative vapor density at 20 °C : 2 Relative density : 0.79 Relative density of saturated gas/air mixture : 1.2 Specific gravity / density : 786 kg/m³ Molecular mass : 58.08 g/mol Solubility : Soluble in water. Soluble in ethanol. Soluble in ether. Soluble in dimethyl ether. Soluble in petroleum spirit. Soluble in chloroform. Soluble in dimethylformamide. Soluble in oils/fats. Water: complete Ethanol: complete Ether: complete Log Pow : -0.24 (Test data) Auto-ignition temperature : 465 °C Decomposition temperature : No data available Viscosity, kinematic : 0.417 mm²/s Viscosity, dynamic : 0.32 mPa·s (20 °C) Explosion limits : 2 - 12.8 vol % 60 - 310 g/m³ Lower explosive limit (LEL): 2 vol % UEL: 12.8 vol % Explosive properties : No data available. Oxidizing properties : None. Acetone Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 04/23/2019 EN (English US) 6/10 9.2. Other information Minimum ignition energy : 1.15 mJ Specific conductivity : 6000000 pS/m (25 °C) Saturation concentration : 589 g/m³ VOC content : 100 % Other properties : Gas/vapour heavier than air at 20°C. Clear. Highly volatile. Neutral reaction. SECTION 10: Stability and reactivity 10.1. Reactivity Violent to explosive reaction with many compounds. Prolonged storage: on exposure to light: release of harmful gases/vapours. 10.2. Chemical stability Unstable on exposure to light. 10.3. Possibility of hazardous reactions Reacts with (strong) oxidizers. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong acids. Strong bases. Strong oxidizers. 10.6. Hazardous decomposition products fume. Carbon monoxide. Carbon dioxide. SECTION 11: Toxicological information 11.1. Information on toxicological effects Likely routes of exposure : Inhalation; Skin and eye contact Acute toxicity : Not classified Acetone (67-64-1) LD50 oral rat 5800 mg/kg (Equivalent or similar to OECD 401, Rat, Female, Experimental value, Oral) LD50 dermal rabbit 20000 mg/kg (Equivalent or similar to OECD 402, Rabbit, Male, Experimental value, Dermal) LC50 inhalation rat (mg/l) 76 mg/l (Other, 4 h, Rat, Female, Experimental value, Inhalation (vapours)) ATE US (oral) 5800 mg/kg body weight ATE US (dermal) 20000 mg/kg body weight ATE US (gases) 30000 ppmV/4h ATE US (vapors) 71 mg/l/4h ATE US (dust, mist) 71 mg/l/4h Skin corrosion/irritation : Not classified pH: 7 (10 g/l) Serious eye damage/irritation : Causes serious eye irritation. pH: 7 (10 g/l) Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Based on available data, the classification criteria are not met Carcinogenicity : Not classified Reproductive toxicity : Not classified Based on available data, the classification criteria are not met Specific target organ toxicity – single exposure : May cause drowsiness or dizziness. Specific target organ toxicity – repeated exposure : Not classified Aspiration hazard : Not classified Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. Acetone Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 04/23/2019 EN (English US) 7/10 Symptoms/effects after inhalation : EXPOSURE TO HIGH CONCENTRATIONS: Feeling of weakness. Irritation of the respiratory tract. Nausea. Vomiting. Headache. Central nervous system depression. Dizziness. Narcosis. Excited/restless. Drunkenness. Disturbed motor response. Respiratory difficulties. Disturbances of consciousness. Symptoms/effects after skin contact : ON CONTINUOUS EXPOSURE/CONTACT: Dry skin. Cracking of the skin. Symptoms/effects after eye contact : Irritation of the eye tissue. Symptoms/effects after ingestion : Dry/sore throat. Risk of aspiration pneumonia. Symptoms similar to those listed under inhalation. AFTER ABSORPTION OF LARGE QUANTITIES: Irritation of the gastric/intestinal mucosa. Change in the blood composition. Change in urine output. Renal disease. Enlargement/disease of the liver. Symptoms/effects upon intravenous administration : Not available. Chronic symptoms : ON CONTINUOUS/REPEATED EXPOSURE/CONTACT: Red skin. Skin rash/inflammation. Dry/sore throat. Headache. Nausea. Feeling of weakness. Loss of weight. Possible inflammation of the respiratory tract. SECTION 12: Ecological information 12.1. Toxicity Ecology - general : Not classified as dangerous for the environment according to the criteria of Regulation (EC) No 1272/2008. Ecology - air : Not included in the list of substances which may contribute to the greenhouse effect (IPCC). Not included in the list of fluorinated greenhouse gases (Regulation (EU) No 517/2014). Not classified as dangerous for the ozone layer (Regulation (EC) No 1005/2009). Ecology - water : Not harmful to crustacea. Not harmful to fishes. Inhibition of activated sludge. Not harmful to algae. Not harmful to plankton. Acetone (67-64-1) LC50 fish 1 5540 mg/l (EU Method C.1, 96 h, Salmo gairdneri, Static system, Fresh water, Experimental value, Nominal concentration) 12.2. Persistence and degradability Acetone (67-64-1) Persistence and degradability Biodegradable in the soil. Biodegradable in the soil under anaerobic conditions. Readily biodegradable in water. Biochemical oxygen demand (BOD) 1.43 g O₂/g substance Chemical oxygen demand (COD) 1.92 g O₂/g substance ThOD 2.2 g O₂/g substance BOD (% of ThOD) 0.872 (20 day(s), Literature study) 12.3. Bioaccumulative potential Acetone (67-64-1) BCF fish 1 0.69 (Pisces) BCF other aquatic organisms 1 3 (BCFWIN, Calculated value) Log Pow -0.24 (Test data) Bioaccumulative potential Not bioaccumulative. 12.4. Mobility in soil Acetone (67-64-1) Surface tension 0.0237 N/m Ecology - soil No (test)data on mobility of the substance available. 12.5. Other adverse effects Other information : Avoid release to the environment. Acetone Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 04/23/2019 EN (English US) 8/10 SECTION 13: Disposal considerations 13.1. Disposal methods Waste disposal recommendations : Do not discharge into drains or the environment. Remove waste in accordance with local and/or national regulations. Hazardous waste shall not be mixed together with other waste. Different types of hazardous waste shall not be mixed together if this may entail a risk of pollution or create problems for the further management of the waste. Hazardous waste shall be managed responsibly. All entities that store, transport or handle hazardous waste shall take the necessary measures to prevent risks of pollution or damage to people or animals. Recycle by distillation. Incinerate under surveillance with energy recovery. Additional information : Hazardous waste according to Directive 2008/98/EC, as amended by Regulation (EU) No 1357/2014 and Regulation (EU) No 2017/997. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Transport document description : UN1090 Acetone, 3, II UN-No.(DOT) : UN1090 Proper Shipping Name (DOT) : Acetone Transport hazard class(es) (DOT) : 3 - Class 3 - Flammable and combustible liquid 49 CFR 173.120 Packing group (DOT) : II - Medium Danger Hazard labels (DOT) : 3 - Flammable liquid DOT Packaging Non Bulk (49 CFR 173.xxx) : 202 DOT Packaging Bulk (49 CFR 173.xxx) : 242 DOT Special Provisions (49 CFR 172.102) : IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized. T4 - 2.65 178.274(d)(2) Normal............. 178.275(d)(3) TP1 - The maximum degree of filling must not exceed the degree of filling determined by the following: Degree of filling = 97 / 1 + a (tr - tf) Where: tr is the maximum mean bulk temperature during transport, and tf is the temperature in degrees celsius of the liquid during filling. DOT Packaging Exceptions (49 CFR 173.xxx) : 150 DOT Quantity Limitations Passenger aircraft/rail (49 CFR 173.27) : 5 L DOT Quantity Limitations Cargo aircraft only (49 CFR 175.75) : 60 L DOT Vessel Stowage Location : B - (i) The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length; and (ii) ‘‘On deck only’’ on passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this section is exceeded. Other information : No supplementary information available. Transportation of Dangerous Goods Transport document description : UN1090 ACETONE, 3, II UN-No. (TDG) : UN1090 Proper Shipping Name (Transportation of Dangerous Goods) : ACETONE TDG Primary Hazard Classes : 3 - Class 3 - Flammable Liquids Packing group : II - Medium Danger Explosive Limit and Limited Quantity Index : 1 L Passenger Carrying Road Vehicle or Passenger Carrying Railway Vehicle Index : 5 L Passenger Carrying Ship Index : Forbidden Acetone Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 04/23/2019 EN (English US) 9/10 Transport by sea Transport document description (IMDG) : UN 1090 acetone, 3, II UN-No. (IMDG) : 1090 Proper Shipping Name (IMDG) : acetone Class (IMDG) : 3 - Flammable liquids Packing group (IMDG) : II - substances presenting medium danger EmS-No. (1) : F-E EmS-No. (2) : S-D Air transport Transport document description (IATA) : UN 1090 Acetone, 3, II UN-No. (IATA) : 1090 Proper Shipping Name (IATA) : Acetone Class (IATA) : 3 - Flammable Liquids Packing group (IATA) : II - Medium Danger SECTION 15: Regulatory information 15.1. US Federal regulations Acetone (67-64-1) Listed on the United States TSCA (Toxic Substances Control Act) inventory RQ (Reportable quantity, section 304 of EPA's List of Lists) 5000 lb SARA Section 311/312 Hazard Classes Immediate (acute) health hazard Fire hazard All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory 15.2. International regulations CANADA Acetone (67-64-1) Listed on the Canadian DSL (Domestic Substances List) EU-Regulations No additional information available National regulations Acetone (67-64-1) Listed on the Canadian IDL (Ingredient Disclosure List) 15.3. US State regulations California Proposition 65 - This product does not contain any substances known to the state of California to cause cancer, developmental and/or reproductive harm SECTION 16: Other information Revision date : 04/24/2018 Other information : None. Full text of H-phrases: see section 16: --- --- H225 Highly flammable liquid and vapour --- --- H319 Causes serious eye irritation --- --- H336 May cause drowsiness or dizziness Acetone Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 04/23/2019 EN (English US) 10/10 NFPA health hazard : 1 - Materials that, under emergency conditions, can cause significant irritation. NFPA fire hazard : 3 - Liquids and solids (including finely divided suspended solids) that can be ignited under almost all ambient temperature conditions. NFPA reactivity : 0 - Material that in themselves are normally stable, even under fire conditions. Hazard Rating Health : 1 Slight Hazard - Irritation or minor reversible injury possible Flammability : 3 Serious Hazard - Materials capable of ignition under almost all normal temperature conditions. Includes flammable liquids with flash points below 73 F and boiling points above 100 F. as well as liquids with flash points between 73 F and 100 F. (Classes IB & IC) Physical : 0 Minimal Hazard - Materials that are normally stable, even under fire conditions, and will NOT react with water, polymerize, decompose, condense, or self-react. Non-Explosives. Personal protection : C C - Safety glasses, Gloves, Synthetic apron SDS US LabChem Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc assumes no liability resulting from the use of this SDS. The user must determine suitability of this information for his application. Trichloroacetic Acid, 80% w/v Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations Date of issue: 10/01/2013 Revision date: 05/15/2018 Supersedes: 10/01/2013 Version: 1.1 05/15/2018 EN (English US) Page 1 SECTION 1: Identification 1.1. Identification Product form : Mixtures Product name : Trichloroacetic Acid, 80% w/v Product code : LC26265 1.2. Recommended use and restrictions on use Use of the substance/mixture : For laboratory and manufacturing use only. Recommended use : Laboratory chemicals Restrictions on use : Not for food, drug or household use 1.3. Supplier LabChem Inc Jackson's Pointe Commerce Park Building 1000, 1010 Jackson's Pointe Court Zelienople, PA 16063 - USA T 412-826-5230 - F 724-473-0647 1.4. Emergency telephone number Emergency number : CHEMTREC: 1-800-424-9300 or +1-703-741-5970 SECTION 2: Hazard(s) identification 2.1. Classification of the substance or mixture GHS-US classification Skin corrosion/irritation Category 1A H314 Causes severe skin burns and eye damage Serious eye damage/eye irritation Category 1 H318 Causes serious eye damage Carcinogenicity Category 2 H351 Suspected of causing cancer (oral) Full text of H statements : see section 16 2.2. GHS Label elements, including precautionary statements GHS-US labeling Hazard pictograms (GHS-US) : GHS05 GHS08 Signal word (GHS-US) : Danger Hazard statements (GHS-US) : H314 - Causes severe skin burns and eye damage H351 - Suspected of causing cancer (oral) Precautionary statements (GHS-US) : P201 - Obtain special instructions before use. P202 - Do not handle until all safety precautions have been read and understood. P260 - Do not breathe mist, vapors, spray. P264 - Wash exposed skin thoroughly after handling. P280 - Wear protective gloves, protective clothing, eye protection, face protection. P301+P330+P331 - IF SWALLOWED: Rinse mouth. Do NOT induce vomiting. P303+P361+P353 - IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. P304+P340 - IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. P305+P351+P338 - If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing P308+P313 - IF exposed or concerned: Get medical advice/attention. P310 - Immediately call a poison center or doctor/physician. P363 - Wash contaminated clothing before reuse. P405 - Store locked up. P501 - Dispose of contents/container to comply with local, state and federal regulations Trichloroacetic Acid, 80% w/v Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/15/2018 EN (English US) 2/8 2.3. Other hazards which do not result in classification Other hazards not contributing to the classification : None. 2.4. Unknown acute toxicity (GHS US) Not applicable SECTION 3: Composition/Information on ingredients 3.1. Substances Not applicable 3.2. Mixtures Name Product identifier % GHS-US classification Trichloroacetic Acid (CAS-No.) 76-03-9 80 Skin Corr. 1A, H314 Eye Dam. 1, H318 Carc. 2, H351 Water (CAS-No.) 7732-18-5 20 Not classified Full text of hazard classes and H-statements : see section 16 SECTION 4: First-aid measures 4.1. Description of first aid measures First-aid measures general : Never give anything by mouth to an unconscious person. If you feel unwell, seek medical advice (show the label where possible). Suspected of causing cancer (Oral). First-aid measures after inhalation : Remove victim to fresh air and keep at rest in a position comfortable for breathing. Immediately call a poison center or doctor/physician. First-aid measures after skin contact : Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Immediately call a poison center or doctor/physician. First-aid measures after eye contact : Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Immediately call a poison center or doctor/physician. First-aid measures after ingestion : Rinse mouth. Do NOT induce vomiting. Immediately call a poison center or doctor/physician. 4.2. Most important symptoms and effects (acute and delayed) Symptoms/effects : Causes severe skin burns and eye damage. Symptoms/effects after eye contact : Causes serious eye damage. Chronic symptoms : Enlargement/affection of the liver. 4.3. Immediate medical attention and special treatment, if necessary No additional information available SECTION 5: Fire-fighting measures 5.1. Suitable (and unsuitable) extinguishing media Suitable extinguishing media : Foam. Dry powder. Carbon dioxide. Water spray. Sand. Unsuitable extinguishing media : Do not use a heavy water stream. 5.2. Specific hazards arising from the chemical Reactivity : Thermal decomposition generates : Corrosive vapors. 5.3. Special protective equipment and precautions for fire-fighters Firefighting instructions : Use water spray or fog for cooling exposed containers. Exercise caution when fighting any chemical fire. Prevent fire-fighting water from entering environment. Protection during firefighting : Do not enter fire area without proper protective equipment, including respiratory protection. SECTION 6: Accidental release measures 6.1. Personal precautions, protective equipment and emergency procedures 6.1.1. For non-emergency personnel Protective equipment : Safety glasses. Gloves. Protective clothing. Combined gas/dust mask with filter type B/P3. Emergency procedures : Evacuate unnecessary personnel. 6.1.2. For emergency responders Protective equipment : Equip cleanup crew with proper protection. Emergency procedures : Ventilate area. Trichloroacetic Acid, 80% w/v Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/15/2018 EN (English US) 3/8 6.2. Environmental precautions Prevent entry to sewers and public waters. Notify authorities if liquid enters sewers or public waters. 6.3. Methods and material for containment and cleaning up Methods for cleaning up : Soak up spills with inert solids, such as clay or diatomaceous earth as soon as possible. Collect spillage. Store away from other materials. 6.4. Reference to other sections See Heading 8. Exposure controls and personal protection. SECTION 7: Handling and storage 7.1. Precautions for safe handling Precautions for safe handling : Wash hands and other exposed areas with mild soap and water before eating, drinking or smoking and when leaving work. Provide good ventilation in process area to prevent formation of vapor. Do not breathe mist, vapors, spray. Avoid contact during pregnancy/while nursing. Obtain special instructions before use. Do not handle until all safety precautions have been read and understood. Hygiene measures : Wash exposed skin thoroughly after handling. 7.2. Conditions for safe storage, including any incompatibilities Technical measures : Comply with applicable regulations. Storage conditions : Keep only in the original container in a cool, well ventilated place away from : Heat sources, incompatible materials. Keep container closed when not in use. Incompatible products : Strong oxidizers. metals. Strong bases. Incompatible materials : Sources of ignition. Direct sunlight. SECTION 8: Exposure controls/personal protection 8.1. Control parameters Trichloroacetic Acid (76-03-9) ACGIH ACGIH TWA (ppm) 0.5 ppm NIOSH NIOSH REL (TWA) (mg/m³) 7 mg/m³ NIOSH NIOSH REL (TWA) (ppm) 1 ppm Water (7732-18-5) Not applicable 8.2. Appropriate engineering controls Appropriate engineering controls : Emergency eye wash fountains should be available in the immediate vicinity of any potential exposure. Provide adequate general and local exhaust ventilation. 8.3. Individual protection measures/Personal protective equipment Personal protective equipment: Chemical resistant apron. Face shield. Gloves. Protective clothing. Safety glasses. Hand protection: Wear protective gloves. Eye protection: Chemical goggles or face shield Skin and body protection: Wear suitable protective clothing Respiratory protection: Trichloroacetic Acid, 80% w/v Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/15/2018 EN (English US) 4/8 Respiratory protection not required in normal conditions Other information: Do not eat, drink or smoke during use. SECTION 9: Physical and chemical properties 9.1. Information on basic physical and chemical properties Physical state : Liquid Appearance : Clear, colorless liquid. Color : Colorless Odor : mild Pungent Odor threshold : No data available pH : No data available Melting point : No data available Freezing point : No data available Boiling point : No data available Flash point : No data available Relative evaporation rate (butyl acetate=1) : No data available Flammability (solid, gas) : Non flammable. Vapor pressure : No data available Relative vapor density at 20 °C : No data available Relative density : No data available Solubility : Soluble in water. Log Pow : No data available Auto-ignition temperature : No data available Decomposition temperature : No data available Viscosity, kinematic : No data available Viscosity, dynamic : No data available Explosion limits : No data available Explosive properties : No data available. Oxidizing properties : None. 9.2. Other information No additional information available SECTION 10: Stability and reactivity 10.1. Reactivity Thermal decomposition generates : Corrosive vapors. 10.2. Chemical stability Stable under normal conditions. 10.3. Possibility of hazardous reactions Reacts violently with (some) bases: release of heat. 10.4. Conditions to avoid Direct sunlight. Extremely high or low temperatures. 10.5. Incompatible materials Strong oxidizers. metals. Strong bases. 10.6. Hazardous decomposition products Chlorine. Carbon monoxide. Carbon dioxide. Thermal decomposition generates : Corrosive vapors. SECTION 11: Toxicological information 11.1. Information on toxicological effects Trichloroacetic Acid, 80% w/v Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/15/2018 EN (English US) 5/8 Likely routes of exposure : Inhalation; Skin and eye contact Acute toxicity : Not classified Trichloroacetic Acid (76-03-9) LD50 oral rat 3320 mg/kg ATE US (oral) 3320 mg/kg body weight Water (7732-18-5) LD50 oral rat ≥ 90000 mg/kg ATE US (oral) 90000 mg/kg body weight Skin corrosion/irritation : Causes severe skin burns and eye damage. Serious eye damage/irritation : Causes serious eye damage. Respiratory or skin sensitization : Not classified Germ cell mutagenicity : Not classified Carcinogenicity : Suspected of causing cancer (oral). Trichloroacetic Acid (76-03-9) IARC group 2B - Possibly carcinogenic to humans Reproductive toxicity : Not classified Specific target organ toxicity – single exposure : Not classified Specific target organ toxicity – repeated exposure : Not classified Aspiration hazard : Not classified Potential Adverse human health effects and symptoms : Based on available data, the classification criteria are not met. Symptoms/effects after eye contact : Causes serious eye damage. Chronic symptoms : Enlargement/affection of the liver. SECTION 12: Ecological information 12.1. Toxicity Trichloroacetic Acid (76-03-9) LC50 fish 1 2000 mg/l (Equivalent or similar to OECD 203, 96 h, Pimephales promelas, Static system, Fresh water, Weight of evidence) EC50 Daphnia 1 2000 mg/l (Equivalent or similar to OECD 202, 48 h, Daphnia magna, Static system, Fresh water, Experimental value) ErC50 (algae) 0.46 mg/l (Other, 14 day(s), Chlorella sp., Static system, Fresh water, Experimental value) 12.2. Persistence and degradability Trichloroacetic Acid, 80% w/v Persistence and degradability Not established. Trichloroacetic Acid (76-03-9) Persistence and degradability Not readily biodegradable in water. Water (7732-18-5) Persistence and degradability Not established. 12.3. Bioaccumulative potential Trichloroacetic Acid, 80% w/v Bioaccumulative potential Not established. Trichloroacetic Acid (76-03-9) BCF fish 1 0.4 - 1.7 mg/l (6 week(s), Cyprinus carpio, Fresh water, Experimental value) Log Pow 1.33 (Experimental value, 25 °C) Bioaccumulative potential Low potential for bioaccumulation (BCF < 500). Water (7732-18-5) Bioaccumulative potential Not established. Trichloroacetic Acid, 80% w/v Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/15/2018 EN (English US) 6/8 12.4. Mobility in soil Trichloroacetic Acid (76-03-9) Surface tension 0.278 N/m (80 °C) Log Koc 0 (log Koc, Other, Experimental value) Ecology - soil Highly mobile in soil. 12.5. Other adverse effects Other information : Avoid release to the environment. SECTION 13: Disposal considerations 13.1. Disposal methods Waste disposal recommendations : Dispose in a safe manner in accordance with local/national regulations. Dispose of contents/container to comply with local, state and federal regulations. Ecology - waste materials : Avoid release to the environment. SECTION 14: Transport information Department of Transportation (DOT) In accordance with DOT Transport document description : UN2564 Trichloroacetic acid, solution, 8, II UN-No.(DOT) : UN2564 Proper Shipping Name (DOT) : Trichloroacetic acid, solution Transport hazard class(es) (DOT) : 8 - Class 8 - Corrosive material 49 CFR 173.136 Packing group (DOT) : II - Medium Danger Hazard labels (DOT) : 8 - Corrosive DOT Packaging Non Bulk (49 CFR 173.xxx) : 202 DOT Packaging Bulk (49 CFR 173.xxx) : 242 DOT Special Provisions (49 CFR 172.102) : A3 - For combination packaging, if glass inner packaging (including ampoules) are used, they must be packed with absorbent material in tightly closed metal receptacles before packing in outer packaging. A6 - For combination packaging, if plastic inner packaging are used, they must be packed in tightly closed metal receptacles before packing in outer packaging. A7 - Steel packaging must be corrosion-resistant or have protection against corrosion. B2 - MC 300, MC 301, MC 302, MC 303, MC 305, and MC 306 and DOT 406 cargo tanks are not authorized. IB2 - Authorized IBCs: Metal (31A, 31B and 31N); Rigid plastics (31H1 and 31H2); Composite (31HZ1). Additional Requirement: Only liquids with a vapor pressure less than or equal to 110 kPa at 50 C (1.1 bar at 122 F), or 130 kPa at 55 C (1.3 bar at 131 F) are authorized. N34 - Aluminum construction materials are not authorized for any part of a packaging which is normally in contact with the hazardous material. T7 - 4 178.274(d)(2) Normal............. 178.275(d)(3) TP2 - a. The maximum degree of filling must not exceed the degree of filling determined by the following: (image) Where: tr is the maximum mean bulk temperature during transport, tf is the temperature in degrees celsius of the liquid during filling, and a is the mean coefficient of cubical expansion of the liquid between the mean temperature of the liquid during filling (tf) and the maximum mean bulk temperature during transportation (tr) both in degrees celsius. b. For liquids transported under ambient conditions may be calculated using the formula: (image) Where: d15 and d50 are the densities (in units of mass per unit volume) of the liquid at 15 C (59 F) and 50 C (122 F), respectively. DOT Packaging Exceptions (49 CFR 173.xxx) : 154 DOT Quantity Limitations Passenger aircraft/rail (49 CFR 173.27) : 1 L DOT Quantity Limitations Cargo aircraft only (49 CFR 175.75) : 30 L Trichloroacetic Acid, 80% w/v Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/15/2018 EN (English US) 7/8 DOT Vessel Stowage Location : B - (i) The material may be stowed ‘‘on deck’’ or ‘‘under deck’’ on a cargo vessel and on a passenger vessel carrying a number of passengers limited to not more than the larger of 25 passengers, or one passenger per each 3 m of overall vessel length; and (ii) ‘‘On deck only’’ on passenger vessels in which the number of passengers specified in paragraph (k)(2)(i) of this section is exceeded. Other information : No supplementary information available. SECTION 15: Regulatory information 15.1. US Federal regulations Trichloroacetic Acid, 80% w/v SARA Section 311/312 Hazard Classes Immediate (acute) health hazard All components of this product are listed, or excluded from listing, on the United States Environmental Protection Agency Toxic Substances Control Act (TSCA) inventory Trichloroacetic Acid (76-03-9) SARA Section 311/312 Hazard Classes Immediate (acute) health hazard 15.2. International regulations CANADA Trichloroacetic Acid (76-03-9) Listed on the Canadian DSL (Domestic Substances List) EU-Regulations No additional information available National regulations Trichloroacetic Acid (76-03-9) Listed on the Canadian IDL (Ingredient Disclosure List) 15.3. US State regulations This product can expose you to Trichloroacetic Acid, which is known to the State of California to cause cancer. For more information go to www.P65Warnings.ca.gov. Trichloroacetic Acid (76-03-9) U.S. - California - Proposition 65 - Carcinogens List U.S. - California - Proposition 65 - Developmental Toxicity U.S. - California - Proposition 65 - Reproductive Toxicity - Female U.S. - California - Proposition 65 - Reproductive Toxicity - Male No significant risk level (NSRL) Yes No No No SECTION 16: Other information Revision date : 05/15/2018 Other information : None. Full text of H-phrases: see section 16: --- --- H314 Causes severe skin burns and eye damage --- --- H318 Causes serious eye damage --- --- H351 Suspected of causing cancer Trichloroacetic Acid, 80% w/v Safety Data Sheet according to Federal Register / Vol. 77, No. 58 / Monday, March 26, 2012 / Rules and Regulations 05/15/2018 EN (English US) 8/8 NFPA health hazard : 3 - Materials that, under emergency conditions, can cause serious or permanent injury. NFPA fire hazard : 0 - Materials that will not burn under typical fire conditions, including intrinsically noncombustible materials such as concrete, stone, and sand. NFPA reactivity : 0 - Material that in themselves are normally stable, even under fire conditions. Hazard Rating Health : 3 Serious Hazard - Major injury likely unless prompt action is taken and medical treatment is given Flammability : 0 Minimal Hazard - Materials that will not burn Physical : 0 Minimal Hazard - Materials that are normally stable, even under fire conditions, and will NOT react with water, polymerize, decompose, condense, or self-react. Non-Explosives. Personal protection : J J - Splash goggles, Gloves, Synthetic apron, Dust & vapor respirator SDS US LabChem Information in this SDS is from available published sources and is believed to be accurate. No warranty, express or implied, is made and LabChem Inc assumes no liability resulting from the use of this SDS. The user must determine suitability of this information for his application. Page 1/10 Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03. Issue date 05/11/2015Reviewed on 05/11/2015 40.3.3 * 1 Identification · Product identifier · Trade name:Pharma-C-Wipe, 70% Isopropyl Alcohol Wipes · Relevant identified uses of the substance or mixture and uses advised against Cleansing Wipes · Product description Isopropyl Alcohol topical wipes. · Details of the supplier of the safety data sheet · Manufacturer/Supplier: Custom Manufactured Products, LLC P.O. Box 6646 Greenville, SC 29606 Phone: 864-527-9715 Fax: 864-655-0021 Toll Free: 1-888-696-7663 2 Hazard(s) identification · Classification of the substance or mixture GHS02 Flame Flam. Liq. 3H226Flammable liquid and vapor. GHS07 Eye Irrit. 2AH319Causes serious eye irritation. STOT SE 3H336May cause drowsiness or dizziness. · Label elements · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms GHS02 GHS07 · Signal word Warning · Hazard-determining components of labeling: Isopropyl alcohol · Hazard statements Flammable liquid and vapor. Causes serious eye irritation. May cause drowsiness or dizziness. · Precautionary statements Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use explosion-proof electrical/ventilating/lighting/equipment. Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. (Contd. on page 2) Page 2/10 Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03. Issue date 05/11/2015Reviewed on 05/11/2015 Trade name:Pharma-C-Wipe, 70% Isopropyl Alcohol Wipes 40.3.3 Wear protective gloves / eye protection / face protection. Wear eye protection / face protection. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wash thoroughly after handling. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison center/doctor if you feel unwell. If eye irritation persists: Get medical advice/attention. In case of fire: Use for extinction: CO2, powder or water spray. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations. · Unknown acute toxicity: 70 percent of the mixture consists of ingredient(s) of unknown toxicity. · Classification system: · NFPA ratings (scale 0 - 4) 2 3 1 Health = 2 Fire = 3 Reactivity = 1 · HMIS-ratings (scale 0 - 4) HEALTH FIRE REACTIVITY 2 3 1 Health = 2 Fire = 3 Reactivity = 1 · Hazard(s) not otherwise classified (HNOC):None known * 3 Composition/information on ingredients CAS: 7732-18-5 RTECS: ZC 0110000 water, distilled, conductivity or of similar purity30% · Chemical characterization: Mixtures · Description:Mixture of substances listed below with nonhazardous additions. · Dangerous Components: CAS: 67-63-0 RTECS: NT 8050000 Isopropyl alcohol Flam. Liq. 2, H225; Eye Irrit. 2, H319; STOT SE 3, H336 70% * 4 First-aid measures · Description of first aid measures · After inhalation: Supply fresh air. If required, provide artificial respiration. Consult doctor if symptoms persist. In case of unconsciousness, place patient securely on side position for transportation. · After skin contact: Generally the product does not irritate the skin. If skin irritation occurs, consult a doctor. (Contd. on page 3) Page 3/10 Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03. Issue date 05/11/2015Reviewed on 05/11/2015 Trade name:Pharma-C-Wipe, 70% Isopropyl Alcohol Wipes 40.3.3 · After eye contact: Rinse opened eye for at least 15 minutes under running water. If symptoms persist, consult a doctor. · After swallowing:If swallowed and symptoms occur, consult a doctor. · Information for doctor: · Most important symptoms and effects, both acute and delayed:No further relevant information available. · Indication of any immediate medical attention and special treatment needed No further relevant information available. * 5 Fire-fighting measures · Extinguishing media · Suitable extinguishing agents: CO₂, extinguishing powder or water spray. Fight larger fires with water spray or alcohol resistant foam. · Special hazards arising from the substance or mixture Carbon Oxides. · Advice for firefighters · Protective equipment: As in any fire, wear self-contained breathing apparatus pressure-demand (NIOSH approved or equivalent), and full protective gear to prevent contact with skin and eyes. * 6 Accidental release measures · Personal precautions, protective equipment and emergency procedures Wear protective equipment. Keep unprotected persons away. · Environmental precautions: Dilute with plenty of water. Do not allow to enter sewers/ surface or ground water. · Methods and material for containment and cleaning up: Pick up mechanically. Dispose contaminated material as waste according to section 13. Ensure adequate ventilation. Dispose of the collected material according to regulations. · Reference to other sections See Section 7 for information on safe handling. See Section 8 for information on personal protection equipment. See Section 13 for disposal information. * 7 Handling and storage · Handling: · Precautions for safe handling Ensure good ventilation/exhaustion at the workplace. · Information about protection against explosions and fires: Keep ignition sources away - Do not smoke. Protect from heat. Protect against electrostatic charges. · Conditions for safe storage, including any incompatibilities Store away from strong acids, strong bases, strong oxidizing agents and strong reducing agents. · Storage: · Requirements to be met by storerooms and receptacles: Store in a well ventilated place. Store only in the original receptacle. Store away from direct sunlight. · Information about storage in one common storage facility:Not required. · Further information about storage conditions: Keep receptacle tightly sealed. (Contd. on page 4) Page 4/10 Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03. Issue date 05/11/2015Reviewed on 05/11/2015 Trade name:Pharma-C-Wipe, 70% Isopropyl Alcohol Wipes 40.3.3 Protect from heat and direct sunlight. · Specific end use(s)No further relevant information available. * 8 Exposure controls/personal protection · Additional information about design of technical systems:No further data; see section 7. · Control parameters All ventilation should be designed in accordance with OSHA standard (29 CFR 1910.94). Use mechanical (general) ventilation for storage areas. Use appropriate ventilation as required to keep Exposure Limits in Air below TLV & PEL limits. · Components with occupational exposure limits: 67-63-0Isopropyl alcohol PELLong-term value: 980 mg/m³, 400 ppm RELShort-term value: 1225 mg/m³, 500 ppm Long-term value: 980 mg/m³, 400 ppm TLVShort-term value: 984 mg/m³, 400 ppm Long-term value: 492 mg/m³, 200 ppm BEI · Ingredients with biological limit values: 67-63-0Isopropyl alcohol BEI40 mg/L urine end of shift at end of workweek Acetone (background, nonspecific) · Additional information:The lists that were valid during the creation of this SDS were used as basis. · Exposure controls · Personal protective equipment: · General protective and hygienic measures: The usual precautionary measures for handling chemicals should be followed. Keep away from foodstuffs, beverages and feed. Immediately remove all soiled and contaminated clothing and wash before reuse. Wash hands before breaks and at the end of work. Avoid contact with the eyes. · Breathing equipment:Not required. · Protection of hands:Not required. · Eye protection:Not required. · Body protection:Not required. * 9 Physical and chemical properties · Information on basic physical and chemical properties · General Information · Appearance: Form:Disposable wipe Color:White · Odor:Alcohol-like · Odor threshold:Not determined. · pH-value:Not determined. (Contd. on page 5) Page 5/10 Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03. Issue date 05/11/2015Reviewed on 05/11/2015 Trade name:Pharma-C-Wipe, 70% Isopropyl Alcohol Wipes 40.3.3 · Change in condition Melting point/Melting range:Not determined. Boiling point/Boiling range:82 °C (180 °F) · Flash point:24 °C (75 °F) · Flammability (solid, gaseous):Not applicable. · Ignition temperature:399 °C (750 °F) · Decomposition temperature:Not determined. · Auto igniting:Product is not self-igniting. · Danger of explosion:Product is not explosive. However, formation of explosive air/vapor mixtures are possible. · Explosion limits: Lower:2.0 Vol % Upper:12.7 Vol % · Vapor pressure @ 20 °C (68 °F):33 mm Hg · Density @ 20 °C (68 °F):> 1.00 g/cm³ (> 8.345 lbs/gal) · Relative density Not determined. · Vapor density @ 20 °C (68 °F)2.1 g/cm³ (17.525 lbs/gal) (air=1) · Evaporation rate @ 20 °C (68 °F)1.7 (Buryl Acetate=1) · Solubility in / Miscibility with Water:Fully miscible. · Partition coefficient (n-octanol/water):Not determined. · Viscosity: Dynamic:Not determined. Kinematic:Not determined. · Solvent content: Organic solvents:70.0 % Water:30.0 % VOC content:70.0 % · Other information No further relevant information available. * 10Stability and reactivity · Reactivity No further relevant information available. · Chemical stability Stable under normal conditions. · Thermal decomposition / conditions to be avoided:No decomposition if used according to specifications. · Possibility of hazardous reactions No dangerous reactions known. · Conditions to avoid Heat, flame and ignition sources. · Incompatible materials:Strong acids, strong bases, strong oxidizing agents and strong reducing agents. · Hazardous decomposition products:Carbon Oxides. (Contd. on page 6) Page 6/10 Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03. Issue date 05/11/2015Reviewed on 05/11/2015 Trade name:Pharma-C-Wipe, 70% Isopropyl Alcohol Wipes 40.3.3 * 11Toxicological information · Information on toxicological effects · Acute toxicity: · LD/LC50 values that are relevant for classification: 67-63-0Isopropyl alcohol OralLD505045 mg/kg (rat) DermalLD5012800 mg/kg (rabbit) InhalativeLC50/4 h30 mg/l (rat) LC50/96 hours9640 mg/l (Pimephales) · Primary irritant effect: · on the skin:No irritating effect. · on the eye: Irritating effect. Causes serious eye irritation. · Additional toxicological information: The product shows the following dangers according to internally approved calculation methods for preparations: Irritant · Carcinogenic categories · IARC (International Agency for Research on Cancer) Group 1 - Carcinogenic to humans Group 2A - Probably carcinogenic to humans Group 2B - Possibly carcinogenic to humans Group 3 - Not classifiable as to its carcinogenicity to humans Group 4 - Probably not carcinogenic to humans 67-63-0Isopropyl alcohol 3 · NTP (National Toxicology Program) None of the ingredients are listed. · OSHA-Ca (Occupational Safety & Health Administration) None of the ingredients are listed. * 12Ecological information · Toxicity · Aquatic toxicity: 67-63-0Isopropyl alcohol EC506851 mg/l (Green algae) 5102 mg/l (Water flea) · Persistence and degradability No further relevant information available. · Behavior in environmental systems: · Bioaccumulative potential No further relevant information available. · Mobility in soil No further relevant information available. · Additional ecological information: · General notes:Not known to be hazardous to water. · Results of PBT and vPvB assessment · PBT:Not applicable. · vPvB:Not applicable. (Contd. on page 7) Page 7/10 Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03. Issue date 05/11/2015Reviewed on 05/11/2015 Trade name:Pharma-C-Wipe, 70% Isopropyl Alcohol Wipes 40.3.3 · Other adverse effects No further relevant information available. * 13Disposal considerations · Waste treatment methods · Recommendation:Recycle or dispose with household trash. · Uncleaned packagings: · Recommendation: Disposal must be made according to official regulations. Dispose of as unused product. · Recommended cleansing agent:Water, if necessary with cleansing agents. * 14Transport information · UN-Number · DOT, ADR, IMDG, IATA UN1987 · UN proper shipping name · DOT Alcohols, n.o.s. (Isopropanol) · ADR UN1987 Alcohols, n.o.s. (Isopropanol) · IMDG, IATA ALCOHOLS, N.O.S. (ISOPROPANOL (ISOPROPYL ALCOHOL)) · Transport hazard class(es) · DOT · Class 3 Flammable liquids · Label 3 · ADR · Class 3 (F1) Flammable liquids · Label 3 · IMDG, IATA · Class 3 Flammable liquids · Label 3 · Packing group · DOT, ADR, IMDG, IATA III · Environmental hazards:Not applicable. · Special precautions for user Warning: Flammable liquids · Danger code (Kemler):30 · EMS Number:F-E,S-D (Contd. on page 8) Page 8/10 Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03. Issue date 05/11/2015Reviewed on 05/11/2015 Trade name:Pharma-C-Wipe, 70% Isopropyl Alcohol Wipes 40.3.3 · Transport in bulk according to Annex II of MARPOL73/78 and the IBC Code Not applicable. · Transport/Additional information: · DOT · Quantity limitations On passenger aircraft/rail: 60 L On cargo aircraft only: 220 L · Remarks:Limited Quantities - Ground, Consumer Commodity · ADR · Excepted quantities (EQ)Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml · IMDG · Limited quantities (LQ)5L · Excepted quantities (EQ)Code: E1 Maximum net quantity per inner packaging: 30 ml Maximum net quantity per outer packaging: 1000 ml · UN "Model Regulation":UN1987, Alcohols, n.o.s. (Isopropanol), 3, III 15Regulatory information · Safety, health and environmental regulations/legislation specific for the substance or mixture · Sara · Section 355 (extremely hazardous substances): None of the ingredients are listed. · Section 313 (Specific toxic chemical listings): 67-63-0Isopropyl alcohol · TSCA (Toxic Substances Control Act): All ingredients are listed. · California Proposition 65 · Chemicals known to cause cancer: None of the ingredients are listed. · Chemicals known to cause reproductive toxicity for females: None of the ingredients are listed. · Chemicals known to cause reproductive toxicity for males: None of the ingredients are listed. · Chemicals known to cause developmental toxicity: None of the ingredients are listed. · Carcinogenic categories · EPA (Environmental Protection Agency) None of the ingredients are listed. · TLV (Threshold Limit Value established by ACGIH) 67-63-0Isopropyl alcohol A4 · NIOSH-Ca (National Institute for Occupational Safety and Health) None of the ingredients are listed. (Contd. on page 9) Page 9/10 Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03. Issue date 05/11/2015Reviewed on 05/11/2015 Trade name:Pharma-C-Wipe, 70% Isopropyl Alcohol Wipes 40.3.3 · GHS label elements The product is classified and labeled according to the Globally Harmonized System (GHS). · Hazard pictograms GHS02 GHS07 · Signal word Warning · Hazard-determining components of labeling: Isopropyl alcohol · Hazard statements Flammable liquid and vapor. Causes serious eye irritation. May cause drowsiness or dizziness. · Precautionary statements Keep away from heat/sparks/open flames/hot surfaces. - No smoking. Use explosion-proof electrical/ventilating/lighting/equipment. Avoid breathing dust/fume/gas/mist/vapors/spray. Use only outdoors or in a well-ventilated area. Wear protective gloves / eye protection / face protection. Wear eye protection / face protection. Ground/bond container and receiving equipment. Use only non-sparking tools. Take precautionary measures against static discharge. Wash thoroughly after handling. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. If in eyes: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a poison center/doctor if you feel unwell. If eye irritation persists: Get medical advice/attention. In case of fire: Use for extinction: CO2, powder or water spray. Store locked up. Store in a well-ventilated place. Keep container tightly closed. Store in a well-ventilated place. Keep cool. Dispose of contents/container in accordance with local/regional/national/international regulations. · National regulations: The product is subject to be classified according with the latest version of the regulations on hazardous substances. · State Right to Know CAS: 67-63-0 RTECS: NT 8050000 Isopropyl alcohol Flam. Liq. 2, H225; Eye Irrit. 2, H319; STOT SE 3, H336 70% CAS: 7732-18-5 RTECS: ZC 0110000 water, distilled, conductivity or of similar purity30% All ingredients are listed. · Chemical safety assessment:A Chemical Safety Assessment has not been carried out. (Contd. on page 10) Page 10/10 Safety Data Sheet (SDS) OSHA HazCom Standard 29 CFR 1910.1200(g) and GHS Rev 03. Issue date 05/11/2015Reviewed on 05/11/2015 Trade name:Pharma-C-Wipe, 70% Isopropyl Alcohol Wipes 40.3.3 16Other information The information and recommendations in this safety data sheet are, to the best of our knowledge, accurate as of the date of issue. Nothing herein shall be deemed to create warranty, expressed or implied and shall not establish a legally valid contractual relationship. It is the responsibility of the user to determine applicability of this information and the suitability of the material or product for any particular purpose. · Date of preparation / last revision 05/11/2015 / - · Abbreviations and acronyms: ADR: The European Agreement concerning the International Carriage of Dangerous Goods by Road ADN: The European Agreement concerning the International Carriage of Dangerous Goods by Inland Waterways IMDG: International Maritime Code for Dangerous Goods DOT: US Department of Transportation IATA: International Air Transport Association ACGIH: American Conference of Governmental Industrial Hygienists EINECS: European Inventory of Existing Commercial Chemical Substances ELINCS: European List of Notified Chemical Substances CAS: Chemical Abstracts Service (division of the American Chemical Society) NFPA: National Fire Protection Association (USA) HMIS: Hazardous Materials Identification System (USA) VOC: Volatile Organic Compounds (USA, EU) LC50: Lethal concentration, 50 percent LD50: Lethal dose, 50 percent Flam. Liq. 2: Flammable liquids, Hazard Category 2 Flam. Liq. 3: Flammable liquids, Hazard Category 3 Eye Irrit. 2: Serious eye damage/eye irritation, Hazard Category 2 Eye Irrit. 2A: Serious eye damage/eye irritation, Hazard Category 2A STOT SE 3: Specific target organ toxicity - Single exposure, Hazard Category 3 · * Data compared to the previous version altered. SDS created by MSDS Authoring Services www.msdsauthoring.com (877) 204-9106